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151 records · Page 9

Sputtered indium tin oxide as a recombination layer formed on the tunnel oxide/poly-Si passivating contact enabling the potential of efficient monolithic perovskite/Si tandem solar cells

We focus on utilizing sputtered indium tin oxide (ITO) as a recombination layer, having low junction damage to an n-type silicon solar cell with a front-side tunnel oxide passivating electron contact, thereby enabling the development of a high efficiency monolithic perovskite/Si tandem device. High transparency and low resistivity ITO films are deposited via low power DC magnetron sputtering at room temperature onto a front-side thin SiO x /n + poly-Si contact in a complete Cz n-Si cell with a back-side Al 2 O 3 /SiN x passivating boron-diffused p + -emitter on a random pyramid textured surface. We report the cell characteristics before and after ITO sputtering, and we find a cure at 250 °C in air is highly effective at mitigating any sputtering induced damage. Our ITO coated sample resulted in an implied open-circuit voltage (iV oc ) of 684.7 ± 11.3 mV with the total saturation current density of 49.2 ± 14.8 fA/cm 2 , an implied fill factor (iFF) of 81.9 ± 0.8%, and a contact resistivity in the range of 60 mΩ-cm 2 to 90 mΩ-cm 2 . After formation of a local Ag contact to the rear emitter and sputtered ITO film as the front-side contact without grid fingers, the pseudo-efficiency of 20.2 ± 0.5% was obtained with the V oc of 670.4 ± 7 mV and pseudo FF of 77.3 ± 1.3% under simulated one sun with the calculated short-circuit current density of 30.9 mA/cm 2 from the measured external quantum efficiency. Furthermore, our modelling result shows that efficiency exceeding 25% under one sun is practically achievable in perovskite/Si tandem configuration using the ITO recombination layer connecting a perovskite top cell and a poly-Si bottom cell.

14 SOLAR ENERGY↗

Qudit Designs and Where to Find Them

Unitary t-designs are some of the most versatile tools in quantum information theory. Their applications range from randomized benchmarking and shadow tomography, to more fundamental ones such as emulating quantum chaos and establishing exponential separations between classical and quantum query complexity. While unitary designs originating from a group structure, such as the Clifford group, have proven to be incredibly useful for qubit systems, unfortunately, this is no longer true for qudits. In fact, the classification of finite-group representations rules out the existence of unitary 2-designs for arbitrary qudit dimensions. This severely limits the applicability of standard quantum information primitives when it comes to qudit systems. We overcome these limitations with a three-fold contribution. First, we introduce a general technique to construct families of weighted state t-designs in arbitrary qudit dimensions. These weighted state-designs generalize classical shadow tomography protocol from qubits to qudits. Second, we introduce a Clifford character RB that allows us to benchmark the qudit Clifford group in any dimension, including non-prime-power dimensions. And third, we establish bounds on the quantum circuit complexity of generating approximate unitary-designs from native gates in existing quantum hardware such as high-spin and cavity-QED qudits. Our work further highlights the analogy between spin and optical coherent states by proving that spin-GKP codewords form a state 2-design while spin coherent states do not; in direct analogy with the optical case. This work is structured as a pedagogical and self-contained introduction to unitary designs and their applications to qudit systems.

Anand, Namit [NASA, Ames; Unlisted, US] (ORCID:000↗

Modulation and Modeling of Three-Dimensional Nanowire Assemblies Targeting Gas Sensors with High Response and Reliability

Despite improved sensitivity, simple downsizing of gas-sensing components to randomly arranged nanostructures often faces challenges associated with unpredictable electrical conduction pathways. In the present study, controlled fabrication of three-dimensional (3D) metal oxide nanowire networks is demonstrated that can greatly improve both signal stability and sensor response compared to random nanowire arrays. For example, the highest ever reported H 2 S gas response value, and a 5 times lower relative standard deviation of baseline resistance than that of random nanowires assemblies, are achieved with the ordered 3D nanowire network. Systematic engineering of 3D geometries and their modeling, utilizing equivalent circuit components, provide additional insights into the electrical conduction and gas-sensing response of 3D assemblies, revealing the critical importance of wire-to-wire junction points and their arrangement. Here these findings suggest new design rules for both enhanced performance and reliability of chemical sensors, which may also be extended to other devices based on nanoscale building blocks.

36 MATERIALS SCIENCE↗

Perovskite superlattices with efficient carrier dynamics

Compared with their three-dimensional (3D) counterparts, low-dimensional metal halide perovskites (2D and quasi-2D; B 2 A n-1 M n X 3n+1 , such as B = R-NH 3 + , A = HC(NH 2 ) 2 + , Cs + ; M = Pb 2+ , Sn 2+ ; X = Cl - , Br - , I - ) with periodic inorganic-organic structures have shown promising stability and hysteresis-free electrical performance. However, their unique multiple-quantum-well structure limits the device efficiencies because of the grain boundaries and randomly oriented quantum wells in polycrystals. In single crystals, the carrier transport through the thickness direction is hindered by the layered insulating organic spacers. Furthermore, the strong quantum confinement from the organic spacers limits the generation and transport of free carriers. Also, lead-free metal halide perovskites have been developed but their device performance is limited by their low crystallinity and structural instability 11 . Here, in this paper, we report a low-dimensional metal halide perovskite BA 2 MA n-1 Sn n I 3n+1 (BA, butylammonium; MA, methylammonium; n = 1, 3, 5) superlattice by chemical epitaxy. The inorganic slabs are aligned vertical to the substrate and interconnected in a criss-cross 2D network parallel to the substrate, leading to efficient carrier transport in three dimensions. A lattice-mismatched substrate compresses the organic spacers, which weakens the quantum confinement. The performance of a superlattice solar cell has been certified under the quasi-steady state, showing a stable 12.36% photoelectric conversion efficiency. Moreover, an intraband exciton relaxation process may have yielded an unusually high open-circuit voltage (V OC ).

36 MATERIALS SCIENCE↗

Learning linear optical circuits with coherent states

We analyze the energy and training data requirements for supervised learning of an M-mode linear optical circuit by minimizing an empirical risk defined solely from the action of the circuit on coherent states. When the linear optical circuit acts non-trivially only on k < M unknown modes (i.e. a linear optical k-junta), we provide an energy-efficient, adaptive algorithm that identifies the junta set and learns the circuit. We compare two schemes for allocating a total energy, E, to the learning algorithm. In the first scheme, each of the T random training coherent states has energy E/T. In the second scheme, a single random MT-mode coherent state with energy E is partitioned into T training coherent states. The latter scheme exhibits a polynomial advantage in training data size sufficient for convergence of the empirical risk to the full risk due to concentration of measure on the $(2MT-1)$-sphere. Specifically, generalization bounds for both schemes are proven, which indicate that for ε-approximation of the full risk by the empirical risk with high probability, $O(E^{2/3}M^{2/3}/\epsilon^{2/3})$ training states are sufficient for the first scheme and $O(E^{1/3}M^{1/3}/\epsilon^{2/3})$ training states are sufficient for the second scheme.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Theory of the phase transition in random unitary circuits with measurements

Here, we present a theory of the entanglement transition tuned by measurement strength in qudit chains evolved by random unitary circuits and subject to either weak or random projective measurements. The transition can be understood as a nonanalytic change in the amount of information extracted by the measurements about the initial state of the system, quantified by the Fisher information. To compute the von Neumann entanglement entropy $\textit{S}$ and the Fisher information $\mathcal{F}$, we apply a replica method based on a sequence of quantities $\tilde{S}^{(n)}$ and $\mathcal{F}^{(n)}$ that depend on the $\textit{n}$th moments of density matrices and reduce to $\textit{S}$ and $\mathcal{F}$ in the limit $\textit{n}$ → 1. These quantities with $\textit{n}$ ≥ 2 are mapped to free energies of a classical spin model with $\textit{n}$! internal states in two dimensions with specific boundary conditions. In particular, $\tilde{S}^{(n)}$ is the excess free energy of a domain wall terminating on the top boundary, and $\mathcal{F}^{(n)}$ is related to the magnetization on the bottom boundary. Phase transitions occur as the spin models undergo ordering transitions in the bulk. Taking the limit of large local Hilbert space dimension $\textit{q}$ followed by the replica limit $\textit{n}$ → 1, we obtain the critical measurement probability $p_c$ = 1/2 and identify the transition as a bond percolation in the 2D square lattice in this limit. Finally, we show there is no phase transition if the measurements are allowed in an arbitrary nonlocal basis, thereby highlighting the relation between the phase transition and information scrambling. We establish an explicit connection between the entanglement phase transition and the purification dynamics of a mixed state evolution and discuss implications of our results to experimental observations of the transition and simulability of quantum dynamics.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Superconducting Shuttle-Flux Shift Register for Race Logic and Its Applications

Here this paper presents a superconducting, magnetically-coupled, shuttle-flux shift register (SF-SR) that stores single flux quantum (SFQ) pulses. This shift register has a DC bias operating margin of ±34% at 10 GHz, with a power dissipation of 3.6 μW and 38% fewer Josephson junctions (JJs) when scaled up to multiple stages compared to a data flip-flop (DFF) based shift register. The clock input is inductively coupled and is independent from the data input. We then present three applications for our SF-SR. In the first application, we add two non-destructive readout (NDRO) cells to construct a buffer that temporarily stores the temporal information of a series of race logic (RL) pulses. The second application is a pseudo-random number generator based on a linear function shift register (LFSR). The third application is N parallel SF-SRs that can act similar to a deserializer or instead can emulate a single SF-SR of N times higher clock frequency. These three applications motivate deep shift registers with many shifting intervals, which our SF-SR can implement with fewer JJs and lower power consumption compared to DFF-based shift registers.

42 ENGINEERING↗