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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9

High-voltage spark carbon-fiber sticky-tape data analyzer

An efficient method for detecting carbon fibers collected on a stick tape monitor was developed. The fibers were released from a simulated crash fire situation containing carbon fiber composite material. The method utilized the ability of the fiber to initiate a spark across a set of alternately biased high voltage electrodes to electronically count the number of fiber fragments collected on the tape. It was found that the spark, which contains high energy and is of very short duration, is capable of partially damaging or consuming the fiber fragments. It also creates a mechanical disturbance which ejects the fiber from the grid. Both characteristics were helpful in establishing a single discharge pulse for each fiber segment.

Yang, L. C.↗

Radiation response and electrical properties of polymer energy storage capacitors: PVF2, Polysulfone, and Mylar

Efforts were made to develop a polymer film capacitor that is tolerant to radiation. The capacitors are to be utilized in a high voltage pulse discharge application. Radiation response data at high dose/dose rate levels are presented for polyvinylidene fluoride (PVF2), polysulfone, and Mylar. The results show that PVF2 is the most radiation tolerant while Mylar is the least tolerant. The data also show that the radiation response is quite dependent on operating electric stress.

Edwards, L. R.↗

The Application of Perfluorocarbons as Impregnants for Plastic Film Capacitors

A liquid impregnated, plastic film (wet) capacitor was developed that is thought to be the most reliable and space efficient capacitor of any type ever produced for high voltage, pulse discharge service. The initial design stores five times the energy of a premium quality dry capacitor of equivalent energy and reliability. The technology, as well as a production capacitor design using this technology are described.

Mauldin, G. H.↗

Determination of the temperature of a dense plasma from a spectral line shift

The method of maximum spectral line shift proposed by Bardocz, et al, (1966) was successfully applied in the diagnostics of dense plasmas produced by high power pulse discharges. It is pointed out that the effect of the shock wave pressure on the spectral line shift has to be taken into account in order to obtain accurate results with this method for high power discharges. A pressure dependent function was introduced in the expression given by those authors to provide the necessary correction.

Sultanov, A. M.↗

Photoabsorption cross sections of OH at 115-183 nm

The absorption spectrum for OH was obtained in the 115-183 nm region. The OH radicals were produced by a pulse discharge of trace H2O in few torr of Ar. Absorption cross sections were obtained by calibration with absorption of the OH (X 2 Pi to A 2 Sigma +) transition. The features in the absorption spectrum are correlated with the excited states 1 2 Sigma -, D 2 Sigma -, 1 2 Delta, B 2 Sigma + and possibly others calculated by van Dishoeck, Langhoff, and Dalgarno. The measured cross sections are comparable with the calculated values.

Nee, J. B.↗

Photoabsorption cross section of OD at 115-180 nm

The photoabsorption cross sections of OD in the 115-180 nm region were measured. The OD radicals were produced from a pulsed discharge in a mixture containing a trace of D2O in a few Torr of argon. Results are compared with the photoabsorption of OH previously measured.

Nee, J. B.↗

On the use of the cross section concept as applied to pulsed CO2 laser dynamics

The 'cross sections' which are commonly used in combination with the molecular vibrational level densities to describe induced transition rates are time dependent in a pulsed discharge. This greatly affects the relative rates of buildup of radiation at the various lines of a molecular gain medium in a nondispersive cavity, and the consequences for line selection by injection in a TEA-CO2 laser are discussed.

Flamant, P. H.↗

Vacuum ultraviolet photoabsorption study of SO

The photoabsorption of SO was investigated by producing the radicals from a pulsed discharge of a trace of SO2 in Ar. The photoabsorption cross section of SO in the 115-135 nm region was measured. A repulsive potential curve is constructed from the observed photoabsorption spectrum.

Nee, J. B.↗

Spacecraft dielectric material properties and spacecraft charging

The physics of spacecraft charging is reviewed, and criteria for selecting and testing semiinsulating polymers (SIPs) to avoid charging are discussed and illustrated. Chapters are devoted to the required properties of dielectric materials, the charging process, discharge-pulse phenomena, design for minimum pulse size, design to prevent pulses, conduction in polymers, evaluation of SIPs that might prevent spacecraft charging, and the general response of dielectrics to space radiation. SIPs characterized include polyimides, fluorocarbons, thermoplastic polyesters, poly(alkanes), vinyl polymers and acrylates, polymers containing phthalocyanine, polyacene quinones, coordination polymers containing metal ions, conjugated-backbone polymers, and 'metallic' conducting polymers. Tables summarizing the results of SIP radiation tests (such as those performed for the NASA Galileo Project) are included.

Frederickson, A. R.↗

Fluorescence yields from photodissociative excitation of HCOOH, HCOOCH3, and CH3COOH in the vacuum-ultraviolet region

The photoexcitation processes of HCOOH, HCOOCH3, and CH3COOH were studied in the vacuum-ultraviolet region by using synchroton radiation and a pulsed discharge lamp as light sources. The absorption and fluorescence cross sections of these molecules were measured in the 106-250-nm region. Fluorescences were detected from photoexcitation of HCOOH and HCOOCH3, but not from CH3COOH. Fluorescence produced at 123.9 nm was dispersed and identified as the excited OH and HCOO radicals. Fluorescence quantum yields of HCOOH and HCOOCH3 increase with decreasing excitation wavelengths with maxima of 5 and 0.3 percent at 106 nm, respectively.

Suto, Masako↗

Makeup and uses of a basic magnet laboratory for characterizing high-temperature permanent magnets

A set of instrumentation for making basic magnetic measurements was assembled in order to characterize high intrinsic coercivity, rare earth permanent magnets with respect to short term demagnetization resistance and long term aging at temperatures up to 300 C. The major specialized components of this set consist of a 13 T peak field, capacitor discharge pulse magnetizer; a 10 in. pole size, variable gap electromagnet; a temperature controlled oven equipped with iron cobalt pole piece extensions and a removable paddle that carries the magnetization and field sensing coils; associated electronic integrators; and sensor standards for field intensity H and magnetic moment M calibration. A 1 cm cubic magnet sample, carried by the paddle, fits snugly between the pole piece extensions within the electrically heated aluminum oven, where fields up to 3.2 T can be applied by the electromagnet at temperatures up to 300 C. A sample set of demagnetization data for the high energy Sm2Co17 type of magnet is given for temperatures up to 300 C. These data are reduced to the temperature dependence of the M-H knee field and of the field for a given magnetic induction swing, and they are interpreted to show the limits of safe operation.

Niedra, Janis M.↗

Particle dynamics and current-free double layers in an expanding, collisionless, two-electron-population plasma

The expansion of a two-electron-population, collisionless plasma into vacuum has been examined in detail. Plasma density, plasma potential, electric field, and particle disribution functions have been measured in situ. It is demonstrated that the presence of a low-pressure (P not less than 2 x 10 to the -5th torr) background neutral gas modifies the expansion of the plasma. A new plasma source creating dense, pulsed discharge plasma with a low background pressure (P not greater than 2 x 10 to the -6th torr) has been developed to perform in situ measurements of the temporal and spatial plasma evolution during its expansion into vacuum.

Hairapetian, G.↗

CO2 laser preionisation

The final report for work done during the reporting period of January 25, 1990 to January 24, 1991 is presented. A literature survey was conducted to identify the required parameters for effective preionization in TEA CO2 lasers and the methods and techniques for characterizing preionizers are reviewed. A numerical model of the LP-140 cavity was used to determine the cause of the transverse mode stability improvement obtained when the cavity was lengthened. The measurement of the voltage and current discharge pulses on the LP-140 were obtained and their subsequent analysis resulted in an explanation for the low efficiency of the laser. An assortment of items relating to the development of high-voltage power supplies is also provided. A program for analyzing the frequency chirp data files obtained with the HP time and frequency analyzer is included. A program to calculate the theoretical LIMP chirp is also included and a comparison between experiment and theory is made. A program for calculating the CO2 linewidth and its dependence on gas composition and pressure is presented. The program also calculates the number of axial modes under the FWHM of the line for a given resonator length. A graphical plot of the results is plotted.

Spiers, Gary D.↗

Suppressing The Growth Of Dendrites In Secondary Li Cells

Proposed technique for suppressing growth of lithium dendrites in rechargeable lithium electrochemical power cells involves periodic interruption of steady charging current with short, high-current discharge pulses. Technique applicable to lithium cells of several different types, including Li/TiS(2), Li/NbSe(3), Li/CoO(2), Li/MoS(2), Li/Vo(x), and Li/MnO(2). Cells candidates for use in spacecraft, military, communications, automotive, and other applications in which high-energy-density rechargeable batteries needed.

Davies, Evan D.↗

Development of a 70 Ah Li-Ion Cell for Aerospace Applications

A viewgraph presentation outlines the development of Li-ion cells at the Li-Ion Technology Center in Missouri. The Li-ion test area is described, as well as the aerospace design and cell construction equipment. Test results are shown for typical charge and discharge, pulse test, and calculated impedance at various temperatures. Near future activities are discussed, including the incorporation of an alternate electrolyte and the optimization of the anode and cathode.

DeGruson, Jim↗

RF Frequency Oscillations in the Early Stages of Vacuum Arc Collapse

RF frequency oscillations may be produced in a typical capacitive charging / discharging pulsed power system. These oscillations may be benign, parasitic, destructive or crucial to energy deposition. In some applications, proper damping of oscillations may be critical to proper plasma formation. Because the energy deposited into the plasma is a function of plasma and circuit conditions, the entire plasma / circuit system needs to be considered as a unit To accomplish this, the initiation of plasma is modeled as a time-varying, non-linear element in a circuit analysis model. The predicted spectra are compared to empirical power density spectra including those obtained from vacuum arcs.

Griffin, Steven T.↗

Spectroscopy of neutral and ionized PAHs. From laboratory studies to astronomical observations

Polycyclic Aromatic Hydrocarbons (PAHs) are an important and ubiquitous component of carbon-bearing materials in space. PAHs are the best-known candidates to account for the IR emission bands (UIR bands) and PAH spectral features are now being used as new probes of the ISM. PAHs are also thought to be among the carriers of the diffuse interstellar absorption bands (DIBs). In the model dealing with the interstellar spectral features, PAHs are present as a mixture of radicals, ions and neutral species. PAH ionization states reflect the ionization balance of the medium while PAH size, composition, and structure reflect the energetic and chemical history of the medium. A major challenge for laboratory astrochemistry is to reproduce (in a realistic way) the physical conditions that are associated with the emission and absorption interstellar zones. An extensive laboratory program has been developed at NASA Ames to assess the physical and chemical properties of PAHs in such environments and to describe how they influence the radiation and energy balance in space and the interstellar chemistry. PAHs, neutrals and ions, are expanded through a pulsed discharge nozzle (PDN) and probed with high-sensitivity cavity ringdown spectroscopy (CRDS). These laboratory experiments provide unique information on the spectra of free, cold large carbon molecules and ions in the gas phase from the ultraviolet and visible range to the near-infrared range. Intrinsic band profiles and band positions of cold gas-phase PAHs can now be measured with high-sensitivity spectroscopy and directly compared to the astronomical data. Preliminary conclusions from the comparison of the laboratory data with astronomical observations of interstellar and circumstellar environments will also be discussed.

Salama, Farid↗

Gallium Electromagnetic (GEM) Thrustor Concept and Design

We describe the design of a new type of two-stage pulsed electromagnetic accelerator, the gallium electromagnetic (GEM) thruster. A schematic illustration of the GEM thruster concept is given in Fig. 1. In this concept, liquid gallium propellant is pumped into the first stage through a porous metal electrode using an electromagneticpump[l]. At a designated time, a pulsed discharge (approx.10-50 J) is initiated in the first stage, ablating the liquid gallium from the porous electrode surface and ejecting a dense thermal gallium plasma into the second state. The presence of the gallium plasma in the second stage serves to trigger the high-energy (approx.500 I), send-stage puke which provides the primary electromagnetic (j x B) acceleration.

Polzin, Kurt A.↗