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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Experimental and Modeling Investigation of Overcooling Transients that Include Freezing, in Fluoride-Salt Cooled High-Temperature Reactors (FHRs). Final Report

The goal of this project was an experimental and modeling investigation of overcooling transients that include freezing in Fluoride-Salt Cooled High-Temperature Reactors (FHRs). The most impactful product of this research collaboration between Professor Scarlat’s group at UW Madison and subsequently at UC Berkeley, and Dr. Rui Hu’s group at Argonne National Laboratory was the initial demonstration of SAM application to FHR transients, and the generation of a freezing module for the SAM code. The national laboratory and industry graduate student internships enabled by this project were valuable for workforce development, and also for knowledge transfer between university, national lab, and industry.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2021

Melting and Re-Freezing Leads to Irreversible Changes in the Morphology and Molecular-Level Dynamics of Pfizer-BioNTech COVID-19 Vaccine

As an mRNA-based vaccine, the Pfizer-BioNTech COVID-19 vaccine has stringent cold storage requirements to preserve functionality of the mRNA active ingredient. To this end, lipid components of the vaccine formulation play an important role in stabilizing and protecting the mRNA molecule for long-term storage. The purpose of the current study was to measure molecular-level dynamics as a function of temperature in the Pfizer-BioNTech COVID-19 vaccine to gain microscopic insight into its thermal stability. Materials and Methods: We used quasielastic and inelastic neutron scattering to probe (1) the vaccine extracted from the manufacturer-supplied vials and (2) unperturbed vaccine in the original manufacturer-supplied vials. The latter measurement was possible due to the high penetrative power of neutrons. Upon warming from the low-temperature frozen state, the vaccine in its original form exhibits two-step melting, indicative of a two-phase morphology. Once the melting is completed (above 0 °C), vaccine re-freezing cannot restore its original two-phase state. This observation is corroborated by the changes in the molecular vibrational spectra. The molecular-level mobility measured in the resulting single-phase state of the re-frozen vaccine greatly exceeds the mobility measured in the original vaccine. Even a brief melting (above 0 °C) leads to an irreversible alteration of the two-phase morphology of the original vaccine formulation. Re-freezing of the vaccine results in a one-phase morphology with much increased molecular-level mobility compared to that in the original vaccine, suggesting irreversible deterioration of the vaccine’s in-storage stability. Neutron scattering can be used to distinguish between the vibrational spectra characteristic of the original and deteriorated vaccines contained in the unperturbed original manufacturer-supplied vials.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2021

ARM Data for Examining the Ice-Nucleating Particles from SGP Part II (ExINP-SGP II) Cryogenic Refrigerator Applied to Freezing Test

Knowledge of airborne particulate matter (PM), especially the particles that have supermicron diameters, is key for understanding ice-nucleating particles (INPs). Supported by the Atmospheric Radiation Measurement (ARM) user facility, we sampled PM and surface soil materials at the Southern Great Plains observatory (SGP; 36° 36′ 18″ N, 97° 29′ 6″ W) to systematically compare the INP abundance and ice nucleation efficiency of different SGP samples (i.e., airborne versus surface materials). The field campaign, named Examing INP from SGP II (ExINP-SGP II), was conducted from 20 January to 20 April, 2021. Our data analysis products include (1) physical surface sorption characterization data (i.e., BET, pore volume) of two sets of samples -- SGP Soil and USDA, (2) X-ray diffraction spectra for the same two samples, (3) immersion freezing assay-based ice nucleation active mass density data as a function of freezing temperature for both ambient and surface samples, and (4) time-series data of ambient meteorological conditions, concentration particle counter-derived aerosol particle concentration, and aerosol particle sizer measurement during ExINP-SGP II.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1970

Development of freeze dried vegetables

The development of freeze dried vegetables to be used in the Apollo food system is discussed. After the initial selection and screening of vegetables, several types of freeze dried vegetables were prepared in small batches. From these small batches, two vegetables were judged satisfactory for further testing and evaluation. These vegetables, mashed potatoes and asparagus, were subjected to storage at 100 deg plus or minus 5 F. for two weeks and then taste tested. The vegetables were also tested to determine if they complied with the microbiological requirements for Apollo food. The space food prototype production guide for the vegetables is submitted.

Larson, R. W.↗
NASA NTRS1973

Preservation of flavor in freeze dried green beans

Before freeze drying, green beans are heated to point at which their cell structure is altered. Beans freeze dried with altered cell structure have improved rehydration properties and retain color, flavor, and texture.

Huber, C. S.↗
NASA NTRS1979

High freezing point fuels used for aviation turbine engines

Broadened-specification aviation fuels could be produced from a greater fraction of crude source material with improvements in fuel supply and price. These fuels, particularly those with increased final boiling temperatures, would have higher freezing temperatures than current aviation turbine fuels. For the small but significant fraction of commercial flights where low fuel temperatures make higher freezing-point fuel use unacceptable, adaptations to the fuel or fuel system may be made to accommodate this fuel. Several techniques are discussed. Fuel heating is the most promising concept. One simple design uses existing heat rejection from the fuel-lubricating oil cooler, another uses an engine-driven generator for electrical heating.

Friedman, R.↗
NASA NTRS1979

Future freeze forecasting

Real time GOES thermal data acquisition, an energy balance minimum temperature prediction model and a statistical model are incorporated into a minicomputer system. These components make up the operational "Satellite Freeze Forecast System" being used to aid NOAA, NWS forecasters in developing their freeze forecasts. The general concept of the system is presented in this paper. Specific detailed aspects of the system can be found in the reference cited.

Bartholic, J. F.↗
NASA NTRS1951

Flight Instrument for Measurement of Liquid-Water Content in Clouds at Temperatures Above and Below Freezing

A principle formerly used in an instrument for cloud detection was further investigated to provide a simple and rapid means for measuring the liquid-water content of clouds at temperatures above and below freezing. The instrument consists of a small cylindrical element so operated at high surface temperatures that the impingement of cloud droplets creates a significant drop in the surface temperature. ? The instrument is sensitive to a wide range of liquid-water content and was calibrated at one set of fixed conditions against rotating multicylinder measurements. The limited conditions of the calibration Included an air temperature of 20 F, an air velocity of 175 miles per hour, and a surface temperature in clear air of 475 F. The results obtained from experiments conducted with the instrument indicate that the principle can be used for measurements in clouds at temperatures above and below freezing. Calibrations for ranges of airspeed, air temperature, and air density will be necessary to adapt the Instrument for general flight use.

Perkins, Porter J.↗
NASA NTRS1981

AgRISTARS: Early warning and crop condition assessment. Plant cover, soil temperature, freeze, water stress, and evapotranspiration conditions

Emissive (10.5 to 12.5 microns) and reflective (0.55 to 1.1 microns) data for ten day scenes and infrared data for six night scenes of southern Texas were analyzed for plant cover, soil temperature, freeze, water stress, and evapotranspiration. Heat capacity mapping mission radiometric temperatures were: within 2 C of dewpoint temperatures, significantly correlated with variables important in evapotranspiration, and related to freeze severity and planting depth soil temperatures.

Wiegand, C. L.↗
NASA NTRS1983

Influence of freezing rate changes of MnBi-Bi eutectic microstructure

In an attempt to explain the influence of space processing on the microstructure of MnBi-Bi, eutectic mixtures were directionally solidified with a sudden change of translation rate. The MnBi fiber spacing was able to adapt to the changing freezing rate as predicted by heat transfer computations. Thus the microstructure adapts more rapidly than the freezing rate could be changed in the present experiments.

Wilcox, W. R.↗
NASA NTRS1985

Rapid Freezing-Point Measurement

Technique developed for rapid determination of freezing-point temperature of fuels. Technique determines freezing point in under 10 minutes and is suitable for use in design of portable device.

Mathiprakasam, B.↗
NASA NTRS1989

Cirrus crystal nucleation by homogeneous freezing of solution droplets

A numerical model consisting of a system of differential equations is used to study cirrus crystal nucleation in a rising parcel containing a distribution of cloud condensation nuclei. The evolution of the particle population and the thermodynamic variables in the parcel are examined. The results suggest that, if homogeneous freezing is not considered, liquid water should be detected below -40 C. If homogeneous freezing is considered, the rapid growth of ice crystals and vapor depletion prevent water saturation from being reached. It is shown that the likelihood of a droplet being frozen is increased by lower temperatures, larger droplet diameter, or lower solution density.

Heymsfield, Andrew J.↗
NASA NTRS1990

Freeze drying for morphological control of inter-penetrating polymer networks

The intrinsic brittleness of BMI resins can be reduced through the creation of an interpenetrating network (IPN) of BMI with a reactive-encapped thermoplastic, such as the presently considered polyimidesulfone, PISO2. The PISO2 and BMI were dissolved in a common solvent, which was then removed from the constituents by freeze drying; in an alternative method, an IPN was formed through dissolution of the constituent in a common solvent with either high or low melting point, followed by evaporative removal of the solvent. The effectiveness of the freeze-drying approach for morphological control is evaluated.

Hansen, Marion G.↗
NASA NTRS1991

Spin glass freezing and superconductivity in YBa2(Cu(1-x)Fe(x))3O7 alloys

The dynamics were studied of the iron spins in superconducting YBa2(Cu(0.94)Fe(0.06))3O7 by neutron time of flight measurements. Two samples were studied with slightly different characteristics, as shown by resistivity and neutron diffraction measurements. The same dynamical anomalies are observed by neutrons in both samples. Differences appear qualitative but not quantitative. In the whole temperature range, the q-dependence of the magnetic intensity mainly reflects the magnetic form factor of iron which shows that the iron spins are almost uncorrelated. The elastic and quasielastic intensities strongly vary with temperature. A spin glass like freezing is revealed at low temperature by a sharp decrease of the quasielastic intensity, an increase of the 'elastic' or resolution limited intensity and a minimum in the quasielastic width. The freezing temperature (T sub f - 18 K) corresponds to that already determined by a magnetic splitting in Mossbauer experiments. Above T sub f, the relaxation of the iron spins in the paramagnetic state is modified by the occurrence of superconductivity. An increase was observed of the quasielastic intensity and of the quasielastic width at the superconducting transition.

Mirebeau, I.↗
NASA NTRS1991

Shrinkage void formation and its effect on freeze and thaw processes of lithium and lithium-fluoride for space applications

The effects of shrinkage void forming during freezing of lithium and lithium fluoride on subsequent thaw processes are investigated using a numerical scheme that is based on a single (solid/liquid) cell approach. Results show that a void forming at the wall appreciably reduces the solid-liquid interface velocity, during both freeze and thaw, and causes a substantial rise in the wall temperature during thaw. However, in the case of Li, the maximum wall temperature was much lower than the melting temperature of PWC-11, which is used as the structure material in the SP-100 system. Hence, it is concluded that a formation of hot spots is unlikely during the startup or restart of the SP-100 system.

Yang, Jae Y.↗
NASA NTRS1993

Radar backscatter measurements from Arctic sea ice during the fall freeze-up

Radar backscatter measurements from sea ice during the fall freeze-up were performed by the United States Coast Guard Icebreaker Polar Star as a part of the International Arctic Ocean Expedition (IAOE'91) from Aug. to Sep. 1991. The U.S. portion of the experiment took place on board the Polar Star and was referred to as TRAPOLEX '91 (Transpolar expedition) by some investigators. Before prematurely aborting its mission because of mechanical failure of her port shaft, the Polar Star reached 84 deg 57 min N latitude at 35 deg E longitude. The ship was in the ice (greater than 50 percent coverage) from 14 Aug. until 3 Sep. and was operational for all but 6 days due to two instances of mechanical problems with the port shaft. The second was fatal to the ship's participation in the expedition. During the expedition, radar backscatter was measured at C-band under a variety of conditions. These included measurements from young ice types as well as from multiyear and first-/second-year sea ice during the fall freeze-up. The sea ice types were determined by measurement of the ice properties at several of the stations and by visual inspection on others. Radar backscatter measurements were performed over a large portion of the ship's transit into the Arctic ice pack. These were accompanied by in situ sea ice property characterization by the U.S. Army Cold Regions Research and Engineering Laboratory (CRREL) at several stations and, when snow was present, its properties were documented by The Microwave Group, Ottawa River (MWG).

Beaven, S.↗
NASA NTRS1993

Green icebergs formed by freezing of organic-rich seawater to the base of Antarctic ice shelves

Samples of Antarctic seawater, basal ice, and green ice from ice cliffs and green icebergs are analyzed in order to examine green icebergs formed by the freezing of organic-rich seawater to the base of Antarctic ice shelves. Spectral reflectance of a green iceberg measured near 67 deg S, 62 deg E confirms that the color is inherent in the ice, not an artifact of the illumination. A constituent that absorbs blue photons is identified by spectrophotometric analysis of core samples from this iceberg and from the Amery basal ice, and of seawater samples from Prydz Bay off the Amery Ice Shelf. Analysis of the samples by fluorescence spectroscopy indicates that the blue absorption, and hence the inherent green color, is due to the presence of marine-derived organic matter in the green iceberg, basal ice, and seawater. Thick accumulations of green ice, in icebergs, and at the base of ice shelves indicate that high concentrations of organic matter exist in seawater for centuries at the depth of basal freezing.

Warren, Stephen G.↗
NASA NTRS1993

Interferometric detection of freeze-thaw displacements of Alaskan permafrost using ERS-1 data

The possibility of making large scale (50 km) measurements of motions of the earth's surface with high resolution (10 m) and very high accuracy (1 cm) from multipass SAR interferometry was established in 1989. Other experiments have confirmed the viability and usefulness of the method. Work is underway in various groups to measure displacements from volcanic activity, seismic events, glacier motion, and in the present study, freeze-thaw cycles in Alaskan permafrost. The ground is known to move significantly in these cycles, and provided that freezing does not cause image decorrelation, it should be possible to measure both ground swelling and subsidence. The authors have obtained data from multiple passes of ERS-1 over the Toolik Lake region of northern Alaska of suitable quality for interferometry. The data are processed into images, and single interferograms are formed in the usual manner. Phase unwrapping is performed, and the multipass baselines are estimated from the images using both orbit ephemerides and scene tie points. The phases are scaled by the baseline ratio, and a double-difference interferogram (DDI) is formed. It is found that there is a residual 'saddle-shape' phase error across the image, which is postulated to be caused by a small divergence (10(exp -2) deg.) in the orbits. A simulation of a DDI from divergent orbits confirms the shape and magnitude of the error. A two-dimensional least squares fit to the error is performed, which is used to correct the DDI. The final, corrected DDI shows significant phase (altitude) changes over the period of the observation.

Werner, Charles L.↗