Search NASA⌕ Search

SEARCH · Search NASA

Results for “mode shift”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Hypersonic Fluid–Structure Interaction on a Cone–Slice–Ramp Geometry

In this study, fluid–structure interactions were measured between a representative control surface and the hypersonic flow deflected by it. The control surface is simplified as a spanwise finite ramp placed on a longitudinal slice of a cone. The front surface of the ramp contains a thin panel designed to respond to the unsteady fluid loading arising from the shock-wave/boundary-layer interactions. Experiments were conducted at Mach 5 and Mach 8 with ramps of different angles. High-speed schlieren captured the unsteady flow dynamics and accelerometers behind the thin panel measured its structural response. Panel vibrations were dominated by natural modes that were excited by the broadband aerodynamic fluctuations arising in the flowfield. However, increased structural response was observed in two distinct flow regimes: 1) attached or small separation interactions, where the transitional regime induced the strongest panel fluctuations. This was in agreement with the observation of increased convective undulations or bulges in the separation shock generated by the passage of turbulent spots, and 2) large separated interactions, where shear layer flapping in the laminar regime produced strong panel response at the flapping frequency. In addition, panel heating during the experiment caused a downward shift in its natural mode frequencies.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2023

Peak Reduction Using Mode Adjustment of Heat Pump Water Heaters in a Residential Neighborhood

Building electrification is putting pressure on distribution grid worldwide. Peak reduction is an important concern that can help reduce the growing stress and allow to defer investments in new capacity. Water heaters represent a convenient way of reducing peak because they are less dependent on weather, and their storage volume allows for asynchronous water heating and hot water use. Previous empirical studies investigated the ability of water heaters to reduce peak through the adjustment of the temperature setpoint. However, not all equipment vendors offer this option. This study aims at understanding the feasibility of peak reduction with an alternative configuration available in the market - by adjusting the device mode rather than temperature setpoint. The peak reduction methodology is tested in an occupied 46-townhome neighborhood located in Atlanta, GA. We find that peak shifting is possible with the adjustable mode approach, with the change in the peak load by 30-60%.

demand response↗
DOE OSTI2020

Wide Operational Windows of Edge-Localized Mode Suppression by Resonant Magnetic Perturbations in the DIII-D Tokamak

Edge-Localized-Mode (ELM) suppression by resonant magnetic perturbations (RMPs) generally occurs over very narrow ranges of the plasma current (or magnetic safety factor $q_{95}$) in the DIII-D tokamak. However, wide $q_{95}$ ranges of ELM suppression are needed for the safety and operational flexibility of ITER and future reactors. In DIII-D ITER Similar Shape (ISS) plasmas with $n$=3 RMPs, the range of $q_{95}$ for ELM suppression is found to increase with decreasing electron density. Nonlinear two-fluid MHD simulations reproduce the observed $q_{95}$ windows of ELM suppression and the dependence on plasma density, based on the conditions for resonant field penetration at the top of the pedestal. When the RMP amplitude is close to the threshold for resonant field penetration, only narrow isolated magnetic islands form near the top of the pedestal, leading to narrow $q_{95}$ windows of ELM suppression. However, as the threshold for field penetration decreases with decreasing density, resonant field penetration can take place over a wider range of $q_{95}$. For sufficiently low density (penetration threshold) multiple magnetic islands form near the top of the pedestal giving rise to continuous $q_{95}$ windows of ELM suppression. The model predicts that wide $q_{95}$ windows of ELM suppression can be achieved at substantially higher pedestal pressure in DIII-D by shifting to higher toroidal mode number ($n$=4) RMPs.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1992

Scattering of p-modes by a sunspot

The acoustic scattering properties of a large sunspot are determined from a Fourier-Hankel decomposition of p-mode amplitudes as measured from a 68-hr subset of a larger set of observations made at the South Pole in 1988. It is shown that significant improvement in the measurement of p-mode scattering amplitudes results from the increased temporal frequency resolution provided by these data. Scattering phase shifts are unambiguously determined for the first time, and the dependence of the p-mode phase shift and absorption with wavenumber and frequency is presented.

Braun, D. C.↗
DOE OSTI2023

Guiding Principles for the Rational Design of Hybrid Materials: Use of DFT Methodology for Evaluating Non‐Covalent Interactions in a Uranyl Tetrahalide Model System

Abstract Together with the synthesis and experimental characterization of 14 hybrid materials containing [UO 2 X 4 ] 2− (X=Cl − and Br − ) and organic cations, we report on novel methods for determining correlation trends in their formation enthalpy (ΔH f ) and observed vibrational signatures. Δ H f values were analyzed through isothermal acid calorimetry and a Density Functional Theory+Thermodynamics (DFT+T) approach with results showing good agreement between theory and experiment. Three factors (packing efficiency, cation protonation enthalpy, and hydrogen bonding energy [ ]) were assessed as descriptors for trends in Δ H f . Results demonstrated a strong correlation between and Δ H f , highlighting the importance of hydrogen bonding networks in determining the relative stability of solid‐state hybrid materials. Lastly, we investigate how hydrogen bonding networks affect the vibrational characteristics of uranyl solid‐state materials using experimental Raman and IR spectroscopy and theoretical bond orders and find that hydrogen bonding can red‐shift U≡O stretching modes. Overall, the tightly integrated experimental and theoretical studies presented here bridge the trends in macroscopic thermodynamic energies and spectroscopic features with molecular‐level details of the geometry and electronic structure. This modeling framework forms a basis for exploring 3D hydrogen bonding as a tunable design feature in the pursuit of supramolecular materials by rational design.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Guiding Principles for the Rational Design of Hybrid Materials: Use of DFT Methodology for Evaluating Non‐Covalent Interactions in a Uranyl Tetrahalide Model System

Abstract Together with the synthesis and experimental characterization of 14 hybrid materials containing [UO 2 X 4 ] 2− (X=Cl − and Br − ) and organic cations, we report on novel methods for determining correlation trends in their formation enthalpy (ΔH f ) and observed vibrational signatures. Δ H f values were analyzed through isothermal acid calorimetry and a Density Functional Theory+Thermodynamics (DFT+T) approach with results showing good agreement between theory and experiment. Three factors (packing efficiency, cation protonation enthalpy, and hydrogen bonding energy [ ]) were assessed as descriptors for trends in Δ H f . Results demonstrated a strong correlation between and Δ H f , highlighting the importance of hydrogen bonding networks in determining the relative stability of solid‐state hybrid materials. Lastly, we investigate how hydrogen bonding networks affect the vibrational characteristics of uranyl solid‐state materials using experimental Raman and IR spectroscopy and theoretical bond orders and find that hydrogen bonding can red‐shift U≡O stretching modes. Overall, the tightly integrated experimental and theoretical studies presented here bridge the trends in macroscopic thermodynamic energies and spectroscopic features with molecular‐level details of the geometry and electronic structure. This modeling framework forms a basis for exploring 3D hydrogen bonding as a tunable design feature in the pursuit of supramolecular materials by rational design.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Magnetostriction of α-RuCl 3 Flakes in the Zigzag Phase

Motivated by the possibility of enhanced magnetic fluctuations in exfoliated α-RuCl 3 flakes, we study magneto-Raman spectra of exfoliated multilayer α-RuCl 3 in out-of-plane magnetic fields of -6 to 6 T at temperatures of 670 mK to 4 K. While the literature currently suggests that bulk α-RuCl 3 is in an antiferromagnetic zigzag phase with R$\bar3$ symmetry at low temperatures, we do not observe R$\bar3$ symmetry in exfoliated α-RuCl 3 at low temperatures. While we saw no magnetic field-driven transitions, the Raman modes exhibit unexpected stochastic shifts in response to the applied magnetic field that are above the uncertainties inferred from Bayesian analysis. Finally, these stochastic shifts are consistent with the emergence of magnetostrictive interactions in exfoliated α-RuCl 3 .

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Strong parametric dispersive shifts in a statically decoupled two-qubit cavity QED system

Qubits in cavity quantum electrodynamic (QED) architectures are often operated in the dispersive regime, in which the operating frequency of the cavity depends on the energy state of the qubit, and vice versa. The ability to tune these dispersive shifts provides additional options for performing either quantum measurements or logical manipulations. Here we couple two transmon qubits to a lumped-element cavity through a shared superconducting quantum interference device (SQUID). In this work, our design balances the mutual capacitive and inductive circuit components so that both qubits are statically decoupled from the cavity with low flux sensitivity, offering protection from decoherence processes. Parametric driving of the SQUID flux enables independent, dynamical tuning of each qubit’s interaction with the cavity. As a practical demonstration, we perform pulsed parametric dispersive readout of both qubits. The dispersive frequency shifts of the cavity mode follow the theoretically expected magnitude and sign. This parametric approach creates an extensible, tunable cavity QED framework with various future applications, such as entanglement and error correction via multi-qubit parity readout, state and entanglement stabilization, and parametric logical gates.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2023

A thermodynamic explanation of the Invar effect

The anomalously low thermal expansion of Fe–Ni Invar has long been associated with magnetism, but to date, the microscopic underpinnings of the Invar behaviour have eluded both theory and experiment. Here we present nuclear resonant X-ray scattering measurements of the phonon and magnetic entropies under pressure. By applying a thermodynamic Maxwell relation to these data, we obtain the separate phonon and magnetic contributions to thermal expansion. We find that the Invar behaviour stems from a competition between phonons and spins. In particular, the phonon contribution to thermal expansion cancels the magnetic contribution over the 0–3 GPa pressure range of Invar behaviour. At pressures above 3 GPa, the cancellation is lost, but our analysis reproduces the positive thermal expansion measured separately by synchrotron X-ray diffractometry. Ab initio calculations informed by experimental data show that spin–phonon interactions improve the accuracy of this cancellation over the range of Invar behaviour. Further, spin–phonon interactions also explain how different phonon modes have different energy shifts with pressure.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Effects of pore connectivity and tortuosity on the dynamics of fluids confined in sub-nanometer pores

Dynamical behavior of fluids under nano-pore confinement is studied extensively as it has important implications for several industrial as well as geological processes. Pore network in many porous materials exhibits a varied degree of inter connections. The extent of this pore connectivity may affect the structural and dynamical behavior of the confined fluid. However, studies of fluid confinement addressing these effects systematically are lacking. In this paper we report molecular dynamics simulation studies addressing the effects of pore connectivity on the dynamics of two representative fluids – CO 2 and ethane in silicalite by systematically varying the degree of pore connectivity through selectively blocking some pore space with immobile methane molecules. By selectively turning off the pore spaces in the shape of straight, or tortuous zigzag channels, we also probe the effects of pore tortuosity. In general, pore connectivity is found to facilitate both the translational as well as rotational dynamics of both fluids, while the intermolecular modes of vibration in both fluids remain largely unaffected. The effects of providing connections between a set of straight or zigzag channel-like pores are however more nuanced. Pore tortuosity facilitates the rotational motion, but suppresses the translational motion of CO 2 , while its effects on the rotational and translational motion of ethane are less pronounced. The intermolecular vibrational modes of both fluids shift to higher energies with an increase in the number of tortuous pores. The results reported here provide a detailed molecular level understanding of the effects of pore connectivity on the dynamics of fluids and thus have implications for applications like fluid separation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Upgrades to the ion cyclotron emission diagnostic on the DIII-D tokamak

The ion cyclotron emission diagnostic on the DIII-D tokamak comprises seven single-turn loops that measure high-frequency (1–100 MHz) magnetic field fluctuations that are often excited by energetic particles in the plasma. The raw voltage signals induced in the loops in response to these fluctuations travel through a series of cables, isolation transformer DC blocks, low-pass filters, and finally a digitizer before being analyzed in frequency space. The diagnostic has been recently upgraded, most notably to include four additional graphite tile loops and a new eight-channel digitizer. The previous three loops are all on the low-field side of the tokamak. The measurement capabilities of the system have been expanded by the addition of a new horizontally oriented loop on the low-field side, an additional toroidal loop on the low-field side, and two toroidal loops on the high-field side. These loops will be used to provide approximate mode polarization, improved toroidal mode number calculations, and information on modes in inward-shifted plasmas, respectively.

47 OTHER INSTRUMENTATION↗
DOE OSTI2021

The role of toroidal rotation in the very high energy confinement quality observed in super H-mode experiments on DIII-D

In this paper, we report the key role that toroidal rotation and the related E × B shear physics played in the very high energy confinement quality (H 98y2 > 1.5) of super H-mode experiments on DIII-D. Experiments show that the energy confinement quality decreases when toroidal rotation decreases due to the decreased externally controlled torque per particle. Meanwhile, the total pedestal pressure in the experiments remains very high during the rotation and confinement quality change. TGYRO transport modeling suggests the contribution from rotation in the E × B shear is responsible for the confinement quality in excess of standard H-mode (H 98y2 ~ 1). CGYRO gyrokinetic simulations reveal the governing physics in the core plasma of super H-modes: significant up-shift of nonlinear the ITG critical gradient is observed when applying E × B shear physics in the modeling based on experimental data. Furthermore, the effects of other physical parameters and contribution from pedestal height, which may play minor roles in this study, are also discussed.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2024

Measurement of small island characteristics using high resolution ECE and CER at DIII-D

Abstract The measurements using the high resolution electron cyclotron emission radiometry and the charge exchange and recombination spectroscopy are processed using analytic formulas to allow for the detection of islands as small as 1.9 cm. In contrast to large, saturated magnetic islands which are relatively well understood to be governed by the loss of bootstrap current inside the island, small islands are less well understood due to the difficulty of their accurate measurement in tokamaks. Here, ‘small’ islands are islands comparable in size to the ion banana width, which can be as small as 0.8 cm at DIII-D. The new measurement methods allow for the detection of small island widths when the predicted increase of mode frequency to match the Doppler shifted ion diamagnetic frequency is observed. Therefore, for the first time, the mode frequency increase can be unambiguously associated to the acceleration of the magnetic island propagation. Such association allows for a further development and validation of the much-debated theory of ion polarization currents, which is thought to govern the small island growth.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2025

Probing electromagnetic nonreciprocity with quantum geometry of photonic states

Reciprocal and nonreciprocal effects in dielectric and magnetic materials provide crucial information about the microscopic properties of electrons. However, experimentally distinguishing the two has proven to be challenging, especially when the associated effects are extremely small. To this end, we propose a contactless detection using a cross-cavity device where a material of interest is placed at its center. We show that the optical properties of the material, such as Kerr and Faraday rotation, or birefringence, manifest in the coupling between the cavity's electromagnetic modes and in the shift of their resonant frequencies. By calculating the dynamics of a geometrical photonic state, we formulate a measurement protocol based on the quantum metric and quantum process tomography that isolates the individual components of the material's complex refractive index and minimizes the quantum mechanical Cramér-Rao bound on the variance of the associated parameter estimation. Our approach is expected to be applicable across a broad spectrum of experimental platforms including Fock states in optical cavities, or coherent states in microwave and THz resonators. Published by the American Physical Society 2025

Petrides, Ioannis (ORCID:0000000174842444)↗
DOE OSTI2024

Dispersive nonreciprocity between a qubit and a cavity

The dispersive interaction between a qubit and a cavity is ubiquitous in circuit and cavity quantum electrodynamics. It describes the frequency shift of one quantum mode in response to excitations in the other and, in closed systems, is necessarily bidirectional, i.e., reciprocal. Here, we present an experimental study of a nonreciprocal dispersive-type interaction between a transmon qubit and a superconducting cavity, arising from a common coupling to dissipative intermediary modes with broken time reversal symmetry. We characterize the qubit-cavity dynamics, including asymmetric frequency pulls and photon shot noise dephasing, under varying degrees of nonreciprocity by tuning the magnetic field bias of a ferrite component in situ. We introduce a general master equation model for nonreciprocal interactions in the dispersive regime, providing a compact description of the observed qubit-cavity dynamics agnostic to the intermediary system. Our result provides an example of quantum nonreciprocal phenomena beyond the typical paradigms of non-Hermitian Hamiltonians and cascaded systems.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2025

Long-Range Allosteric Communication Modulated by Active Site Mn(II) Coordination Drives Catalysis in Xanthobacter autotrophicus Acetone Carboxylase

Acetone carboxylase (AC) from Xanthobacter autotrophicus is a 360 KDa α2β2γ2 heterohexamer that catalyzes the ATP-dependent formation of phosphorylated acetone and bicarbonate intermediates that react at Mn(II) metal active sites to form acetoacetate. Structural models of X. autotrophicus AC (XaAC) with and without nucleotides reveal that the binding and phosphorylation of the two substrates occurs ~40 Å from the Mn(II) active sites where acetoacetate is formed. Based on the crystal structures, a significant conformational change was proposed to open and close a tunnel that facilitates the passage of reaction intermediates between the sites for nucleotide binding and phosphorylation of substrates and Mn(II) sites of acetoacetate formation. We have employed electron paramagnetic resonance (EPR), kinetic assays, and hydrogen/deuterium exchange mass spectrometry (HDX-MS) of poised ligand-bound states and site-specific amino acid variants to complete an in-depth analysis of Mn(II) coordination and allosteric communication throughout the catalytic cycle. In contrast with the established paradigms for carboxylation, our analyses of XaAC suggested a carboxylate shift that couples both local and long-range structural transitions. Shifts in the coordination mode of a single carboxylic acid residue (αE89) mediate both catalysis proximal to a Mn(II) center and communication with an ATP active site in a separate subunit of a 180 kDa α2β2γ2 complex at a distance of 40 Å. This work demonstrates the power of combining structural models from X-ray crystallography with solution-phase spectroscopy and biophysical techniques to elucidate functional aspects of a multi-subunit enzyme.

Biochemistry & Molecular Biology↗
DOE OSTI2022

The role of toroidal rotation in the very high energy confinement quality observed in super H-mode experiments on DIII-D

In this paper, we report the key role that toroidal rotation and the related ExB shear physics played in the very high energy confinement quality (H98y2>1.5) of super H-mode experiments on DIII-D. Experiments show that the energy confinement quality decreases when toroidal rotation decreases due to the decreased externally controlled torque per particle. Meanwhile, the total pedestal pressure in the experiments remains very high during the rotation and confinement quality change. TGYRO transport modeling suggests the contribution from rotation in the ExB shear is responsible for the confinement quality in excess of standard H-mode (H98y2~1). CGYRO gyrokinetic simulations reveal the governing physics in the core plasma of super H-modes: significant up-shift of nonlinear the ITG critical gradient is observed when applying ExB shear physics in the modeling based on experimental data. The effects of other physical parameters and contribution from pedestal height, which may play minor roles in this study, are also discussed.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1981

End region and current consolidation effects upon the performance of an MHD channel for the ETF conceptual design

The effects of MHD channel end regions on the overall power generation were considered. The peak plant thermodynamic efficiency was found to be slightly lower than for the active region (41%). The channel operating point for the peak efficiency was shifted to the supersonic mode (Mach No., M sub c approx. 1.1) rather than the previous subsonic operation (M sub c approx. 0.9). The sensitivity of the channel performance to the B-field, diffuser recovery coefficient, channel load parameter, Mach number, and combustor pressure is also discussed. In addition, methods for operating the channel in a constant-current mode are investigated. This mode is highly desirable from the standpoint of simplifying the current and voltage consolidation for the inverter system. This simplification could result in significant savings in the cost of the equipment. The initial results indicate that this simplification is possible, even under a strict Hall field constraint, with resonable plant thermodynamic efficiency (40.5%).

Wang, S. Y.↗