Carbon compounds in Apollo 12 lunar samples
Carbon compounds in Apollo 12 lunar fines and core samples, using pyrolysis, mass spectrometry, ion exchange chromatography and optical and electron microscopy
Drew, C. M.↗
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Probabilistic Round Trip Contamination Analysis of a Mars Sample Acquisition and Handling Process Using Markovian Decompositions
A method for evaluating the probability of a Viable Earth Microorganism (VEM) contaminating a sample during the sample acquisition and handling (SAH) process of a potential future Mars Sample Return mission is developed. A scenario where multiple core samples would be acquired using a rotary percussive coring tool, deployed from an arm on a MER class rover is analyzed. The analysis is conducted in a structured way by decomposing sample acquisition and handling process into a series of discrete time steps, and breaking the physical system into a set of relevant components. At each discrete time step, two key functions are defined: The probability of a VEM being released from each component, and the transport matrix, which represents the probability of VEM transport from one component to another. By defining the expected the number of VEMs on each component at the start of the sampling process, these decompositions allow the expected number of VEMs on each component at each sampling step to be represented as a Markov chain. This formalism provides a rigorous mathematical framework in which to analyze the probability of a VEM entering the sample chain, as well as making the analysis tractable by breaking the process down into small analyzable steps.
Hudson, Nicolas↗
Mineralogical and Lithological Data from Great Basin Geothermal Systems
Mineralogical and lithological data from core samples taken at various geothermal wells in the Great Basin: Dixie Valley, Beowawe, Roosevelt, Mammoth, Steamboat Springs, Coso
15 GEOTHERMAL ENERGY↗
Experimental Results of Rover-Based Coring and Caching
Experimental results are presented for experiments performed using a prototype rover-based sample coring and caching system. The system consists of a rotary percussive coring tool on a five degree-of-freedom manipulator arm mounted on a FIDO-class rover and a sample caching subsystem mounted on the rover. Coring and caching experiments were performed in a laboratory setting and in a field test at Mono Lake, California. Rock abrasion experiments using an abrading bit on the coring tool were also performed. The experiments indicate that the sample acquisition and caching architecture is viable for use in a 2018 timeframe Mars caching mission and that rock abrasion using an abrading bit may be feasible in place of a dedicated rock abrasion tool.
coring↗
DOE Award No.: DE-FE0023919 Phase 3 Scientific/Technical Report
This is the Phase 3 Report for the ‘Deepwater Methane Hydrate Characterization and Scientific Assessment or Genesis of Methane Hydrates in the Gulf of Mexico (GOM2)’ research project (DOE Award No. DE-FE0023919). The report summarizes activities from January 16, 2018 to September 30, 2019. The project is led by the University of Texas at Austin (UT). The objective is to gain insight into the nature, formation, occurrence and physical properties of methane hydrate-bearing sediments for the purpose of methane hydrate resource appraisal through the planning and execution of drilling, coring, logging, testing and analytical activities that assess the geologic occurrence, regional context, and characteristics of marine methane hydrate deposits in the Gulf of Mexico outer continental shelf (OCS). We determined that it would not be possible to pursue the project with the International Ocean Discovery Program (IODP) and then developed a revised science and operations plan to maximize the science using a commercial vessel within the budget that is available. We improved the scientific capability of the UT pressure core center by adding the ability to X-ray pressure cores, and the ability to cut and store multiple core samples for experimental analysis. We transferred pressure cores to peer institutions, including the National Energy Technology Lab (NETL) the United States Geological Survey (USGS Woods Hole). We made advances in understanding the composition and source of gasses locked in the methane hydrate from Green Canyon 955 (GC-955). We developed approaches to determine the in-situ salinity of hydrate-bearing samples, revealing that the in situ salinity of the GC 955 reservoir is just above that of seawater. We determined that the GC-955 hydrate reservoir is composed of sandy silt with a high concentration of hydrate interbedded with clayey silt with no hydrate present. We determined that some or all of the intervals bounding the hydrate reservoir are composed of material similar to the reservoir (sandy silt with hydrate and clayey silt with no hydrate), but with a lower net to gross. We determined that the reservoir effective permeability at a hydrate saturation of ~80-90 % is ~0.1 mD (or 1.0×10-16 m2) to ~0.5 mD (or 5.0×10-16 m2) and the intrinsic permeability is ~12 mD (or 1.2×10-14 m2). The GC-955 reservoir in-situ porosity of sandy silt is 0.38 to 0.40 and is largely independent of effective stress, and that the porosity of clayey silt is 0.33 at an in situ effective stress of 3.8 MPa to ~0.37 at zero effective stress. We developed a systematic, repeatable approach to studying hydrate reservoir properties by reconstituting individual lithofacies from dissociated pressure cores. We determined index properties of GC-955 reservoir, including liquid limit and plasticity, porosity, capillary behavior, and particle size distribution. We developed a more robust pressure coring technology. We finalized and published the UT-GOM2-1 Expedition Volume and we finalized a dedicated volume on the UT-GOM2-1 expedition that will be published in the American Association of Petroleum Geologists Bulletin (AAPG) in spring 2020.
03 NATURAL GAS↗
CO 2 Mineral Sequestration in Naturally Porous Basalt
Continental flood basalts are extensive geologic features currently being evaluated as reservoirs that are suitable for long-term storage of carbon emissions. Favorable attributes of these formations for containment of injected carbon dioxide (CO2) include high mineral trapping capacity, unique structural features, and enormous volumes. We experimentally investigated mineral carbonation in whole core samples retrieved from the Grand Ronde basalt, the same formation into which ~1000 t of CO2 was recently injected in an eastern Washington pilot-scale demonstration. The rate and extent of carbonate mineral formation at 100 °C and 100 bar were tracked via time-resolved sampling of bench-scale experiments. Basalt cores were recovered from the reactor after 6, 20, and 40 weeks, and three-dimensional X-ray tomographic imaging of these cores detected carbonate mineral formation in the fracture network within 20 weeks. Under these conditions, a carbon mineral trapping rate of 1.24 ± 0.52 kg of CO2/m3 of basalt per year was estimated, which is orders of magnitude faster than rates for deep sandstone reservoirs. On the basis of these calculations and under certain assumptions, available pore space within the Grand Ronde basalt formation would completely carbonate in ~40 years, resulting in solid mineral trapping of ~47 kg of CO2/m3 of basalt.
Xiong, Wei↗
A lunar differentiation model in light of new chemical data on Luna 20 and Apollo 16 soils.
Fines from a Luna 20 soil sample and from three Apollo 16 deep drill core samples have been analyzed for major-minor element abundances by a combined, semi-micro atomic absorption spectrophotometric and colorimetric method. Both the major element and large ion lithophile trace element abundances in these soils, the first from interior highland sites, are greatly influenced by the very high normative plagioclase content, being distinctly richer in Al and Ca, and poorer in K, P, Cr, Mn, Fe, and Ti, than most bulk soil samples from previous lunar missions. The relatively large compositional variations in the Apollo 16 core can be ascribed almost entirely to decreasing plagioclase with increasing depth. The chemical composition of the Luna 20 soil indicates less plagioclase and less KREEP than in the Apollo 16 soils. A lunar differentiation model is presented in which is made the suggestion that KREEP is the result of a second fusion event in a lunar crust consisting of early feldspathic cumulates and primary aluminous 'liquid.'
Nava, D. F.↗
Analytical study of comet nucleus samples
Analytical procedures for studying and handling frozen (130 K) core samples of comet nuclei are discussed. These methods include neutron activation analysis, x ray fluorescent analysis and high resolution mass spectroscopy.
Albee, A. L.↗
Preliminary Surface Thermal Design of the Mars 2020 Rover
The Mars 2020 rover, scheduled for launch in July 2020, is currently being designed at NASA's Jet Propulsion Laboratory. The Mars 2020 rover design is derived from the Mars Science Laboratory (MSL) rover, Curiosity, which has been exploring the surface of Mars in Gale Crater for over 2.5 years. The Mars 2020 rover will carry a new science payload made up of 7 instruments. In addition, the Mars 2020 rover is responsible for collecting a sample cache of Mars regolith and rock core samples that could be returned to Earth in a future mission. Accommodation of the new payload and the Sampling Caching System (SCS) has driven significant thermal design changes from the original MSL rover design. This paper describes the similarities and differences between the heritage MSL rover thermal design and the new Mars 2020 thermal design. Modifications to the MSL rover thermal design that were made to accommodate the new payload and SCS are discussed. Conclusions about thermal design flexibility are derived from the Mars 2020 preliminary thermal design experience.
Novak, Keith S.↗
Applying the core-satellite species concept: Characteristics of rare and common riverine dissolved organic matter
Introduction: Dissolved organic matter (DOM) composition varies over space and time, with a multitude of factors driving the presence or absence of each compound found in the complex DOM mixture. Compounds ubiquitously present across a wide range of river systems (hereafter termed core compounds) may differ in chemical composition and reactivity from compounds present in only a few settings (hereafter termed satellite compounds). Here, we investigated the spatial patterns in DOM molecular formulae presence (occupancy) in surface water and sediments across 97 river corridors at a continental scale using the “Worldwide Hydrobiogeochemical Observation Network for Dynamic River Systems—WHONDRS” research consortium. Methods: We used a novel data-driven approach to identify core and satellite compounds and compared their molecular properties identified with Fourier-transform ion cyclotron resonance mass spectrometry (FT-ICR MS). Results: In this work, we found that core compounds clustered around intermediate hydrogen/carbon and oxygen/carbon ratios across both sediment and surface water samples, whereas the satellite compounds varied widely in their elemental composition. Within surface water samples, core compounds were dominated by lignin-like formulae, whereas protein-like formulae dominated the core pool in sediment samples. In contrast, satellite molecular formulae were more evenly distributed between compound classes in both sediment and water molecules. Core compounds found in both sediment and water exhibited lower molecular mass, lower oxidation state, and a higher degree of aromaticity, and were inferred to be more persistent than global satellite compounds. Higher putative biochemical transformations were found in core than satellite compounds, suggesting that the core pool was more processed. Discussion: The observed differences in chemical properties of core and satellite compounds point to potential differences in their sources and contribution to DOM processing in river corridors. Overall, our work points to the potential of data-driven approaches separating rare and common compounds to reduce some of the complexity inherent in studying riverine DOM.
54 ENVIRONMENTAL SCIENCES↗
Fracture Shearing in the Eau Claire Formation
This data set consists of Computed Tomographic (CT) data for five sheared Eau Claire Formation core samples with complex and heterogeneous lithology. Each sample was prefractured, housed in a specially adapted core holder, and sheared in incremental fashion. CT scans were taken before and after each shearing event.
Computed Tomography↗
A Non-Invasive Approach for Elucidating the Spatial Distribution of in-situ Stress in Deep Subsurface Geologic Formations Considered for CO 2 Storage (Task 4 (Field Testing) Report)
"This document presents a summary of TASK 4 (Field Testing) of the project entitled “A Non-Invasive Approach for Elucidating the Spatial Distribution of in-situ Stress in Deep Subsurface Geologic Formations Considered for CO 2 Storage (FE0031686)”. This three-year project is part of the U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) Carbon Storage program to research and address gaps that affect the economics of commercial CCS projects. One of these key gaps is the lack of certainty in predicting the geomechanical impacts of pressure migration due to CO 2 injection into a storage complex. This report documents field testing that was conducted under TASK 4 to obtain input data needed to develop the site-specific geomechanical model in TASK 5 and to verify the model results (i.e. calculated stresses) for this site. The field work entailed collecting geophysical logs and core samples and conducting geomechanical stress tests in the Core Energy LLC State Otsego Lake (SOL 8-15A) well, located in Otsego County, Michigan."
58 GEOSCIENCES↗
Rays for Roots - Integrating Backscatter X-Ray Phenotyping, Modeling and Genetics to Increase Carbon Sequestration and Switchgrass Resource Use (Final Report)
To increase carbon (C) deposition in the soil and enhance crop resource use efficiency, characterizing root form and function is essential. Several root and soil traits have been linked to increased root-to-soil C transfer. Technology that could provide high-resolution characterization of many of these traits in field conditions would revolutionize our ability to study and understand how to increase C sequestration. In this effort, we developed an initial early prototype backscatter X-ray system for non-destructive imaging of root traits. We collected initial backscatter X-ray data in field and lab settings and carried out early analysis of these data. Along with this prototype, we also developed a suite of root phenotyping approaches including advanced minirhizotron image analysis, soil core imaging, and mesocosm imaging. Minirhizotron (MR) tubes are clear tubes inserted into the soil in the field and used to image roots and the surrounding soil. Our team has developed deep learning-based methods that can segment roots from soil that can learn from imprecise image-level labels. The ability to learn or fine-tune our deep learning algorithms from image-level labels allows easier and faster application of these approaches to new locations and new plant species. We have successfully implemented and applied our MR analysis approaches to thousands of switchgrass MR images collected across geographical regions. An advantage of MR imaging is the ability to collect root and soil images over time. Our soil core analysis included collecting hundreds of soil core samples from harvested switchgrass fields and imaging these cores with both X-ray CT and backscatter X-ray imaging. Initial segmentation approaches for the X-ray CT images of these cores have been developed and applied. An advantage of soil core analysis is that it preserves the three-dimensional structures of the roots and soil in the core collected. Our group also developed photogrammetry-based mesocosm root imaging and phenotyping approaches. In this approach, a plant was grown in a large mesocosm with a three-dimensional grid of thin supporting lines inserted throughout the mesocosm. After the plant (and, correspondingly, the root architecture is grown and established) the soil media was removed and the supporting lines approximately preserved the three-dimensional root architecture. Then, we applied photogrammetry techniques to create a three-dimensional digital representation of the root architecture for which we developed analysis algorithms including skeletonization. We carried out our phenotyping development with powerful switchgrass resources and physiological and agroecosystem modeling to deliver novel technology. This project contributes to multiple ARPA-E missions including reduction of foreign imports of energy, reduction of energy-related emissions including greenhouse gases, and ensuring that the United States maintains a technological lead in developing and deploying advanced energy technology. Furthermore, the developed tools could transform public and private plant breeding and could be broadly applicable to other crops and, potentially, other application areas. Our team of engineers, plant and soil scientists, and modelers i) developed an early prototype backscatter X-ray platform that can operate in field conditions; ii) developed a suite of root phenotyping and characterization approaches as described above; iii) developed and carried out plant biology and physiology roots studies and; iv) developed and implemented mechanistic physiological modeling.
42 ENGINEERING↗
Apollo 14: Some geochemical aspects
Chemical analyses were obtained for five samples of Apollo 14 regolith fines, three 14230 core samples, soil clod 14049, breccias 14305 and 14319, 14310 basalt, and some separated phases. The chemical uniformity of these Apollo 14 samples indicates thorough mixing and/or uniform source rocks. Basalt 14310 can be matched well in composition by a four to one mixture of soil and plagioclase. The Eu(2+)/Eu(3+) ratios calculated for 14310 pigeonite and plagioclase are similar to those for Apollo 12 and 15 mare-type basalt phases; this indicates similar redox conditions. Apollo 14 samples are chemically similar to Apollo 12 and 15 KREEP as distinct from Apollo 11, 12, and 15 and Luna 16 mare-type basalts.
Philpotts, J. A.↗
Apollo 16 special samples, part B
Information is presented concerning special samples which were collected for specific investigations. The methods of sample collection are described along with fillet and core samples.
Hoerz, F.↗
Apollo 14 - Some geochemical aspects.
Chemical analyses have been obtained for five samples of Apollo 14 regolith fines, three 14230 core samples, 14049 soil clod, 14305 and 14319 breccias, 14310 basalt, and some separated phases. The chemical uniformity of these Apollo 14 samples indicates thorough mixing and/or uniform source rocks. Basalt 14310 can be matched well in composition by a four-to-one mixture of soil and plagioclase. Eu(2+)/Eu(3+) ratios calculated for 14310 pigeonite and plagioclase are similar to those for Apollo 12 and 15 mare-type basalt phases; this indicates similar redox conditions. The investigated Apollo 14 samples are chemically similar to Apollo 12 and 15 KREEP as distinct from Apollo 11, 12, and 15, and Luna 16 mare-type basalts. A relationship between the two types of basalt, in which mare-basalts would represent fused cumulates, is suggested.
Philpotts, J. A.↗
Geophysical, geochemical, and geological investigations of the Dunes geothermal system, Imperial Valley, California
The Dunes anomaly is a water-dominated geothermal system in the alluvium of the Salton Trough, lacking any surface expression. It was discovered by shallow-temperature gradient measurements. A 612-meter-deep test well encountered several temperature-gradient reversals, with a maximum of 105 C at 114 meters. The program involves surface geophysics, including electrical, gravity, and seismic methods, down-hole geophysics and petrophysics of core samples, isotopic and chemical studies of water samples, and petrological and geochemical studies of the cores and cuttings. The aim is (1) to determine the source and temperature history of the brines, (2) to understand the interaction between the brines and rocks, and (3) to determine the areal extent, nature, origin, and history of the geothermal system. These studies are designed to provide better definition of exploration targets for hidden geothermal anomalies and to contribute to improved techniques of exploration and resource assessment.
Elders, W. A.↗
Apollo drill core depth relationships
Preliminary depth relationships are presented for the Apollo 15, 16, and 17 drill core samples. For a given depth in any of these drill stems, the in situ lunar surface depth can be estimated. Ranges of uncertainty are also established, based on percent core recovery and degree of sample disturbance. The most likely explanation for the sample disturbance observed in the top three sections of the Apollo 16 drill stem is sample migration after the stem was capped on the lunar surface; essentially no sample was lost. Similar disturbance occurred in the Apollo 17 drill core, although to a lesser degree. The average original bulk densities (i.e., before any disturbance occurred) of the Apollo 15, 16, and 17 drill cores are 1.76, 1.59, and 1.87 g/cu cm, respectively. The Apollo 15 and 17 values are probably close to the in situ values; but the Apollo 16 average in situ density could be as much as 13% less than the already low density in the drill core.
Carrier, W. D., III↗