SEARCH · Search NASA
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
A simple fringe reduction method for FM diode laser spectroscopy is discussed. The fringes can be effectively suppressed by using a modulation frequency that is an integral multiple of the free spectral range of the fringes. The technique is experimentally confirmed by two-tone FM spectroscopy of water vapor absorption lines. A factor of 20 fringe reduction is observed.
The application of optical-fiber image scramblers in wavelength-precise slit spectroscopy is discussed together with the design strategy for the optimal instrument configuration incorporating an optical-fiber image scrambler. Particular attention is given to the aspects of data analysis and interpretation techniques which must be specially designed for high-precision spectroscopy. In a specific application to an existing coude spectrograph, the instrumentation and data reduction techniques described in this paper demonstrate an achievable precision corresponding to a systematic radial velocity error of about 30 m/sec.
Three studies are described characterizing the possible contributions of surface science to tribology. These include surface contamination formed by the interaction of a surface with the environment, contaminants obtained with diffusion of compounds, and surface chemical changes resulting from selective thermal evaporation. Surface analytical tools such as Auger electron spectroscopy (AES) and x ray photoelectron spectroscopy (XPS) incorporated directly into adhesion and friction systems are primarily used to define the nature of tribological surfaces before and after tribological experimentation and to characterize the mechanism of solid-to-solid interaction. Emphasis is on fundamental studies involving the role of surfaces in controlling the adhesion and friction properties of materials emerging as a result of the surface analyses. The materials which were studied include metals and ceramics such as elemental metals, amorphous alloys (metallic glasses), and silicon-based ceramics.
Because of the power of remote sensing reflectance spectroscopy in determining mineralogy, it was used as the major method of identifying possible mineral analogs of the Martian surface. A summary of proposed Martian surface compositions from reflectance spectroscopy before 1979 was presented. Since that time, iron-rich montmorillonite clay, nanocrystalline or nanophase hematite, and palagonite were suggested as Mars soil analog materials.
Imaging spectroscopy of the lunar surface was carried out using a CCD spectrograph employed as an imaging spectrometer at the University of Hawaii 2.24-m telescope at Mauna Kea Observatory. A portion of the Humorum multiringed impact basin was observed, yielding an imaging spectroscopic dataset consisting of approximately 400,000 spectra covering the wavelength region 0.7-0.98 microns at a spectral resolution of 200 (lambda/Delta-lambda). Results of this analysis included (1) identifying craters and other explosures of highland material within the bounds of Mare Humorum, (2) identifying craters in the highlands adjacents to Mare Humorum that excavate buried mare basalt, and (3) identifying two spectral units in the highlands that likely represent compositional units. The region is shown to be extremely diverse spectrally and demonstrates the ability of imaging spectroscopy to enable a qualitative improvement in the ability to identify and map compositional units.
The use of high resolution gamma-ray spectroscopy in astrophysics is discussed with specific attention given to the application of the Nuclear Astrophysics Explorer (NAE). The gamma-ray lines from nuclear transitions in radionucleic decay and positron annihilation permits the study of current sites, rates and models of nucleosynthesis, and galactic structure. Diffuse galactic emission is discussed, and the high-resolution observations of gamma-ray lines from discrete sites are also described. Interstellar mixing and elemental abundances can also be inferred from high-resolution gamma-ray spectroscopy of nucleosynthetic products. Compact objects can also be examined by means of gamma-ray emissions, allowing better understanding of neutron stars and the accreting black hole near the galactic center. Solar physics can also be investigated by examining such features as solar-flare particle acceleration and atmospheric abundances.
Velocity-modulation spectroscopy is often used to obtain absorption spectra of ions in discharges. However, there have been few studies of the line shape. The resonance line shape in velocity-modulation spectroscopy is derived in the present work. Both sinusoidal modulation and square-wave modulation are treated, and the differences in the resulting line shapes are emphasized. The results are relevant to measurements of ion mobilities, resolved with respect to the internal state of the ion.
Constituents of solutions identified in situ. Liquid-arc/spark-excitation atomic-emission spectroscopy (LAES) is experimental variant of atomic-emission spectroscopy in which electric arc or spark established in liquid and spectrum of light from arc or spark analyzed to identify chemical elements in liquid. Observations encourage development of LAES equipment for online monitoring of process streams in such industries as metal plating, electronics, and steel, and for online monitoring of streams affecting environment.
The Burst and Transient Source Experiment (BATSE) Spectroscopy Analysis System (BSAS) is the software system which is the primary tool for the analysis of spectral data from BATSE. As such, Guest Investigators and the community as a whole need to know its basic properties and characteristics. Described here are the characteristics of the BATSE spectroscopy detectors and the BSAS.
The Mariner 9 UV spectrometer scanned from 2100 to 3500 Angstroms in one of its two spectral channels every 3 seconds with a spectral resolution of 15 Angstroms and an effective field-of-view of approximately 300 km(exp 2). The only gaseous absorption in the 2000 to 3000 Angstrom region was assumed to come from the Hartley band system of ozone, and therefore the amount of ozone was inferred by fitting this absorption feature with laboratory data of ozone absorption. Mars O3 as inferred from these spectra shows strong seasonal and latitudinal variation, with column abundances ranging from 0.2 microns at equatorial latitudes to 60 microns over the northern winter polar latitudes. The detectability limit of the spectrometer was approximately 3 microns. I use a radiative transfer model based on the discrete ordinate method to calculate synthetic radiance spectra. When typical amounts of dust and cloud are present, significant underestimation of O3 occurs. A factor of 3 times as much O3 is needed to generate the same spectrum for cloudy, dusty atmospheres as for a clear atmosphere. If the scattering properties of Martian clouds and dust were well known, then their appearance would not be a problem, as a model would be capable of retrieving the O3 abundance. However, these properties are not well known, which raises doubts about the effectiveness of the current UV spectroscopy technique used to measure O3. Spatial and temporal variability in temperature and water vapor have been claimed to account for the scatter of the data points. However, water vapor is a small source of odd hydrogen in the winter polar atmosphere, and may not account for most of the variability. Masking by clouds and dust may also account for some of the observed O3 variability, because the nature and opacity of the clouds and dust in the polar hood change dramatically in latitude and even on a day-to-day basis. As the maximum O3 abundance resides near the surface, spacecraft must be able to observe through the entire cloud and dust abundance in order to actually see the total O3 column abundance. If reflectance spectroscopy is used, as on Mariner 9, then the cloud and the airborne dust must be traversed twice; first by the incoming solar flux down to the surface, and then once again upon reflection from the surface out to the spacecraft.
Pyroxene reflectance and transmittance spectra have been examined in a search for systematic relationships between spectral features and compositional variations and to assess the applicability of reflectance spectroscopy to pyroxene geothermometry. Orthopyroxenes containing up to about 11 percent Wollastonite show a positive correlation between Fe(2+) content and wavelength positions of the major absorption bands. Aluminum-rich orthopyroxenes display absorption bands at lower than expected wavelengths. Spectral-compositional relationships are more complex for clinopyroxenes, showing both positive and negative correlations between band positions and major cation abundances. These relationships are further complicated by the presence of significant amounts of other transition series elements such as Ti and Cr and by the presence of exsolved phases and compositional zonations. Contours of the wavelength positions of band minima projected onto the pyroxene tetralateral generally exhibit concave downward shapes. The orientations of the contours relative to pyroxene geotherms are such as to effectively preclude the use of spectroscopy to significantly constrain the temperatures of formation of pyroxenes.
Report describes use of electrochemical impedance spectroscopy (EIS) to investigate resistances of 19 alloys to corrosion under conditions similar to those of corrosive, chloride-laden seaside environment of Space Transportation System launch site. Alloys investigated: Hastelloy C-4, C-22, C-276, and B-2; Inconel(R) 600, 625, and 825; Inco(R) G-3; Monel 400; Zirconium 702; Stainless Steel 304L, 304LN, 316L, 317L, and 904L; 20Cb-3; 7Mo+N; ES2205; and Ferralium 255. Results suggest electrochemical impedance spectroscopy used to predict corrosion performances of metal alloys.
One of the most fundamental pieces of information about any planetary body is the elemental and mineralogical composition of its surface materials. We are developing an instrument to obtain such data at ranges of up to several hundreds of meters using the technique of Laser-Induced Breakdown Spectroscopy (LIBS). We envision our instrument being used from a spacecraft in close rendezvous with small bodies such as comets and asteroids, or deployed on surface-rover vehicles on large bodies such as Mars and the Moon. The elemental analysis is based on atomic emission spectroscopy of a laser-induced plasma or spark. A pulsed, diode pumped Nd:YAG laser of several hundred millijoules optical energy is used to vaporize and electronically excite the constituent elements of a rock surface remotely located from the laser. Light emitted from the excited plasma is collected and introduced to the entrance slit of a small grating spectrometer. The spectrally dispersed spark light is detected with either a linear photo diode array or area CCD array. When the latter detector is used, the optical and spectrometer components of the LIBS instrument can also be used in a passive imaging mode to collect and integrate reflected sunlight from the same rock surface. Absorption spectral analysis of this reflected light gives mineralogical information that provides a remote geochemical characterization of the rock surface. We performed laboratory calibrations in air and in vacuum on standard rock powders to quantify the LIBS analysis. We performed preliminary field tests using commercially available components to demonstrate remote LIBS analysis of terrestrial rock surfaces at ranges of over 25 m, and we have demonstrated compatibility with a six-wheeled Russian robotic rover vehicle. Based on these results, we believe that all major and most minor elements expected on planetary surfaces can be measured with absolute accuracy of 10-15 percent and much higher relative accuracy. We have performed preliminary systems analysis of a LIBS instrument to evaluate probable mass and power requirements; results of this analysis are summarized.
Because of the power of remote sensing reflectance spectroscopy in determining mineralogy, it has been used as the major method of identifying a possible mineral analogue of the martian surface. A summary of proposed martian surface compositions from reflectance spectroscopy before 1979 was presented by Singer et al. Since that time, iron-rich montmorillonite clay, nanocrystalline or nanophase hematite, and palagonite have been suggested as Mars soil analogue materials. Palagonite in petrological terms is best described as an amorphous, hydrated, ferric iron, silica gel. Montmorillonite is a member of the smectite clay group, and its structure is characterized by an octahedral sheet in coordination with two tetrahedral sheets in which oxygen atoms are shared. The crystal unity of montmorillonite is well defined in contrast to palagonite where it is considered amorphous or poorly crystalline at best. Because of the absence of the diagnostic strong 2.2-micron reflectance band characteristic of clays in the near-infrared (NIR) spectrum of Mars and palagonite and based upon a consideration of wide wavelength coverage (0.3-50 microns), Roush et al. concluded that palagonite is a more likely Mars surface analogue. In spite of the spectral agreement of palagonite and the Mars reflectance spectrum in the 2.2-micron region, palagonite shows poor correspondence with the results of the Viking LR experiment. In contrast, iron-rich montmorillonite clays show relatively good agreement with the results of the Viking LR experiment. This spectral study was undertaken to evaluate the spectral properties of mixtures of palagonite and Mars analogue iron-rich montmorillonite clay (16-18 wt. percent Fe as Fe2O3) as a Mars surface mineralogical model. Mixtures of minerals as Mars surface analogue materials have been studied before, but the mixtures were restricted to crystalline clays and iron oxides.
This paper describes the collection, reduction, and analysis of 0.4-1.0-micron Mars imaging spectroscopy data obtained during the 1988 and 1990 oppositions from Mauna Kea Observatory and provides a general outline for the acquisition and analysis of similar imaging spectroscopy data sets. The U.H. 2.24-m Wide Field Grism CCD Spectrograph was used to collect 13 3D image cubes covering 90 percent of the planet south of 50 deg N in the 0.4-0.8 micron region and covering 55 percent of the planet south of 50 deg N in the 0.5-1.0 micron region. Spectra extracted from these image cubes reveal the detailed character of the Martian near-UV to visible spectrum. Images at red wavelengths reveal the 'classical' albedo markings at 100-500 km spatial resolution while images at blue wavelengths show little surface feature contrast and are dominated by condensate clouds/hazes and polar ice.
We describe the channel-to-energy calibration of the Spectroscopy Detectors of the Burst and Transient Source Experiment (BATSE) on the Compton Gamma Ray Observatory (GRO). These detectors consist of NaI(TI) crystals viewed by photomultiplier tubes whose output in turn is measured by a pulse height analyzer. The calibration of these detectors has been complicated by frequent gain changes and by nonlinearities specific to the BATSE detectors. Nonlinearities in the light output from the NaI crystal and in the pulse height analyzer are shifted relative to each other by changes in the gain of the photomultiplier tube. We present the analytical model which is the basis of our calibration methodology, and outline how the empirical coefficients in this approach were determined. We also describe the complications peculiar to the Spectroscopy Detectors, and how our understanding of the detectors' operation led us to a solution to these problems.
Thin films of Fomblin Z25, a perfluoropolyalkylether lubricant, were vapor deposited onto clean, oxidized aluminum, and onto sapphire surfaces, and their behavior at different temperatures was studied using X-ray photoelectron spectroscopy and temperature desorption spectroscopy (TDS). The interfacial fluid molecules decompose on the native oxide at room temperature, and continue to decompose at elevated temperatures, as previous studies had shown to occur on the clean metal. TDS indicated that different degradation mechanisms were operative for clean and oxidized aluminum. On sapphire substrates, no reaction was observed at room temperature. The native oxide of aluminum is neither passive nor protective towards Fomblin Z25. At higher temperatures (150 C), degradation of the polymer on sapphire produced a debris layer at the interface with a chemical composition similar to the one formed on aluminum oxide. Rubbing a Fomblin film on a single crystal sapphire also induced the decomposition of the lubricant in contact with the interface and the formation of a debris layer.
A new, compact Fourier Transform Michelson interferometer (FTUV) with an apodized resolving power greater than 300,000 at 300 nm, high throughput and wide spectral coverage has been developed. The objectives include atmospheric spectroscopy (direct solar absorption and solar scattering) and laboratory spectroscopy of transient species. In this paper, we will briefly describe the prototype FTUV instrument and the results of preliminary laboratory investigations of OH and ClO spectra in emission and absorption.