Kinetic theory of dense fluid mixtures. III.
Doublet distribution functions for binary dense fluid mixtures by solving Rice-Allnatt equations, deriving expressions for transport coefficients of mixtures
Davis, H. T.↗
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Angular size of OH emission regions.
Angular diameters of OH lambda-doublet frequencies emitting regions using interferometry
Ball, J. A.↗
Detection of the super 2 pi 3/2, J equals 5/2 state of OH at 5-centimeter wavelength.
Lambda-doublet radiation from excited state of interstellar OH detected at 5 cm wavelength
Palmer, P.↗
Absorption coefficients of O2 at the Lyman- alpha line and of other O2 transmission windows
Oxygen absorption coefficients at Lyman alpha line and other transmission windows, verifying dependence on pressure source line width and doublet separation
Ogawa, M.↗
The effect of rocket plume contamination on the optical properties of transmitting and reflecting materials
The preliminary results of plume contamination from a 5-pound thrust single-doublet, bipropellant rocket engine on the transmittance of quartz and the reflectance of a silicon monoxide overcoated aluminum mirror are presented. Changes in quartz transmittance were found to be significant and were due to both absorption and scattering effects. Contaminant absorption effects were predominant at the short wavelengths and scattering effects were greatest in the visible wavelengths. Measured changes in mirror reflectance were due primarily to contaminant absorption. Scattering effects were found to be as much as 9 percent of the total reflected energy from the mirror. There were no noticeable chemical or erosion effects on either the quartz or the front surface mirror.
Jack, J. R.↗
Oxidation state of iron in plagioclase from lunar basalts.
Determination of the oxidation state of iron in the plagioclase from the coarse-grained basalts 10044 and 12021, using Mossbauer spectroscopy. The location of iron in the crystal structure was also investigated. The spectra show that iron is in the high-spin ferrous state, and they located at least two distinct positions with different coordination numbers. Some excess resonant absorption is probably due to Fe(3+), although the Fe(3+) doublet could not be positively resolved.
Hafner, S. S.↗
The effect of rocket plume contamination on the optical properties of transmitting and reflecting materials.
The preliminary results of plume contamination from a 5-pound thrust single-doublet, bipropellant rocket engine on the transmittance of quartz and the reflectance of a silicon monoxide overcoated aluminum mirror have been presented. Changes in quartz transmittance were found to be significant and were due to both absorption and scattering effects. Contaminant absorption effects were predominant at the short wavelengths and scattering effects were greatest in the visible wavelengths. Measured changes in mirror reflectance were due primarily to contaminant absorption. Scattering effects were found to be as much as 9% of the total reflected energy from the mirror. There were no noticeable chemical or erosion effects on either the quartz or the front surface mirror.
Jack, J. R.↗
Ultraviolet spectrophotometry of Arcturus from a rocket.
Results of spectrophotometric observations of Arcturus were obtained at the resolution of about 7 A in the wavelength region from 2700 to 4000 A from an Aerobee rocket. Although the payload was capable of obtaining observations shortward of 2700 A, the stellar flux was too weak for meaningful measurements below that wavelength. The most significant feature in the ultraviolet shortward of the atmospheric cutoff is an emission feature at 2800 A identified as the resonance line of the Mg II doublet.
Kondo, Y.↗
Temperature-dependent Mg, Fe distribution in a lunar olivine.
The nuclear hyperfine doublets of Fe-57 at the two nonequivalent octahedrally coordinated positions M1 and M2 in an olivine from lunar basalt 12018 have been analyzed in the temperature range between 250 and 450 C. The Mg(2+), Fe(2+) is somewhat ordered, the Fe(2+) occupancy being greater at one of the two M positions by approximately 20%. After heating at 1155 C for seven days, the distribution was almost completely disordered. Studies of natural and heated olivines from terrestrial rocks show that the Mg(2+), Fe(2+) exchange reaction in olivines is considerably more sluggish than in chain silicates. Generally no change in site occupancy can be observed after heating at temperatures of approximately 900 C over several days. The observed degree of ordering in the lunar olivine is indicative of slow cooling during crystallization.
Virgo, D.↗
Vibrational spectra and structure of azomethane and azomethane-d6.
The infrared and Raman spectra of azomethane and azomethane-d(6) were examined in detail. Vibrational data provided definitive verification of a trans-structure with C(2h) symmetry. A vibrational assignment is proposed for the 24 fundamental modes based upon the observed contours, isotopic shift ratios, and group frequency correlations. Spectra of the polycrystalline samples indicate that there are at least four molecules per unit cell, since a number of the bands were observed to be split into doublets. The crystal also appeared to have a center of symmetry, since mutual exclusion was clearly operative.
Durig, J. R.↗
Boundary cooled rocket engines for space storable propellants
An evaluation of an existing analytical heat transfer model was made to develop the technology of boundary film/conduction cooled rocket thrust chambers to the space storable propellant combination oxygen difluoride/diborane. Critical design parameters were identified and their importance determined. Test reduction methods were developed to enable data obtained from short duration hot firings with a thin walled (calorimeter) chamber to be used quantitatively evaluate the heat absorbing capability of the vapor film. The modification of the existing like-doublet injector was based on the results obtained from the calorimeter firings.
Kesselring, R. C.↗
Extraction of longitudinal aerodynamic coefficients from forward-flight conditions of a tilt-wing V/STOL airplane
A parameter-estimation algorithm was used to extract the longitudinal aerodynamic derivatives from flight data for the XC-142A airplane in a cruise condition. The flight data were the response to a tail-plane doublet input. Results of this study showed that a set of derivatives were determined which yielded a calculated aircraft response in close agreement with the measured response. This calculated response was in much closer agreement with the flight data than the response obtained by using derivatives which were calculated from empirical methods. There were large differences between some of the important derivatives extracted from flight data and those calculated from empirical methods. The reasons for these differences were not identified.
Williams, J. L.↗
Injector design guidelines for gas/liquid propellant systems
Injector design guidelines are provided for gas/liquid propellant systems. Information was obtained from a 30-month applied research program encompassing an analytical, design, and experimental effort to relate injector design parameters to simultaneous attainment of high performance and component (injector/thrust chamber) compatibility for gas/liquid space storable propellants. The gas/liquid propellant combination studied was FLOX (82.6% F2)/ ambient temperature gaseous methane. Design criteria that provide for simultaneous attainment of high performance and chamber compatibility are presented for both injector types. Parametric data are presented that are applicable for the design of circular coaxial and like-doublet injectors that operate with design parameters similar to those employed. However, caution should be exercised when applying these data to propellant combinations whose elements operate in ranges considerably different from those employed in this study.
Falk, A. Y.↗
Earth storable bimodal engine, phase 1
An in-depth study of an Earth Storable Bimodal (ESB) Engine using earth storable propellants N2O/N2H4 and operating in either a monopropellant or bipropellant mode was conducted. Detailed studies were completed for both a hot-gas, regeneratively cooled thrust chamber and a ducted hot-gas, film cooled thrust chamber. Hydrazine decomposition products were used for cooling in either configuration. The various arrangements and configurations of hydrazine reactors, secondary injectors, chambers and gimbal methods were considered. The two basic materials selected for the major components were columbium alloys and L-605. The secondary injector types considered were previously demonstrated by JPL and consisted of a liquid-on-gas triplet, a liquid-on-gas doublet, and a liquid-on-gas coaxial injector. Various design tradeoffs were made with different reactor types located at: the secondary injector station, the thrust chamber throat, and the nozzle/extension interface. Associated thermal, structural, and mass analyses were completed.
Source record↗
Moessbauer spectra of ferrite catalysts used in oxidative dehydrogenation
Room temperature Mossbauer spectroscopy was used to examine bulk changes which occur in low surface area CoFe2O4 and CuFe2O4 catalysts as a result of contact with various mixtures of trans-2-butene and O2 during oxidative dehydrogenation reactions at about 420 C. So long as there was at least some O2 in the gas phase, the CoFe2O4 spectrum was essentially unchanged. However, the spectrum changed from a random spinel in the oxidized state to an inverse spinel as it was reduced by oxide ion removal. The steady state catalyst lies very near the fully oxidized state. More dramatic solid state changes occurred as the CuFe2O4 underwent reduction. Under severe reduction, the ferrite was transformed into Cu and Fe3O4, but it could be reversibly recovered by oxidation. An intense doublet located near zero velocity persisted in all spectra of CuFe2O4 regardless of the state of reduction.
Cares, W. R.↗
Analysis of an entrainment model of the jet in a crossflow
A theoretical model has been proposed for the problem of a round jet in an incompressible cross-flow. The method of matched asymptotic expansions has been applied to this problem. For the solution to the flow problem in the inner region, the re-entrant wake flow model was used with the re-entrant flow representing the fluid entrained by the jet. Higher order corrections are obtained in terms of this basic solution. The perturbation terms in the outer region was found to be a line distribution of doublets and sources. The line distribution of sources represents the combined effect of the entrainment and the displacement.
Chang, H. S.↗
Flutter analysis and testing of pairs of aerodynamically interfering delta wings
To examine the effect on flutter of the aerodynamic interference between pairs of closely spaced delta wings, several structurally uncoupled 1/80th-scale models were studied by experiment and analysis. Flutter test boundaries run in a 26-in transonic blowdown wind tunnel were compared with subsonic analytical results generated using the doublet lattice method. Trends for several combinations of vertical and longitudinal wing separation showed that flutter speeds can be significantly lowered in closely spaced configurations. For some configurations, a new flutter mechanism, characterized by coupling of the flexible modes from both surfaces at a distinctive flutter frequency, was predicted and observed.
Chipman, R. R.↗
Mariner 9 ultraviolet spectrometer experiment - Structure of Mars' upper atmosphere.
Mariner 9 observations of the limb intensity profile of the CO Cameron bands in the Martian airglow demonstrate the validity of a postulated relationship between the equivalent subsolar zenith intensity and the 10.7-cm solar radio flux. Comparison of averaged limb intensities of the CO2+ doublet and the Cameron bands on four favorable occasions is consistent with the intensities being directly proportional in a ratio of 0.24 to 1.
Stewart, A. I.↗