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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1974

Processings of the Workshop on Electron Contamination in X-Ray Astronomy Experiments

The proceedings of a conference to investigate the effects of extraterrestrial radiation and particle contamination of X-ray astronomical data are presented. The subjects discussed include the following: (1) electrons at low altitudes which affect soft X-ray astronomy, (2) the geographical distribution of 100 keV electrons above the earth's atmosphere, (3) midlatitude electron precipitation, (4) particle background observed by X-ray detectors on board Copernicus satellite, and (5) a survey of trapped low energy electrons near the inner boundary of the inner radiation zone as determined by OSO-7.

Holt, S. S.↗
NASA NTRS1985

Signal processing in SETI

It is believed that the Galaxy might contain ten billion potential life sites. In view of the physical inaccessibility of extraterrestrial life on account of the vast distances involved, a logical first step in a search for extraterrestrial intelligence (SETI) appears to be an attempt to detect signals already being radiated. The characteristics of the signals to be expected are discussed together with the search strategy of a NASA program. It is pointed out that all presently planned searches will use existing radio-astronomy antennas. If no extraterrestrial intelligence signals are discovered, society will have to decide whether SETI justifies a dedicated facility of much greater collecting area. Attention is given to a multichannel spectrum analyzer, CW signal detection, pulse detection, the pattern detector, and details of SETI system operation.

Cullers, D. K.↗
NASA NTRS2005

Intensive Titan exploration begins

The Cassini Orbiter spacecraft first skimmed through the tenuous upper atmosphere of Titan on 26 October 2004. This moon of Saturn is unique in our solar system, with a dense nitrogen atmosphere that is cold enough in places to rain methane, the feedstock for the atmospheric chemistry that produces hydrocarbons, nitrile compounds, and Titan's orange haze. The data returned from this flyby supply new information on the magnetic field and plasma environment around Titan, expose new facets of the dynamics and chemistry of Titan's atmosphere, and provide the first glimpses of what appears to be a complex, fluid-processed, geologically young Titan surface.

Spacecraft↗
NASA NTRS1989

Radio frequency interference at Jodrell Bank Observatory within the protected 21 cm band

Radio frequency interference (RFI) will provide one of the most difficult challenges to systematic Searches for Extraterrestrial Intelligence (SETI) at microwave frequencies. The SETI-specific equipment is being optimized for the detection of signals generated by a technology rather than those generated by natural processes in the universe. If this equipment performs as expected, then it will inevitably detect many signals originating from terrestrial technology. If these terrestrial signals are too numerous and/or strong, the equipment will effectively be blinded to the (presumably) weaker extraterrestrial signals being sought. It is very difficult to assess how much of a problem RFI will actually represent to future observations, without employing the equipment and beginning the search. In 1983 a very high resolution spectrometer was placed at the Nuffield Radio Astronomy Laboratories at Jodrell Bank, England. This equipment permitted an investigation of the interference environment at Jodrell Bank, at that epoch, and at frequencies within the 21 cm band. This band was chosen because it has long been "protected" by international agreement; no transmitters should have been operating at those frequencies. The data collected at Jodrell Bank were expected to serve as a "best case" interference scenario and provide the minimum design requirements for SETI equipment that must function in the real and noisy environment. This paper describes the data collection and analysis along with some preliminary conclusions concerning the nature of the interference environment at Jodrell Bank.

NASA Discipline Number 52-60↗
NASA NTRS2004

AsterAnts: A Concept for Large-Scale Meteoroid Return and Processing using the International Space Station

AsterAnts is a concept calling for a fleet of solar sail powered spacecraft to retrieve large numbers of small (1/2-1 meter diameter) Near Earth Objects (NEOs) for orbital processing. AsterAnts could use the International Space Station (ISS) for NEO processing, solar sail construction, and to test NEO capture hardware. Solar sails constructed on orbit are expected to have substantially better performance than their ground built counterparts [Wright 1992]. Furthermore, solar sails may be used to hold geosynchronous communication satellites out-of-plane [Forward 1981] increasing the total number of slots by at least a factor of three. potentially generating $2 billion worth of orbital real estate over North America alone. NEOs are believed to contain large quantities of water, carbon, other life-support materials and metals. Thus. with proper processing, NEO materials could in principle be used to resupply the ISS, produce rocket propellant, manufacture tools, and build additional ISS working space. Unlike proposals requiring massive facilities, such as lunar bases, before returning any extraterrestrial larger than a typical inter-planetary mission. Furthermore, AsterAnts could be scaled up to deliver large amounts of material by building many copies of the same spacecraft, thereby achieving manufacturing economies of scale. Because AsterAnts would capture NEOs whole, NEO composition details, which are generally poorly characterized, are relatively unimportant and no complex extraction equipment is necessary. In combination with a materials processing facility at the ISS, AsterAnts might inaugurate an era of large-scale orbital construction using extraterrestrial materials.

Globus, Al↗
NASA NTRS1990

Advanced engineering software for in-space assembly and manned planetary spacecraft

Meeting the objectives of the Lunar/Mars initiative to establish safe and cost-effective extraterrestrial bases requires an integrated software/hardware approach to operational definitions and systems implementation. This paper begins this process by taking a 'software-first' approach to systems design, for implementing specific mission scenarios in the domains of in-space assembly and operations of the manned Mars spacecraft. The technological barriers facing implementation of robust operational systems within these two domains are discussed, and preliminary software requirements and architectures that resolve these barriers are provided.

Delaquil, Donald↗
NASA NTRS2003

CO2 Acquisition Membrane (CAM)

The objective of CAM is to develop, test, and analyze thin film membrane materials for separation and purification of carbon dioxide (CO2) from mixtures of gases, such as those found in the Martian atmosphere. The membranes are targeted toward In Situ Resource Utilization (ISRU) applications that will operate in extraterrestrial environments and support future unmanned and human space missions. A primary application is the Sabatier Electrolysis process that uses Mars atmosphere CO2 as raw material for producing water, oxygen, and methane for rocket fuel and habitat support. Other applications include use as an inlet filter to collect and concentrate Mars atmospheric argon and nitrogen gases for habitat pressurization, and to remove CO2 from breathing gases in Closed Environment Life Support Systems (CELSS). CAM membrane materials include crystalline faujasite (FAU) zeolite and rubbery polymers such as silicone rubber (PDMS) that have been shown in the literature and via molecular simulation to favor adsorption and permeation of CO2 over nitrogen and argon. Pure gas permeation tests using commercial PDMS membranes have shown that both CO2 permeance and the separation factor relative to other gases increase as the temperature decreases, and low (Delta)P(Sub CO2) favors higher separation factors. The ideal CO2/N2 separation factor increases from 7.5 to 17.5 as temperature decreases from 22 C to -30 C. For gas mixtures containing CO2, N2, and Ar, plasticization decreased the separation factors from 4.5 to 6 over the same temperature range. We currently synthesize and test our own Na(+) FAU zeolite membranes using standard formulations and secondary growth methods on porous alumina. Preliminary tests with a Na(+) FAU membrane at 22 C show a He/SF6 ideal separation factor of 62, exceeding the Knudsen diffusion selectivity by an order of magnitude. This shows that the membrane is relatively free from large defects and associated non-selective (viscous flow) transport mechanisms. The Membrane Test Facility (MTF) has been developed to measure membrane permeance over a wide range of temperature and pressure. The facility uses two volume compartments separated by the membrane that are instrumented to measure temperature, delta pressure across the membrane, and gas composition. A thermal shroud supports and encloses the membrane, and provides temperature control. Methods were developed to determine membrane permeance using the first order decay of the pressure difference between the sealed compartments, using the total pressure for pure gases, and partial pressure of each species in gas mixtures. The technique provides an end-to-end measurement of gas permeance that includes concentration polarization effects. Experiments have shown that in addition to membrane permeance properties, the geometry and design of associated structures play an important role in how membrane systems will function on Mars.

Mason, Larry W.↗
NASA NTRS2014

A Super-Resolution Algorithm for Enhancement of FLASH LIDAR Data: Flight Test Results

This paper describes the results of a 3D super-resolution algorithm applied to the range data obtained from a recent Flash Lidar helicopter flight test. The flight test was conducted by the NASA's Autonomous Landing and Hazard Avoidance Technology (ALHAT) project over a simulated lunar terrain facility at NASA Kennedy Space Center. ALHAT is developing the technology for safe autonomous landing on the surface of celestial bodies: Moon, Mars, asteroids. One of the test objectives was to verify the ability of 3D super-resolution technique to generate high resolution digital elevation models (DEMs) and to determine time resolved relative positions and orientations of the vehicle. 3D super-resolution algorithm was developed earlier and tested in computational modeling, and laboratory experiments, and in a few dynamic experiments using a moving truck. Prior to the helicopter flight test campaign, a 100mX100m hazard field was constructed having most of the relevant extraterrestrial hazard: slopes, rocks, and craters with different sizes. Data were collected during the flight and then processed by the super-resolution code. The detailed DEM of the hazard field was constructed using independent measurement to be used for comparison. ALHAT navigation system data were used to verify abilities of super-resolution method to provide accurate relative navigation information. Namely, the 6 degree of freedom state vector of the instrument as a function of time was restored from super-resolution data. The results of comparisons show that the super-resolution method can construct high quality DEMs and allows for identifying hazards like rocks and craters within the accordance of ALHAT requirements.

Bulyshev, Alexander↗
NASA NTRS1991

Theoretical studies of the extraterrestrial chemistry of biogenic elements and compounds

Organic compounds, molecules related to those in living systems, are found in many different extraterrestrial environments. The study of organic astrochemistry is important to exobiology both because it demonstrates the ubiquity of processes which led to life on Earth and because the dust clouds where molecules are found are analogs of the solar nebula from which the Earth formed. In the long chain of events leading from the Big Bang, and a universe composed of atomic hydrogen and helium, to the emergence of life on Earth, molecular interstellar clouds are an early link, the most primitive objects which display any significant organic chemistry. One such cloud was the direct precursor to the solar system and to all objects which it contains. Theoretical methods are ideally suited to studying interstellar cloud chemistry. They have been applied to determine spectroscopic constants of candidate interstellar molecules, mechanisms of ion-molecule reactions, and composition of dust grains. Accurate predictions of rotational constants and dipole moments of long-chain carbon molecules HC13N, HC15N, and C5O have been made to aid in determining the size limit of gas-phase interstellar molecules. Models of gas-phase interstellar chemistry use reaction rate constants measured at room temperature and extrapolated to interstellar temperatures. The temperature dependence of NH3(+)+H2 yields NH4(+)+H is anomalous, however, with a minimum rate at about 100K, casting doubt on the extrapolation procedures. The temperature dependence has now been explained.

Defrees, D. J.↗
NASA NTRSDate not supplied

The ExCALiBR Instrument for Lipid-Based Life Detection on Mars

Lipids are key molecular targets to search for evidence of life, as they can reveal information about life processes and their chemical origins (Georgiou and Deamer, 2014). Essential for terrestrial life and likely required for putative extraterrestrial organisms, lipids make up the membranes that separate cell contents from an external environment. They are well preserved in the geologic record, some recording the activity of organisms that lived over a billion years ago (Eigenbrode, 2008), an order of magnitude longer than other types of molecular biosignatures. Lipids are also synthesized abiotically, making up ~60% of soluble organics detected in carbonaceous chondrite meteorites (Sephton, 2005). However, there are numerous challenges to the successful detection of relevant lipids in situ, including interference by inorganics, molecular complexity of the lipids, limitations on their solubility, and low lipid abundance

M. B. Wilhelm↗
NASA NTRS1993

Horizontal stresses induced by vertical processes in planetary lithospheres

Understanding the state of stress in the elastic lithosphere is of fundamental importance for planetary geophysics, as it is the link between the observed geologic structures on the surface and the processes which form and modify these structures. As such, it can provide valuable constraints for the difficult problem of determining interior structure and processes. On the Earth, most large scale, organized deformation can be related to lateral tectonics associated with plate dynamics; however, the tectonics on many extraterrestrial bodies (such as the Moon, Mars, and most of the outer-planet satellites) appears to be primarily vertical in nature, and the horizontal stresses induced by vertical motions and loads are expected to dominate the deformation of their lithospheres. The largest stress contributions from vertical loading come from the flexure of the lithosphere, which induces both bending moments and membrane stresses. We are concerned here only with nonflexural changes in the state of stress induced by processes such as sedimentary and volcanic deposition, erosional denudation, and changes in the thermal gradient that induce uplift or subsidence. This analysis is important both for evaluating stresses for specific regions in which the vertical stress history can be estimated, as well as for applying the proper loading conditions to global stress models. It is also of interest for providing a reference state of stress for interpreting stress measurements in the crust of the Earth.

Banerdt, W. B.↗
NASA NTRS2012

Metals and Oxygen Mining from Meteorites, Asteroids and Planets using Reusable Ionic Liquids

In order for humans to explore beyond Low Earth Orbit both safely and economically, it will be essential to learn how to make use of in situ materials and energy in an environment much different than on earth. Precursor robotic missions will be necessary to determine what resources will be available and to demonstrate the capabilities for their use. To that end, we have recently been studying acidic Ionic Liquid (IL) systems for use in a low temperature (< 200 C) process to solubilize regolith, and to extract, as water, the oxygen available in metal oxides. Using this method, we have solubilized lunar regolith simulant (JSC-1A), as well as extraterrestrial materials in the form of meteorites, and have extracted up to 80% of the available oxygen. Moreover, by using a hydrogen gas electrode, we have shown that the IL can be regenerated at the anode and metals (e.g. iron) can be plated onto the cathode. These results indicate that IL processing is an excellent candidate for extracting oxygen in situ, for life support and propulsion, and for extracting metals to be used as feedstock in fabrication processes. We have obtained small amounts of meteorite materials believed by meteoriticists to have originated from our moon, Mars, and the asteroid Vesta, and were able to solubilize those using acidic IL systems. From the Vesta meteorite, we were able to extract about 60% of the available oxygen as water. As far as is known, this is the first time that extraterrestrial/earth hybrid water has been obtained. NMR analysis provided proof that the liquid retrieved is indeed water. We have also been able to electro-plate nickel and iron contained in meteorite material. By varying voltage they can be plated separately (electro-winning), and we plan to soon have sufficient quantities to form usable parts utilizing the additive manufacturing process.

Karr, Laurel J.↗
NASA NTRS1984

Applicability of La-Ce systematics to planetary samples

Cesium isotopic compositions in several terrestrial and extraterrestrial materials were determined in order to investigate the applicability of using Ce as an isotropic tracer to geological processes. A tenuous anticorrelation was observed between (epsilon)Ce and (epsilon)Nd for terrestrial basalts and granites, indicating that with some improvement in analytical techniques the Ce isotopic composition may prove useful as tracer for geological processes. A very low (epsilon)Ce predicted from the Ce anomaly in the REE pattern of the Kholar L3 chondrite was not observed, indicating that the anomaly may be caused by terrestrial contamination or alteration.

Nakamura, N.↗
NASA NTRS1986

Cooperation of catalysts and templates

In order to understand how self-reproducing molecules could have originated on the primitive Earth or extraterrestrial bodies, it would be useful to find laboratory models of simple molecules which are able to carry out processes of catalysis and templating. Furthermore, it may be anticipated that systems in which several components are acting cooperatively to catalyze each other's synthesis will have different behavior with respect to natural selection than those of purely replicating systems. As the major focus of this work, laboratory models are devised to study the influence of short peptide catalysts on template reactions which produce oligonucleotides or additional peptides. Such catalysts could have been the earliest protoenzymes of selective advantage produced by replicating oligonucleotides. Since this is a complex problem, simpler systems are also studied which embody only one aspect at a time, such as peptide formation with and without a template, peptide catalysis of nontemplated peptide synthesis, and model reactions for replication of the type pioneered by Orgel.

White, D. H.↗
NASA NTRS1991

Oxygen plant breadboard design, and techniques for improving mission figure-of-merit

A breadboard oxygen plant to process anaerobic carbon dioxide is designed and constructed; the objective is not only to produce a key propellant component extraterrestrially, but also to develop the important technologies that are necessary for a successful operation of in-situ materials utilization hardware. The solid electrolytic cells are supplied to specifications by an established vendor. The cell thermal control, electrical control, and flow control are installed after detailed designs. Extensive data are obtained that characterize the operation of the plant as the input parameters are varied. The initial mass, energy, and volume-needs provide the input to a figure-of-merit software program to calculate the impact of various candidate technologies upon the overall mission. The desirability of studies on storage and high-density propellants is shown. This task dovetails into other tasks that are evaluating alternative cell materials, catalysis for compactness, and smart sensors for effective control.

Ramohalli, Kumar↗
NASA NTRSDate not supplied

The Search for Chiral Asymmetry as a Potential Biosignature in Samples from Mars

The search for evidence of extraterrestrial life in our solar system has been guided by our under-standing of terrestrial biology and its associated biosignatures. The observed homochirality in all life on Earth, that is, the predominance of “left-handed” or L-amino acids and “right-handed” or D-sugars, is a unique property of life that is crucial for molecular recognition, enzymatic function, information storage and structure, and is thought to be a prerequisite for the origin or early evolution of life. Therefore, the detection of L- or D-excesses of chiral amino acids or sugars could be a powerful indicator of extant or extinct life on Mars or other habitable environments in our solar system. However, studies of primitive meteorites have revealed that they contain extraterrestrial amino acids and sugar acids with large enantiomeric excesses (60% and higher) that resulted from non-biological processes [1], complicating the use of chiral asymmetry by itself as a definitive biosignature. The exploration of habitable environments on Mars, including an assessment of the preservation potential for complex organics of either abiotic or biological origin, is an objective of both current and future Mars missions. Now with the unambiguous detection of indigenous organic matter in sedimentary rocks by the Sample Analysis at Mars (SAM) instrument suite on Mars [2-5], NASA’s Curiosity rover has found evidence of the preservation of potential chemical biosignatures in the martian near surface. Although amino acids have not yet been identified by in situ measurements on Mars [5], indigenous achiral amino acids have been identified in one martian meteorite [6]. It is expected that amino acid racemization would be very slow and any chiral or isotopic signatures from an extinct martian biota could be preserved for billions of years, given the extremely cold and dry surface conditions [7]. The ESA/Roscosmos ExoMars mission scheduled for launch next year includes the Rosalind Franklin rover designed to acquire samples from a depth of ~2 m and deliver them to a suite of instruments, including the Mars Organic Molecule Analyzer (MOMA). The MOMA instrument contains a wet chemistry experiment designed specifically for the detection of amino acids and measurement of their enantiomeric compositions [8]. The complexity and limited duration of spaceflight operations, and the known analytical challenges associated with in situ extraction and characterization of trace reduced organic com-pounds in ancient rocks, make it challenging to determine the origins of martian organic matter found to date. Coordinated state-of-the-art laboratory measurements of returned samples from Mars that include spatially resolved chemical, mineralogical, bulk and molecule-specific isotopic, and enantiomeric measurements will be required to firmly establish whether the complex organic matter detected on Mars derives from bio-tic or abiotic processes. Ultimately, Mars Sample Return of rock cores collected by NASA’s Perseverance rover may be our best chance of identifying chemical biosignatures, including any chiral amino acid asymmetry resulting from a past or present martian biota, if one ever existed on Mars. Here we review our current knowledge of the distributions, and enantiomeric and isotopic com-positions of amino acids found in meteorites compared to terrestrial biochemistry. We also propose a set of measurement criteria that should be used to help establish the sources of any amino acids detected in samples returned from Mars using state-of-the-art gas and liquid chromatography mass spectrometry techniques [1].

D P Glavin↗