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At least 163 records · Page 9
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A Path to Improving Simulated Properties of Low Clouds over the Beaufort Sea using Airborne In Situ Observations of Subgrid-Scale Variability

Arctic low clouds influence the evolution of the Arctic system through their effects on radiative fluxes, boundary layer mixing, stability, turbulence, humidity, and precipitation. Unfortunately, atmospheric models and retrospective analysis (reanalysis) products struggle to accurately simulate the occurrence and properties of low clouds in the Arctic. One of the main reasons for this problem are the possible unrealistic assumptions that models/reanalyses make about the subgrid-scale (SGS) variability of meteorological properties, as well as the relationship between SGS variability and grid-scale (GS) cloud properties. We utilize cloud and thermodynamic data of low level (primarily) liquid clouds collected from two aircraft campaigns conducted over the Beaufort Sea to better understand and characterize this problem. Examining data from the September 2014 Arctic Radiation-IceBridge Sea and Ice Experiment (ARISE) airborne campaign reveals that GS cloud water variability is closely related with SGS distribution of total water (i.e. water vapor + cloud water). Multiple models/reanalyses use SGS supersaturated total water (relative to GS saturation) as a threshold for partitioning available water for condensation, and indeed we find significant correlation between GS cloud water and SGS supersaturation. However, we also find that the assumption of a static threshold of 100% saturation to be unrealistic. Empirical calculations from the ARISE data show a large sensitivity of this threshold to GS relative humidity, and so a microphysical parameterization allowing the threshold to vary according to GS thermodynamic properties may result in more realistic GS cloud water values. Finally, to determine how sensitive the ARISE-derived results are to that particular campaign, we include additional data from the First International Satellite Cloud Climatology Project (ISCCP) Regional Experiment (FIRE)–Arctic Cloud Experiment (ACE) conducted in 1998. The inclusion of the second dataset will help with demonstrating the robustness of the results and their utility in improving the representation of Arctic clouds in models and reanalyses.

J Brant Dodson↗
NASA NTRS2022

Seasonal Updraft Speeds Change Cloud Droplet Number Concentrations in Low Level Clouds Over the Western North Atlantic

To determine the impact of dynamic and aerosol processes on marine low clouds, we examine the seasonal impact of updraft speed w and cloud condensation nuclei concentration at 0.43 % supersaturation () on the cloud droplet number concentration (N(C)) of low-level clouds over the western North Atlantic Ocean. Aerosol and cloud properties were measured with instruments on board the NASA LaRC Falcon HU-25 during the ACTIVATE (Aerosol Cloud meTeorology Interactions oVer the western ATlantic Experiment) mission in summer (August) and winter (February–March) 2020. The data are grouped into different loadings, and the density functions of NC and w near the cloud bases are compared. For low updrafts (w < 1.3 m s−1), NC in winter is mainly limited by the updraft speed and in summer additionally by aerosols. At larger updrafts (w > 3 m s−1), NC is impacted by the aerosol population, while at clean marine conditions cloud nucleation is aerosol-limited, and for high it is influenced by aerosols and updraft. The aerosol size distribution in winter shows a bimodal distribution in clean marine environments, which transforms to a unimodal distribution in high due to chemical and physical aerosol processes, whereas unimodal distributions prevail in summer, with a significant difference in their aerosol concentration and composition. The increase of is accompanied with an increase of organic aerosol and sulfate compounds in both seasons. We demonstrate that NC can be explained by cloud condensation nuclei activation through upwards processed air masses with varying fractions of activated aerosols. The activation highly depends on w and thus supersaturation between the different seasons, while the aerosol size distribution additionally affects NC within a season. Our results quantify the seasonal influence of w and on NC and can be used to improve the representation of low marine clouds in models.

Simon Kirschler↗
NASA NTRS2024

Effect of the Liquid-Vacuum Transition on the Relative Abundances of Amino and Fatty Acids Sought as Biosignatures on Icy Ocean Worlds

Interpreting measurements by robotic missions searching for signs of life in material erupted by cryovolcanic ocean worlds (e.g., Enceladus, Europa, Ceres) requires linking the composition of this material to that of its subsurface liquid source. Irrespective of the properties of –and processes along– the path of ejection, material erupted on airless worlds undergoes a transition from liquid to vacuum. Here, we investigate experimentally the effect of a direct transition from liquid to vacuum environments on the relative abundances of amino and carboxylic (fatty) acids, a metric used to distinguish between biological and abiotic sources for these compounds. Amino acids were dissolved in parent solutions prepared with 1 wt.% NaCl and pH 9–10 to match properties inferred from Enceladus plume grains. Compositional analysis of the dry solids resulting from the injection of this solution into vacuum indicates a < 50% change in amino acid abundances relative to glycine. Injection of two fatty acids, phenylacetic acid (soluble and undersaturated in the parent solution) and palmitic acid (insoluble and supersaturated) resulted in a change of less than a factor of 7 in their relative abundances. At this bulk scale (all grains aggregated together), proportions of amino and fatty acids were sufficiently conserved to allow distinction between end-member example biological and abiotic sources. We did not find strong correlations between the relative enrichment or depletion of amino or fatty acids with molecular properties such as molecular mass, hydrophobicity, functionality, or charge, other than high under-or supersaturation. Most of the organic residue was deposited along the experimental injection path, which suggests that cryovolcanic conduit walls on icy ocean worlds may be enriched in organic material relative to material having undergone the liquid-vacuum transition.

Amino acids↗
NASA NTRS2024

Aerosol Size Distribution Properties Associated With Cold-Air Outbreaks in the Norwegian Arctic

The aerosol particles serving as cloud condensation and ice nuclei contribute to key cloud processes associated with cold-air outbreak (CAO) events but are poorly constrained in climate models due to sparse observations. Here we retrieve aerosol number size distribution modes from measurements at Andenes, Norway, during the Cold-Air Outbreaks in the Marine Boundary Layer Experiment (COMBLE) and at Zeppelin Observatory, approximately 1000 km upwind from Andenes at Svalbard. During CAO events at Andenes, the sea-spray-mode number concentration is correlated with strong over-ocean winds with a mean of 8±4 cm−3 that is 71 % higher than during non-CAO conditions. Additionally, during CAO events at Andenes, the mean Hoppel minimum diameter is 6 nm smaller than during non-CAO conditions, though the estimated supersaturation is lower, and the mean number concentration of particles that likely activated in-cloud is 109±61 cm−3 with no statistically significant difference from the non-CAO mean of 99±66 cm−3. For CAO trajectories between Zeppelin Observatory and Andenes, the upwind-to-downwind change in number concentration is the largest for the accumulation mode with a mean decrease of 93±95 cm−3, likely attributable primarily to precipitation scavenging. These characteristic properties of aerosol number size distributions during CAO events provide guidance for evaluating CAO aerosol–cloud interaction processes in models.

accumulation mode particle scavenging↗
NASA NTRS1972

Study of X-ray diffraction on aging alloys with different degrees of volume discrepancy between the precipitation phase and the matrix

Study of the diffraction patterns of X rays diffracted by dispersion-hardened alloys with various degrees of difference between the specific atomic volumes of their precipitation phases and matrices. Experiments were performed on aging alloys KhN77TIuR (nimonic) and KhN67VMTIuO, which have the same types of gamma solid solutions and precipitating gamma prime phases, but differ considerably with respect to the volume factor. It is found that in the decay of supersaturated solid solutions for which the difference between the specific atomic volumes of the precipitation phase and the matrix is small (alloy KhN67VMTIuO) the nature of the intensity distribution of the diffraction lines remains practically unchanged regardless of the aging, while in cases where the volume discrepancy is large (alloy KhN77TIuR) significant changes in the appearance of the diffraction lines are recorded.-

Gitgarts, M. I.↗
NASA NTRS1972

Manufacturing in space.

Space, in contrast to earth, offers total gravity control and unequaled vacuum, temperature, pressure, and radiation characteristics. In zero-g molecular forces such as cohesion and adhesion become controlling factors even in the largest bulk processes. The absence of relative mass accelerations eliminates the need for support of solid matter. Stability in liquid-solid, liquid-liquid, or liquid-gas mixtures, and the absence of thermal convection is obtained because there is no relative motion in fluids due to differences in density. Applications of these characteristics include liquid-matrix preparation of composites, fine-grain castings, supersaturated alloys, combinations which exhibit liquid-phase immiscibility, the containerless free suspension of materials, surface-tension casting, surface-tension drawing, adhesion casting, and controlled density casting.

Wuenscher, H. F.↗
NASA NTRS1973

Condensation in CO2 free jet expansions. II - Growth of small clusters.

An investigation into the kinetics of molecular clustering processes which occur in the highly supersaturated vapor of a CO2 free jet is described. Terminal cluster concentrations in expansions from room temperature and reservoir pressures in the range from 400 to 900 torr were determined for trimeric CO2 for nozzle diameters of .0076 cm, .015 cm, and .023 cm and in the case of CO2 tetramer and pentamer for .015 cm nozzle diameter. The measurements were made mass spectrometrically in a supersonic molecular beam apparatus. A kinetic analysis was developed from an extension of the critical nucleus concept of nucleation theory and rate equations based on intermolecular collisions. The observed cluster populations could be accounted for by the theory by adopting sticking probabilities of approximately .03 for monomer impinging on dimer, trimer, and tetramer.

Dorfeld, W. G.↗
NASA NTRS1973

Laboratory simulation of graphite formation in stellar envelopes

A technique has been developed which permits laboratory simulation of graphite condensation in the envelopes of cool, late sequence stars. Processes in the stellar envelope were simulated by allowing hydrogen-carbon mixtures of typical circumstellar composition and temperature to expand freely into vacuum, cooling and supersaturating the vapor. Expansion products were determined mass spectrometrically through the use of molecular beam techniques. The results of laboratory expansions were scaled to those occurring near M and N stars by comparing the number of collisional events in each case. Kinetic considerations indicate that the important rate process in rarefied envelopes will be C2 formation; consequently scaling by termolecular collisions was employed. Results of this study imply that envelope expansions near M giants contribute at most .01 of the observed interstellar grain density. In the case of pulsating N stars, on the other hand, the results are not inconsistent with previous predictions of essentially complete carbon condensation.

Dorfeld, W. G.↗
NASA NTRS1974

The GISS model of the global atmosphere

A description and numerical results are presented for a global atmospheric circulation model developed at the Goddard Institute for Space Studies (GISS). The model version described is a 9-level primitive-equation model in sigma coordinates. It includes a realistic distribution of continents, oceans and topography. Detailed calculations of energy transfer by solar and terrestrial radiation make use of cloud and water vapor fields calculated by the model. The model hydrologic cycle includes two precipitation mechanisms: large-scale supersaturation and a parameterization of subgrid-scale cumulus convection. Results are presented both from a comparison of the 13th to the 43rd days (January) of one integration with climatological statistics, and from five short-range forecasting experiments. In the extended integration, the near-equilibrium January-mean model atmosphere exhibits an energy cycle in good agreement with observational estimates, together with generally realistic zonal mean fields of winds, temperature, humidity, transports, diabatic heating, evaporation, precipitation, and cloud cover.

Somerville, R. C. J.↗
NASA NTRS1973

Crystallization of plagioclase in mare basalts

A detailed study has been made of the morphology, zoning and major- and minor-element chemistry of plagioclase in mare basalt 12021 and for comparison, in several other mare basalts. Two types of plagioclase can be distinguished based on growth rate as expressed by the formation of hollow as opposed to lath-shaped crystals. The liquidus plagioclase is the most sodic part of the hollow crystals and is more sodic than the lath-shaped crystals. Hollow grains show oscillatory zoning, whereas the lath-shaped grains show normal zoning. The ratios FeO/(FeO + MgO) and K2O/(K2O + Na2O) increased in both types of plagioclase as they grew, and these ratios can be used as a guide to the crystallization history of the plagioclase. The FeO/(FeO + MgO) ratios are similar to those of coprecipitating pyroxene. The data presented here suggest the onset of plagioclase nucleation is primarily controlled by magma composition, and the point at which the magma becomes supersaturated with plagioclase.

Crawford, M. L.↗
NASA NTRS1975

Nonstationary homogeneous nucleation

A computer calculation was made of the relaxation time to steady-state nucleation in a supersaturated vapor. A binary-collision model of nucleation based on classical liquid-drop thermodynamics was used. The nondimensional nucleation relaxation time is plotted as a function of the critical drop size for various values of the surface-tension parameter. The curves permit a rough estimation of the limit of the validity of steady-state nucleation theory.

Harstad, K. G.↗
NASA NTRS1975

Oxide nucleation on thin films of copper during in situ oxidation in an electron microscope

Single-crystal copper thin films were oxidized at an isothermal temperature of 425 C and at an oxygen partial pressure of 0.005 torr. Specimens were prepared by epitaxial vapor deposition onto polished faces of rocksalt and were mounted in a hot stage inside the ultrahigh-vacuum chamber of a high-resolution electron microscope. An induction period of roughly 30 min was established which was independent of the film thickness but depended strongly on the oxygen partial pressure and to exposure to oxygen prior to oxidation. Neither stacking faults nor dislocations were found to be associated with the Cu2O nucleation sites. The experimental data, including results from oxygen dissolution experiments and from repetitive oxidation-reduction-oxidation sequences, fit well into the framework of an oxidation process involving the formation of a surface charge layer, oxygen saturation of the metal with formation of a supersaturated zone near the surface, and nucleation followed by surface diffusion of oxygen and bulk diffusion of copper for lateral and vertical oxide growth, respectively.

Heinemann, K.↗
NASA NTRS1975

Report on computation of repetitive hyperbaric-hypobaric decompression tables

The tables were constructed specifically for NASA's simulated weightlessness training program; they provide for 8 depth ranges covering depths from 7 to 47 FSW, with exposure times of 15 to 360 minutes. These tables were based up on an 8 compartment model using tissue half-time values of 5 to 360 minutes and Workmanline M-values for control of the decompression obligation resulting from hyperbaric exposures. Supersaturation ratios of 1.55:1 to 2:1 were used for control of ascents to altitude following such repetitive dives. Adequacy of the method and the resultant tables were determined in light of past experience with decompression involving hyperbaric-hypobaric interfaces in human exposures. Using these criteria, the method showed conformity with empirically determined values. In areas where a discrepancy existed, the tables would err in the direction of safety.

Edel, P. O.↗