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At least 163 records · Page 9

The energy distribution cross section in threshold electron-atom impact ionization

The flatness of the energy differential cross section in impact ionization is derived analytically in the Wannier theory. However it is shown that the Wannier zone is confined to a region of the order E/5 is less than or equal to epsilon is less than or equal to 4E/5, where E is the available energy and epsilon is the energy of the electrons. By contrasting the known results of photoionization and photodetachment, one can cogently argue that in the complementary region where electrons share their energy very unequally the cross section rises to a value independent of E, and that this region determines the form of the threshold law.

Temkin, A.↗

Mass spectrometric determination of partial and total electron impact ionization cross sections of SO2 from threshold up to 200 eV

The partial and total ionization cross section for the formation of O(+), S(+), SO(+) and SO2(+) from the impact ionization of SO2 are reported, extending the electron impact energies to 200 eV. The relative flow technique is used to determine the cross section values. The threshold potentials for the products are 23.5 eV for O(+), 16.5 eV for S(+), 16.5 eV for SO(+), and 12.5 eV for SO2(+). Good agreement with the literature is found for SO(+) and SO2(+).

Orient, O. J.↗

Pure rotational excitation of H2 at electron impact energies of 3 to 100 eV

Cross sections for pure rotational excitation in H2 are obtained using two different crossed-beam type electron-impact spectrometers with three sets of conditions: at electron energies of 15-100 eV and scattering angles of 115 deg; 3-40 eV at 20 deg; 40 eV at 10-135 deg. For intermediate-energy electrons the pure rotational excitation cross section at large scattering angles exceeds the elastic scattering cross section at electron energies greater than about 30 eV. Rotational cross sections are found to decrease slowly with decreasing electron energy, with a magnitude at their peak (at 4 eV) about 20 times that at 100 eV. It is suggested that these results may account in part for the large population of excited rotational states observed in interstellar H2.

Srivastava, S. K.↗

Total Electron-Impact Ionization Cross-Sections of CFx and NFx (x = 1 - 3)

The discrepancy between experimental and theoretical total electron-impact ionization cross sections for a group of fluorides, CFx, and NFx, (x = 1 - 3), is attributed to the inadequacies in previous theoretical models. Cross-sections calculated using a recently developed siBED (simulation Binary-Encounter-Dipole) model that takes into account the shielding of the long-range dipole potential between the scattering electron and target are in agreement with experimentation. The present study also carefully reanalyzed the previously reported experimental data to account for the possibility of incomplete collection of fragment ions and the presence of ion-pair formation channels. For NF3, our experimental and theoretical cross-sections compare well with the total ionization cross-sections recently reported by Haaland et al. in the region below dication formation.

Huo, Winifred M.↗

Measurements of Electron Impact Excitation Cross Sections at the Harvard-Smithsonian Center for Astrophysics

The analysis of absolute spectral line intensities and intensity ratios with spectroscopic diagnostic techniques provides empirical determinations of chemical abundances, electron densities and temperatures in astrophysical objects. Since spectral line intensities and their ratios are controlled by the excitation rate coefficients for the electron temperature of the observed astrophysical structure, it is imperative that one have accurate values for the relevant rate coefficients. Here at the Harvard-Smithsonian Center for Astrophysics, we have been carrying out measurements of electron impact excitation (EIE) for more than 25 years.

Gardner, L. D.↗

Cross sections for H(-) and Cl(-) production from HCl by dissociative electron attachment

A crossed target beam-electron beam collision geometry and a quadrupole mass spectrometer have been used to conduct dissociative electron attachment cross section measurements for the case of H(-) and Cl(-) production from HCl. The relative flow technique is used to determine the absolute values of cross sections. A tabulation is given of the attachment energies corresponding to various cross section maxima. Error sources contributing to total errors are also estimated.

Orient, O. J.↗

Data analysis and theoretical studies for atmospheric Explorer C, D and E

The research concentrated on construction of a comprehensive model of the chemistry of the ionosphere. It proceeded by comparing detailed predictions of the atmospheric parameters observed by the instrumentation on board the Atmospheric Explorer Satellites with the measured values and modifying the chemistry to bring about consistency. Full account was taken of laboratory measurements of the processes identified as important. The research programs were made available to the AE team members. Regularly updated tables of recommended values of photoionization cross sections and electron impact excitation and ionization cross sections were provided. The research did indeed lead to a chemistry model in which the main pathways are quantitatively secure. The accuracy was sufficient that remaining differences are small.

Dalgarno, A.↗

Electron impact ionization and attachment cross sections for H2S

Experiments were performed to measure, by electron impact, appearance potentials and the cross sections for ionization, dissociative ionization, and electron attachment for H2S. Results are presented, and discussed individually, for both positive and negative ions. A schematic diagram of the experimental setup is included.

Rao, M. V. V. S.↗

Excitation cross sections for krypton by electrons in the 15-100-eV impact-energy range

Differential, integral, and momentum-transfer cross sections have been determined for the excitation of the 24 lowest electronic states of Kr (some of the transitions are unresolved). The inelastic-scattering cross sections were normalized to the absolute scale with the help of the elastic-scattering differential cross sections (DCS's) which in turn were normalized with respect to absolute He DCS's. The impact energies were 15, 20, 30, 50, and 100 eV and the DCS's were obtained over the range of 5-135 deg scattering angles. The error limits associated with the differential, integral, and momentum-transfer cross sections have been estimated at 25%, 38%, and 46%, respectively.

Trajmar, S.↗