Optical effect of the contamination of infrared windows by the outgassing of materials in outer space
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Samples of S-13 paint on aluminum, reflection grating anomalies as affected by dielectric coatings, and rocket effluents were analyzed along with Skylab window scrapings and a gas activated semiconductor. Development of an HCl detector is also discussed. Results are briefly summarized.
Recent measurements of rare gas abundances on Mars by Viking are used in testing an inhomogeneous accretion model for Mars. It is found that not only the relative abundance of H, C, N, Ne-20, A-36, Kr, and Xe, but their total amounts can be best explained if the outer layers of earth and Mars were made of a material similar to ordinary chondrites.
Attitude control of levitated object achieved by using laser to vaporize selectively sublimate coating. Laser heats material that will sublime or outgas. To obtain torque reaction force vector from subliming material must not pass through center-of-mass of object. Laser provides beam suitable for controlling objects in noncontact manufacturing processes in acoustic levitation chambers.
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A purge and trap technique which was employed to collect and separate the chemicals desorbing from the space shuttle heat protection tiles is described. The instrumentation included a mass spectrometer and gas chromatograph.
An alternative time-independent model of the ion partitioning in the hot Io torus is proposed which introduces the ratio of sulfur to oxygen in the neutral source as a free parameter. Measurements of the ion abundances in the torus plasma are presented and discussed, noting some ambiguities and identifying the features that are well established. Physical processes important to the understanding of the ion partitioning calculation are reviewed. The results of the model are discussed in the context of observational constraints, and spectroscopic constraints are discussed. It is concluded that a bimodal source model, together with a small percentage of hot electrons and a relatively short diffusion time scale, can account for the principal observational features without invoking significant time variability. In particular, the O III deficiency observed in 1981 can be obtained in a model that produces other aspects of the torus ion partitioning measured during the Voyager 1 encounter.
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A concept of a collimated flow of ejecta from a discrete source (vent) on the surface of a rotating cometary nucleus is applied to P/Encke, based on positional observations of its sunward fanlike coma at 13 apparitions between 1924 and 1984. The major results include a finding that the observations are consistent with an invariable position of the rotation pole during the 60 yr (yielding an obliquity of 70 deg), although this is not to be interpreted as an indication that the nucleus is not precessing. Two vents are identified on the nucleus surface: one on the northern hemisphere at a latitude of +55 deg, of an estimated sublimitation area of 0.4 sq km, which is active along the inbound leg of the comet's orbit until a few days preperihelion and again beginning several weeks postperihelion; the other on the southern hemisphere at -75 deg, of an estimated area of 0.6 sq km, whose activity prevails in the intervening time. There appears to be a significant difference between the two regions in terms of dust content in their emissions.
Argon and Xe in the Martian atmosphere are radiogenic relative to the Martian mantle if the SNC meteorites are from Mars. Decay of the short lived isotope I-129 to Xe-129 (t sub 1/2 = 16 m.y.) is the most plausible source of the radiogenic Xe. This short half life constrains any process responsible for the elevated Xe-129/Xe-132 ratio of the Martian atmosphere to occur very early in solar system history. Musselwhite et al. proposed that the differential solubility of I and Xe in liquid water played a key role in producing the radiogenic signature in the Martian atmosphere. Here we explore an alternative hypothesis involving purely igneous processes, and motivated in part by new experimental results on the partitioning of I and Xe between minerals and melt.
Similarities in the size and mean density of Earth and Venus encourage the use of Earth-analogue models for the evolution of Venus. However, the amount of water in the present Venus atmosphere is miniscule compared to Earth's oceans. The 'missing' water is thus one of the most significant problems related to the origin and evolution of Venus. Other researchers proposed that Venus accreted with less water, but this was challenged. The high D/H ratio in Venus' atmosphere is consistent with an earlier water mass more than 100 times higher than at present conditions and is often cited to support a 'wet' Venus, but this amounts to only 0.01 to 0.1 percent of the water in terrestrial oceans and the high D/H ratio on Venus could easily reflect cometary injection. Nevertheless, many authors begin with the premise that Venus once had an oceanlike water mass on its surface, and investigate the many possible mechanisms that might account for its loss. In this paper we propose that Venus degassed to lower degree than the Earth and never had an oceanlike surface water mass.
Conceptual models for various types of features observed in cometary comae (jets, spirals, halos, fans, etc.), their computer simulation, and the hydrodynamic models for jet formation are critically reviewed, and evidence for anisotropic, strongly collimated flows of ejecta emanating from discrete active regions (vents) on the rotating cometary nuclei is presented. Techniques employed to generate synthetic comet images that simulate the features observed are described, and their relevance to the primary objects of coma-morphology studies is discussed. Modeling of temporal variations in the water emission from discrete active regions suggests that production curves asymmetric with respect to perihelion should be commonplace. Critical comparisons with the activity profiles of Enke's comet and with light curves of disappearing comets and comets that undergo outbursts are presented. Recent developments in the understanding of the processes that cause the nongravitational perturbations of cometary motions are reviewed, and the observed discontinuities are identified with the birth of new sources and/or deactivation of old vents.
Isoline maps of the Style II nongravitational parameters A1 and A2 of periodic comets are presented for a baseline model as functions of the parameters of the inertially fixed spin vector and the source's location-dependent thrust angle. The parameters A1 and A2 for a collection of sources are equal to the sum of their values for the individual contributors, thus depending on the source distribution. The model is consistent with even the most extreme among detected perturbations, including instances of rapid temporal changes in A2 and the discontinuous orbital anomalies, which are interpreted as products of a sudden redistribution of the transferred momentum due to episodic activation of short-lived sources. It is argued that the lifetimes of active regions vary considerably from case to case, and forced precession of the nucleus strongly influences the comet's activity pattern.
The recontamination of a spacecraft surface directly exposed to the ram flux is investigated. It is assumed that the surface has been contaminated by a rocket plume contact and that, subsequent to the exposure, the contaminated surface is placed in the ram flux. A BGK-simulation was compared to both a Direct Simulation Monte Carlo (DSMC) and a Full Flow Monte Carlo (FFMC) using sensitivity analysis. Results indicate that the BGK-based simulation underpredicted the return flux contamination as compared to both the DSMC and FFMC techniques. Results from the full flow model suggest that the BGK model is inadequate to represent this physical problem.
A new release rate equation to model the phase change of water to steam in composite materials was derived from the theory of molecular diffusion and equilibrium moisture concentration. The new model is dependent on internal pressure, the microstructure of the voids and channels in the composite materials, and the diffusion properties of the matrix material. Hence, it is more fundamental and accurate than the empirical Arrhenius rate equation currently in use. The model was mathematically formalized and integrated into the thermostructural analysis code CHAR. Parametric studies on variation of several parameters have been done. Comparisons to Arrhenius and straight-line models show that the new model produces physically realistic results under all conditions.
Work done in the period Jan. - June 1994 is summarized. Two threads of research have been followed. First, the thermodynamics approach was used to model the chemical and mechanical responses of composites exposed to high temperatures. The thermodynamics approach lends itself easily to the usage of variational principles. This thermodynamic-variational approach has been applied to the transpiration cooling problem. The second thread is the development of a better algorithm to solve the governing equations resulting from the modeling. Explicit finite difference method is explored for solving the governing nonlinear, partial differential equations. The method allows detailed material models to be included and solution on massively parallel supercomputers. To demonstrate the feasibility of the explicit scheme in solving nonlinear partial differential equations, a transpiration cooling problem was solved. Some interesting transient behaviors were captured such as stress waves and small spatial oscillations of transient pressure distribution.
The photolysis of three organic materials, by vacuum ultraviolet (VUV) radiation, has been quantified using 15-MHz temperature-controlled quartz microbalances (TQCM's). The rate at which molecular species, released from the individual samples, condensed on two TQCM s was measured for periods of up to 139.9-hours. The individual samples were heated in an effusion cell and the emitted molecular species collected on a pair of TQCM's which were maintained at -40 degrees Celsius. At several points during the deposition measurement, the deposition surface of one TQCM was illuminated by a 30 Watt deuterium lamp, and the loss of material from that surface was observed. V W illumination of the TQCM, concurrent with condensation, reduced the rate that material was lost from the deposition surface. These measurements present a contrasting picture of molecular deposition, in the presence of VUV, to that presented by other investigators who observed an enhanced rate of molecular deposition, when the deposition surface was illuminated by VUV.