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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9

Could the chemical industry mitigate rapid global cooling from a catastrophic volcanic eruption?

Abstract Estimates based on historical data place the probability of a catastrophic volcanic eruption in the next 100 years at around one in six. Large volcanic eruptions can lead to significant global cooling for 2–4 years, with potentially devastating impacts on global agriculture. In principle, the negative impacts of volcano‐induced cooling could be reduced by deliberate emission of short‐lived chemicals with high greenhouse gas intensity into the atmosphere. This article examines the physical feasibility of this concept for a wide range of short‐lived climate pollutants, using the global chemical industry for context. Deliberate emission of any known chemical species would require gigatons of material, which would have to be produced and stored far in advance of the volcanic event. The cost of this undertaking would be immense. In addition to these daunting logistical challenges, a range of other uncertainties and complications associated with this concept are discussed.

Sholl, David S. [University of Tennessee‐Oak Ridge↗

Seasonal grassland productivity forecast for the U.S. Great Plains using Grass–Cast

Every spring, ranchers in the drought-prone U.S. Great Plains face the same difficult challenge —trying to estimate how much forage will be available for livestock to graze during the upcoming summer grazing season. To reduce this uncertainty in predicting forage availability, we developed an innovative new grassland productivity forecast system, named Grass-Cast, to provide science-informed estimates of growing season above ground net primary production (ANPP). Grass-Cast uses over 30 yr of historical data including weather and the satellite-derived normalized vegetation difference index (NDVI)—combined with ecosystem modeling and seasonal precipitation forecasts—to predict if rangelands in individual counties are likely to produce below-normal, near-normal, or above-normal amounts of grass biomass (lbs/ac). Grass-Cast also provides a view of rangeland productivity in the broader region, to assist in larger scale decision-making—such as where forage resources for grazing might be more plentiful if a rancher’s own region is at risk of drought. Grass-Cast is updated approximately every two weeks from April through July. Each Grass-Cast forecast provides three scenarios of ANPP for the upcoming growing season based on different precipitation outlooks. Near real-time 8-d NDVI can be used to supplement Grass-Cast in predicting cumulative growing season NDVI and ANPP starting in mid-April for the Southern Great Plains and mid-May to early June for the Central and Northern Great Plains. Here, we present the scientific basis and methods for Grass-Cast along with the county-level production forecasts from 2017 and 2018 for ten states in the U.S. Great Plains. The correlation between early growing season forecasts and the end-of growing season ANPP estimate is >50% by late May or early June. In a retrospective evaluation, we compared Grass-Cast end-of-growing season ANPP results to an independent dataset and found that the two agreed 69% of the time over a 20-yr period. Although some predictive tools exist for forecasting upcoming growing season conditions, none predict actual productivity for the entire Great Plains. The Grass-Cast system could be adapted to predict grassland ANPP outside of the Great Plains or to predict perennial biofuel grass production.

54 ENVIRONMENTAL SCIENCES↗

Understanding long-term groundwater flow at Pahute Mesa and vicinity, Nevada National Security Site, USA, from naturally occurring geochemical and isotopic tracers

Abstract Recently collected naturally occurring geochemical and isotopic groundwater tracers were combined with historic data from the Pahute Mesa area of the Nevada National Security Site (NNSS), Nevada, USA, to provide insights into long-term regional groundwater flow patterns, mixing and recharge. Pahute Mesa was the site of 85 nuclear detonations between 1965 and 1992, many of them deeply buried devices that introduced radionuclides directly into groundwater. The dataset examined included major ions and field measurements, stable isotopes of hydrogen (δ 2 H), oxygen (δ 18 O), carbon (δ 13 C) and sulfur (δ 34 S), and radioisotopes of carbon ( 14 C) and chloride ( 36 Cl). Analysis of the patterns of groundwater 14 C data and the δ 2 H and δ 18 O signatures indicates that groundwater recharge is predominantly of Pleistocene age, except for a few localized areas near major ephemeral drainages. Steep gradients in sulfate (SO 4 ) and chloride (Cl) define a region near the western edge of the NNSS where high-concentration groundwater flowing south from north of the NNSS merges with dilute groundwater flowing west from eastern Pahute Mesa in a mixing zone that coincides with a groundwater trough associated with major faults. The 36 Cl/Cl and δ 34 S data suggest that the source of the high Cl and SO 4 in the groundwater was a now-dry, pluvial-age playa lake north of the NNSS. Patterns of groundwater flow indicated by the combined data sets show that groundwater is flowing around the northwest margin of the now extinct Timber Mountain Caldera Complex toward regional discharge areas in Oasis Valley.

58 GEOSCIENCES↗

Comprehensive characterization of the irradiation effects of glassy carbon

Carbon materials have become increasingly diverse, finding applications in high-temperature and high-radiation environments. Glassy carbon, an allotrope known for its exceptional chemical inertness and desirable mechanical properties. However, understanding neutron irradiation effects in glassy carbon has proven challenging, primarily because of its unique nanopore structure. Here, this study presents a highly detailed microstructural characterization investigation of neutron-induced changes in glassy carbon, revealing how changes in nanopore structure and crystallinity impact the irradiation-induced shrinkage. Aberration-corrected scanning transmission electron microscopy (STEM) reveals pore closure that leads to material densification in the irradiated samples. Dimensional analysis combined with comparison to historical data suggest significant length shrinkage to occur. Neutron and in situ electron irradiation experiments suggest that glassy carbon transforms into so-called carbon onions, supporting the concept of shrinkage saturation. Investigating irradiation temperature effects using STEM, electron energy loss spectroscopy, x-ray diffraction, and Raman spectroscopy revealed partial amorphization at 210 °C–230 °C and preserved order in glassy carbon at 860 °C, coinciding with pore closure. Thermal property measurements were also conducted to assess the effects of densification and other changes in the atomic structure of glassy carbon. The results of this study have broad implications in the deployment of glassy carbon to nuclear environments, based around the observed changes in the thermal properties, and demonstrates the operational window for the onset of densification.

36 MATERIALS SCIENCE↗

Assessing parallel path cooling tower performance via artificial neural networks

Real-time monitoring of a research nuclear reactor, a system in which all generated power is dissipated to the environment, can be performed via analysis of the heat rejection from the cooling system. Given an inlet water temperature and flow rate, the reactor power can be well-approximated from the outlet water temperature; however, the instrumentation to measure outlet conditions may not be robust or accurate. If we know how a cooling tower performs from historical data, but cannot measure the outlet temperature, a mathematical representation of the system can be inverted to obtain the outlet water temperature that describes the cooling capacity. Unfortunately, model inversion processes are computationally expensive. To address this, an artificial neural network (ANN) is implemented to assess the performance of a multi-cell cooling tower for a nuclear reactor. This approach leverages the Merkel model to obtain an extensive data set describing performance of the cooling tower cells throughout a wide array of potential operating conditions. The Merkel model is expressed as a function of four parameters: the inlet and outlet water temperatures, inlet air wet bulb temperature, and ratio of liquid-to-gas mass flow rates (L/G), which together provide a non-dimensional number indicative of cooling tower performance, called the Merkel integral. Computing a 4-dimensional data structure that describes finite combinations of the Merkel integral, an inverse model is then generated using an ANN to determine the cell outlet water temperature from the other three model parameters along with the computed Merkel integral. Compared to traditional model inversion methods, the ANN reduces the computational time by approximately 4 orders of magnitude, with effectively no sacrifice to solution accuracy, and could be applied for different cooling towers in the event the performance curve is known. Finally, three use cases of the ANN are then reviewed: (1) determining the cell outlet water temperatures when gas flow at rated conditions (GFRC) is known, (2) performing the prior case without knowledge of the GRFC, and (3) assessing performance differences between the individual tower cells.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Evaluating the Feasibility of Transactive Approach for Voltage Management Using Inverters of a PV Plant

This article evaluates the feasibility of a double-auction-based Transactive Energy System (TES) for engaging the reactive power (Var) capability of inverters in a utility-scale pho¬tovoltaic (PV) plant for voltage management in distribution feed¬ers. In this approach, a PV plant owner (seller) provides Var supply curves in terms of price-quantity pairs consider¬ing the inverters’ P-Q capability, efficiency, opportunity cost for real power curtail¬ment, losses, etc. At the same time, the utility (buyer) proposes Var demand curves in price-quantity pairs exhibiting the marginal price of Var. Then, market clearing points are obtained from the intersection points of supply and demand curves which are then used to create Var dispatch sig-nals from the PV plant. To conduct a fea¬sibility study of this approach, an Australian distribution network with a utility-scale PV plant (capacity 3.275 MWP) is modeled in RSCAD and simu¬lated in real-time on MATLAB, RSCAD-RTDS co-simulation platform using real historical data. Consid¬ering a use case, namely, conservation voltage reduction (CVR), the operational feasibility along with cost-benefit analysis is demonstrated in software-in-the-loop (SIL) and hardware-in-the-loop (HIL) platform. Another use case, exploring the benefit from tap-change reduction of step-voltage-regulator, is investigated. These studies explore further use cases, e.g., PV hosting capacity, network reconfiguration, etc., to be incorporated in TES for experiencing substantial economic benefits.

Alam, Mollah Rezaul↗

Model-Free Voltage Control of Active Distribution System with PVs Using Surrogate Model-Based Deep Reinforcement Learning

Accurate knowledge of the distribution system topology and parameters is required to achieve good voltage control performance, but this is difficult to obtain in practice. This paper proposes a physical-model-free voltage control method based on a surrogate-model-enabled deep reinforcement learning approach. Specifically, a surrogate model is trained in a supervised manner using the recorded limited number of historical data to learn the relationship between the power injections and voltage fluctuations of each node. Then, the deep reinforcement learning algorithm is applied to learn an optimal control strategy from the experiences obtained by continuous interactions with the surrogate model. The proposed method can achieve physical-model-free control of unbalanced distribution network and inform real-time decisions to deal with fast voltage fluctuations caused by the rapid variation of PV generation. Simulation results on an unbalance IEEE 123-bus system show that the proposed method can achieve similar performance as that of perfect physical-model-based approaches while being advantageous over other traditional methods.

active distribution network↗

Using concentrating-solar-power plants as economic carbon-free capacity resources

Deep decarbonization of electricity systems raises concerns about the need for generating capacity that can maintain reliable energy supply. Given this concern, we explore the ability of concentrating-solar-power plants with thermal energy storage to provide a carbon-free source of such capacity. We develop an approach to assessing the capacity contribution of concentrating-solar-power plants that considers future systems. Such considerations are important, because of potential differences in net-load patterns compared to today (e.g., due to higher renewable-energy penetrations). Using historical data spanning an 18-year period, we demonstrate that concentrating-solar-power plants with thermal energy storage can provide this necessary capacity with little impact on their financial viability. We examine the impact of myopic decisions and imperfect foresight of future system conditions on the operation of concentrating-solar-power plants and the resultant impact on their capacity contributions. We find that imperfect foresight can have limited impacts on such a use of concentrating-solar-power plants, so long as proper forecasting techniques are developed and used. Overall, our work shows that concentrating-solar-power plants with thermal energy storage may have a role to play in delivering reliable electricity supply in a decarbonized energy system.

14 SOLAR ENERGY↗

Optimization under uncertainty of a hybrid waste tire and natural gas feedstock flexible polygeneration system using a decomposition algorithm

Market uncertainties motivate the development of flexible polygeneration systems that are able to adjust operating conditions to favor production of the most profitable product portfolio. However, this operational flexibility comes at the cost of higher capital expenditure. A scenario-based two-stage stochastic nonconvex Mixed-Integer Nonlinear Programming (MINLP) approach lends itself naturally to optimizing these trade-offs. This work studies the optimal design and operation under uncertainty of a hybrid feedstock flexible polygeneration system producing electricity, methanol, dimethyl ether, olefins or liquefied (synthetic) natural gas. A recently developed C++ based software framework (named GOSSIP) is used for modeling the optimization problem as well as its efficient solution using the Nonconvex Generalized Benders Decomposition (NGBD) algorithm. Two different cases are studied: The first uses estimates of the means and variances of the uncertain parameters from historical data, whereas the second assesses the impact of increased uncertain parameter volatility. The value of implementing flexible designs characterized by the value of the stochastic solution (VSS) is in the range of 260–405 M$ for a scale of approximately 893 MW of thermal input. Increased price volatility around the same mean results in higher expected net present value and VSS as operational flexibility allows for asymmetric exploitation of price peaks.

42 ENGINEERING↗

Grey-box and ANN-based building models for multistep-ahead prediction of indoor temperature to implement model predictive control

Model-based predictive control (MPC) strategies for heating, ventilation, and air-conditioning (HVAC) systems present an opportunity to lower building energy consumption and operational costs. Such approaches rely on the development of a model to precisely forecast building thermal dynamics, such as room air temperature or heating/cooling rate, and make control-related decisions. The control-oriented modeling of building energy systems should be accurate in predicting indoor conditions and present low computational complexity. These features are the key challenge of implementing advanced control methods such as MPC. Extant studies on building modeling for MPC have focused on step-ahead forecasting techniques to forecast building thermal dynamics, while multistep-ahead forecasting is essential. Moreover, machine learning model suitable in case of the domain-based engineering expertise are also not available. To this aim, we perform a comparative analysis of the grey-box model based on a resistance-capacitance (RC) thermal network and a machine learning model composed of an artificial neural network (ANN) for multistep-ahead prediction of building thermal dynamics using current and historical data. Actual experimental data obtained from the Flexible Research Platform (FRP) in Oak Ridge National Laboratory (US) are used for estimation and validation purposes. The average root mean squared error (RMSE) of the grey-box and ANN models are 0.89 °C and 1.02°C, respectively. Finally, the results indicate that the grey-box model outperforms the ANN model in the considered validation periods in terms of accuracy and prediction stability.

42 ENGINEERING↗

Validation of SPH code Spheral to model interacting solid bodies in a supersonic flow

Contemporary discussions of planetary defense involve analyzing the risks posed by smaller sized, 20 to 200 m diameter, asteroids which are capable of breaking up in the atmosphere and generating a blast wave. Consequence assessments for this size class of asteroids are performed through fast-running analytic or semi-analytic models which are informed by high-fidelity hydrocode simulations of asteroid entry and breakup. However, insufficient historical data necessitates validating the independent physical processes which dominate airburst events. Here, the Fluid Solid Interface Smoothed Particle Hydrodynamics solver was previously used by Pearl et al. in 2023 to model the Chelyabinsk airburst and is used here to perform a series of validation simulations. The first effort involves modeling a cylinder in a hypersonic flow and comparing the bow shock geometry to that predicted by analytic theory. The second effort involves modeling the separation of two spherical bodies in supersonic flow and validating against experimental footage. Combined, these exercises demonstrate the ability of the code to model the flight-path of interacting solid bodies in a hypersonic flow.

Airburst↗

Incorporating civilian radioxenon background estimates in anomaly detection

A nuclear explosion screening exercise in 2023 (Maurer et al., 2023) found challenges with discerning anomalous radioxenon activity concentrations relative to elevated background concentrations. Research has continued into methods to detect anomalous radioxenon concentrations by comparing samples to estimates of atmospheric radioxenon background concentrations caused by releases at nuclear reactors or medical isotope production facilities. A new approach estimates the sample concentrations using time-varying radioxenon release rates obtained using optimization techniques that constrain the facility release rates to plausible amounts based on historical data or facility knowledge. The purpose of the optimization is to determine whether any combination of plausible release rates from emitting facilities can explain a series of radioxenon measurements at one or more sampling stations. A case study uses radioxenon data collected at three locations in western Europe for a month in 2021 and considers releases from 77 locations. Fewer samples are identified as being anomalous using a simplistic flagging rule than from an application of the current International Monitoring System (IMS) activity concentration-level rule.

Environmental sciences↗

Diagnostic-free onboard battery health assessment

Diverse usage patterns induce complex and variable aging behaviors in lithiumion batteries, complicating accurate health diagnosis and prognosis. Separate diagnostic cycles are often used to untangle the battery’s current state of health from prior complex aging patterns. However, these same diagnostic cycles alter the battery’s degradation trajectory, are time-intensive, and cannot be practically performed in onboard applications. Here, in this work, we leverage portions of operational measurements in combination with an interpretable machine learning model to enable rapid, onboard battery health diagnostics and prognostics without offline diagnostic testing and the requirement of historical data. We integrate mechanistic constraints within an encoder-decoder architecture to extract electrode states in a physically interpretable latent space and enable improved reconstruction of the degradation path. The health diagnosis model framework can be flexibly applied across diverse application interests with slight fine-tuning.

battery aging reconstruction↗

Chromium-doped uranium dioxide fuels: A review

UO 2 doped with parts per million CR 2 O 3 powder is considered a potential near term accident tolerant fuel candidate. Here, the results of decades of industry and academic research into Cr-doped UO 2 are analyzed and their shortcomings are critiqued. Focusing on the incorporation mechanisms of Cr into the fuel matrix, we explore a mechanistic understanding of the characteristic properties of Cr-doped UO 2 , notably, enhanced fission gas retention attributed to enlarged grain sizes following sintering, along with marginal improvements in the thermophysical properties. The findings of recent X-ray Adsorption Near Edge Spectroscopy studies were compared and put into conversation with historic data regarding the incorporation of Cr in UO 2 . On the basis of defect mechanisms, the case is made for the substitutional incorporation of Cr governing the lattice solubility but not the enhanced U diffusivity. Instead, Cr/CR 2 O 3 redox chemistry in a well-defined oxygen potential explains the differences in the U diffusivity and O/M ratio. The primary mechanism of doping enhanced grain growth is found to be liquid assisted sintering due to a CRO (1) eutectic phase at the grain boundaries. The role of inhomogeneities in Cr concentration in UO 2 at various length scales across the materials microstructure is highlighted and connected to promising experimental and modeling work to fill in the gaps in the current understanding of Cr-doped UO 2 . The review considers both the open scientific questions and engineering applications to illustrate the deep connections between the practice and theory in the design of accident tolerant nuclear fuels. In conclusion, the review ends with an outline of future works that combine meticulous irradiation studies and high resolution experiments with next generation modeling and simulations techniques empowered by machine learning advances to accelerate the fabrication and adoption of Cr-doped UO 2 light water reactors.

Cleveland, Mack Wesley [Massachusetts Inst. of Tec↗

Discriminating Underground Nuclear Explosions Leading To Late-Time Radionuclide Gas Seeps

Utilizing historical data from the U.S. nuclear test program and freely available barometric pressure data, we performed an analytical barometric-pumping efficiency analysis to determine factors resulting in late-time radionuclide gas seeps from underground nuclear explosions. In this work, we considered 16 underground nuclear explosions with similar geology and test setup, of which five resulted in the measurement of late-time radionuclide gas concentrations at the ground surface. Additionally, the factors we considered include barometric frequency and amplitude, depth of burial, air-filled porosity, intact-rock permeability, fracture aperture, and fracture spacing. The analysis indicates that the best discriminators of late-time radionuclide gas seeps for these explosions are barometric frequency and amplitude and air-filled porosity. While geologic information on fracture aperture and spacing is not available for these explosions, the sensitivity of barometric-pumping efficiency to fracture aperture indicates that it would likely also be a good discriminator.

58 GEOSCIENCES↗

Anthropogenic Contributions to the 2021 Pacific Northwest Heatwave

Abstract Daily maximum temperatures during the 2021 heatwave in the Pacific Northwest United States and Canada shattered century old records. Multiple causal factors, including anthropogenic climate change, contributed to these high temperatures, challenging traditional methods of attributing human influence. We demonstrate that the observed 2021 daily maximum temperatures are far above the bounds of Generalized Extreme Value distributions fitted from historical data. Hence, confidence in Granger causal inference statements about the human influence on this heatwave is low. Alternatively, we present a more conditional hindcast attribution study using two regional models. We performed ensembles of simulations of the heatwave to investigate how the event would have changed if it had occurred without anthropogenic climate change and with future warming. We found that global warming caused a ∼0.8°C–1°C increase in heatwave temperatures. Future warming would lead to a ∼5°C increase in heatwave temperature by the end of the 21st century.

54 ENVIRONMENTAL SCIENCES↗

Design principles for NASICON super-ionic conductors

Na Super Ionic Conductor (NASICON) materials are an important class of solid-state electrolytes owing to their high ionic conductivity and superior chemical and electrochemical stability. In this paper, we combine first-principles calculations, experimental synthesis and testing, and natural language-driven text-mined historical data on NASICON ionic conductivity to achieve clear insights into how chemical composition influences the Na-ion conductivity. These insights, together with a high-throughput first-principles analysis of the compositional space over which NASICONs are expected to be stable, lead to the successful synthesis and electrochemical investigation of several new NASICONs solid-state conductors. Among these, a high ionic conductivity of 1.2 mS cm ₋1 could be achieved at 25 °C. We find that the ionic conductivity increases with average metal size up to a certain value and that the substitution of PO 4 polyanions by SiO 4 also enhances the ionic conductivity. While optimal ionic conductivity is found near a Na content of 3 per formula unit, the exact optimum depends on other compositional variables. Surprisingly, the Na content enhances the ionic conductivity mostly through its effect on the activation barrier, rather than through the carrier concentration. These deconvoluted design criteria may provide guidelines for the design of optimized NASICON conductors.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗