Search NASA⌕ Search

SEARCH · Search NASA

Results for “effect”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Remote effects of Tibetan Plateau spring land temperature on global subseasonal to seasonal precipitation prediction and comparison with effects of sea surface temperature: the GEWEX/LS4P Phase I experiment

The prediction skill for precipitation anomalies in late spring and summer months—a significant component of extreme climate events—has remained stubbornly low for years. This paper presents a new idea that utilizes information on boreal spring land surface temperature/subsurface temperature (LST/SUBT) anomalies over the Tibetan Plateau (TP) to improve prediction of subsequent summer droughts/floods over several regions over the world, East Asia and North America in particular. The work was performed in the framework of the GEWEX/LS4P Phase I (LS4P-I) experiment, which focused on whether the TP LST/SUBT provides an additional source for subseasonal-to-seasonal (S2S) predictability. The summer 2003, when there were severe drought/flood over the southern/northern part of the Yangtze River basin, respectively, has been selected as the focus case. With the newly developed LST/SUBT initialization method, the observed surface temperature anomaly over the TP has been partially produced by the LS4P-I model ensemble mean, and 8 hotspot regions in the world were identified where June precipitation is significantly associated with anomalies of May TP land temperature. Consideration of the TP LST/SUBT effect has produced about 25–50% of observed precipitation anomalies in most hotspot regions. The multiple models have shown more consistency in the hotspot regions along the Tibetan Plateau-Rocky Mountain Circumglobal (TRC) wave train. The mechanisms for the LST/SUBT effect on the 2003 drought over the southern part of the Yangtze River Basin are discussed. For comparison, the global SST effect has also been tested and 6 regions with significant SST effects were identified in the 2003 case, explaining about 25–50% of precipitation anomalies over most of these regions. This study suggests that the TP LST/SUBT effect is a first-order source of S2S precipitation predictability, and hence it is comparable to that of the SST effect. With the completion of the LS4P-I, the LS4P-II has been launched and the LS4P-II protocol is briefly presented.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2019

The effects of ultra-fine-grained structure and cryogenic temperature on adiabatic shear localization in titanium

The deformation at low temperatures (173 K and 77 K) in ultrafine-grained (100 and 500 nm) titanium is investigated and its effect on adiabatic shear localization is established. In comparison with coarse grained titanium, the strength of ultrafine-grained titanium is higher due to the classic Hall-Petch effect while the strain hardening approaches zero. Our results show that shear localization in dynamic deformation is also altered. The width of the shear band of coarse-grained titanium decreases from 30 to 18 mm (by 40%) with decreasing the initial deformation temperature to 77 K. In contrast, for 100 nm titanium, the width of shear band decreases more significantly, from 4 mmat room temperature to 1 mm (a 75% decrease) at 77 K. This difference is attributed to the combined effects of the decrease in the thermal conductivity and specific heat capacity, and the increase in thermal softening rate. These changes in the width are consistent with the predictions of the Grady and Bai-Dodd theories. Ultrafine- and nanorecrystallized grains are observed inside the bands which are dependent on initial grain size and initial deformation temperature. Here, the dislocation evolution is evaluated for the different conditions using a Kocks-Mecking formulation; the rotational dynamic recrystallization mechanism responsible for forming the ultrafine/nanosized grains (40-250 nm) is successfully modeled incorporating the differences in initial temperature and grain size. Our results and analysis are important in enhancing the understanding of the structural evolution processes under high strain-rates and cryogenic temperatures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Potential Effects of Climate Change and Solar Radiation Modification on Renewable Energy Resources

Solar radiation modification (SRM) is a possible deliberate approach to decrease or reflect incoming solar radiation with the goal of reducing global temperatures, which have increased over the last decades due to high atmospheric greenhouse gas concentrations. Stratospheric aerosol injection, specifically, has shown potential for successfully reducing global temperatures in climate model simulations. Despite the growing literature in the areas of climate change and SRM, their combined effects on renewable energy generation, a climate change mitigation strategy, have not been addressed. In this review paper, we synthesize previous literature on the possible effects of climate change and SRM on renewable energy resources (i.e., wind energy, solar energy, biomass energy, and hydropower), review the status of climate change and SRM research, and explore potential effects of SRM on renewable energy primarily in the Continental United States (CONUS), but with global perspectives as well. We discuss the research challenges and impacts of SRM on renewable energy and conclude by discussing the potential implications of SRM for renewables for SRM governance and policy. This work is not advocating for or against SRM. It is highlighting an important potential impact for future decision makers.

Kumler, Andrew [National Renewable Energy Laborato↗
DOE OSTI2016

Reversed Nanoscale Kirkendall Effect in Au–InAs Hybrid Nanoparticles

Metal–semiconductor hybrid nanoparticles (NPs) offer interesting synergistic properties, leading to unique behaviors that have already been exploited in photocatalysis, electrical, and optoelectronic applications. A fundamental aspect in the synthesis of metal–semiconductor hybrid NPs is the possible diffusion of the metal species through the semiconductor lattice. The importance of understanding and controlling the co-diffusion of different constituents is demonstrated in the synthesis of various hollow-structured NPs via the Kirkendall effect. Here, we used a postsynthesis room-temperature reaction between AuCl 3 and InAs nanocrystals (NCs) to form metal–semiconductor core–shell hybrid NPs through the “reversed Kirkendall effect”. In the presented system, the diffusion rate of the inward diffusing species (Au) is faster than that of the outward diffusing species (InAs), which results in the formation of a crystalline metallic Au core surrounded by an amorphous, oxidized InAs shell containing nanoscale voids. We used time-resolved X-ray absorption fine-structure (XAFS) spectroscopy to monitor the diffusion process and found that both the size of the Au core and the extent of the disorder of the InAs shell depend strongly on the Au-to-NC ratio. We have determined, based on multielement fit analysis, that Au diffuses into the NC via the kick-out mechanism, substituting for In host atoms; this compromises the structural stability of the lattice and triggers the formation of In–O bonds. These bonds were used as markers to follow the diffusion process and indicate the extent of degradation of the NC lattice. Time-resolved X-ray diffraction (XRD) was used to measure the changes in the crystal structures of InAs and the nanoscale Au phases. By combining the results of XAFS, XRD, and electron microscopy, we correlated the changes in the local structure around Au, As, and In atoms and the changes in the overall InAs crystal structure. This correlative analysis revealed a co-dependence of different structural consequences when introducing Au into the InAs NCs. Therefore, this study of diffusion effects in nanocrystals has relevance to powerful concepts in solid-state nanochemistry related to processes of cation exchange, doping reactions, and diffusion mechanisms.

36 MATERIALS SCIENCE↗
DOE OSTI2015

Interfacial Effects on Lithium Superoxide Disproportionation in Li-O 2 Batteries

During the cycling of Li-O-2 batteries the discharge process gives rise to dynamically evolving agglomerates composed of lithium-oxygen nanostructures; however, little is known about their composition. In this paper, we present results for a Li-O-2 battery based on an activated carbon cathode that indicate interfacial effects can suppress disproportionation of a LiO2 component in the discharge product. High-intensity X-ray diffraction and transmission electron microscopy measurements are first used to show that there is a LiO2 component along with Li2O2 in the discharge product. The stability of the discharge product was then probed by investigating the dependence of the charge potential and Raman intensity of the superoxide peak with time. The results indicate that the LiO2 component can be stable for possibly up to days when an electrolyte is left on the surface of the discharged cathode. Density functional calculations on amorphous LiO2 reveal that the disproportionation process will be slower at an electrolyte/LiO2 interface compared to a vacuum/LiO2 interface. The combined experimental and theoretical results provide new insight into how interfacial effects can stabilize LiO2 and suggest that these interfacial effects may play an important role in the charge and discharge chemistries of a Li-O-2 battery.

interface↗
DOE OSTI2014

Effects of strain on effective work function for Ni/HfO{sub 2} interfaces

The effective work functions for Ni/HfO{sub 2} interfaces under two strain modes (uniaxial and triaxial strains) were studied by using first-principles methods based on density functional theory. The calculated results indicate that the effective work functions are strongly affected by the type of interface and the strain states (tensile and compressive strains). For the both above strain states, the changed value of the effective work functions linearly increases with increasing strain. Moreover, it is observed that for a certain strain, the variation of the effective work function for triaxial strain state is almost larger than that for uniaxial strain state. Finally, the electrons gas model, the interface dipole, and screening role of HfO{sub 2} were used to analyze and explain the strain and interface effects in metal-oxide interfaces. The evident difference between the effective work functions of Ni-Hf and Ni-O interfaces is found to be attributed to different metallic bondings and ionic bondings via the analysis of the charge density distributions. Our work strongly suggests that controlling the strain and interface structure is a promising way for modulating the work function of Ni/HfO{sub 2} interfaces.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2015

Modeling the effect of lithium-induced pedestal profiles on scrape-off-layer turbulence and the heat flux width

The effect of lithium (Li) wall coatings on scrape-off-layer (SOL) turbulence in the National Spherical Torus Experiment (NSTX) is modeled with the Lodestar SOLT (SOL Turbulence) code. Specifically, the implications for the SOL heat flux width of experimentally observed, Li-induced changes in the pedestal profiles are considered. The SOLT code used in the modeling has been expanded recently to include ion temperature evolution and ion diamagnetic drift effects. This work focuses on two NSTX discharges occurring pre- and with-Li deposition. The simulation density and temperature profiles are constrained, inside the last closed flux surface only, to match those measured in the two experiments, and the resulting drift-interchange-driven turbulence is explored. The effect of Li enters the simulation only through the pedestal profile constraint: Li modifies the experimental density and temperature profiles in the pedestal, and these profiles affect the simulated SOL turbulence. The power entering the SOL measured in the experiments is matched in the simulations by adjusting “free” dissipation parameters (e.g., diffusion coefficients) that are not measured directly in the experiments. With power-matching, (a) the heat flux SOL width is smaller, as observed experimentally by infrared thermography and (b) the simulated density fluctuation amplitudes are reduced with Li, as inferred for the experiments as well from reflectometry analysis. The instabilities and saturation mechanisms that underlie the SOLT model equilibria are also discussed.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2015

Bell-Plesset effects in Rayleigh-Taylor instability of finite-thickness spherical and cylindrical shells

Bell-Plesset (BP) effects account for the influence of global convergence or divergence of the fluid flow on the evolution of the interfacial perturbations embedded in the flow. The development of the Rayleigh-Taylor instability in radiation-driven spherical capsules and magnetically-driven cylindrical liners necessarily includes a significant contribution from BP effects due to the time dependence of the radius, velocity, and acceleration of the unstable surfaces or interfaces. An analytical model is presented that, for an ideal incompressible fluid and small perturbation amplitudes, exactly evaluates the BP effects in finite-thickness shells through acceleration and deceleration phases. The time-dependent dispersion equations determining the “instantaneous growth rate” are derived. It is demonstrated that by integrating this approximate growth rate over time, one can accurately evaluate the number of perturbation e-foldings during the inward acceleration phase of the implosion. As a result, in the limit of small shell thickness, exact thin-shell perturbationequations and approximate thin-shell dispersion equations are obtained, generalizing the earlier results [E. G. Harris, Phys. Fluids 5, 1057 (1962); E. Ott, Phys. Rev. Lett. 29, 1429 (1972); A. B. Bud'ko et al., Phys. Fluids B 2, 1159 (1990)].

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2016

Vlasov simulations of electron-ion collision effects on damping of electron plasma waves

Collisional effects can play an essential role in the dynamics of plasma waves by setting a minimum damping rate and by interfering with wave-particle resonances. Kinetic simulations of the effects of electron-ion pitch angle scattering on Electron Plasma Waves (EPWs) are presented here. In particular, the effects of such collisions on the frequency and damping of small-amplitude EPWs for a range of collision rates and wave phase velocities are computed and compared with theory. Both the Vlasov simulations and linear kinetic theory find the direct contribution of electron-ion collisions to wave damping significantly reduced from that obtained through linearized fluid theory. To our knowledge, this simple result has not been published before. Simulations have been carried out using a grid-based (Vlasov) approach, based on a high-order conservative finite difference method for discretizing the Fokker-Planck equation describing the evolution of the electron distribution function. Details of the implementation of the collision operator within this framework are presented. Such a grid-based approach, which is not subject to numerical noise, is of particular interest for the accurate measurements of the wave damping rates.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2016

Viscous effects on the Rayleigh-Taylor instability with background temperature gradient

Here we studied the growth rate of the compressible Rayleigh-Taylor instability in the presence of a background temperature gradient, Θ, using a normal mode analysis. The effect of Θ variation is examined for three interface types corresponding to the combinations of the viscous properties of the fluids (inviscid-inviscid, viscous-viscous, and viscous-inviscid) at different Atwood numbers, At, and when at least one of the fluids' viscosity is non-zero, as a function of the Grashof number. For the general case, the resulting ordinary differential equations are solved numerically; however, dispersion relations for the growth rate are presented for several limiting cases. An analytical solution is found for the inviscid-inviscid interface and the corresponding dispersion equation for the growth rate is obtained in the limit of large Θ. For the viscous-inviscid case, a dispersion relation is derived in the incompressible limit and Θ=0. Compared to Θ=0 case, the role of Θ<0 (hotter light fluid) is destabilizing and becomes stabilizing when Θ>0 (colder light fluid). The most pronounced effect of Θ ≠ 0 is found at low At and/or at large perturbation wavelengths relative to the domain size for all interface types. On the other hand, at small perturbation wavelengths relative to the domain size, the growth rate for the Θ<0 case exceeds the infinite domain incompressible constant density result. The results are applied to two practical examples, using sets of parameters relevant to Inertial Confinement Fusion coasting stage and solar corona plumes. The role of viscosity on the growth rate reduction is discussed together with highlighting the range of wavenumbers most affected by viscosity. The viscous effects further increase in the presence of background temperature gradient, when the viscosity is temperature dependent.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2015

Successful N{sub 2} leptogenesis with flavour coupling effects in realistic unified models

In realistic unified models involving so-called SO(10)-inspired patterns of Dirac and heavy right-handed (RH) neutrino masses, the lightest right-handed neutrino N{sub 1} is too light to yield successful thermal leptogenesis, barring highly fine tuned solutions, while the second heaviest right-handed neutrino N{sub 2} is typically in the correct mass range. We show that flavour coupling effects in the Boltzmann equations may be crucial to the success of such N{sub 2} dominated leptogenesis, by helping to ensure that the flavour asymmetries produced at the N{sub 2} scale survive N{sub 1} washout. To illustrate these effects we focus on N{sub 2} dominated leptogenesis in an existing model, the A to Z of flavour with Pati-Salam, where the neutrino Dirac mass matrix may be equal to an up-type quark mass matrix and has a particular constrained structure. The numerical results, supported by analytical insight, show that in order to achieve successful N{sub 2} leptogenesis, consistent with neutrino phenomenology, requires a “flavour swap scenario” together with a less hierarchical pattern of RH neutrino masses than naively expected, at the expense of some mild fine-tuning. In the considered A to Z model neutrino masses are predicted to be normal ordered, with an atmospheric neutrino mixing angle well into the second octant and the Dirac phase δ≃20{sup ∘}, a set of predictions that will be tested in the next years in neutrino oscillation experiments. Flavour coupling effects may be relevant for other SO(10)-inspired unified models where N{sub 2} leptogenesis is necessary.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2017

An effective description of dark matter and dark energy in the mildly non-linear regime

In the next few years, we are going to probe the low-redshift universe with unprecedented accuracy. Among the various fruits that this will bear, it will greatly improve our knowledge of the dynamics of dark energy, though for this there is a strong theoretical preference for a cosmological constant. We assume that dark energy is described by the so-called Effective Field Theory of Dark Energy, which assumes that dark energy is the Goldstone boson of time translations. Such a formalism makes it easy to ensure that our signatures are consistent with well-established principles of physics. Since most of the information resides at high wavenumbers, it is important to be able to make predictions at the highest wavenumber that is possible. Furthermore, the Effective Field Theory of Large-Scale Structure (EFTofLSS) is a theoretical framework that has allowed us to make accurate predictions in the mildly non-linear regime. In this paper, we derive the non-linear equations that extend the EFTofLSS to include the effect of dark energy both on the matter fields and on the biased tracers. For the specific case of clustering quintessence, we then perturbatively solve to cubic order the resulting non-linear equations and construct the one-loop power spectrum of the total density contrast.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2018

Effective anisotropy due to the surface of magnetic nanoparticles

Analytical solution has been discovered for the second-order effective anisotropy of magnetic nanoparticles of a cubic shape due to the surface anisotropy (SA) of the Néel type. Similarly to the spherical particles, for the simple cubic lattice the grand-diagonal directions (±1,±1,±1) are favored by the effective cubic anisotropy but the effect is twice as strong. Uniaxial core anisotropy and applied magnetic field cause screening of perturbations from the surface at the distance of the domain-wall width and reduce the effect of SA near the energy minima. Yet, screening disappears near the uniaxial energy barrier, and the uniform barrier state of larger particles may become unstable. For these effects the analytical solution is obtained as well, and the limits of the additive formula with the uniaxial and effective cubic anisotropies for the particle are established. Thermally-activated magnetization-switching rates have been computed by the pulse-noise technique for the stochastic Landau-Lifshitz equation for a system of spins.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2020

Effective field theory interactions for liquid argon target in DarkSide-50 experiment

We reanalize data collected with the DarkSide-50 experiment and recently used to set limits on the spin-independent interaction rate of weakly interacting massive particles (WIMPs) on argon nuclei with an effective field theory framework. The dataset corresponds to a total (16660 ± 270) kg d exposure using a target of low-radioactivity argon extracted from underground sources. We obtain upper limits on the effective couplings of the 12 leading operators in the nonrelativistic systematic expansion. For each effective coupling we set constraints on WIMP-nucleon cross sections, setting upper limits between 2.4×10-45 cm2 and 2.3×10-42 cm2 (8.9 ×10-45 cm2 and 6.0 ×10-42 cm2) for WIMPs of mass of 100 GeV/c2 (1000 GeV/c2) at 90% confidence level.

Agnes, P↗
DOE OSTI2021

Validation Metrics for Fixed Effects and Mixed-Effects Calibration

The modern scientific process often involves the development of a predictive computational model. To improve its accuracy, a computational model can be calibrated to a set of experimental data. A variety of validation metrics can be used to quantify this process. Some of these metrics have direct physical interpretations and a history of use, while others, especially those for probabilistic data, are more difficult to interpret. In this work, a variety of validation metrics are used to quantify the accuracy of different calibration methods. Frequentist and Bayesian perspectives are used with both fixed effects and mixed-effects statistical models. Through a quantitative comparison of the resulting distributions, the most accurate calibration method can be selected. Two examples are included which compare the results of various validation metrics for different calibration methods. It is quantitatively shown that, in the presence of significant laboratory biases, a fixed effects calibration is significantly less accurate than a mixed-effects calibration. This is because the mixed-effects statistical model better characterizes the underlying parameter distributions than the fixed effects model. The results suggest that validation metrics can be used to select the most accurate calibration model for a particular empirical model with corresponding experimental data.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2023

The Effects of Channel Supplies on Overall Film-Cooling Effectiveness

Abstract Cooling components in the hot section of a gas turbine are essential to component durability. Common methods of cooling include rib turbulators in internal passages and film cooling on external surfaces. The holes that produce the film cooling are fed from the internal channels often containing ribs. Consequently, there is an interdependence of internal heat transfer and external film cooling. The purpose of this study was to obtain a better understanding of the interaction of ribs and film cooling. To quantify the cooling performance, the surface temperatures were measured, from which overall effectiveness was calculated. For the experiments, additively manufactured test coupons were made of Inconel 718 to match engine Biot numbers. These test coupons had internal feed channels with and without ribs and had both cylindrical holes and meter-diffuser-shaped holes with 15 deg lateral expansion angles and a 1 deg forward expansion angle. A single rectangular channel was one type of feed channel. The other type of feed channel was individual circular channels, with each circular channel supplying an individual film-cooling hole. The experimental results showed that the circular individual channels have 80% higher baseline overall effectiveness than the single rectangular channels without any film cooling. Ribbed turbulators without film cooling also increased the overall effectiveness by 21% for single rectangular channels and by 29% for the circular individual channels compared to the respective non-ribbed channels. While the film cooling increased the overall effectiveness of all geometries, the single rectangular channels had increased overall effectiveness levels by up to twice that of the no film-cooling case. On average, the single rectangular channels had an 80% improvement from film cooling, whereas the individual channel feeds, on average, had only a 50% improvement, given their high baseline effectiveness levels.

Engineering↗
DOE OSTI2017

The Effect of Transient Fuel Staging on Self-Excited Instabilities in a Multi-Nozzle Model Gas Turbine Combustor

Combustion instability in gas turbines can be mitigated using active techniques or passive techniques, but passive techniques are almost exclusively used in industrial settings. While fuel staging, a common passive technique, is effective in reducing the amplitude of self-excited instabilities in gas turbine combustors at steady-state conditions, the effect of transients in fuel staging on self-excited instabilities is not well understood. This paper examines the effect of fuel staging transients on a laboratory-scale five-nozzle can combustor undergoing self-excited instabilities. The five nozzles are arranged in a four-around-one configuration and fuel staging is accomplished by increasing the center nozzle equivalence ratio. When the global equivalence ratio is φ = 0.70 and all nozzles are fueled equally, the combustor undergoes self-excited oscillations. These oscillations are suppressed when the center nozzle equivalence ratio is increased to φ = 0.80 or φ = 0.85. Two transient staging schedules are used, resulting in transitions from unstable to stable operation, and vice-versa. It is found that the characteristic instability decay times are dependent on the amount of fuel staging in the center nozzle. It is also found that the decay time constants differ from the growth time constants, indicating hysteresis in stability transition points. High speed CH* chemiluminescence images in combination with dynamic pressure measurements are used to determine the instantaneous phase difference between the heat release rate fluctuation and the combustor pressure fluctuation throughout the combustor. This analysis shows that the instability onset process is different from the instability decay process.

Culler, Wyatt↗