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At least 163 records · Page 9

Carbon-Based Compounds and Exobiology

The Committee for Planetary and Lunar Explorations (COMPLEX) posed questions related to exobiological exploration of Mars and the possibility of a population of carbonaceous materials in cometary nuclei to be addressed by future space missions. The scientific objectives for such missions are translated into a series of measurements and/or observations to be performed by Martian landers. These are: (1) A detailed mineralogical, chemical, and textural assessment of rock diversity at a landing site; (2) Chemical characterization of the materials at a local site; (3) Abundance of Hydrogen at any accessible sites; (4) Identification of specific minerals that would be diagnostic of aqueous processes; (5) Textual examination of lithologies thought to be formed by aqueous activity; (6) Search for minerals that might have been produced as a result of biological processes; (7) Mapping the distribution, in three dimensions, of the oxidant(s) identified on the Martian surface by the Viking mission; (8) Definition of the local chemical environment; (9) Determination of stable-isotopic ratios for the biogenic elements in surface mineral deposits; (10) Quantitative analysis of organic (non-carbonate) carbon; (11) Elemental and isotopic composition of bulk organic material; (12) Search for specific organic compounds that would yield information about synthetic mechanisms, in the case of prebiotic evolution, and about possible bio-markers, in the case of extinct or extant life; (13) and Coring, sampling, and detection of entrained gases and cosmic-ray induced reaction products at the polar ice cap. A discussion of measurements and/or observations required for cometary landers is included as well.

Kerridge, John↗

Planetary optical and infrared imaging

The purpose of this investigation is to obtain and analyze high spatial resolution charge coupled device (CCD) coronagraphic images of extra-solar planetary material and solar system objects. These data will provide information on the distribution of planetary and proto-planetary material around nearby stars leading to a better understanding of the origin and evolution of the solar system. Imaging within our solar system will provide information on the current cloud configurations on the outer planets, search for new objects around the outer planets, and provide direct support for Voyager, Galileo, and CRAF by imaging material around asteroids and clouds on Neptune. Over the last year this program acquired multispectral and polarization images of the disk of material around the nearby star Beta Pictoris. This material is believed to be associated with the formation of planets and provides a first look at a planetary system much younger than our own. Preliminary color and polarization data suggest that the material is very low albedo and similar to dark outer solar system carbon rich material. A coronagraphic search for other systems is underway and has already examined over 100 nearby stars. Coronagraphic imaging provided the first clear look at the rings of Uranus and albedo limits for the ring arcs around Neptune.

Terrile, R. J.↗

Unified System Of Data On Materials And Processes

Wide-ranging sets of data for aerospace industry described. Document describes Materials and Processes Technical Information System (MAPTIS), computerized set of integrated data bases for use by NASA and aerospace industry. Stores information in standard format for fast retrieval in searches and surveys of data. Helps engineers select materials and verify their properties. Promotes standardized nomenclature as well as standarized tests and presentation of data. Format of document of photographic projection slides used in lectures. Presents examples of reports from various data bases.

Key, Carlo F.↗

Non-aqueous cleaning solvent substitution

A variety of environmental, safety, and health concerns exist over use of chlorinated and fluorinated cleaning solvents. Sandia National Laboratories, Lawrence Livermore National Laboratories, and the Kansas City Division of AlliedSignal have combined efforts to focus on finding alternative cleaning solvents and processes which are effective, environmentally safe, and compliant with local, state, and federal regulations. An alternative solvent has been identified, qualified, and implemented into production of complex electronic assemblies, where aqueous and semi-aqueous cleaning processes are not allowed. Extensive compatibility studies were performed with components, piece-parts, and materials. Electrical testing and accelerated aging were used to screen for detrimental, long-term effects. A terpene, d-limonene, was selected as the solvent of choice, and it was found to be compatible with the components and materials tested. A brief history of the overall project will be presented, along with representative cleaning efficiency results, compatibility results, and residual solvent data. The electronics industry is constantly searching for proven methods and environmentally-safe materials to use in manufacturing processes. The information in this presentation will provide another option to consider on future projects for applications requiring high levels of quality, reliability, and cleanliness from non-aqueous cleaning processes.

Meier, Gerald J.↗

Analysis for Be-7 and Be-10 on LDEF materials and their sources

Work has continued on the search for 10Be on metals other than aluminum flown on LDEF. Much time-consuming extractive chemistry has been performed at Rutgers University on turnings obtained from the ends of two stainless steel trunnions from LDEF and prepared samples will be run on the University of Pennsylvania accelerator mass spectrometer. We have continued to investigate our discovery of naturally-occurring 10Be contamination in bauxite and industrial aluminum from different sources. Measurements of 10Be in ores from three different sites, and from four different samples of commercial aluminum have been made.

Gregory, John C.↗

Materials processing threshold report. 1: Semiconductor crystals for infrared detectors

An extensive search was performed of the open literature pertaining to infrared detectors to determine what constitutes a good detector and in what way performance is limited by specific material properties. Interviews were conducted with a number of experts in the field to assess their perceptions of the state of the art and of the utility of zero-gravity processing. Based on this information base and on a review of NASA programs in crystal growth and infrared sensors, NASA program goals were reassessed and suggestions are presented as to possible joint and divergent efforts between NASA and DOD.

Sager, E. V.↗

A new structure for comparing surface passivation materials of GaAs solar cells

The surface recombination velocity (S sub rec) for bare GaAs is typically as high as 10 to the 6th power to 10 to the 7th power cm/sec, which dramatically lowers the efficiency of GaAs solar cells. Early attempts to circumvent this problem by making an ultra thin junction (xj less than .1 micron) proved unsuccessful when compared to lowering S sub rec by surface passivation. Present day GaAs solar cells use an GaAlAs window layer to passivate the top surface. The advantages of GaAlAs in surface passivation are its high bandgap energy and lattice matching to GaAs. Although GaAlAs is successful in reducing the surface recombination velocity, it has other inherent problems of chemical instability (Al readily oxidizes) and ohmic contact formation. The search for new, more stable window layer materials requires a means to compare their surface passivation ability. Therefore, a device structure is needed to easily test the performance of different passivating candidates. Such a test device is described.

Desalvo, Gregory C.↗

Lunar and Planetary Science XXXV: Astrobiology: Analogs and Applications to the Search for Life

The session "Astrobiology: Analogs and Applications to the Search for Life" included the folowing reports:The Search for Life on Mars Using Macroscopically Visible Microbial Mats (Stromatolites) in 3.5/3.3 Ga Cherts from the Pilbara in Australia and Barberton in South Africa as Analogues; Life in a Mars Analog: Microbial Activity Associated with Carbonate Cemented Lava Breccias from NW Spitsbergen; Groundwater-fed Iron-rich Microbial Mats in a Freshwater Creek: Growth Cycles and Fossilization Potential of Microbial Features; Episodic Fossilization of Microorganisms on an Annual Timescale in an Anthropogenically Modified Natural Environment: Geochemical Controls and Implications for Astrobiology; Proterozoic Microfossils and Their Implications for Recognizing Life on Mars; Microbial Alteration of Volcanic Glass in Modern and Ancient Oceanic Crust as a Proxy for Studies of Extraterrestrial Material ; Olivine Alteration on Earth and Mars; Searching for an Acidic Aquifer in the R!o Tinto Basin. First Geobiology Results of MARTE Project; In-Field Testing of Life Detection Instruments and Protocols in a Mars Analogue Arctic Environment; Habitability of the Shallow Subsurface on Mars: Clues from the Meteorites; Mars Analog Rio Tinto Experiment (MARTE): 2003 Drilling Campaign to Search for a Subsurface Biosphere at Rio Tinto Spain; Characterization of the Organic Matter in an Archean Chert (Warrawoona, Australia); and The Solfatara Crater, Italy: Characterization of Hydrothermal Deposits, Biosignatures and Their Astrobiological Implication.

Lunar and Planetary Institute↗

Extraction of Organic Molecules from Terrestrial Material: Quantitative Yields from Heat and Water Extractions

In the robotic search for life on Mars, different proposed missions will analyze the chemical and biological signatures of life using different platforms. The analysis of samples via analytical instrumentation on the surface of Mars has thus far only been attempted by the two Viking missions. Robotic arms scooped relogith material into a pyrolysis oven attached to a GC/MS. No trace of organic material was found on any of the two different samples at either of the two different landing sites. This null result puts an upper limit on the amount of organics that might be present in Martian soil/rocks, although the level of detection for each individual molecular species is still debated. Determining the absolute limit of detection for each analytical instrument is essential so that null results can be understood. This includes investigating the trade off of using pyrolysis versus liquid solvent extraction to release organic materials (in terms of extraction efficiencies and the complexity of the sample extraction process.) Extraction of organics from field samples can be accomplished by a variety of methods such utilizing various solvents including HCl, pure water, supercritical fluid and Soxhelt extraction. Utilizing 6N HCl is one of the most commonly used method and frequently utilized for extraction of organics from meteorites but it is probably infeasible for robotic exploration due to difficulty of storage and transport. Extraction utilizing H2O is promising, but it could be less efficient than 6N HCl. Both supercritical fluid and Soxhelt extraction methods require bulky hardware and require complex steps, inappropriate for inclusion on rover spacecraft. This investigation reports the efficiencies of pyrolysis and solvent extraction methods for amino acids for different terrestrial samples. The samples studied here, initially created in aqueous environments, are sedimentary in nature. These particular samples were chosen because they possibly represent one of the best terrestrial analogs of Mars and they represent one of the absolute best case scenarios for finding organic molecules on the Martian surface.

Beegle, L. W.↗

Extraterrestrial Amino Acids and Amines Identified in Asteroid Ryugu Samples Returned By the Hayabusa2 Mission

The hot water and acid extracts of two different Ryugu samples collected by the Hayabusa2 mission were analyzed for the presence of aliphatic amines and amino acids. The abundances and relative distributions of both classes of molecules were determined, as well as the enantiomeric compositions of the chiral amino acids. The Ryugu samples studied here were recovered from sample chambers A and C, which were composed of surface material, and a combination of surface and possible subsurface material, respectively. A total of thirteen amino acids were detected and quantitated in these samples, with an additional five amino acids that were tentatively identified but not quantitated. The abundances of four aliphatic amines identified in the Ryugu samples were also determined in the current work. Amino acids were observed in the acid hydrolyzed and unhydrolyzed hot water extracts of asteroid Ryugu regolith using liquid chromatography with UV fluorescence detection and high-resolution mass spectrometry. Conversely, aliphatic amines were only analyzed in the unhydrolyzed hot water Ryugu extracts. Two- to six-carbon (C 2 -C 6 ) amino acids with individual abundances ranging from 0.02 to 15.8 nmol g −1 , and one- to three-carbon (C 1 -C 3 ) aliphatic amines with individual abundances from 0.05 to 34.14 nmol g −1 , were found in the hot water extracts. Several non-protein amino acids that are rare in biology, including β-amino-n-butyric acid (β-ABA) and β-aminoisobuytric acid (β-AIB), were racemic or very nearly racemic, thus indicating their likely abiotic origins. Trace amounts of select protein amino acids that were enriched in the ւ-enantiomer may indicate low levels of terrestrial amino acid contamination in the samples. However, the presence of elevated abundances of free and racemic alanine, a common protein amino acid in terrestrial biology, and elevated abundances of the predominately free and racemic non-protein amino acids, β-ABA and β-AIB, indicate that many of the amino acids detected in the Ryugu water extracts were indigenous to the samples. Although the Ryugu samples have been found to be chemically similar to CI type carbonaceous chondrites, the measured concentrations and relative distributions of amino acids and aliphatic amines in Ryugu samples were notably different from those previously observed for the CI1.1 carbonaceous chondrite, Orgueil. This discrepancy could be the result of differences in the original chemical compositions of the parent bodies and/or alteration conditions, such as space weathering. In addition to α-amino acids that could have been formed by Strecker cyanohydrin synthesis during a low temperature aqueous alteration phase, β-, γ-, and δ-amino acids, including C 3 – C 5 straight-chain n-ω-amino acids that are not formed by Strecker synthesis, were also observed in the Ryugu extracts. The suite of amino acids measured in the Ryugu samples indicates that multiple amino acid formation mechanisms were active on the Ryugu parent body. The analytical techniques used here are well-suited to search for similar analytes in asteroid Bennu material collected by the NASA OSIRIS-REx mission scheduled for Earth return in September 2023.

Hayabusa2↗

A finite element propagation model for extracting normal incidence impedance in nonprogressive acoustic wave fields

A propagation model method for extracting the normal incidence impedance of an acoustic material installed as a finite length segment in a wall of a duct carrying a nonprogressive wave field is presented. The method recasts the determination of the unknown impedance as the minimization of the normalized wall pressure error function. A finite element propagation model is combined with a coarse/fine grid impedance plane search technique to extract the impedance of the material. Results are presented for three different materials for which the impedance is known. For each material, the input data required for the prediction scheme was computed from modal theory and then contaminated by random error. The finite element method reproduces the known impedance of each material almost exactly for random errors typical of those found in many measurement environments. Thus, the method developed here provides a means for determining the impedance of materials in a nonprogressirve wave environment such as that usually encountered in a commercial aircraft engine and most laboratory settings.

Watson, Willie R.↗

Ultraviolet observations of V471 Tauri - Evidence for a nova-like outburst?

A search for accretion of wind-flare material onto the white dwarf in V471 Tauri has unexpected by revealed what appears to be shortward-shifted absorption, centered on two distinct velocities, near heliocentric velocities of -300 and -590 km/s in the line of sight toward V471 Tauri. The possibility that these features are due to instrumental effects is explored. The narrow interstellar-like appearance of the -590 km/s component and lack of variability with orbital phase indicate that the observed high-velocity absorption components are formed at a great distance from the V471 Tauri system and probably owe their origins to a discrete mass ejection event.

Bruhweiler, F. C.↗

Cockpit resource management at USAir

The current USAir CRM program is presented. The lessons learned and the program issues are combined. The training material was developed after an extensive literature search and pilot interview survey to determine the problem. The investigation led to the design, implementation, and evaluation of a behavioral science awareness training program. The need was found, and the target population was identified as the pilot group.

Sellards, Robert↗

A preliminary study of a Mars penetrator system for subsurface exobiological exploration

The earth seems to stand alone among the planets of the solar system in that its surface, atmosphere, and hydrosphere provide an environment conducive to the maintenance of life. At one time, Mars was also considered to have the potential to harbor life. However, the absence of detectable organic molecules at the two Viking landing sites and the absence of liquid water anywhere on the surface seems to indicate that life is not present on Mars now. There are, however, many indications that the surface of Mars was less hostile in the distant past and the possibility that life may have existed on primordial Mars or that prebiotic chemistry may have occurred can not be excluded. The search for the organic evidence of this prebiotic or biotic activity will require a subsurface study of possible sediments at several sites. The purpose of this paper is to propose and describe a device termed a penetrator to emplant the required instrumentation beneath the surface (2-4 m) at likely sites to search for the evidence of biogenic organic material. The paper examines, in detail, the rationale for the scientific activity, any issues of technical feasibility, and describes the associated system requirements.

Swenson, Byron L.↗

Optically thin gas in the broad-line region of Seyfert galaxies

Profile comparisons between the H-alpha and O I 8446 emission lines in Seyfert galaxies are used to search for the presence of optically thin material in the broad-line region. In a sample of 12 objects with detected O I 8446, only four show significant profile differences. In the two clearest cases with profile differences, these can be explained as arising from an outflow of optically thin material. Also presented are high-resolutions spectra of a feature at 9210 A. It is suggested that Mg II pumped by a fluorescence with Ly-beta may be a significant contributor.

Morris, Simon L.↗

Fatigue analysis of mini-mast space truss

The functional, structural adequacy of a 20 meter long generic space truss (Mini-Mast), subjected to fatigue loading, was examined with respect to the failure modes which are most likely to occur during services. The space truss is made of thin-walled tubes having unidirectional, zero degree layups of Celanese G50 graphite fibers/Narmco 5217 epoxy composites. The approach used to investigate the most probable failure mode of the truss under fatigue loading is to determine the stress level, including the types of stress, in the member first, then followed by failure mode analysis based on the stress level just determined. To begin, an approximate beam-parameter truss (BPT) model is analyzed first, followed by a detailed analysis of the truss using a finite element model (FEM) run with NASTRAN code. The response results of the BPT model are used to compare FEM results and to check any major deviation of trend derived from the FEM. The purpose of the work was to search available fatigue data of the tube material, to conduct approximate dynamical stress analysis of the BPT model, to run detailed dynamical stress analysis of the FEM model using NASTRAN code, and to predict the fatigue life of the truss member based on limited fatigue data.

Hwang, Shoi Y.↗

Boundary Conditions for the Paleoenvironment: Chemical and Physical Processes in the Pre-Solar Nebula

The basic theme of this program is the study of molecular complexity and evolution in interstellar clouds and in primitive solar system objects. Research has included the detection and study of a number of new interstellar molecules and investigation of reaction pathways for astrochemistry from a comparison of theory and observed molecular abundances. The latter includes studies of cold, dark clouds in which ion-molecule chemistry should predominate, searches for the effects of interchange of material between the gas and solid phases in interstellar clouds, unbiased spectral surveys of particular sources, and systematic investigation of the interlinked chemistry and physics of dense interstellar clouds. In addition, the study of comets has allowed a comparison between the chemistry of such minimally thermally processed objects and that of interstellar clouds, shedding light on the evolution of the biogenic elements during the process of solar system formation.

Irvine, William M.↗