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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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234 records · Page 9

Thermal Performance of Common Bulk-Fill Cryogenic Insulation Materials in Helium and Hydrogen Background Gases

Maritime shipping of vast quantities of liquid hydrogen (LH 2 ) will be necessary to facilitate a global hydrogen ecosystem; with some studies estimating volumes up to 172,000 m 3 for individual tanker ships, and requiring stationary storage tanks at terminals of 50,000 m 3 to 100,000 m 3 —ten to fifteen times larger than the current largest tank, located at launch pad B at NASA Kennedy Space Center (KSC). Such a radical scale-up will push the boundary of traditional, vacuum-insulated tank designs. Hence, a potential need exists for non-vacuum solutions, which necessitates exploring the thermal performance of insulation materials in non-condensable background gasses at LH 2 temperatures, namely helium and hydrogen. Testing of two bulk-fill insulation materials common to large LH 2 storage tanks, perlite and glass bubbles, in helium and hydrogen was recently conducted by the Cryogenics Test Laboratory at KSC using the Cryostat-100 liquid nitrogen boiloff calorimeter per the ASTM C1774 standard methodology. Effective thermal conductivity (k e ) and heat flux (q) results for each insulation/gas combination are presented across the full vacuum range, as well as thermal profiles through the insulation thickness between 78 K and 293 K.

A M Swanger

Advanced Liquid Propulsion Systems

The Advanced Liquid Propulsion Systems program is investigating selected problems generated by spacecraft operational requirements for propulsion systems capable of high inherent reliability, long-term storage in the space environment, multiple start in free fall (zero gravity), and engine throttling. The solutions proposed to satisfy these requirements are coordinated for practical application in a system.

PROPULSION SYSTEM

Controls for Electrified Aircraft Propulsion

Advanced electrified aircraft propulsion (EAP) concepts with integrated power, propulsion, and thermal systems require the development of equally sophisticated controllers to fly safe and efficient missions. Hybrid electric aircraft utilize electric machines mechanically coupled to the engine shafts to extract and insert power for a variety of purposes. Additionally, electric machines may drive propulsive fans pulling from a combination of on-board energy storage devices and engine extracted power. NASA’s investment in hybrid electric aircraft hardware-in-the-loop testing enables controls research on representative engine models using a novel emulation and scaling methodology. High-voltage, high-power electrical powertrain presents several technical risks at altitude. High-power requires high efficiency to minimize losses. Superconducting electric machines and power distribution research at NASA has identified key challenges with potential controls solutions. These risks necessitate the development of controllers robust to model uncertainty, disturbances, and fault conditions. System health management and fault detection schemes play an important role in a multi-layer controls approach that utilizes a supervisor which oversees inner loops for the highly coupled power, propulsion, and thermal systems. Such a supervisory controller enables coordinates energy transfer between engines, energy storage devices, electric machines, propulsors, and heat exchangers. Existing methods have shown an improvement in engine operability using the hybrid electric powertrain.

Halle E Buescher

Safety considerations for fabricating lithium battery packs

Lithium cell safety is a major issue with both manufacturers and end users. Most manufacturers have taken great strides to develop the safest cells possible while still maintaining performance characteristics. The combining of lithium cells for higher voltages, currents, and capacities requires the fabricator of lithium battery packs to be knowledgable about the specific electrochemical system being used. Relatively high rate, spirally wound (large surface area) sulfur oxychloride cells systems, such as Li/Thionyl or Sulfuryl chloride are considered. Prior to the start of a design of a battery pack, a review of the characterization studies for the cells should be conducted. The approach for fabricating a battery pack might vary with cell size.

Ciesla, J. J.

Primary battery design and safety guidelines handbook

This handbook provides engineers and safety personnel with guidelines for the safe design or selection and use of primary batteries in spaceflight programs. Types of primary batteries described are silver oxide zinc alkaline, carbon-zinc, zinc-air alkaline, manganese dioxide-zionc alkaline, mercuric oxide-zinc alkaline, and lithium anode cells. Along with typical applications, the discussions of the individual battery types include electrochemistry, construction, capacities and configurations, and appropriate safety measures. A chapter on general battery safety covers hazard sources and controls applicable to all battery types. Guidelines are given for qualification and acceptance testing that should precede space applications. Permissible failure levels for NASA applications are discussed.

Bragg, Bobby J.

RCA SATCOM Battery in Orbit Performance Update and Accelerated Life Test Results

No significant degradation of nickel cadmium battery performance in SATCOM F1 and F2 after almost 8 and 7-3/4 years in orbit was shown. Battery minimum discharge voltage data are presented for these spacecraft. In addition, 2 groups of nickel cadmium cells which are representative of those in orbit are undergoing real time eclipse-reduced suntime cycling in the laboratory. These groups of cells, which are being cycled at a maximum of 53% and 62% depth of discharge (based on actual capacity), have completed 14 and 15 eclipse seasons, respectively. Data for these groups of cells are presented and are compared with the in-orbit battery data.

Gaston, S. J.

Bosch Carbon Catalyst Regeneration in Water I: Bosch Carbon Removal from Reacted Beads Utilizing Mechanical Agitation

The ability to recover oxygen from metabolic carbon dioxide is crucial for crewed long duration missions in which the atmosphere must be recycled. Two physiochemical methods are primarily employed for this purpose: the Bosch process and the Sabatier reaction. This paper focuses on the Bosch process. It utilizes hydrogen in the presence of a catalyst to form water and solid carbon out of metabolic carbon dioxide. The solid carbon product deposits onto the catalyst and eventually causes reactor over pressurization issues. Multiple methods are currently being investigated to regenerate the catalyst’s surface and break up the pressure causing carbon clogs. This paper explores whether water and mechanical abrasion would work to remove Bosch carbon by testing multiple washing conditions. The different washing conditions involved agitation intensity, heating, duration, and volume of water. It was found that it is possible to break up the clumps of carbon formed in the reactor through agitation with room temperature water in one hour and shows promise for completely cleaning the carbon off the beads’ surface.

Agitation

Cryopump for Large Pulses of Hydrogen

A test involving a flow of hot hydrazine decomposition products at a rate of 13.6 g/s (0.03 lb/s) established the requirement to maintain pressure in an 11.9-m-(39 ft) diameter space chamber below 200 microns. The flow, 2/3 hydrogen and 1/3 nitrogen by volume, continued for several periods ranging from 3 to 15 min. The pressure requirement was necessary to minimize thermal effects of the gas on the test vehicle but was well beyond the capability of the existing facility pumps. Various methods of obtaining additional temporary jump capacity were considered. From these, the slugged-charcoal approach was selected as the quickest and least expensive method to implement.

B C Moore

Synthetic battery cycling techniques

The group of techniques that as a class are referred to as synthetic battery cycling are described with reference to spacecraft battery systems. Synthetic battery cycling makes use of the capability of computer graphics to illustrate some of the basic characteristics of operation of individual electrodes within an operating electrochemical cell. It can also simulate the operation of an entire string of cells that are used as the energy storage subsystem of a power system.

Leibecki, H.

Nitrile/Buna N Material Failure Assessment for an O-Ring used on the Gaseous Hydrogen Flow Control Valve (FCV) of the Space Shuttle Main Engine

After the rollout of Space Shuttle Discovery in April 2005 in preparation for return-to-flight, there was a failure of the Orbiter (OV-103) helium signature leak test in the gaseous hydrogen (GH2) system. Leakage was attributed to the Flow Control Valve (FCV) in Main Engine 3. The FCV determined to be the source of the leak for OV-103 is designated as LV-58. The nitrile/Buna N rubber O-ring seal was removed from LV-58, and failure analysis indicated radial cracks providing leak paths in one quadrant. Cracks were eventually found in 6 of 9 FCV O-rings among the three Shuttle Orbiters, though none were as severe as those for LV-58, OV-103. Testing by EM10 at MSFC on all 9 FCV O- rings included: laser dimensional, Shore A hardness and properties from a dynamic mechanical analyzer (DMA) and an Instron tensile machine. The following test data was obtained on the cracked quadrant of the LV-58, OV-103 O-ring: (1) the estimated compression set was only 9.5%, compared to none for the rest of the O-ring; (2) Shore A hardness for the O.D. was higher by almost 4 durometer points than for the rest of the O-ring; and (3) DMA data showed that the storage/elastic modulus E was almost 25% lower than for the rest of the O-ring. Of the 8 FCV O-rings tested on an Instron, 4 yielded tensile strengths that were below the MIL spec requirement of 1350 psi-a likely influence of rubber cracking. Comparisons were made between values of modulus determined by DNA (elastic) and Instron (Young s). Each nitrile/Buna N O-ring used in the FCV conforms to the MIL-P-25732C specification. A number of such O-rings taken from shelf storage at MSFC and Kennedy Space Center (KSC) were used to generate a reference curve of DMA glass transition temperature (Tg) vs. shelf storage time ranging from 8 to 26 years. A similar reference curve of TGA onset temperature (of rubber weight loss) vs. shelf storage time was also generated. The DMA and TGA data for the used FCV O-rings were compared to the reference curves. Correlations were also made between the DMA modulus (at 22 C) and Shore A hardness for all 9 of the FCV O-rings used among the three Shuttle Orbiters. The radial cracking in the FCV O-rings was determined to be due to ozone attack, as nitrile/Buna N rubber is susceptible to such attack. Nitrile/Buna N material under MIL-P25732C should be used in a hydraulic fluid environment to help protect it from cracking. However, the FCV O-rings were used in an air only environment. The FCV design has as much as a 9-mil gap that allows the O.D. of the O-ring to be directly exposed to ozone, pressurized air and some elevated temperatures, accelerating the weathering process that leads to O-ring cracking. Space Shuttle flights will likely not continue past 2010. Therefore, Shuttle management decided to continue using the nitrile/Buna N material for the FCVs, but have each O-ring replaced after 3 years to minimize any chances for crack initiation.

Doug Wingard

Dynamic Analysis of the STARC-ABL Propulsion System

In the pursuit of Electrified Aircraft Propulsion (EAP), much of the attention is on the development of hybrid electric concept vehicles and their propulsion systems from a steady state performance perspective. While it is steady-state performance that largely determines the efficiency of civil air transports, engine operability and transient performance define constraints for the steady state design that impact efficiency and system viability. Neglecting dynamics and control technologies can result in an over-designed, sub optimal propulsion system or a concept that is not feasible. Thus, dynamic system studies were conducted on the propulsion system of the conceptual aircraft design known as the Single-aisle Turboelectric AiRCraft with Aft Boundary Layer propulsor (STARC-ABL). This paper describes the development of a controller to verify the baseline concept's feasibility from an operability perspective. Further, studies were conducted to identify excessive stability margin in the baseline design that could be traded for potential benefits in efficiency through an engine re design. This study revealed the potential to reduce the high pressure compressor (HPC) stall margin by 3%. Finally, a study was conducted to investigate the potential benefit of adding energy storage to the STARC-ABL concept that further improves operability and enables more gains in engine efficiency and performance. The energy storage provided an additional 0.5% stall margin can be removed from the HPC.

hybrid electric propulsion

Optimization of a 10–Step Reduced CH₄/O₂ Combustion Mechanism for RDRE Applications

A 10-step, 9-species reduced mechanism for methane/oxygen combustion is evaluated and optimized for use in rotating detonation rocket engine (RDRE) simulations at an operating pressure of 10 bar. The mechanism is assessed against GRI-Mech 3.0 for ignition delay times, adiabatic equilibrium temperature and species, Chapman-Jouguet (CJ) detonation parameters, and laminar flame speed. A sequential Nelder–Mead optimization procedure is applied to the rate constants of reactions R1, R4, and R5, targeting ignition delay agreement over the equivalence ratio range φ = 1.0–1.4 and temperature range T = 1400–2000 K. The optimized mechanism achieves ignition delay agreement within 28% of GRI-Mech 3.0 for the temperature range relevant to RDRE operation (τ ≥ 5 μs). Adiabatic equilibrium temperatures and CJ detonation parameters are reproduced within 0.15% of GRI-Mech 3.0 values, confirming thermodynamic consistency of the mechanism. Laminar flame speed predictions deviate significantly from GRI-Mech 3.0, which is attributed to the absence of HO₂ chemistry in the reduced mechanism; this limitation does not affect RDRE simulation fidelity since laminar flame propagation is of secondary importance in RDREs.

Computational Fluid Dynamics

Battery Control Boards for Li-Ion Batteries on Mars Exploration Rovers

Rechargeable Lithium-ion batteries have been operating successfully on both Spirit and Opportunity rovers for the last two years, which includes six months of Assembly Launch and Test Operations (ATLO), seven months of cruise and about eleven months of surface operations. The Battery Control Boards designed and fabricated in-house would protect cells against overcharge and over-discharge and provide cell balance. Their performance has thus far been quite satisfactory. The ground data o the mission simulation battery project little capacity loss of less than 3% during cruise and 180 sols. Batteries are poised to extend the mission beyond six months, if not a couple of years.

Ewell, R.

The Chemical Composition of the Cores of the Terrestrial Planets and the Moon

Using models of the quasi-chemical theory of solutions, the activity coefficients of silicon are calculated in the melts Fe-Si, Ni-Si, and Fe-Ni-Si. The calculated free energies of solution of liquid nickel and silicon in liquid iron in the interval 0 to 1400 kbar and 1500 to 4000 K, shows that Fe-Ni-Si alloy is stable under the conditions of the outer core of the Earth and the cores of the terrestrial planets. The oxidation-reduction conditions are studied, and the fugacity of oxygen in the mantles of the planets and at the core-mantle boundary are calculated. The mechanism of reduction of silicon is analyzed over a broad interval of P and T. The interaction between the matter of the core and mantle is studied, resulting in the extraction of silicon from the mantle and its solution in the material of the core. It is concluded that silicon can enter into the composition of the outer core of the Earth and Venus, but probably does not enter into the composition of the cores of Mercury, Mars, and the Moon, if in fact the latter possesses one.

O L Kuskov

Self Discharge of Nickel-Hydrogen Cells

Values for the capacity loss with time, naturally on open circuit stand, and information regarding the minimum amount of circuit charge needed to keep the cell charged can be determined from the self-discharge behavior of nickel hydrogen cells. Furthermore, the rate of reaction between hydrogen and a charged nickel electrode is also open for nickel cadmium batteries. In a nickel hydrogen cell, the hydrogen is stored as pressurized gas and the cell stack with the charge that is oxidized nickel-hydroxide electrode is in direct contact with the hydrogen. Therefore, the rate of reaction can be measured easily and precisely by monitoring the charge, the change in hydrogen pressure with time. Measures made on twelve 15 ampere hour nickel hydrogen cells of different stack configurations built for COMSAT are discussed.

G Holleck

A Study of Space Environment Effect on Highly Thermally Conductive Hybrid Carbon Fiber Polymer Composites

A set of novel highly thermally conductive hybrid carbon fiber (CF) polymer composites has been developed for lightweight thermal radiator applications in space missions. This study investigates the effects of the space environment on these materials following exposure in low-Earth orbit (LEO) during the Materials International Space Station Experiment (MISSE)-17 flight mission, where samples experienced 159 days of combined atomic oxygen (AO), ultraviolet (UV) radiation, high vacuum, space radiation and thermal cycling. Post-flight characterization included weight loss, surface morphology, thermo-optical properties, molecular structures, glass transition temperature, thermal degradation and thermal conductivity analyses. The pyrolytic graphite sheet (PGS) samples exhibited negligible weight loss, stable thermo-optical property, and only minor oxidation signature on the exposed surface. Although AO erosion of the epoxy polymer matrix was evident, carbon nanotube (CNT)-infused PGS/CF epoxy composites retained high thermal emissivity and preserved their high thermal conductivities. These results demonstrate that the novel highly thermally conductive hybrid CF composites possess strong environmental resilience and are promising candidates for lightweight thermal radiators and thermal management components in future space exploration missions.

Space Environment

Battery Cell Thermal Runaway Calorimeter

We currently have several methods for determining total energy output of an 18650 lithium ion cell. We do not, however, have a good method for determining the fraction of energy that dissipates via conduction through the cell can vs. the energy that is released in the form of ejecta. Knowledge of this fraction informs the design of our models, battery packs, and storage devices; (a) No longer need to assume cell stays together in modeling (b) Increase efficiency of TR mitigation (c) Shave off excess protection.

Darcy, Eric

Transit Thermal Control Design for Galileo Entry Probe for Planet Jupiter

A totally passive design was completed for the thermal control of the Galileo entry probe during its transit to the planet Jupiter. The design utilizes radio isotope heater units, multilayer insulation blankets and a thermal radiator in conjunction with a design conductance support structure to achieve both the required storage and critical initial planet atmosphere entry temperatures. The probe transit thermal design was completed and verified based on thermal vacuum testing of a prototype probe thermal test model.

George C. Haverly