SEARCH · Search NASA

Results for “essential water variables”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 163 records · Page 9

All sources NASA NTRS DOE OSTI

NASA NTRSDate not supplied

Monitoring Vegetation Health and Water Availability in Bryce Canyon National Park for Drought Stress Mitigation Planning

Bryce Canyon National Park is home to groundwater-dependent ecosystems (GDEs) that are threatened by a multidecadal drought and increased groundwater extraction due to a spike in tourism. These ecosystems contain unique species that are only found in areas where near-surface groundwater is present, such as aspen groves and willows. GDEs contribute to the high biodiversity found in Bryce Canyon, which boosts an ecosystem’s productivity and increases the overall ecological health of the park. Unfortunately, many GDEs in this area are too small to identify with traditional Earth observation platforms and are difficult to physically reach for identification and monitoring. NASA DEVELOP partnered with the National Park Service to establish a framework that both identified and assessed the health of GDEs within Bryce Canyon from 2013–2022. The team used high-resolution PlanetScope and Landsat 8 Operational Land Imager (OLI) to map springs, seeps, and GDEs. Modeled data from the Western Land Data Assimilation System (WLDAS) and in situ precipitation data were used to produce time series of climatic variables for the National Park Service to gain an understanding of how the GDEs are changing with the ongoing drought. This study is essential to the goal of the National Park Service to conserve the health of these GDEs.

Aaron Carr↗

DOE OSTI2021

Modeling State Transition and Head-Dependent Efficiency Curve for Pumped Storage Hydro in Look-Ahead Dispatch

As one of the most widely installed utility-scale storage facilities, pumped storage hydro (PSH) plays an essential role in providing flexibility for power systems worldwide. Thus, to accurately quantify the flexibility of PSH units in operational optimization problems is important. The conventional PSH models in the literature rarely consider detailed state transitions due to their hourly-based settings. However, it becomes imperative for operational optimization on short-term intervals, especially with increasing shares of renewable energy in power systems. To this end, this paper presents a novel deterministic PSH model that considers the transition time and trajectory between three states of PSH units in look-ahead dispatch. Moreover, to better characterize the varying efficiency of PSH units with water head and flow rate, this paper proposes to model detailed headdependent efficiency curves (hereafter called input-output curves) in look-ahead dispatch, which encounters heavy computational burdens when short time intervals are applied. In this work, a zig-zag piece-wise linear approximation method is used for input-output curve modeling. This can enable an accurate quantification for variable efficiency and head dependence in a computationally effective manner. Here, numerical results are presented to show performances of the proposed PSH model in both flexibility quantification and computation time.

13 HYDRO ENERGY↗

NASA NTRSDate not supplied

Space Crop Production Gaps and Challenges

As astronauts venture farther from Earth, and stay for longer periods, the space food system will increase in importance. Crop production can supplement a pre-packaged space diet to provide nutrition and dietary variety for space crews. In future missions, bioregenerative approaches may be used to generate a larger percentage of the diet, as well as help to reduce life support system burdens and resupply from Earth. Plants may also provide behavioral health benefits to crew members living in the isolated, confined environment of a space habitat. A number of unique challenges exist for growth of plants in microgravity and on other reduced gravity surfaces like the moon and Mars. Testing plant growth inside the Veggie and Advanced Plant Habitat (APH) chambers on the International Space Station is allowing us to understand the impacts of gravity and spaceflight on crop growth, nutritional content, acceptability, and the importance of plants to astronauts living and working away from Earth. We are also gaining a better understanding of food safety concerns and the behavior of space plant microbiomes and plant pathogens, but major gaps in knowledge remain. As we move from research towards operational space crop production to enable exploration, there are numerous gaps in technology, knowledge, and practice related to space crop growth that must be addressed. Research and development in key focus areas such as effective water and nutrient delivery at variable gravity levels, autonomous plant health monitoring, growth system cleaning and disinfection, and selection of ideal space crops are needed to fill these gaps. Breeding or engineering custom space crops may impact areas including plant growth and development, plant physiology, produce nutrition, organoleptic acceptability, and post-harvest characteristics, and these may further enable space crop production scenarios. Space crop challenges are multifaceted and require diverse interdisciplinary teams working together to develop effective solutions. Solving these requires an array of skill sets from across the biological and physical sciences, engineering, and human social sciences. Solutions to help ensure food security off-Earth may also translate to more sustainable terrestrial crop production approaches, and regular dialog between industry, academia, and government organizations working in related fields benefit all. Additional help can come from engagement with student researchers at various levels through courses, participatory science projects, and open science activities which can provide useful data. Global coordination and integration between space agencies and partners will be essential.

Gioia Donna Massa↗

NASA NTRSDate not supplied

Space Crop Production Gaps and Challenges

Gioia Massa↗

NASA NTRS2005

Three Years of TRMM Precipitation Features: Radar, Radiometric, and Lightning Characteristics - Part 1

During its first three years, the Tropical Rainfall Measuring Mission (TRMM) satellite observed nearly six million precipitation features. The population of precipitation features is sorted by lightning flash rate, minimum brightness temperature, maximum radar reflectivity. areal extent, and volumetric rainfall. For each of these characteristics, essentially describing the convective intensity or the size of the features, the population is broken into categories consisting of the top 0.001%, top 0.01%, top 0.1%, top 1%, top 2.4%. and remaining 97.6%. The set of weakest/smallest features composes 97.6% of the population because that fraction does not have detected lightning, with a minimum detectable flash rate of 0.7 flashes (fl) per minute. The greatest observed flash rate is 1351 fl per minute; the lowest brightness temperatures are 42 K (85 GHz) and 69 K (37 GHz). The largest precipitation feature covers 335 000 square kilometers and the greatest rainfall from an individual precipitation feature exceeds 2 x 10 kg per hour of water. There is considerable overlap between the greatest storms according to different measures of convective intensity. The largest storms are mostly independent of the most intense storms. The set of storms producing the most rainfall is a convolution of the largest and the most intense storms. This analysis is a composite of the global Tropics and subtropics. Significant variability is known to exist between locations. seasons, and meteorological regimes. Such variability will be examined in Part II. In Part I, only a crude land-ocean separation is made. The known differences in bulk lightning flash rates over land and ocean result from at least two differences in the precipitation feature population: the frequency of occurrence of intense storms and the magnitude of those intense storms that do occur. Even when restricted to storms with the same brightness temperature, same size, or same radar reflectivity aloft, the storms over water are considerably less likely to produce lightning than are comparable storms over land.

Cecil, Daniel J.↗

NASA NTRS2004

The Eastern Pacific ITCZ during the Boreal Spring

The 6-year (1998-2003) rainfall products from the Tropical Rainfall Measuring Mission (TRMM) are used to quantify the Intertropical Convergence Zone (ITCZ) in the eastern Pacific (defined by longitudinal averages over 90 degrees W-130 degrees W) during boreal spring (March-April). The double ITCZ phenomenon, represented by the occurrence of two maxima with respect to latitude in monthly mean rainfall, is observed in most but not all of the years studied. The relative spatial locations of maxima in sea surface temperature (SST), rainfall, and surface pressure are examined. Interannual and weekly variability are characterized in SST, rainfall, surface convergence, total column water vapor, and cloud water. There appears to be a competition for rainfall between the two hemispheres during this season. When one of the two rainfall maxima is particularly strong, the other tends to be weak, with the total rainfall integrated over the two varying less than does the difference between the rainfall integrated over each separately. There is some evidence for a similar competition between the SST maxima in the two hemispheres, but this is more ambiguous, and there is evidence that some variations in the relative strengths of the two rainfall maxima may be independent of SST. Using a 25-year (1979-2003) monthly rainfall dataset from the Global Precipitation Climatology Project (GPCP), four distinct ITCZ types during March-April are defined, based on the relative strengths of rainfall peaks north and south of, and right over the equator. Composite meridional profiles and spatial distributions of rainfall and SST are documented for each type. Consistent with previous studies, an equatorial cold tongue is essential to the existence of the double ITCZs. However, too strong a cold tongue may dampen either the southern or northern rainfall maximum, depending on the magnitude of SST north of the equator.

Gu, Guojun↗

DOE OSTI2020

Multimodel simulation of vertical gas transfer in a temperate lake

In recent decades, several lake models of varying complexity have been developed and incorporated in numerical weather prediction systems and climate models. To foster enhanced forecasting ability and verification, improvement of these lake models remains essential. This especially applies to the limited simulation capabilities of biogeochemical processes in lakes and greenhouse gas exchanges with the atmosphere. Here we present multi-model simulations of physical variables and dissolved gas dynamics in a temperate lake (Harp Lake, Canada). The five models (ALBM, FLake, LAKE, LAKEoneD, MTCR-1) considered within this most recent round of the Lake Model Intercomparison Project (LakeMIP) all captured the seasonal temperature variability well. In contrast, none of the models is able to reproduce the exact dates of ice-cover and ice-off, leading to considerable errors in the simulation of eddy diffusivity around those dates.We then conducted an additional modeling experiment with a diffusing passive tracer to isolate the effect of the eddy diffusivity on gas concentration. Remarkably, sophisticated k -" models do not demonstrate a significant difference in the vertical diffusion of a passive tracer compared to models with much simpler turbulence closures. All models simulate less intensive spring overturn compared to autumn. Reduced mixing in the models consequently leads to the accumulation of the passive tracer distribution in the water column. The lake models with a comprehensive biogeochemical module, such as ALBM and LAKE, predict dissolved oxygen dynamics adequate to the observed data. However, for the surface carbon dioxide concentration the correlation between modeled (ALBM, LAKE) and observed data is weak (~0.3). Overall our results indicate the need to improve the representation of physical and biogeochemical processes in lake models, thereby contributing to enhanced weather prediction and climate projection capabilities.

Guseva, Sofya↗

NASA NTRS1999

Permeation Resistance of Chlorinated Polyethylene Against Hydrazine Fuels

The permeation resistance of chlorinated polyethylene (CPE) used in chemical protective clothing against the aerospace fuels hydrazine, monomethylhydrazine (MMH), and uns-dimethylhydrazine (UDMH) was determined by measuring breakthrough times and time-averaged vapor transmission rates using an ASTM F 739 permeation cell. Two exposure scenarios were simulated: a 2 hour (h) fuel vapor exposure, and a liquid fuel "splash" followed by a 2 h vapor exposure. To simulate internal suit pressure during operation, a positive differential pressure of 0.3 in. water (75 Pa) on the collection side of the permeation apparatus was used. Breakthrough was observed after exposure to liquid MMH, and to vapor and liquid UDMH. No breakthrough was observed after exposure to vapor and liquid hydrazine, or vapor MMH. A model was then used to calculate propellant concentrations inside a totally encapsulating chemical protective suit based on the ASTM permeation data obtained in the present study. Concentrations were calculated under conditions of fixed vapor transmission rate, variable breathing air flow rate, and variable splash exposure area. Calculations showed that the maximum allowable permeation rates of hydrazine fuels through CPE were of the order of 0.05 to 0.08 ng sq cm/min for encapsulating suits with low breathing air flow rates (of the order of 5 scfm or 140 L/min). Above these permeation rates, the 10 parts per billion (ppb) threshold limit value time - weighted average could be exceeded for chemical protective suits having a CPE torso. To evaluate suit performance at ppb level concentrations, use of a sensitive analytical method such as cation exchange high performance liquid chromatography with amperometric detection was found to be essential.

Waller, J. M.↗

DOE OSTI2025

IrrigationViz: A Geospatial Visualization Application to Facilitate Irrigation Modernization

Irrigation water delivery infrastructure, such as canals and pipelines, are essential to agriculture in the Western U.S., yet many of these systems are reaching the end of their useful lives. Reinvestment can achieve a wide variety of benefits, from water conservation to energy savings or renewable energy generation. Modernization requires significant planning, design, and implementation funding which can be a challenge for many irrigation districts. Here, this paper introduces IrrigationViz, a web-based mapping application designed to help irrigation districts visualize and generate high-level cost and benefit estimates for infrastructure modernization projects. These estimates can help water managers identify projects that benefit from additional engineering resources and ultimately obtain funding. IrrigationViz includes map interactions, graphs, and visualization components to facilitate planning and communication to stakeholders and funders. IrrigationViz combines user-provided information about a water-delivery system with public datasets and basic engineering formulas to generate estimates of the benefits of reinvestment. Estimates include the amount of water seepage in earthen canals, potential hydropower generation associated with replacing a canal with a pressurized pipe, and pipe size recommendations. We found that hydropower generation estimates compared favorably with real world projects, but seepage loss estimates showed high variability relative to on-the-ground measurements

99 - GENERAL AND MISCELLANEOUS↗

NASA NTRS2005

Measurement of hydraulic characteristics of porous media used to grow plants in microgravity

Understanding the effect of gravity on hydraulic properties of plant growth medium is essential for growing plants in space. The suitability of existing models to simulate hydraulic properties of porous medium is uncertain due to limited understanding of fundamental mechanisms controlling water and air transport in microgravity. The objective of this research was to characterize saturated and unsaturated hydraulic conductivity (K) of two particle-size distributions of baked ceramic aggregate using direct measurement techniques compatible with microgravity. Steady state (Method A) and instantaneous profile measurement (Method B) methods for K were used in a single experimental unit with horizontal flow through thin sections of porous medium providing an earth-based analog to microgravity. Comparison between methods was conducted using a crossover experimental design compatible with limited resources of space flight. Satiated (natural saturation) K ranged from 0.09 to 0.12 cm s-1 and 0.5 to >1 cm s-1 for 0.25- to 1- and 1- to 2-mm media, respectively. The K at the interaggregate/intraaggregate transition was approximately 10(-4) cm s-1 for both particle-size distributions. Significant differences in log(10)K due to method and porous medium were less than one order of magnitude and were attributed to variability in air entrapment. The van Genuchten/Mualem parametric models provided an adequate prediction of K of the interaggregate pore space, using residual water content for that pore space. The instantaneous profile method covers the range of water contents relevant to plant growth using fewer resources than Method A, all advantages for space flight where mass, volume, and astronaut time are limited.

NASA Center JSC↗

DOE OSTI2025

Intersection of Hydrologic Change and Hydropower in the United States: Needs for Future Research and Practice

Hydropower is crucial for electric‐grid stability in the context of variable renewables but faces threats from changing hydrology. Here, we summarize the state of the science at the intersection of hydropower operations and planning, hydrologic science, and climate. We focus on the United States, outlining research, development, and training needs. Key knowledge gaps include the risk that intensification of compound extreme events poses to future generation, as well as uncertainties surrounding greenhouse gas emissions from hydropower reservoirs with relevance to hydropower's role in energy decarbonization. Quantifying such impacts and reducing uncertainty are critical where possible, but remaining irreducible or deep uncertainty will require new approaches. Future monitoring and modeling methods must provide a better understanding of the complexity inherent in large watersheds that is critical to managing both hydropower and watersheds in the context of hydrologic change. Yet, research and development will have little impact if they do not inform practice. Standardization and consolidation of platforms are essential for data, modeling, and tool translation to local scales and small operators. An enhanced industry‐academia dialog is pivotal for fostering a robust pipeline of hydropower professionals. Collaboration among researchers, policymakers, authorities, and industry stakeholders emerges as a recurring theme, highlighting the imperative for collective efforts.

13 HYDRO ENERGY↗

NASA NTRS2021

Vegetation Monitoring Optimization with Normalized Difference Vegetation Index and Evapotranspiration Using Remote Sensing Measurements and Land Surface Models Over East Africa

The majority of people in East Africa rely on the agro-pastoral system for their livelihood, which is highly vulnerable to droughts and flooding. Agro-pastoral droughts are endemic to the region and are considered the main natural hazard that contributes to food insecurity. Drought begins with rainfall deficit, gradually leading to soil moisture deficit, higher land surface temperature, and finally impacts to vegetation growth. Therefore, monitoring vegetation conditions is essential in understanding the progression of drought, potential effects on food security, and providing early warning information needed for drought mitigation decisions. Because vegetation processes couple the land and atmosphere, monitoring of vegetation conditions requires consideration of both water provision and demand. While there is consensus in using either the Normalized Difference Vegetation Index (NDVI) or evapotranspiration(ET) for vegetation monitoring, a comprehensive assessment optimizing the use of both has not yet been done. Moreover, the evaluation methods for understanding the relationships between NDVI and ET for vegetation monitoring are also limited. Taking these gaps into account we have developed a framework to optimize vegetation monitoring using both NDVI and ET by identifying where they perform the best by using triple collocation and cross-correlation methods. We estimated the random error structure in Moderate Resolution Imaging Spectroradiometer (MODIS) NDVI; ET from the Operational Simplified Surface Energy Balance (SSEBop) model; and ET from land surface models (LSMs). LSM ET and SSEBop ET have been found to be better indicators for vegetation monitoring during extreme drought events, while NDVI could provide better information on vegetation condition during wetter than normal conditions. The random error structures of these variables suggest that LSM ET is most likely to provide important information for vegetation monitoring over low and high ends of the vegetation fraction areas. Over moderate vegetative areas, any of these variables could provide important vegetation information for drought characterization and food security assessments. While this study provides a framework for optimizing vegetation monitoring for drought and food security assessments over East Africa, the framework can be adopted to optimize vegetation monitoring over any other drought and food insecure region of the world.

triple collocation↗

NASA NTRS2004

CoSSIR: A New Instrument for Exploring the Utility of Submillimeter-wave Radiometry for Earth Observation

The Conical Scanning Submillimeter-wave Imaging Radiometer (CoSSIR) has been developed to study the application of submillimeter-wave radiometry for remote sensing of cirrus clouds and humidity sounding. Measurements of the global distribution of ice cloud mass and particle size are important for understanding the Earth s energy budget and for evaluating global climate models. The spatial variability and the wide variety of cloud particle shapes and sizes make ice clouds particularly difficult to measure. Ice clouds are essentially undetectable at microwave frequencies due to the low dielectric of ice and small size of the particles relative to wavelength. However, submillimeter wavelengths demonstrate significant response to the presence of ice clouds thus this frequency regime is applicable to measuring ice clouds. Another potentially viable application for submillimeter-wave radiometry is humidity and temperature sounding. The principle of sounding at submillimeter wavelengths is similar to that at microwavelengths. Submillimeter-wave radiometry has the advantage of achieving finer spatial resolution using a smaller antenna aperture which is an important consideration for spaceborne observatories. Submillimeter-wave radiometry also offers the potential of sounding over land and as a surrogate measurement for precipitation. CoSSIR is a new instrument to explore these applications. The CoSSIR is designed to fly aboard the ER-2 aircraft and its modest size (approximately 100 kg) permits it to be configured for other aircraft. A dual-axes gimbals mechanism provides conical, across-track, and along-track scanning capability. In its present configuration CoSSIR has fifteen channels between 183 GHz and 640 GHz. Three channels are centered about the 183 GHz water vapor absorption line, four channels are centered about the 380 GHz water vapor absorption line, and three dual-polarized channels are centered about the 487 GHz oxygen absorption line. Two channels are located in atmospheric windows at 220 GHz and 640 GHz. All channels are single-linear polarized with the exception of those near 487 GHz. Calibration is achieved by periodically observing two blackbody radiators; one blackbody is heated to approximately 325 K and the other is approximately 250 K during flight. Details of the instrument design as well as measurements from the Cirrus Regional Study of Tropical Anvils and Cirrus Layers - Florida Area Cirrus Experiment will be presented.

Racette, P. E.↗

NASA NTRS1962

BOILING HEAT TRANSFER TO LIQUID HYDROGEN AND NITROGEN IN FORCED FLOW

Boiling heat transfer to liquid hydrogen and nitrogen was investigated experimentally. Results are presented from a study of bulk boiling inside a cylindrical tube under vertically upward forced-flow conditions. A 0.555-inch-inside-diameter and 16 (1/8)-inch-long electrically heated stainless-steel tube was used. The range of variables studied for hydrogen were mass velocity of 2850 to 17,000 pounds per hour per square foot, local heat flux of 3600 to 40,000 Btu per hour per square foot, inlet pressure of 30 to 74 pounds per square inch absolute, and inlet subcooling of 0° to 9° R. Nitrogen test conditions were mass velocity of 15,000 to 56,000 pounds per hour per square foot, local heat flux of 2300 to 40,000 Btu per hour per square foot, inlet pressure of 47 to 56 pounds per square inch absolute, and inlet sub cooling of 1° to 6° R. The axial distribution of the tube-wall temperatures is presented. A transition in the type of boiling heat transfer was obtained. The critical heat flux corresponding to this transition was determined over a range of flow and heating rates and local qualities. At specific combinations of flow and transition location, a range of critical-heat-flux values was obtained and maximum values were determined. The maximum critical heat flux increased with increasing fluid-flow rate and decreased with increasing length of tube before transition. Similar variations of the maximum critical heat flux have been reported for water. The tube-inner-wall temperatures upstream of transition were essentially uniform and were only slightly greater than the fluid saturation temperature. The Wall-temperature profiles downstream of transition generally resembled those obtained in film-boiling studies and appeared to be strongly dependent upon local quality at the point of transition. Maximum wall temperatures of 9000 and 18000 R were obtained with hydrogen and nitrogen, respectively. Fluctuations of pressure, flow rate, and temperature occurred during some of the boiling tests. Under some conditions, maximum critical-heat-flux values were attained during steady-state operation with fluctuations. In other cases the fluctuations became uncontrolled, and critical-flux values less than the maximum values were obtained upon restabilization of the test conditions. No measurable pressure drop across the test section was obtained at any condition.

LIQUID HYDROGEN↗

NASA NTRS2004

The Search for Young Planetary Systems And the Evolution of Young Stars

The Space Interferometer Mission (SIM) will provide a census of planetary systems by con- ducting a broad survey of 2,000 stars that will be sensitive to the presence of planets with masses as small as approx. 15 Earth masses (1 Uranus mass) and a deep survey of approx. 250 of the nearest, stars with a mass limit of approx.3 Earth masses. The broad survey will include stars spanning a wide range of ages, spectral types, metallicity, and other important parameters. Within this larger context, the Young Stars and Planets Key Project will study approx. 200 stars with ages from 1 Myr to 100 Myr to understand the formation and dynamical evolution of gas giant planets. The SIM Young Stars and Planets Project will investigate both the frequency of giant planet formation and the early dynamical history of planetary systems. We will gain insight into how common the basic architecture of our solar system is compared with recently discovered systems with close-in giant planets by examining 200 of the nearest (less than 150 pc) and youngest (1-100 Myr) solar-type stars for planets. The sensitivity of the survey for stars located 140 pc away is shown in the planet mass-separation plane. We expect to find anywhere from 10 (assuming that only the presently known fraction of stars. 5-7%, has planets) to 200 (all young stars have planets) planetary systems. W-e have set our sensitivity threshold to ensure the detection of Jupiter-mass planets in the critical orbital range of 1 to 5 AU. These observations, when combined with the results of planetary searches of mature stars, will allow us to test theories of planetary formation and early solar system evolution. By searching for planets around pre-main sequence stars carefully selected to span an age range from 1 to 100 Myr, we will learn a t what epoch and with what frequency giant planets are found at the water-ice snowline where they are expected to form. This will provide insight into the physical mechanisms by which planets form and migrate from their place of birth, and about their survival rate. With these data in hand, we will provide data, for the first time, on such important questions as: What processes affect the formation and dynamical evolution of planets? When and where do planets form? What is initial mass distribution of planetary systems around young stars? How might planets be destroyed? What is the origin of the eccentricity of planetary orbits? What is the origin of the apparent dearth of companion objects between planets and brown dwarfs seen in mature stars? The observational strategy is a compromise between the desire to extend the planetary mass function as low as possible and the essential need to build up sufficient statistics on planetary occurrence. About half of the sample will be used to address the "where" and "when" of planet formation. We will study classical T Tauri stars (cTTs) which have massive accretion disks and post- accretion, weak-lined T Tauri stars (wTTs). Preliminary estimates suggest the sample will consist of approx. 30% cTTs and approx. 70% wTTs, driven in part by the difficulty of making accurate astrometric measurements toward objects with strong variability or prominent disks.

Beichman, Charles A.↗

DOE OSTI2023

Thermodynamics of Minerals Stable near Earth's Surface

Project “Thermodynamics of Minerals Stable Near the Earth’s Surface” uses specialized calorimetric techniques to obtain new thermochemical data for solid phases of interest in the Earth’s “critical zone”, the near surface regions of the planet most directly affecting and affected by human activity. Major activity was in three areas: manganese oxide materials, aluminum clusters which are precursors to aluminum oxyhydroxide precipitates, and zeolites. All these classes of minerals are potential carriers of heavy metals and radionuclides in the environment, both within their crystal structures and as adsorbed layers or colloids. Their thermodynamic stability, as well as the sequence of stability of competing phases, governs the aqueous solubility of contaminants (and nutrients) in soil, groundwater, and sediments. The thermodynamics of these phases is strongly affected by particle size and crystallinity, since they often occur as very fine particles which do not coarsen in the near-surface environment. Many of these materials exhibit extensive polymorphism, multicomponent solid solution, and variable hydration states. Thus, one must define and systematize important thermodynamic variables, since one cannot make measurements on each and every possible phase, particle size, and composition. A major finding of the work on manganese oxides was labile water-induced oxidation-reduction reactions. These will be studied further by a combination of thermodynamic and synchrotron-based spectroscopic methods, the latter in collaboration with Peggy O’Day at UC Merced. The adsorption of other species, including simple organics, on such redox-active surfaces will also be investigated by a combination of thermochemical and spectroscopic studies. Studies of the energetics of water adsorption on mineral surfaces will be expanded to emphasize the adsorption of CO2 and small organic molecules, relevant to soil, groundwater, and the subsurface environment. Gas adsorption calorimetry, immersion calorimetry, and solution calorimetry will be combined with appropriate analytical and spectroscopic techniques to obtain a comprehensive picture of the interactions and their energetics. The evolution of aqueous aluminum clusters to form aluminum oxyhydroxide precipitates will be studied in detail by a combination of calorimetric and structural methods applied to aqueous samples aged at room temperature. The energetics of new classes of clusters will be explored. The project addresses several common themes relevant to the broad mission of the Department of Energy. Thermochemical data for minerals stable near the Earth’s surface, though still incomplete, are essential for understanding both natural and anthropogenic processes that affect our very existence on this planet. Such data contribute to the fundamental underpinning for mitigation and management strategies for the extraction and use of energy. Fundamental thermodynamic and mechanistic understanding is required to model processes ranging from heavy metal pollution to nuclear waste disposal to climate change.

58 GEOSCIENCES↗

NASA NTRSDate not supplied

Status of the Microwave Barometric Radar and Sounder (MBARS)

Atmospheric surface pressure and pressure profiles are essential variables in weather modeling and forecasting. Pressure gradients generate atmospheric motion and are essential to the air-sea heat exchange feedbacks within the planetary boundary layer (PBL) that lead to convective storms and heavy precipitation. Despite the importance of pressure and pressure gradients on meso-, synoptic-, and global-scale weather patterns, current technology relies almost entirely on buoy measurements over the majority of the ocean. These measurements are too sparse to capture pressure gradients of even many synoptic scale events, and leave models starved of information. NASA/Goddard Space Flight Center (GSFC), NASA/Langley Research Center (LaRC), and Tomorrow.io have begun development of the Microwave Barometric Radar and Sounder (MBARS), an airborne sensor to retrieve surface air pressure and vertical pressure profiles, especially over oceans. MBARS is a new combined active/passive microwave instrument in the O2 absorption V-band (64-70 GHz) funded by the NASA Earth Science Technology Office (ESTO) Instrument Incubator Program (IIP). This instrument consists of an innovative scanning multi-channel differential absorption radar (DAR) to provide an estimation of total atmospheric column oxygen content and thus the surface dry air pressure. MBARS also will provide hyperspectral radiometric temperature profiling to enables vertical pressure profiles using the hypsometric relationship between pressure and temperature. A co-located microwave radiometer will provide the integrated water vapor mass contribution to atmospheric pressure. This presentation will summarize the project, retrieval concept, and engineering status of the MBARS project.

Radar, Radiometer↗

NASA NTRS2021

Using SMAP Level-4 Soil Moisture to Constrain MOD16 Evapotranspiration over the Contiguous USA

Evapotranspiration (ET) is a key hydrologic variable linking the Earth’s water, carbon and energy cycles. At large spatial scales, remote sensing-based (RS) models are often used to quantify ET. Despite the large number of RS ET models available, few include soil moisture as a key environmental input, which can degrade model accuracy and utility. Here, we use model assimilation enhanced soil moisture estimates from the NASA SMAP (Soil Moisture Active Passive) mission as a water supply control in the MOD16 ET algorithm framework. SMAP-derived daily surface (0-5cm depth) and root zone (0-1m depth) soil moisture are used with MODIS (Moderate Resolution Imaging Spectroradiometer) vegetation observations, and 4km gridded regional surface meteorology (Gridmet) as primary inputs for estimating daily ET and underlying model soil and stomatal conductance terms. We calibrated the model environmental response parameters using tower eddy covariance ET observations representing major North American biomes. The model ET results were validated using a holdout set of tower observations spanning a large regional climate gradient. The updated ET estimates outperform the baseline MOD16 product across all tower validation sites (RMSE = 0.758 vs 1.108 mm day-1; R2 = 0.68 vs0.45, respectively). Smaller relative improvements were obtained using a recalibrated model with 4km Gridmet meteorology, but no soil moisture control (RMSE = 0.813 mm day-1; R2 = 0.66), indicating that these changes are essential for the improved model performance. The soil moisture-constrained model improvements and relative benefits from the SMAP observations are greater in arid climates, consistent with stronger soil moisture control on ET in water-limited regions. The use of SMAP soil moisture as an additional model constraint improves MOD16 regional performance and provides a new framework for investigating both soil and atmosphere controls on ET.

SMAP↗