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At least 163 records · Page 9

Paleo-Environment and C-14 Dating: The Key to the Depositional Age of the Tha Chang and Related Sand Pits, Northeastern Thailand

Tha Chang sand pits, Nakhon Ratchasima Province and many other sand pits in the area adjacent to the Mun River are characterized by their fluviatile environment in association with mass wasting deposits, along the paleo-river channel and the flood plain of the Mun River. Sediments of these deposits are characterized by clasts of various rock types especially the resistant ones with frequent big tree trunks, logs and wood fragments in different sizes and various stages of transformation from moldering stage to lignification and petrification. Widespread pyritization of the lower horizon suggests strongly reducing environment during burial. The Tha Chang deposits have been received much attention from geoscientists especially paleontologist communities, as they contain fragments of some distinct vertebrate species such as Stegadon sp., hominoid primate, rhinoceros Aceratherium and others. Based on the associated mammal fauna and hominoid fossils, the late Miocene ( 9 - 6 Ma) was given for the time of deposition of this sand and gravel unit. Some other reports believed that sediments and materials of these sand and gravel quarries (pits) were deposited by high-energy flood pulses contemporaneous with the tektites forming event during mid-Pleistocene at c. 0.8 Ma. Interpretation from Palynostratigraphical study suggested that the lower horizon of Tha Chang sand pit was deposited during Pliocene/Pleistocene period and the upper horizons are Pleistoncene/Holocene. It is crystal clear that all the fluviatile sediments including tektites and almost all fossil fragments being deposited in these sand pits were, likely a multiple times reworked materials. Only some old bamboo trees, some old crowling trees and fossils grasses observed on the old river bank are considered in situ. C-14 dating of 5 old wood specimens from Tha Chang Sand Pits, 15 old wood specimens from Chumpuang Sand Pits and one sample of old pottery from a Chumpuang Sand Pit were carried out in the NSF- Arizona AMS Laboratory. Although, there is no sharp boundary between the unconsolidated sedimentary horizons in the pits, C-14 ages obtained from the Tha Chang vary from 34,340 BP at the middle horizon (approx 10 m below ground zero) to >49,900 BP at the lower horizon with unknown basal formation (highly pyritized zone approx 20 - 25 m below ground zero). The ages for the Chumpuang vary from 41,700 BP, >45,900 BP and >49,900 BP from the upper most to the lower most of a broad horizon (approx 8 m to approx 12 m below ground zero). The C-14 age of the pottery collected from layer approximately 5 m below ground zero is 2,514 BP. The nature of fluviatile together with occasional mass wasting characteristics of all sand pits studies suggest the relatively faster depositional rate of the lower horizon which involved more flooding and mass wasting deposits than those of the upper horizons. The apparent of some mixing of the wood ages may indicate reworking and lag deposits nature of the area. The depositional rate of the upper most sand and soil horizon (5 m thick) is approximately 1 m per 500 years which mean both erosion and deposition had played a significant role during that time period. In term of the true age of the formation, we argue that since most of the materials deposited are reworked materials, all ages obtained from fossil fragments could not be the age of sand and gravel formation. Furthermore, the maximum age of all the tektite bearing horizons cannot be older than 0.8 Ma. The oldest C-14 age of 49,900 BP is interpreted as the minimum age of the Tha Chang and related sand pits formation when geomorphology of the area was a lot more hilly and much higher gradient than that of the present day.

Putthapiban, P.↗

Chronology of Steno Crater Basalt

The Apollo Next Generation Sample Analysis (ANGSA) program was designed to investigate specially curated samples returned by the Apollo 15 and 17 missions [1]. As part of this effort, we are examining a suite of Apollo 17 basalts collected from the rim of Steno Crater, to investigate the magmatic and post-magmatic volatile histories of these samples. Here we report initial 207Pb-206Pb chronology of accessory phases for two steno crater basalts, which will ultimately be paired with (40)Ar*/(39)Ar chronology and (38)Ar exposure ages to constrain crystallization and surface histories. The chronology of these samples will help determine if the samples derive from the one lava sequence or represent multiple lava flows, and will allow us to place petrologic and volatile data into the wider context of the magmatic suite [1,2]. Note: Extended abstract on document.

S. J. Pomeroy↗

Microcomputer-based programmable optical signal processor

A microcomputer-based real-time programmable optical signal processing system utilizing a magneto-optic spatial light modulator (MOSLM) and a liquid crystal light valve (LCLV) is described. This system can perform a myriad of complicated optical operations, such as image correlation, image subtraction, and matrix multiplication. Its important asserts are its programmability and the capability of real-time addressing. These are important for telerobotic vision in space automation applications. Design specifications and suggestions for practical implementation of the system are discussed. Some preliminary experimental demonstrations are conducted to demonstrate applications of the proposed system to image correlation for optical pattern recognition, image subtraction for lC chip inspection, and matrix multiplication for optical computing.

Yu, F. T. S.↗

QCM Thermo-Gravimetric Analysis (QTGA) Comparisons

The ASTM E-1559 apparatus has been used for years at NASA/Goddard Space Flight Center (GSFC) to determine in situ outgassing rate information, as well as pertinent in situ TML and multiple VCM values. The apparatus also affords the opportunity to experimentally compute the evaporation rates of molecular species that are reemitted as the Quartz Crystal Microbalances (QCMs) are gradually warmed up at some controlled temperature. Typically the molecular mass that accumulates onto the test QCMs are a compilation of species that are outgassing from the sample due to their respective activation energies and the desorption processes that the sample undergoes at various tested temperatures. It has been speculated that if there is too much molecular buildup of condensed water vapor (ice) onto the QCM crystal that a significantly higher temperature would be needed to break these "ice" bonds. ASTM E-1559 data plots will be used to demonstrate the thermogravimetric effects of water and other miscible molecular species with various water/ice thicknesses and at different evaporation rates.

Rosecrans, Glenn↗

Thermoelectric properties of Co(x)Ni(4-x)Sb(12-y)Sn(y) ternary skutterudites

Thermoelectric materials based on the skutterudite crystal structure have demonstrated enhanced performance (ZT greater than 1), along with good thermal stability and favorable mechanical properties. Binary skutterudites, with single and multiple fillers, have been intensively studied in recent years. Compared to binary skutterudites, the ternary systems have received less attention, e.g. Ni4Sb8Sn4. Ternary skutterudites are isoelectronic variants of binary skutterudites; cation substitutions appear to be isostructural to their binary analogues. In general, ternary skutterudites exhibit lower thermal conductivity. Ternary systems of Ni4Bi8Ge4, Ni4Sb8Ge4, and Ni4Sb8Sn4 were investigated using combined solidification and sintering steps. Skutterudite formation was not achieved in the Ni4Bi8Ge4 and Ni4Sb8Ge4 systems; skutterudite formation occurred in Ni4Sb8Sn4 system. P-type material was achieved by Co substitution for Ni. Thermoelectric properties were measured from 298 K to 673 K for Ni4Sb8Sn4, Ni4 Sb7Sn5 and Co2Ni2Sb7Sn5. N-type Ni4Sb8Sn4 exhibit the highest figure of merit of 0.1 at 523 K.

Seebeck Effect↗

Multiple scattering lidar returns from stratus clouds

Multiple scattering lidar returns from stratus clouds were measured using a multi-field-of-view (MFOV) lidar operating at 1.054 microns. The detector consists of four concentric silicon photodiodes which define half-angle fields of view (FOV) of 3.8, 12.5, 25 and 38.5 mrad. The central FOV receives the conventional lidar signal, while the outer FOV's receive only multiply scattered contributions. The ratios of the signals in the outer FOV's to the signal in the central FOV is an indication of the lateral spreading of the scattered component of the laser pulse as it propagates through the cloud. MFOV lidar returns from stratus clouds measured between October 1991 and March 1992 can be divided into two distinct types, those with large multiple scattering ratios and those with small ratios. An example of each type of return is shown. Both measurements were made at an elevation angle of 45 degrees. Clouds with small multiple scattering signals probably have a high concentration of much larger particles on the order of hundreds of micrometers in size. This is a typical size range for suspended ice crystals or precipitations. Stratus clouds often have a high concentration of ice crystals even when there is no precipitation. Large ice crystals would give smaller signals in the outer FOV's because much of the scattered intensity is contained in a narrow diffraction peak with an angular width on the order of milliradians. The result is that for a given extinction, many more orders of scattering are required for the laser pulse to spread out. So far we have not been able to do simulations of MFOV lidar returns from ice crystal clouds because of uncertainties about the phase function of the crystals, particularly the magnitude of the backscatter peak at 180 degrees. On two occasions, MFOV lidar returns measured just prior to snowfall, showed a striking vertical profile. An example is shown. From 900 to 1300m, the multiply scattered signals are negligible compared to the return in the central FOV. Abruptly, at 1300m strong signals begin in the outer FOVs. These results could be explained by the presence of a cloud layer composed of water droplets at a range of 1300m (or 900m above ground) with snow precipitations forming at the bottom of the cloud. By measuring the polarization ratio of lidar signals, Pal and Carswell have observed snow precipitating from a cloud layer composed of water droplets. Based on these results, we believe that analysis of multiple scattering lidar returns can yield important information on the phase of cloud particles.

Hutt, D. L.↗

Optical transmission measurements on monocrystalline and polycrystalline cesium iodide

A summary is presented of optical measurements performed on a variety of cesium iodide samples to characterize quantitatively the optical quality of the materials, and to define and measure parameters which determine its suitability as a detector material for high energy cosmic ray experiments on HEAO-A. The general case of light transmission through a long rectangular slab under multiple internal reflections is discussed along with transmission and scattering as a function of wavelength at normal incidence. Scattering parameters are tabulated for encapsulated single crystal CsI and polyscin.

Viehmann, W.↗

ADRF experiments using near n.pi pulse strings

Adiabatic demagnetization (ADRF) can be achieved in a dipolar coupled nuclear spin system in solids by applying a string of short RF pulses and gradually modulating the pulse amplitudes or pulse angles. This letter reports an adiabatic inverse polarization effect in solids and a rotary spin echo phenomenon observed in liquids when the pulse angle is gradually changed across integral multiples of pi during a string of RF pulses. The RF pulse sequence used is illustrated along with the NMR signal from a CaF2 single crystal as observed between the RF pulses and the rotary spin echo signal observed in liquid C6F6 for n = 2. The observed effects are explained qualitatively on the basis of average Hamiltonian theory.

Rhim, W. K.↗

Nucleation and Growth According to Lysozyme

How does one take a molecule, strongly asymmetric in both shape and charge distribution, and assemble it into a crystal? We propose a model for the nucleation and crystal growth process for tetragonal lysozyme that may be very germane to other monomeric proteins. The first species formed is postulated to be a dimer. Through repeating associations involving the same intermolecular interactions this becomes the 4(sub 3) helix, that in turn serves as the basic unit for nucleation and crystal growth. High salt attenuates surface charges while promoting hydrophobic interactions. Symmetry facilitates helix self-association. Assembly stability is enhanced when a four helix structure is obtained, with each bound to two neighbors. Only two unique interactions are required. The first are those for helix formation, where the dominant interaction is the intermolecular bridging anion. The second is the anti-parallel side-by-side helix-helix interaction, guided by alternating pairs of symmetry related salt bridges along each side. At this stage all eight unique positions of the P4(sub 3)2(sub 1)2(sub 1) unit cell are filled. From the above, the process is one of a) attenuating the most strongly interacting groups, such that b) the molecules begin to self-associate in defined patterns, so that c) symmetry is obtained, which d) propagates as a growing crystal. Simple and conceptually obvious in hindsight, this tells much about what we are empirically doing when we crystallize macromolecules. By adjusting the solution parameters we are empirically balancing the intermolecular interactions, preferentially attenuating the dominant strong (for lysozyme the charged groups) while strengthening the lesser strong (hydrophobic) interactions. Lysozyme is atypical in the breadth of its crystallization conditions; many proteins only crystallize under narrowly defined conditions, pointing to the criticality of the empirical balancing process. Lack of a singularly defined association pathway leads to formation of multiple species, i.e., amorphous precipitation. Weak interactions, such as hydrogen bonds, are promiscuous, serving to strengthen rather than define specific interactions. Participation in an interaction sequesters that surface from subsequent interactions, and we expect the strongest bonds to form first. When two molecules self associate the resulting species will have an axis of symmetry. Subsequent interactions between two associated species having equivalent interactions will also have symmetry. Only a few unique sets of interactions are required to give any of the commonly found space groups for monomeric proteins. This model and what it suggests will be discussed.

Pusey, Marc L.↗

A Tool for Medical Research

California Measurements, Inc.'s PC-2 Aerosol Particle Analyzer, developed by William Chiang, a former Jet Propulsion Laboratory (JPL) engineer, was used in a study to measure the size of particles in the medical environment. Chiang has a NASA license for the JPL crystal oscillator technology and originally built the instrument for atmospheric research. In the operating room, it enabled researchers from the University of California to obtain multiple sets of data repeatedly and accurately. The study concluded that significant amounts of aerosols are generated during surgery when power tools are employed, and most of these are in the respirable size. Almost all contain blood and are small enough to pass through surgical masks. Research on the presence of blood aerosols during oral surgery had similar results. Further studies are planned to determine the possibility of HIV transmission during surgery, and the PC-2H will be used to quantify blood aerosols.

Source record↗

Progress of Crew Autonomous Scheduling Test (CAST) On the ISS

The United States space policy is evolving toward missions beyond low Earth orbit. In an effort to meet that policy, NASA has recognized Autonomous Mission Operations (AMO) as a valuable capability. Identified within AMO capabilities is the potential for autonomous planning and replanning during human spaceflight operations. That is allowing crew members to collectively or individually participate in the development of their own schedules. Currently, dedicated mission operations planners collaborate with international partners to create daily plans for astronauts aboard the International Space Station (ISS), taking into account mission requirements, ground rules, and various vehicle and payload constraints. In future deep space operations the crew will require more independence from ground support due to communication transmission delays. Furthermore, crew members who are provided with the capability to schedule their own activities are able to leverage direct experience operating in the space environment, and possibly maximize their efficiency. CAST (Crew Autonomous Scheduling Test) is an ISS investigation designed to analyze three important hypotheses about crew autonomous scheduling. First, given appropriate inputs, the crew is able to create and execute a plan in a reasonable period of time without impacts to mission success. Second, the proximity of the planner, in this case the crew, to the planned operations increases their operational efficiency. Third, crew members are more satisfied when given a role in plan development. This presentation shows the progress done in this study with a single astronaut test subject participating in five CAST sessions. CAST is a technology demonstration payload sponsored by the ISS Research Science and Technology Office, and performed by experts in Mission Operations Planning from the Flight Operations Directorate at NASA Johnson Space Center, and researchers across multiple NASA centers.

Healy, Matthew↗

Apollo-Soyuz pamphlet no. 8: Zero-g technology

The behavior of liquids in zero gravity environments is discussed with emphasis on foams, wetting, and wicks. A multipurpose electric furnace (MA-010) for the high temperature processing of metals and salts in zero-g is described. Experiments discussed include: monolectic and synthetic alloys (MA-041); multiple material melting point (MA-150); zero-g processing of metals (MA-070); surface tension induced convection (MA-041); halide eutectic growth; interface markings in crystals (MA-060); crystal growth from the vapor phase (MA-085); and photography of crystal growth (MA-028).

Page, L. W.↗

Thermosolutal convection during directional solidification. II - Flow transitions

The influence of thermosolutal convection on solute segregation in crystals grown by vertical directional solidification of binary metallic alloys or semiconductors is studied. Finite differences are used in a two-dimensional time-dependent model which assumes a planar crystal-melt interface to obtain numerical results. It is assumed that the configuration is periodic in the horizontal direction. Consideration is given to the possibility of multiple flow states sharing the same period. The results are represented in bifurcation diagrams of the nonlinear states associated with the critical points of linear theory. Variations of the solutal Rayleigh number can lead to the occurrence of multiple steady states, time-periodic states, and quasi-periodic states. This case is compared to that of thermosolutal convection with linear vertical gradients and stress-free boundaries.

Mcfadden, G. B.↗

Monolithic, High-Speed Fiber-Optic Switching Array for Lidar

Current fiber switch technologies use mechanical means to redirect light beams, resulting in slow switch time, as well as poor reliability due to moving parts wearing out quickly at high speeds. A non-mechanical ability to switch laser output into one of multiple fibers within a fiber array can provide significant power, weight, and costs savings to an all-fiber system. This invention uses an array of crystals that act as miniature prisms to redirect light as an electric voltage changes the prism s properties. At the heart of the electro-optic fiber-optic switch is an electro- optic crystal patterned with tiny prisms that can deflect the beam from the input fiber into any one of the receiving fibers arranged in a linear array when a voltage is applied across the crystal. Prism boundaries are defined by a net dipole moment in the crystal lattice that has been poled opposite to the surrounding lattice fabricated using patterned, removable microelectrodes. When a voltage is applied across the crystal, the resulting electric field changes the index of refraction within the prism boundaries relative to the surrounding substrate, causing light to deflect slightly according to Snell s Law. There are several materials that can host the necessary monolithic poled pattern (including, but not limited to, SLT, KTP, LiNbO3, and Mg:LiNbO3). Be cause this is a solid-state system without moving parts, it is very fast, and does not wear down easily. This invention is applicable to all fiber networks, as well as industries that use such networks. The unit comes in a compact package, can handle both low and high voltages, and has a high reliability (100,000 hours without maintenance).

Suckow, Will↗

Local heat transfer measurement with liquid crystals on rotating surfaces including non-axisymmetric cases

An overview and summary of test methods and results are given for the problem of measuring local heat transfer on rotating surfaces that model gas turbine engine disks. Disk cavity situations generically similar to those encountered in the high pressure stage disk cooling are considered, with cooling air supplied both at or near the wheel centerline as well as through single or multiple jets impinging outboard on the wheel near the blade attachment region. In some situations provision has been made for ingestion into the disk-cavity from the gas path region radially outboard of the disk. Local heat transfer rates in all cases are determined from the color display from a thin coating of encapsulated liquid crystals sprayed onto the disk, in conjunction with use of a video camera and computer vision system. For cases with axisymmetric disk surfaces, the coated surfaces are illuminated and viewed continuously, and detailed radial distributions of local Nusselt number are obtained. For non-axisymmetric disk surfaces, such as encountered in the vicinity of bolt heads, the disk is illuminated with stroboscopic light, and a method has been developed and used to synchronize the computer frame grabber with the illumination.

Metzger, D. E.↗

Interfacial and Hydrodynamic Behavior of Thin Spherical Bubbles of Smectic Liquid Crystal in Microgravity

The Observation and Analysis of Smectic Islands in Space (OASIS) project comprises a series of experiments that probe the interfacial and hydrodynamic behavior of thin spherical bubbles of smectic liquid crystal in microgravity. Smectic films are the thinnest known structures formed of condensed phases, making them ideal for studies of two-dimensional (2D) coarsening dynamics and thermocapillary phenomena. The OASIS flight hardware was launched on SpaceX-6 in April 2015 and experiments were carried out on the International Space Station using four different smectic A and C liquid crystal materials in separate sample chambers. We will describe the behavior of collective island dynamics on the bubbles, including temperature-gradient-induced thermomigration, 2D Rayleigh-Plateau Instability, Oswald ripening dynamics, the single and multiple island diffusion on the curved surface and coalescence-driven coarsening dynamics of island emulsions in microgravity. On Earth, such island emulsions would rapidly sediment to the bottom of the bubble and coalesce, but in microgravity, coarsening of the emulsion can be observed free of gravitational effects.

liquid crystal↗

A Proposed Model for Protein Crystal Nucleation and Growth

How does one take a molecule, strongly asymmetric in both shape and charge distribution, and assemble it into a crystal? We propose a model for the nucleation and crystal growth process for tetragonal lysozyme, based upon fluorescence, light, neutron, and X-ray scattering data, size exclusion chromatography experiments, dialysis kinetics, AFM, and modeling of growth rate data, from this and other laboratories. The first species formed is postulated to be a 'head to side' dimer. Through repeating associations involving the same intermolecular interactions this grows to a 4(sub 3) helix structure, that in turn serves as the basic unit for nucleation and subsequent crystal growth. High salt attenuates surface charges while promoting hydrophobic interactions. Symmetry facilitates subsequent helix-helix self-association. Assembly stability is enhanced when a four helix structure is obtained, with each bound to two neighbors. Only two unique interactions are required. The first are those for helix formation, where the dominant interaction is the intermolecular bridging anion. The second is the anti-parallel side-by-side helix-helix interaction, guided by alternating pairs of symmetry related salt bridges along each side. At this stage all eight unique positions of the P4(sub3)2(sub 1),2(sub 1) unit cell are filled. The process is one of a) attenuating the most strongly interacting groups, such that b) the molecules begin to self-associate in defined patterns, so that c) symmetry is obtained, which d) propagates as a growing crystal. Simple and conceptually obvious in hindsight, this tells much about what we are empirically doing when we crystallize macromolecules. By adjusting the growth parameters we are empirically balancing the intermolecular interactions, preferentially attenuating the dominant strong (for lysozyme the charged groups) while strengthening the lesser strong (hydrophobic) interactions. In the general case for proteins the lack of a singularly defined association pathway may lead to formation of multiple species, i.e., amorphous precipitation. Weak interactions, such as hydrogen bonds, are promiscuous, serving to strengthen rather than define specific interactions. Participation in an interaction sequesters that surface from subsequent interactions, and we expect the strongest bonds to form first. This model, its basis, how it fits into the currently understood osmotic second virial coefficient approach to crystallization, and what it suggests will be discussed.

Pusey, Marc↗

Ultrasonic transducer with a two-dimensional Gaussian field profile

A transducer is described which generates a two-dimensional Gaussian field by controlling both the position of multiple circular electrodes and the voltage applied to each electrode. The transducer is constructed by depositing concentric rings electrodes onto one flat surface of a circular piezoelectric crystal disk and attaching the rings to an impedance matching network which acts as a voltage divider. Geometrical inter-ring separations and electrical inter-ring impedances are designed to minimize the error between the generated acoustic field, modeled as a piecewise linear function, and the desired Gaussian distribution. Total mean squared error between the averaged far-field data and a Gaussian shape is less than two percent.

Claus, R. O.↗