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At least 163 records · Page 9
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NASA NTRS1991

Movement of Trace Elements During Residence in the Antarctic Ice: a Laboratory Simulation

Recent work has determined that differences in the trace element distribution between Antarctic eucrites and non-Antarctic eucrites may be due to weathering during residence in the ice, and samples that demonstrate trace element disturbances do not necessarily correspond to eucrites that appear badly weathered to the naked eye. This study constitutes a preliminary test of the idea that long-term residence in the ice is the cause of the trace element disturbances observed in the eucrites. Samples of a non-Antarctic eucrite were leached in water at room temperature conditions. Liquid samples were analyzed for rare earth element abundances using ion chromatography. The results for the short-term study showed little or no evidence that leaching had occurred. However, there were tantalizing hints that something may be happening. The residual solid samples are currently being analyzed for the unleached trace metals using instrumental neutron activation analysis and should show evidence of disturbance if the chromatography clues were real. In addition, another set of samples continues to be intermittently sampled for later analysis. The results should give us information about the movement of trace elements under our conditions and allow us to make some tentative extrapolations to what we observe in actual Antarctic eucrite samples.

Strait, Melissa M.↗
NASA NTRS1996

REE Partition Coefficients from Synthetic Diogenite-Like Enstatite and the Implications of Petrogenetic Modeling

Determining the petrogenesis of eucrites (basaltic achondrites) and diogenites (orthopyroxenites) and the possible links between the meteorite types was initiated 30 years ago by Mason. Since then, most investigators have worked on this question. A few contrasting theories have emerged, with the important distinction being whether or not there is a direct genetic link between eucrites and diogenites. One theory suggests that diogenites are cumulates resulting from the fractional crystallization of a parent magma with the eucrites crystallizing, from the residual magma after separation from the diogenite cumulates. Another model proposes that diogenites are cumulates formed from partial melts derived from a source region depleted by the prior generation of eucrite melts. It has also been proposed that the diogenites may not be directly linked to the eucrites and that they are cumulates derived from melts that are more orthopyroxene normative than the eucrites. This last theory has recently received more analytical and experimental support. One of the difficulties with petrogenetic modeling is that it requires appropriate partition coefficients for modeling because they are dependent on temperature, pressure, and composition. For this reason, we set out to determine minor- and trace-element partition coefficients for diogenite-like orthopyroxene. We have accomplished this task and now have enstatite/melt partition coefficients for Al, Cr, Ti, La, Ce, Nd, Sm, Eu, Dy, Er, Yb, and La.

Schwandt, C. S.↗
NASA NTRS2014

Compositional Diversity of the Vestan Regolith Derived from Howardite Compositions and Dawn VIR Spectra

Howardite, eucrite and diogenite meteorites likely come from asteroid 4 Vesta [1]. Howardites - physical mixtures of eucrites and diogenites - are of two subtypes: regolithic howardites were gardened in the true regolith; fragmental howardites are simple polymict breccias [2]. The Dawn spacecraft imaged the howarditic surface of Vesta with the visible and infrared mapping spectrometer (VIR) resulting in qualitative maps of the distributions of distinct diogenite-rich and eucrite-rich terranes [3, 4]. We are developing a robust basis for quantitative mapping of the distribution of lithologic types using spectra acquired on splits of well-characterized howardites [5, 6]. Spectra were measured on sample powders sieved to <75 μm in the laboratories of the Istituto di Astrofisica e Planetologia Spaziali and Brown University. Data reduction was done using the methods developed to process Dawn VIR spectra [4]. The band parameters for the ~1 and ~2 μm pyroxene absorption features (hereafter BI and BII) can be directly compared to Dawn VIR results. Regolithic howardites have shallower BI and BII absorptions compared to fragmental howardites with similar compositions. However, there are statistically significant correlations between Al or Ca contents and BI or BII center wavelengths regardless of howardite subtype. Diogenites are poor in Al and Ca while eucrites are rich in these elements. The laboratory spectra can thus be directly correlated with the percentage of eucrite material contained in the howardites. We are using these correlations to quantitatively map Al and Ca distributions, and thus the percentage of eucritic material, in the current regolith of Vesta.

Mittlefehldt, D. W.↗
NASA NTRS2014

Experimental Constraints on a Vesta Magma Ocean

A magma ocean model was devised to relate eucrites (basalts) and diogenites (orthopyroxenites), which are found mixed together as clasts in a suite of polymict breccias known as howardites. The intimate association of eucritic and diogenitic clasts in howardites argues strongly that these three classes of achondritic meteorites all originated from the same planetoid. Reflectance spectral evidence (including that from the DAWN mission) has long suggested that Vesta is indeed the Eucrite Parent Body. Specifically, the magma ocean model was generated as follows: (i) the bulk Vesta composition was taken to be 0.3 CV chondrite + 0.7 L chondrite but using only 10% of the Na2O from this mixture; (ii) this composition is allowed to crystallize at 500 bar until approx. 80% of the system is solid olivine + low-Ca pyroxene; (iii) the remaining 20% liquid crystallizes at one bar from 1250C to 1110C, a temperature slightly above the eucrite solidus. All crystallization calculations were performed using MELTS. In this model, diogenites are produced by cocrystallization of olivine and pyroxene in the >1250C temperature regime, with Main Group eucrite liquids being generated in the 1300-1250C temperature interval. Low-Ca pyroxene reappears at 1210C in the one-bar calculations and fractionates the residual liquid to produce evolved eucrite compositions (Stannern Trend). We have attempted to experimentally reproduce the <1250C portion of the MELTS Vesta magma ocean. In the MELTS calculation, the change from 500 bar to one bar results in a shift of the olivine:low-Ca pyroxene boundary so that the 1250C liquid is now in the olivine field and, consequently, olivine should be the first-crystallizing phase, followed by low-Ca pyroxene at 1210C, and plagioclase at 1170C. Because at one bar the olivine:low-Ca pyroxene boundary is a peritectic, fractional crystallization of the 1210C liquid proceeds with only pyroxene crystallization until plagioclase appears. Thus, the predictions of the MELTS calculation are clear and straightforward.

Hoff, C.↗
NASA NTRS1987

Volatile degassing of basaltic achondrite parent bodies Evidence from alkali elements and phosphorus

The Na, K, Rb, Cs, and P abundances in eucrites, diogenites, basaltic clasts from polymict eucrite, howardites, and mesosiderites are examined, and compared with an average of highly incompatible refractory (AHIR) elements normalized to cosmic abundances. It is observed that basaltic eucrites and basaltic clasts show a positive correlation between K, Rb, and Cs, and alkali element/AHIR ratios; the volatile loss of the alkali elements from the basalt affects the parent body inventory of volatile elements. The data reveal that for diogenites, the alkali /AHIR ratios are 1.4-2 times greater than in basaltic eucrites and are more variable; and the negative relation between K, Rb, Cs, and the alkali/AHIR ratio correlate with progressive alkali loss through volatile outgassing during crystallization of one or more magmas resulting in a greater than 90 percent loss of the volatile element inventory from the parent body. It is also detected that P displays volatile loss from the basaltic eucrites and elevated P/AHIR ratios in diogenites.

Mittlefehldt, David W.↗
NASA NTRS2013

Petrologic and Chemical Characterization of a Suite of Antarctic Diogenites

The origin of diogenites, ultramafic cumulates related to eucrites, is an unresolved problem [1]. Most diogenites are orthopyroxenites, a few are harzburgites [2], and some are transitional to cumulate eucrites [1, 3]. Cumulate eucrites are gabbros formed by crystal fractionation from basaltic eucrites [4]. The consensus view is that basaltic eucrites are residual melts from global-magma-ocean crystallization on their parent asteroid [4] which is plausibly Vesta [5]. However, the petrologic and compositional characteristics of diogenites seem to preclude a magma ocean origin [1, 4]. We are doing a petrologic and chemical study of new or unusual diogenites with the ultimate goals of constraining their genesis, and the geologic evolution of Vesta.

Mittlefehldt, D. W.↗
NASA NTRS2014

Geological Structures in the WaIls of Vestan Craters

A compelling case can be made that Vesta is the parent asteroid for the howardite, eucrite and diogenite (HED) meteorites [1], although this interpretation has been questioned [2]. Generalized models for the structure of the crust of Vesta have been developed based on petrologic studies of basaltic eucrites, cumulate eucrites and diogenites. These models use inferred cooling rates for different types of HEDs and compositional variations within the clan to posit that the lower crust is dominantly diogenitic in character, cumulate eucrites occur deep in the upper crust, and basaltic eucrites dominate the higher levels of the upper crust [3-5]. These models lack fine-scale resolution and thus do not allow for detailed predictions of crustal structure. Geophysical models predict dike and sill intrusions ought to be present, but their widths may be quite small [6]. The northern hemisphere of Vesta is heavily cratered, and the southern hemisphere is dominated by two 400-500 km diameter basins that excavated deep into the crust [7-8]. Physical modeling of regolith formation on 300 km diameter asteroids predicts that debris layers would reach a few km in thickness, while on asteroids of Vesta's diameter regolith thicknesses would be less [9]. This agrees well with the estimated ≤1 km thickness of local debris excavated by a 45 km diameter vestan crater [10]. Large craters and basins may have punched through the regolith/megaregolith and exposed primary vestan crustal structures. We will use Dawn Framing Camera (FC) [11] images and color ratio maps from the High Altitude and Low Altitude Mapping Orbits (HAMO, ~65 m/pixel; LAMO, ~20 m/pixel) to evaluate structures exposed on the walls of craters: two examples are discussed here.

Mittlefehldt, David↗
NASA NTRS2014

Petrology and Geochemistry of Unbrecciated Harzburgitic Diogenite MIL 07001: A Window Into Vestan Geological Evolution

There is a strong case that asteroid 4 Vesta is the parent of the howardite, eucrite and diogenite (HED) meteorites. Models developed for the geological evolution of Vesta can satisfy the compositions of basaltic eucrites that dominate in the upper crust. The bulk compositional characteristics of diogenites - cumulate harzburgites and orthopyroxenites from the lower crust - do not fit into global magma ocean models that can describe the compositions of basaltic and cumulate eucrites. Recent more detailed formation models do make provision for a more complicated origin for diogenites, but this model has yet to be completely vetted. Compositional studies of bulk samples has led to the hypothesis that many diogenites were formed late by interaction of their parent melts with a eucritic crust, but those observations may alternatively be explained by subsolidus equilibration of trace elements between orthopyroxene and plagioclase and Ca-phosphate in the rocks. Differences in radiogenic Mg-26 content between diogenites and eucrites favors early formation of the former, not later formation. Understanding the origin of diogenites is crucial for understanding the petrologic evolution of Vesta. We have been doing coordinated studies of a suite of diogenites including petrologic investigations, bulk rock major and trace element studies, and in situ trace element analyses of orthopyroxene. Here we will focus on an especially unusual, and potentially key, diogenite, MIL 07001.

Mittlefehldt, D. W.↗
NASA NTRS1973

Uranium and thorium in achondrites.

The abundances of U and Th in 19 achondrites and two pallasite olivines have been measured by radiochemical neutron activation analysis. Brecciated eucrites are enriched relative to chondrites in both elements by factors between 10 and 20, perhaps as a result of a magmatic differentiation process. Two unbrecciated eucrites are far less enriched, possibly due to their origin as igneous cumulates. The diogenites Johnstown and Shalka contain approximately chondritic levels of U and Th, but Ellemeet is 10 times lower. The abundances in three howardites are in good agreement with those expected from major element data for a mixing model with eucrite and diogenite end members. The high O-18 basaltic achondrites Nakhla, Shergotty and Angra dos Reis have a range of U and Th abundances similar to the brecciated eucrites and howardites, but have systematically higher Th/U ratios.

Morgan, J. W.↗
NASA NTRS1981

A preliminary report on the achondrite meteorites in the 1979 U.S. Antarctic meteorite collection

Seventy-three meteorite samples were collected in Antarctica during the austral summer of 1979-80. A description is presented of the seven achondrites found among the meteorite samples. The achondrites described include an ALHA79017-polymict eucrite, an EETA79001-shergottite, an EETA79002-diogenite, an EETA79004-eucrite, an EETA79005-polymict eucrite, an EETA79006-howardite, and an EETA79011-polymict eucrite. The most exciting single aspect of the 1979 collection is undoubtedly the discovery of a new member of the shergottite group of meteorites. Sample EETA79001 is just under 8 kg and should thus provide ample material for detailed studies. In addition to the achondrites, a unique iron meteorite with abundant silicate (orthopyroxene) inclusions and a large diogenite is also discussed.

Reid, A. M.↗
NASA NTRS1986

Terrestrial Kr-81-Kr ages of Antarctic meteorites

The production rate of Ar-38 in meteorites P(38), has been determined, as a function of the sample's chemical composition, from Kr-81-Kr exposure ages of four eucrite falls. The cosmogenic Kr-78/Kr-83 ratio is used to estimate the shielding dependence of P(38). From the 'true' Ar-38 exposure ages and the apparent Kr-81-Kr exposure ages of nine Antarctic eucrite finds, terrestrial ages are calculated. They range from about 300,000 ages (Pecora Escarpment 82502) to very recent falls (Thiel Mountains 82502). Polymict eucrites from the Allan Hills (A78132, A79017, and A81009) have within the limits of error the same exposure age (15.2 x 10 to the 6th ages) and the same terrestrial age (110,000 ages). This is taken as strong evidence that these meteorites are fragments of the same fall. A similar case is the Elephant Moraine polymict eucrites A79005, A79006, and 82600 with an exposure age of 26 x 10 to the 6th ages and a terrestrial age of 180,000 ages. EETA 79004 may be different from this group because its exposure age and terrestrial age are 21 x 10 to the 6th ages and 250,000 ages, respectively. The distribution of terrestrial ages of Allan Hills meteorites is discussed. Meteorites from this blue ice field have two sources: directly deposited falls and meteorites transported to the Allen Hills inside the moving Antarctic ice sheet. During the surface residence time meteorites decompose due to weathering processes. The weathering 'half-life' is about 160,000 ages. From the different age distributions of Allan Hills and Yamato meteorites, it is concluded that meteorite concentrations of different Antarctic ice fields need different explanations.

Freundel, M.↗
NASA NTRS1987

Monticello - A glass-rich howardite

Monticello is a new howardite similar to Malvern in that it contains abundant (15 percent) glass fragments, which show a range of compositions from olivine-normative to quartz-normative. Like Kapoeta, it contains pyroxene grains that range up to highly magnesian compositions, Fs16. Because their pyroxenes are more magnesian than those occurring in diogenites, Monticello and Kapoeta are exceptions to the simple two-component mixing model in which howardites are considered to be mechanical mixtures of fragmented eucrites and diogenites. Monticello also contains clasts of what appear to be a cumulate eucrite and a noncumulate eucrite, as well as a radiating pyroxene chondrule from a chondrite. Monticello is a regolith breccia containing more evolved components than are usually considered in eucrite-diogenite genesis models. As such, it supports those models that involve reworking of a complex parent body crust rather than straightforward partial melting of primitive chondritic parent material.

Olsen, Edward J.↗
NASA NTRS1990

The Bholghati howardite - Petrography and mineral chemistry

A 10 g sample of the Bholghati howardite was disaggregated in order to separate two eucrite clasts, several small carbonaceous clasts, fragments of diogenitic pyroxene, and bulk matrix. The eucrite clasts show evidence of moderately rapid cooling from a melt, followed by prolonged subsolidus annealing. The carbonaceous clasts mostly resemble CM2 carbonaceous chondrites with low-iron silicates and Fe-Ni sulphides in a fine grained dark matrix. One clast, however, is mineralogically, petrographically, and compositionally similar to a CI1 chondrite. Both carbonaceous and eucritic clasts have a complex history prior to incorporation into the howardite matrix with no evidence of significant metamorphism since assembly. Most clasts in the howardite breccia are monomineralic, with pyroxene and plagioclase predominant. Pyroxenes range from 'diogenitic' to 'eucritic' with diogenitic compositions most abundant; a significant number of intermediate compositions are present, consistent with derivation from a series of rocks related by fractionation.

Reid, A. M.↗
NASA NTRS2004

Ibitira: A basaltic achondrite from a distinct parent asteroid

I have done detailed petrologic study of Ibitira, nominally classified as a basaltic eucrite. The Fe/Mn ratio of Ibitira pyroxenes with <10 mole % wollastonite component is 36.4 0.4, and is well-resolved from those of five basaltic eucrites studied for comparison; 31.2-32.2. Data for the latter completely overlap. Ibitira pyroxenes have lower Fe/Mg than the basaltic eucrite pyroxenes. Thus, the higher Fe/Mn ratio does not reflect a simple difference in oxidation state. Ibitira also has an oxygen isotopic composition, alkali element contents and a Ti/Hf ratio that distinguish it from basaltic eucrites. These differences support derivation from a distinct parent asteroid. Ibitira is the first recognized representative of the fifth known asteroidal basaltic crust.

Mittlefehldt, David W.↗
NASA NTRS2011

Fluid-Mediated Alteration on 4 Vesta - Evidence from Orthopyroxene Clasts in Howardites

The howardite, eucrite and diogenite (HED) meteorites represent the products of igneous processes and impact mixing on a differentiated asteroid. Eucrites are basaltic composition rocks that were formed as flows and as shallow and deep intrusive bodies. Some eucrites are cumulate gabbros. Diogenites are cumulate orthopyroxenites widely considered to be of deep crustal origin. Impact processes have excavated material from deep levels of the crust, and mixed it with surface rocks into a suite of polymict breccias. Howardites are one such rock type, being composed mostly of mixtures of clasts and mineral fragments of eucritic and diogenitic parentage [see 1]. The consensus view is that 4 Vesta is the parent asteroid of HED meteorites [2]. As part of a larger study of the record of impact mixing contained within howardites, we undertook an investigation of the compositions of orthopyroxene clasts in a suite of howardites [3]. We discovered a subset of orthopyroxene clasts in some howardites with unusual textural and compositional characteristics that are reminiscent of those previously observed in phenocrysts in a pyroxene-phyric melt clast in howardite EET 92014 [4]. The textural and compositional characteristics of the phenocrysts in this clast were interpreted as originating via interaction with an FeO-rich fluid phase.

Mittlefehldt, Daid W.↗
NASA NTRS2011

The Regolith of 4 Vesta - Inferences from Howardites

Asteroid 4 Vesta is quite likely the parent asteroid of the howardite, eucrite and diogenite meteorites - the HED clan. Eucrites and diogenites are the products of igneous processes; the former are basaltic composition rocks from flows, and shallow and deep intrusive bodies, whilst the latter are cumulate orthopyroxenites thought to have formed deep in the crust. Impact processes have excavated these materials and mixed them into a suite of polymict breccias. Howardites are polymict breccias composed mostly of clasts and mineral fragments of eucritic and diogenitic parentage, with neither end-member comprising more than 90% of the rock. Early work interpreted howardites as representing the lithified regolith of their parent asteroid. Recently, howardites have been divided into two subtypes; fragmental howardites, being a type of non-regolithic polymict breccia, and regolithic howardites, being lithified remnants of the active regolith of 4 Vesta. We are in the thralls of a collaborative investigation of the record of impact mixing contained within howardites, which includes studies of their mineralogy, petrology, bulk rock compositions, and bulk rock and clast noble gas contents. One goal of our investigation is to test the hypothesis that some howardites represent breccias formed from an ancient, well-mixed regolith on Vesta. Another is to use our results to further understand regolith processing on differentiated asteroids as compared to what has been learned from the Moon. We have made petrographic observations and electron microprobe analyses on 21 howardites and 3 polymict eucrites. We have done bulk rock analyses using X-ray fluorescence spectrometry and are completing inductively coupled plasma mass spectrometry analyses. Here, we discuss our petrologic and bulk compositional results in the context of regolith formation. Companion presentations describe the noble gas results and compositional studies of low-Ca pyroxene clasts.

Mittlefehldt, D. W.↗
NASA NTRS2012

The Vestal Cataclysm

The currently operating Dawn mission shows asteroid 4 Vesta to be an extensively cratered body, with craters in a variety of morphologies and preservation states The crater size-frequency distribution for Vesta, modeled using the lunar chronology and scaled to impact frequencies modeled for Vesta, shows that both the north and south pole areas are ancient in age [1]. We have in our meteorite collection products from 4 Vesta in the form of the HED (howardite, eucrite, diogenite) meteorites. The HED parent body globally differentiated and fully crystallized by approx.4.56 Ga; subsequently, the eucrites were brecciated and heated by large impacts into the parent body surface, reflected in their disturbance ages [2, 3]. Dawn images have also shown that Vesta is covered with a well-developed regolith that is spectrally similar to howardite meteorites [4, 5]. Howardites are polymict regolith breccias made up mostly of clasts of eucrites and diogenites, but which also contain clasts formed by impact into the regolith. Impact-melt clast ages from howardites extend our knowledge of the impact history of Vesta, expanding on eucrite disturbance ages and helping give absolute age context to the observed crater-counts on Vesta.

Cohen, Barbara A.↗
NASA NTRS2014

Geologic History of Asteroid 4 Vesta

Some types of meteorites - most irons, stony irons, some achondrites - hail from asteroids that were heated to the point where magmatism occurred within a very few million years of the formation of the earliest solids in the solar system. The largest clan of achondrites, the howardite, eucrite and diogenite (HED) meteorites, represent the crust of their parent asteroid]. Diogenites are cumulate harzburgites and orthopyroxenites from the lower crust whilst eucrites are basalts, diabases and cumulate gabbros from the upper crust. Howardites are impact-engendered breccias mostly of diogenites and eucrites. There remains only one large asteroid with a basaltic crust, 4 Vesta, which is thought to be the source of the HED clan. Differentiation models for Vesta are based on HED compositions. Proto-Vesta consisted of chondritic materials containing Al-26, a potent, short-lived heat source. Inferences from compositional data are that Vesta was melted to high degree (≥50%) allowing homogenization of the silicate phase and separation of a metallic core. Convection of the silicate magma ocean allowed equilibrium crystallization, forming a harzburgitic mantle. After convective lockup occurred, melt collected between the mantle and the cool thermal boundary layer and underwent fractional crystallization forming an orthopyroxene-rich (diogenite) lower crust. The initial thermal boundary layer of chondritic material was replaced by a mafic upper crust through impact disruption and foundering. The mafic crust thickened over time as additional residual magma intrudes and penetrates the mafic crust forming plutons, dikes, sills and flows of cumulate and basaltic eucrite composition. This magmatic history may have taken only 2-3 Myr. This magma ocean scenario is at odds with a model of heat and magma transport that indicates that small degrees of melt would be rapidly expelled from source regions, precluding development of a magma ocean. Constraints from radiogenic Mg-26 distibutions suggest that the parent asteroid of HEDs was much smaller than Vesta. Thus, first-order questions regarding asteroid differentiation remain.

Mittlefehldt, David W.↗