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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

A landscape view of biomass, LAI, and photosynthetic capacity for FIFE

Canopy properties in the tallgrass prairie are examined in terms of spatial and temporal variability to determine how the variability constrains the ecosystem-atmosphere exchange of H2O, CO2, and momentum. Canopy structure and photosynthetic capacity are examined by measuring soil properties, canopy biomass, and canopy nitrogen along continuous strips. Special attention is given to sites of maximum and minimum biomass where parameters such as leaf-area index (LAI), photosynthetic rate, chemistry, and structures for both burned and unburned areas. The LAI/biomass data and the canopy attributes show that soil properties are shaped by soil-forming and geomorphic processes. The variables that cause the greatest variation in LAI, canopy stratification, and photosynthetic capacity are found to be management (burning and/or grazing) and landscape position.

Kittel, T. G. F.↗
NASA NTRS2001

TRMM Observations of Convective Regimes in the Amazon

This study utilizes TRMM satellite precipitation radar, lightning imaging sensor, and passive microwave imager data together with ground-based lightning data to investigate the vertical structure, lightning, and rainfall characteristics of Amazonian and central South American convection for three separate wet-seasons. These characteristics are partitioned as a function of 850 mb zonal wind direction, motivated by observations collected during the six-week TRMM-LBA field campaign. The TRMM-LBA field campaign observations suggest that systematic variations in Amazonian convective vertical structure, lightning, and rainfall are all linked to bimodal variations in the low-level zonal wind (e.g., easterly and westerly regimes). The more spatially and temporally comprehensive TRMM dataset used in this study extends the TRMM-LBA observations by examining regime variability in Amazonian and South American convective structure over a continental scale domain. On a continental-scale, patterns of east and west regime 850 mb winds combined with LIS lightning flash densities suggest the presence of synoptic-scale controls (e.g., intrusion of extratropical frontal systems and interaction with the SACZ) on regional-scale variability in convective vertical structure. TRMM PR, TMI and ground-based lightning data suggest that regional variability in wet-season convective structure is most evident over the southern Amazon, Mato Grosso, Altiplano, southern Brazil, and eastern coastal regions of central and southern South America. Convective vertical structure, rain fall rates, and lightning activity are all more pronounced during easterly (westerly) regimes over the southern Amazon and Mato Grosso (Altiplano, and southern Brazil). Importantly, when considered with case-study results from TRMM-LBA, the systematic differences in convective structure that occur as a function of regime suggest that associated regime-differences may exist in the vertical distribution of diabatic heating. Hence the discrimination of convective vertical structure "regimes" over parts of the Amazon and vicinity based on a resolved variable such as the 850 mb zonal wind direction, while far from being perfect, may have important applications to the problems of cumulus parameterization, rainfall estimation and retrievals of latent heating over the Amazon.

Petersen, W. A.↗
NASA NTRS1976

The structure of lightning flashes HF-UHF: 12 September 1975, Atlanta, Georgia

Simultaneous measurement of sferics at 3, 30, 139, and 295 MHz were made during thunderstorms. Wideband electronics and an analogue tape recorder continuously recorded the radiation from lightning with about 300 kHz of bandwidth. The data were obtained during the passage of a cold front. Flashing rate, burst rate and the structure of individual flashes were recorded. The record of a typical flash begins with a sudden burst of closely spaced pulses whose temporal structure is typical of the stepped leader, and ends in a large pulse suggestive of a first return stroke. The remainder of the flash consists of a sequence of pulses of varying amplitude separated by quiet periods of the order of milliseconds. The shape of these pulses and the temporal structure suggest that the first few large pulses are return strokes. Other discharges begin with widely spaced discrete pulses and resemble the preceding discharge less the leader and return stroke phase. The radiation exhibits a similar structure, at each of the frequencies monitored.

Levine, D. M.↗
NASA NTRS1985

Effects of stratospheric lapse rate on numerically simulated thunderstorm cloud top structure

The study of overshooting midlatitude severe thunderstorm tops has led to the detection of some intriguing patterns. This paper provides a summary of an investigation of the effects of stratospheric stability on thunderstorm cloud top structure, taking into account the utilization of a fully three-dimensional (3D) anelastic model discussed by Schlesinger (1975, 1978, 1984). The layout of model experiments is discussed, giving attention to initial environmental soundings, and initial forcing. The time variation of the vertical velocity extreme is examined, and a description of the mature storm structure is presented. Constant-altitude plane views throughout storm depth are considered along with cloud top height fields. With the stratospheric lapse, the warm region is small and breaks down into separate spots with secondary cold spots downshear of them.

Schlesinger, R. E.↗
NASA NTRS1985

Effects of stratospheric lapse rate on numerically simulated thunderstorm cloud top structure

The three-dimensional anelastic model of Schlesinger (1975, 1978, 1984) is utilized to study the effects of stratospheric stability on thunderstorm cloud top structure. Three experiments were conducted; in the first the stratosphere is assumed isothermal, in the second test there is a temperature lapse of 3 K/km, and in the third case there is a 3 K/km inversion. Time variations of vertical velocity, mature storm structure, and cloud top are examined. It is observed that the cloud summit height is lowered as stratospheric stability increases, a cloud-top thermal couplet occurs in all cases, the cold region has a U or V shape, and there is a height minimum in the warm regions.

Schlesinger, Robert E.↗
NASA NTRS1999

Combustion of Metals in Reduced-Gravity and Extra Terrestrial Environments

The combustion of metals is a field with important practical applications in rocket propellants, high-temperature flames, and material synthesis. Also, the safe operation of metal containers in high-pressure oxygen systems and with cryogenic fuels and oxidizers remains an important concern in industry. The increasing use of metallic components in spacecraft and space structures has also raised concerns about their flammability properties and fire suppression mechanisms. In addition, recent efforts to embark on unmanned and manned planetary exploration, such as on Mars, have also renewed the interest in metal/carbon-dioxide combustion as an effective in situ resource utilization technology. In spite of these practical applications, the understanding of the combustion properties of metals remains far behind that of the most commonly used fuels such as hydrocarbons. The lack of understanding is due to the many problems unique to metal- oxidizer reactions such as: low-temperature surface oxidation prior to ignition, heterogeneous reactions, very high combustion temperatures, product condensation, high emissivity of products, and multi-phase interactions. Very few analytical models (all neglecting the influence of gravity) have been developed to predict the burning characteristics and the flame structure details. Several experimental studies attempting to validate these models have used small metal particles to recreate gravity-free conditions. The high emissivity of the flames, rapid reaction, and intermittent explosions experienced by these particles have made the gathering of any useful information on burning rates and flame structure very difficult. The use of a reduced gravity environment is needed to clarify some of the complex interactions among the phenomena described above. First, the elimination of the intrusive buoyant flows that plague all combustion phenomena is of paramount importance in metal reactions due to the much higher temperatures reached during combustion. Second, a low-gravity environment is absolutely essential to remove the destructive effect of gravity on the shape of a molten metal droplet in order to study a spherically symmetric condition with large bulk samples. The larger size of the spherical metal droplet and the longer burning times available in reduced gravity extend the spatial and temporal dimensions to permit careful probing of the flame structure and dynamics. Third, the influence of the radiative heat transfer from the solid oxides can be studied more carefully by generating a stagnant spherical shell of condensed products undisturbed by buoyancy.

Branch, M.C.↗
NASA NTRS1993

Shear sensitive monomer-polymer laminate structure and method of using same

Monomer cholesteric liquid crystals have helical structures which result in a phenomenon known as selective reflection, wherein incident white light is reflected in such a way that its wavelength is governed by the instantaneous pitch of the helix structure. The pitch is dependent on temperature and external stress fields. It is possible to use such monomers in flow visualization and temperature measurement. However, the required thin layers of these monomers are quickly washed away by a flow, making their application time dependent for a given flow rate. The laminate structure according to the present invention comprises a liquid crystal polymer substrate attached to a test surface of an article. A light absorbing coating is applied to the substrate and is thin enough to permit bonding steric interaction between the liquid crystal polymer substrate and an overlying liquid crystal monomer thin film. Light is directed through and reflected by the liquid crystal monomer thin film and unreflected light is absorbed by the underlying coating. The wavelength of the reflected light is indicative of the shear stress experienced by the test surface. Novel aspects of the invention include its firm bonding of a liquid crystal monomer to a model and its use of a coating to reduce interference from light unreflected by the monomer helical structure.

Singh, Jag J.↗
NASA NTRS1976

F-region enhancements induced by solar flares

ATS-6 total electron content (NT) observations during solar flares exhibit four types of response: (1) a sudden increase in NT (SITEC) for about 2 min with several maxima in growth rate, then a maximum or a distinct slowing in growth, followed by a slow smooth increase to a flat peak, and finally a slow decay in NT; (2) a SITEC that occurs during ionospheric storms, where NT decays abruptly after the first maximum; (3) slow enhancements devoid of distinct impulsive structure in growth rate; and (4) no distinct response in NT, even for relatively large soft X-ray flares. Flare-induced increases in NT are dominated by low-loss F2 ionization produced by 90-911-A emission. The impulsive flare component is relatively intense in the 90-911-A range, but is short lived and weak for flares near the edge of the visible solar disk and for certain slow flares. The impulsive flare component produces the rapid rise, the sharp maxima in growth rate, and the first maximum in SITECs. The slow flare components are strong in the 1-90-A range but relatively weak in the 90-911-A range and accumulatively contribute to the second maximum in type 1 and 3 events, except during storms when F2 loss rates are abnormally high in type 2 events.

Donnelly, R. F.↗
NASA NTRS2002

Gas-Phase Reaction Pathways and Rate Coefficients for the Dichlorosilane-Hydrogen and Trichlorosilane-Hydrogen Systems

As part of NASA Ames Research Center's Integrated Process Team on Device/Process Modeling and Nanotechnology our goal is to create/contribute to a gas-phase chemical database for use in modeling microelectronics devices. In particular, we use ab initio methods to determine chemical reaction pathways and to evaluate reaction rate coefficients. Our initial studies concern reactions involved in the dichlorosilane-hydrogen (SiCl2H2--H2) and trichlorosilane-hydrogen (SiCl2H-H2) systems. Reactant, saddle point (transition state), and product geometries and their vibrational harmonic frequencies are determined using the complete-active-space self-consistent-field (CASSCF) electronic structure method with the correlation consistent polarized valence double-zeta basis set (cc-pVDZ). Reaction pathways are constructed by following the imaginary frequency mode of the saddle point to both the reactant and product. Accurate energetics are determined using the singles and doubles coupled-cluster method that includes a perturbational estimate of the effects of connected triple excitations (CCSD(T)) extrapolated to the complete basis set limit. Using the data from the electronic structure calculations, reaction rate coefficients are obtained using conventional and variational transition state and RRKM theories.

Dateo, Christopher E.↗
NASA NTRS2021

Tunable Pseudocapacitive Intercalation of Chloroaluminate Anions into Graphite Electrodes for Rechargeable Aluminum Batteries

Rechargeable aluminum-graphite batteries using chloroaluminate-containing electrolytes have been the focus of significant research, particularly due to their high-rate capabilities. Engineered graphite electrodes have been shown to exhibit supercapacitor-like rate performance, despite the fact they store charge via the electrochemical intercalation of polyatomic AlCl4− anions. However, the origins of such rate capabilities are not well understood. Here, using electrochemical techniques, we disentangle quantitatively the diffusion-limited Faradaic, pseudocapacitive, and capacitive contributions to charge storage, revealing that AlCl4− anions intercalate into graphite with significant pseudocapacitive characteristics due to low ion diffusion limitations. Pristine and mildly exfoliated graphites are compared, where exfoliation resulted in significantly higher pseudocapacitive AlCl4− intercalation at the highest potential redox pair as well as higher galvanostatic capacity retention at faster discharge rates. The relationships between graphite structure, ion mass transport, and the overall rate of electrochemical AlCl4− intercalation are discussed. Ion diffusion within the electrolyte phase of the porous electrode is shown to play a key role in controlling the rate of intercalation at higher potentials and faster rates, which can be enhanced by reducing electrode tortuosity. The results establish that chloroaluminate anion intercalation into graphite exhibits non-diffusion-limited pseudocapacitive contributions that are tunable by modifying the graphite structure.

Jeffrey H. Xu↗
NASA NTRS1991

Radiation-Controlled, Opposed-Flow Flame Spread in a Microgravity Environment

The effects of surface and gas-phase radiation on the rate and the structure of laminar flame spread over thin fuels are investigated using a flame-spread model which consists of the continuity, momentum, species, and energy equations in the gas and the continuity and energy equations in the solid. Numerical calculations, complemented by scaling arguments, show that, at high velocities of the oxidizer flow, radiation effects are unimportant; the spread rate decreases with increasing opposing velocity due to finite-rate gas-phase kinetics. However, radiation becomes progressively important when the opposing velocity is below a certain value: the flame cools, shrinks in size, and its spread rate falls sharply with decreasing opposing velocity.

Bhattacharjee, Subrata↗
NASA NTRS1995

Inference of 3-dimensional structure underlying large-scale coronal events observed by Yohkoh and Ulysses

The Yohkoh/SXT images provide full-disk coverage of the solar corona, usually extending before and after one of the large-scale eruptive events that occur in the polar crown These produce large arcades of X-ray loops, often with a cusp-shaped coronal extension, and are known to be associated with coronal mass ejections. The Yohkoh prototype of such events occurred 12 Nov. 1991. This allows us to determine heights from the apparent rotation rates of these structures. In comparison v with magnetic-field extrapolations from Wilcox Solar Observatory. use use this tool to infer the three dimensional structure of the corona in particular cases: 24 Jan. 1992, 24 Feb. 1993, 14 Apr. 1994, and 13 Nov. 1994. The last event is a long-duration flare event.

Slater, G. L.↗
NASA NTRS1991

Surface activation of air oxidation of hydrazine on kaolinite. 2. Consideration of oxidizing/reducing entities in relationship to other compositional, structural, and energetic factors

The rates (previously reported) for the air oxidation of hydrazine on kaolinite and substituent oxides of kaolinite showed a complex dependence on the relative amounts of several structural oxidizing/reducing entities within the reaction-promoting solids. The rates indicated an important role of the clay but no dominant role of any one of the oxidizing/reducing entities. In this paper we review (a) the reaction-promoting activity of these centers as studied in other systems, (b) various spectroscopic results showing interaction between these entities in clays, and (c) reported spectroscopic studies of the complexation between hydrazine and aluminosilicate surfaces as a whole, in an effort to propose a mechanism for the reaction. Whereas some uncertainties remain, the present synthesis concludes that a mechanism operating through single electron/hole transfers and hydrogen atom transfers by discrete centers is adequate to explain the observed rate behaviors including the observed second order dependence of the oxidation rate on catalyst amount. The effects of these operations on the catalyst can result in no alteration of, or complete or partial electronic relaxation of its contingent of trapped separated charge pairs. The degree to which surface complexation as a whole, intercalation, or luminescent processes may also be associated with the reaction cannot be adequately assessed with the information in hand.

NASA Program Exobiology↗
NASA NTRS2006

Protograph LDPC Codes Over Burst Erasure Channels

In this paper we design high rate protograph based LDPC codes suitable for binary erasure channels. To simplify the encoder and decoder implementation for high data rate transmission, the structure of codes are based on protographs and circulants. These LDPC codes can improve data link and network layer protocols in support of communication networks. Two classes of codes were designed. One class is designed for large block sizes with an iterative decoding threshold that approaches capacity of binary erasure channels. The other class is designed for short block sizes based on maximizing minimum stopping set size. For high code rates and short blocks the second class outperforms the first class.

protgraph based codes↗
NASA NTRS1994

LQG optimal compensator transfer function for the NASA LaRC CSI Evolutionary Model

Following the general form for LQG optimal compensators for flexible structures with collocated rate sensors we develop an explicit compensator transfer function for the NASA LaRC CSI Evolutionary model in the form: psi(i omega) = g i omega B(sub u)(sup *)(-M(sub b)omega(exp 2) + T(i omega) + i gamma omega B(sub u)Bu(sub u)(sup *))(exp -1)B(sub u) where T(i omega) is a 48 x 48 positive definite matrix whose derivation is the main result of this report. The undamped mode frequencies can be expressed in terms of T(i omega) as the zeros of Det (-omega(exp 2)M(sub b) + T(i omega)) while 'clamped-clamped' modes of the structure (with all nodes clamped) are the poles.

Balakrishnan, A. V.↗
NASA NTRS1993

Development of a CFD code for casting simulation

Because of high rejection rates for large structural castings (e.g., the Space Shuttle Main Engine Alternate Turbopump Design Program), a reliable casting simulation computer code is very desirable. This code would reduce both the development time and life cycle costs by allowing accurate modeling of the entire casting process. While this code could be used for other types of castings, the most significant reductions of time and cost would probably be realized in complex investment castings, where any reduction in the number of development castings would be of significant benefit. The casting process is conveniently divided into three distinct phases: (1) mold filling, where the melt is poured or forced into the mold cavity; (2) solidification, where the melt undergoes a phase change to the solid state; and (3) cool down, where the solidified part continues to cool to ambient conditions. While these phases may appear to be separate and distinct, temporal overlaps do exist between phases (e.g., local solidification occurring during mold filling), and some phenomenological events are affected by others (e.g., residual stresses depend on solidification and cooling rates). Therefore, a reliable code must accurately model all three phases and the interactions between each. While many codes have been developed (to various stages of complexity) to model the solidification and cool down phases, only a few codes have been developed to model mold filling.

Murph, Jesse E.↗