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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
NASA NTRS1969

Mixed ether bath for electrodeposition of aluminum

Anisole added to the bath mixture improves Brenner aluminum plating bath technique. Mixture has lower bath vapor-pressure and the electro-deposits obtained have greater physical strength than deposits from the Brenner bath.

Lui, K.↗
NASA NTRS1971

Elastohydrodynamic film thickness measurements with advanced ester, fluorocarbon, and polyphenyl ether lubricants to 589 K (600 F)

Elastohydrodynamic (EHD) film thicknesses have been measured, by means of an X-ray technique, under conditions that closely simulate the ball-race contact in advanced turbine engine thrust bearings. The experiments were conducted with a rolling-disk machine using disks which yield a contact zone similar to that in the actual bearing. Both the rolling and spinning motions of the ball relative to the race were simulated by the apparatus. Four lubricants were evaluated at temperatures to 600 F and maximum Hertz stresses to 350,000 psi. The X-ray film thickness data correlated well with observations of surface distress (or lack thereof) in full-scale bearing tests with the same lubricants under similar conditions of temperature and load. The predicted variation of film thickness with speed and viscosity as verified, although the magnitude of measured film thickness was generally one-half to one-third of predicted values. An effect of stress greater than predicted was consistently observed in the higher stress range.

Parker, R. J.↗
NASA NTRS1975

Polyperfluoroalkylene ethers as high-temperature sealants

After a review of some of the literature to point out limitations in fluoroether synthesis, current work is discussed that is designed to alleviate deficiencies in obtaining high molecular weights, and projections on some of the challenges for future work in this area are given. Several mechanisms are diagrammed. The work of Dr. Price is emphasized.

Rosser, R. W.↗
NASA NTRS1978

Phytanyl-glycerol ethers and squalenes in the archaebacterium Methanobacterium thermoautotrophicum

Gas chromatographic and mass- and infrared-spectrometric techniques are used to assay the lipids of a thermophilic chemolithotroph, Methanobacterium thermoautotrophicum. Of the chloroform-soluble lipids, 79% are polar and 21% non-polar. Attention is given to the detection of squalene and hydrosqualene derivatives, which, coupled with 16S r-RNA sequence homologies, indicate that the extreme halophiles and the methanogens share a common ancestor.

Tornabene, T. G.↗
NASA NTRS1981

Synthesis and characteristics of polyarylene ether sulfones

A method utilizing potassium carbonate/dimethyl acetamide, as base and solvent respectively, was used for the synthesis of several homopolymers and copolymers derived from various bisphenols. It is demonstrated that this method deviates from simple second order kinetics; this deviation being due to the heterogeneous nature of the reaction. Also, it is shown that a liquid induced crystallization process can improve the solvent resistance of these polymers. Finally, a Monte Carlo simulation of the triad distribution of monomers in nonequilibrium copolycondensation is discussed.

Viswanathan, R.↗
NASA NTRS1984

Perfluoroalkylene-Ether Triazine Elastomers

New process yields product that resists heat and action of oxygen and water. Ring closing step, which gives elastomer its stability, imidoylamidine dinitrile reacts with perfluoroether acide, yielding prepolymer. Prepolymer then treated with ammonia and cured by heating to form polymer. Elastomers are highly resistant to heat, oxidation, and hydrolysis.

Rosser, R. W.↗
NASA NTRS1984

The ethereal rings of Jupiter and Saturn

The brighter main band of the Jovian ring, which is tenuous and exhibits little substructure, lies in the equatorial plane at 1.7-1.8 Jupiter radii, R(J); this is well within the Roche limit. Since dynamical evolution times and survival lifetimes for micron grains are of the order of less than 100-1000 years, the visible Jovian ring must be continuously replenished. It is suggested that most small grains are generated by micrometeoroids colliding into unseen parent bodies residing in the main band. The halo is composed of still smaller particles and is radially localized at about 1.3-1.7 R(J). Unlike the rings of Saturn and Uranus, the Jovian rings are distinguished by the determination of their form by single-particle dynamics rather than collective effects.

Burns, J. A.↗
NASA NTRS1985

The effects of metals and inhibitors on thermal oxidative degradation reactions of unbranched perfluoroalkyl ethers

Thermal oxidative degradation studies were performed on unbranched perfluoroalkylethers at 288 C in oxygen. Metals and alloys studied included Ti, Al, and Ti (4 Al, 4 Mn). The mechanism of degradation was by chain scission. Ti and Al promoted less degradation than Ti (4 Al, 4 Mn). The two inhibitors investigated (a perfluorophenyl phosphine and a phosphatriazine) reduced degradation rates by several orders of magnitude. Both inhibitors were effective for the same duration (75 to 100 hours). The phosphatriazine appeared to provide more surface protection.

Jones, W. R., Jr.↗