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At least 163 records · Page 9

Processes affecting the composition and structure of silicate grains in cometary nuclei

Characteristics which might be observed in silicate grains from a cometary nucleus are examined on the basis of theoretical studies of the life cycle of refractory grains and laboratory experiments using simple analogs to the complex natural system. The life-cycle of a typical silicate grain is reviewed from condensation in a circumstellar outflow to incorporation into a cometary parent body. The possibility for grain metamorphism in the cometary environment is discussed and results are presented from experiments on the properties of interstellar grains. Also, consideration is given to the information about presolar refractory grains that might be gained from studying samples returned from a cometary nucleus.

Nuth, Joseph A., III↗

On the interactions between large-scale structure and fine-grained turbulence in a free shear flow. II - The development of spatial interactions in the mean

The interactions between large-scale structure and fine-grained turbulence in a spatially developing mixing layer are investigated. Both a conditioned average and a time average are employed to separate the nonrandom and random fluctuations in the kinetic energy treatment of the interactions. Shape assumptions applying to the interaction integrals are adopted to obtain a solution to the closure problem. Energy-transfer mechanisms among the mean flow, the fine-grained turbulence and the large-scale structure are discussed. The magnitude of the large-scale structure and its streamwise lifetime both prove to be important in accounting for fine-grained turbulence enhancement.

Alper, A.↗

Multiscale Modeling of Grain Boundaries in ZrB2: Structure, Energetics, and Thermal Resistance

A combination of ab initio, atomistic and finite element methods (FEM) were used to investigate the structures, energetics and lattice thermal conductance of grain boundaries for the ultra high temperature ceramic ZrB2. Atomic models of idealized boundaries were relaxed using density functional theory. Information about bonding across the interfaces was determined from the electron localization function. The Kapitza conductance of larger scale versions of the boundary models were computed using non-equilibrium molecular dynamics. The interfacial thermal parameters together with single crystal thermal conductivities were used as parameters in microstructural computations. FEM meshes were constructed on top of microstructural images. From these computations, the effective thermal conductivity of the polycrystalline structure was determined.

Lawson, John W.↗

A study of the interactions between large-scale coherent structures and fine-grained turbulence in a round jet

An approximate energy integral description is used to study the development of large-scale coherent structures in the technologically important problem of the round turbulent jet. The analysis begins from the radially integrated form of the kinetic energy equations of the mean flow, the large-scale structure and the fine-grained turbulence, which are obtained by using the usual Reynolds time average and a conditional average with reference to the frequency of the idealized monochromatic component of the large-scale wavelike structure. This is the basis for obtaining the amplitude equations for the three components of the flow in terms of the mean flow momentum thickness, the large-scale structure kinetic energy and the fine-grained turbulence kinetic energy across the jet.

Mankbadi, R.↗

On the interactions between large-scale structure and fine-grained turbulence in a free shear flow. III - A numerical solution

The results of a numerical computation of the interactions between the horizontally periodic monochromatic component of a large-scale coherent structure and the fine-grained turbulence in a mixing layer are presented. In the numerical calculations, the appropriate dependent variable is one which comprises both the mean and the large-scale coherent structure. The dynamical equations obtained for such a total coherent structure quantity are identical to the unsteady equations for the mean quantities in the Reynolds sense, except that the fine-grained turbulent stresses are interpreted as being conditionally averaged. It is shown how three dimensional fine-grained turbulence can be produced indirectly from the two dimensional large-scale structure via the isotropizing process of the approximated pressure-strain correlation.

Gatski, T. B.↗

Infrared and Raman spectroscopic studies of structural variations in minerals from Apollo 11, 12, 14 and 15 samples, volume 3

Infrared and Raman vibrational spectroscopic data, yielding direct information on molecular structure, were obtained for single grains ( 150 microns) of minerals, basalts, and glasses isolated from Apollo 11, 12, 14, and 15 rock and dust samples, and for grains in Apollo 14 polished butt samples. From the vibrational data, specification substitutions were determined for the predominant silicate minerals of plagioclase, pyroxene, and olivine. Unique spectral variations for grains of K-feldspar, orthopyroxene, pyroxenoid, and ilmenite were observed to exceed the ranges of terrestrial samples, and these variations may be correlatable with formation histories. Alpha-quartz was isolated as pure single grains, in granitic grains composited with sanidine, and in unique grains that were intimately mixed with varying amounts of glass. Accessory minerals of chromite and ulvospinel were isolated as pure grains and structurally characterized from their distinctive infrared spectra. Fundamental vibrations of the SiO4 tetrahedra in silicate minerals were used to classify bulk compositions in dust sieved fractions, basalt grains and glass particles, and to compare modal characteristics for maria, highland and rille samples. No hydrated minerals were found in any of the samples studied, indicating anhydrous formation conditions.

Estep, P. A.↗

Microstructural and magnetic characterization of rapidly solidified and annealed Pt-Co-B alloys

Significant increases in intrinsic coercivity (Hic) of Pt-Co alloys have been obtained by the addition of boron and the application of rapid solidification processing. After rapid solidification by double anvil splat quenching with subsequent annealing at 650 C for 30 min, an alloy of Pt42Co45B13 exhibits an Hic as high as 14 kOe. Annealing of the Pt-Co-B influences the L1(0) superlattice structure and grain size of the matrix, the crystal structure and size of Co-boride precipitate, and the distribution of magnetic domain walls. A microstructural analysis shows that the maximum H(ic) occurs when Co borides, having the Co3B structure, are within the single magnetic domain size. The magnetic hardening mechanism in Pt-Co-B is believed to be a combination of inhibited magnetic domain nucleation and difficult reverse magnetic domain growth caused by the interaction of the magnetically anisotropic Co borides with the L1(0) Pt-Co matrix.

Qiu, N.↗

Processing and microstructure of melt spun NiAl alloys

The influence of various melt spinning parameters and the effect of consolidation on the microstructure of melt spun NiAl and NiAl + W alloys have been examined by optical and electron microscopy techniques. It was found that the addition of 0.5 at. pct W to NiAl results in a fine dispersion of W particles after melt spinning which effectively controls grain growth during annealing treatments or consolidation at temperatures between 1523 and 1723 K. Increased wheel speeds are effective at reducing both the ribbon thickness and grain size, such that proper choice of both composition and casting parameters can produce structures with grain sizes as small as 2 microns. Finally, fabrication of continuous fiber-reinforced composites which used pulverized ribbon as the matrix material was demonstrated.

Locci, I. E.↗

Increased resistance to stress corrosion of aluminum alloys

Stress corrosion resistance is increased by distorting surface grain-boundary structure and by interrupting the corrosion and stress corrosion. The first is accomplished by machining or shot peening and the second by removal from and later reexposure to the corrosive environment.

Brummer, S. B.↗

The interstellar carbon abundance toward Delta Scorpii

Observations are presented of a semiforbidden transition of C II at lambda 2325 toward Delta Scorpii. This line is intrinsically so weak that saturation and blending problems are completely absent, allowing the C II column density to be determined unambiguously. Furthermore, since C II is the dominant ionization state of carbon in H I regions, the total carbon abundance follows directly. While the detection of weak, semiforbidden interstellar lines requires high resolution and high photometric accuracy, observations of these lines promise substantial improvements concerning the knowledge of gas-phase abundances and, consequently, of the composition and structure of grains. The reported results represent the first direct evidence from absorption measurements that carbon is depleted from the interstellar gas by amounts sufficient to provide a substantial fraction of the mass of interstellar grains.

Hobbs, L. M.↗

The nature and origin of type B1 and B2 Ca-Al-rich inclusions in the Allende meteorite

The Type B Ca-Al-rich inclusions in the Allende carbonaceous chondrite form a continuous range from the mineralogically concentrically zoned B1 subtype to the unzoned B2 subtype. These subtypes differ in (1) structure, texture, grain size and shape, (2) mineralogical proportions and compositions, (3) accessory mineralogy, (4) relative abundance of spinel framboids, (5) rim layering, (6) major element chemistry, and (7) degree of secondary alteration. These differences, together with observations on the crystallization of synthetic melts, suggest that the B1 inclusions crystallized relatively rapidly from molten parental material while B2 types crystallized relatively slowly close to the solidus from material that had not been completely melted. The same data are used to construct an evaporative residue model for the origin of the parental Type B materials. In the model, dust in the protosolar nebula was heated with removal of more volatile elements, leaving completely melted (Type B1) residues at the highest temperatures and incompletely melted, less highly evaporated (Type B2) residues at lower temperatures.

Wark, D. A.↗

The interstellar medium

Observations and models of interstellar matter in the Milky Way are reviewed. The general structure of the gas layer, high velocity gas, and heavy element depletion patterns are outlined. The IUE survey of Fe and Si abundances, and the correlation of Fe and Si depletions with infrared cirrus are described. Studies of neutral hydrogen may disagree with three-phase models of the interstellar medium, dominated by supernova remnants. The effects of shock waves on interstellar medium structure, the grain population, and refractory element abundances are considered. It appears that the frequency, distribution, energy, and dynamical effects of supernovae in the galaxy may be overestimated.

Shull, J. Michael↗

Cometary memory of interstellar aluminum

It is shown that the distribution of refractory metals in a comet-nucleus drill core carries a chemical memory quite distinct from that of volatiles. Using aluminum as an example, it is demonstrated that very refractory structures, either grain cores or refractory aggregates of cores, must be much older than the volatile component. It is argued that isotopic anomalies are specifically associated with aluminum. An evolutionary model capable of rationalizing the interstellar gas depletions of Al and Mg is advocated. The distribution of Al in comets is shown to be crucial to understanding the origin of comets and of the solar system.

Clayton, Donald D.↗

The magnitude of the magnetic field near the surface of a high-T(sub c) superconductor with a trapped flux

In 1986, much excitement was caused by the discovery of a class of materials that conducted electricity with zero resistance at temperatures above the boiling temperature of liquid nitrogen. This excitement was checked by the difficulties of manufacturing ceramics and the usefulness of high temperature superconductors that were restricted by their becoming high resistive conductors at small current densities. A lack of pinning of the magnetic field flux caused the return of high resistance as the current was increased in these materials. A study of the magnetic field near the surface of a high temperature superconductor is the first step in the search for a means of pinning the flux lines and increasing their critical current densities. The author found that a comparison between the defects in the surface of the superconductor and the magnetic field showed only a change in the field near the notch and the edge. No correlation was found between the surface grain or structure and the oscillations in the magnetic field. The observed changes in the magnetic field show resonances which may give an indication of the non-flux pinning in these superconductors. A flux pinning mechanism will increase the critical current densities; therefore, other methods of determining this field should be tried. The author proposes using a flux gate magnetometer with a detector wound on a ferrite core to measure the magnitude and direction of the magnetic field.

Overcash, Dan R.↗

Studies of the charging of a thin dust layer in a plasma

The present study is designed to extend Wilson's model to include refinements in the actual operational design of the simulation code itself and to include additional physics in order to assess the resulting electric field structure and grain charges. Most of the initial phases of the work have focussed on the fact that the code, though in principle reliable, suffers from severe time constraints, requiring as must as 10-50 hours of CPU time for typical runs on a VAX computer. It is likely that by staging the code into steps in which early steps are carried out crudely and later steps successively fine tuned the total CPU time can be cut significantly. Preliminary results indicate the possibility to cut CPU time to as much as 1/3 or 1/5 the former time. The original Wilson code has been carefully examined, tested and documented. Shortcuts and staging systems have been introduced and tested which should make the code produce more accurate results with a finer grid system than would have been feasible heretofor. Continued testing and implementation of these refinements will be carried out at the author's home institution in the near future. In addition to the effort at reducing CPU time to a manageable amount, work is in progress to include a dust-size distribution instead of assuming all dust grains have the same size.

Peterson, Lennart R.↗