A comparison of the bromination dynamics of pitch-based and vapor-grown graphite fibers
The electrical resistance of pitch based P-100 fibers and experimental organic vapor grown fibers was recorded in-situ during bromination and subsequent exposure to ambient laboratory air. The results indicate that the bromination and debromination reactions proceed much slower for vapor grown fibers than for pitch based. While this may be due in part to the larger diameter of the vapor grown fibers, the majority of the effect can probably be attributed to the differences in graphene plane orientation between the fiber types. Although the reactions are slower in the vapor grown than in the pitch based fibers, the extent of reaction as measured by the change in electrical resistance is essentially the same, with comparable (or larger) decreases in resistivity. The bromination reaction proceeds with one or more plateaus in the resistance versus time curves, which suggests staging and strengthens the argument that these fibers produce true intercalation compounds.