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NASA NTRSDate not supplied

HSRL-2 Observations over the Houston, TX Region during TRACER-AQ

During field missions in 2021 and 2023, the airborne NASA Langley Research Center High Spectral Resolution Lidar 2 (HSRL 2) measured the temporal and spatial evolution of ozone and aerosol distributions impacting urban air quality over the four most populated cities in the United States. HSRL-2 measurements in 2021 were acquired over the Houston metropolitan region, including Galveston Bay and the Houston Ship Channel, as part of the NASA Tracking Aerosol Convection Experiment – Air Quality (TRACER-AQ) mission conducted in collaboration with the Department of Energy. HSRL-2 measurements were acquired over Los Angeles, Chicago, and New York City in 2023 as part of the NASA Synergistic TEMPO Air Quality Science (STAQS) mission conducted in collaboration with the NOAA Atmospheric Emissions and Reactions Observed from Megacities to Marine Areas (AEROMMA) mission. HSRL 2 provided nadir vertical profiles of ozone, aerosol backscatter, extinction, and depolarization as the aircraft flew lawnmower type patterns at 9 km for several hours over these urban areas. HSRL-2 measured profiles of aerosol extinction and aerosol optical depth (AOD) via the HSRL technique at 355 and 532 nm and profiles of aerosol backscatter and depolarization at 355, 532, and 1064 nm. Mixed Layer Heights (MLH) were derived by locating sharp vertical gradients in the profiles of aerosol backscatter. The flights were comprised of up to three repeating lawnmower patterns over each city showing the evolution of the ozone and aerosol distributions from the morning through the afternoon. The HSRL-2 measurements reveal ozone enhancements near the surface as well as in the free troposphere above the mixed layer. Some lidar measurements over Chicago and New York City show the daytime boundary layer growing into elevated layers of biomass burning aerosol. These layers complicate efforts to use column-integrated satellite measurements to infer surface air quality. As expected, mixed layer height (MLH) typically increased significantly during the day; however, during some flights, particularly over the Houston area, MLH also showed large spatial variability associated with changes in surface cover and/or small scale circulations. Often HSRL-2 measurements of AOD also showed large spatial and temporal variability throughout the day over these cities. We discuss how the ozone and aerosol profiles are averaged over different vertical and horizontal scales near the surface for use in assessments of regional air quality models and near-surface ozone retrievals from NASA’s recently launched Tropospheric Emissions: Monitoring Pollution (TEMPO) satellite.

Lidar↗
NASA NTRS2014

Increase of Ozone Concentrations, Its Temperature Sensitivity and the Precursor Factor in South China

Concerns have been raised about the possible connections between the local and regional photochemical problem and global warming. The current study assesses the trend of ozone in Hong Kong and the Pearl River Delta (PRD) in South China and investigates the interannual changes of sensitivity of ozone to air temperature, as well as the trends in regional precursors. Results reveal, at the three monitoring sites from the mid-1990s to 2010, an increase in the mean ozone concentrations from 1.0 to 1.6 microgram m(exp -3) per year. The increase occurred in all seasons, with the highest rate in autumn. This is consistent with trends and temperature anomalies in the region. The increase in the sensitivity of ozone to temperature is clearly evident from the correlation between ozone (OMI [Ozone Monitoring Instrument] column amount) and surface air temperature (from the Atmospheric Infrared Sounder) displayed in the correlation maps for the PRD during the prominently high ozone period of July September. It is observed to have increased from 2005 to 2010, the latter being the hottest year on record globally. To verify this temporal change in sensitivity, the ground-level trends of correlation coefficients/regression slopes are analysed. As expected, results reveal a statistically significant upward trend over a 14-year period (19972010). While the correlation revealed in the correlation maps is in agreement with the corresponding OMI ozone maps when juxtaposed, temperature sensitivity of surface ozone also shows an association with ozone concentration, with R0.5. These characteristics of ozone sensitivity are believed to have adverse implications for the region. As shown by ground measurements and/or satellite analyses, the decrease in nitrogen oxides (NO2) and NO(sub x) in Hong Kong is not statistically significant whileNO2 of thePRD has only very slightly changed. However, carbon dioxide has remarkably declined in the whole region. While these observations concerning precursors do not seem to adequately support an increasing ozone trend, measured surface levels of formaldehyde, a proxy for volatile organic compound (VOC) emissions, have risen significantly in the PRD (20042010). Hence, the reactive VOCs in the PRD are likely to be the main culprit for the increase of ozone, as far as precursors are concerned. Despite the prevailing problem, model simulations suggest prospects for improvement in the future.

South China↗
NASA NTRS1987

The characterization of an air pollution episode using satellite total ozone measurements

A case study is presented which demonstrates that measurements of total ozone from a space-based platform can be used to study a widespread air pollution episode over the southeastern U.S. In particular, the synoptic-scale distribution of surface-level ozone obtained from an independent analysis of ground-based monitoring stations appears to be captured by the synoptic-scale distribution of total ozone, even though about 90 percent of the total ozone is in the stratosphere. Additional analyses of upper air meteorological data, other satellite imagery, and in situ aircraft measurements of ozone likewise support the fact that synoptic-scale variability of tropospheric ozone is primarily responsible for the observed variability in total ozone under certain conditions. The use of the type of analysis discussed in this study may provide an important technique for understanding the global budget of tropospheric ozone.

Fishman, Jack↗
NASA NTRS2008

Assimilation of Aura Ozone Data and Comparisons with In Situ Observations

Ozone data from the Ozone Monitoring Instrument (OMI) and the Microwave Limb Sounder (MLS) onboard EOS Aura satellite were assimilated into the Goddard Earth Observing System Version 4 (GEOS-4) ozone assimilation system. Comparison of assimilated ozone with ozone sonde and MOZAIC data indicate an agreement within 10% in the lower stratosphere, where dynamical processes dominate. Assimilation of OMI and MLS data improves tropospheric column estimates in the Atlantic region, but leads to an overestimation in the tropical Pacific in comparison with SHADOZ sondes. Transport and data biases are considered in order to understand these discrepancies. Comparisons of assimilated tropospheric ozone columns with ozone sonde data reveal root-mean-square (RMS) differences of 2.9 to 7.2 DU, which are typically smaller than the model-sonde RMS differences. Four different definitions of the tropopause using temperature lapse rate, potential vorticity (PV) and isentropic surfaces or ozone isosurfaces are compared with respect to their global impact on the estimated tropospheric ozone column. The largest sensitivity in the tropospheric ozone column is found near the subtropical jet, where the ozone or PV determined tropopause typically lies below the lapse rate tropopause.

Stajner, Ivanka↗
NASA NTRS2000

Dynamical and Chemical Behavior of the Lower Stratosphere and Interactions with the Troposphere

This research program investigated changes of dynamical and chemical structure of the lower stratosphere and how they are related to elements of the tropospheric general circulation. These considerations were explored in total ozone data from TOMS on board the Nimbus-7 satellite. It was shown that most of the daily variance of total ozone was accounted for by quasi-horizontal transport of ozone along isentropic surfaces in the lower stratosphere. Air descending along theta surfaces experiences compression that increases the local ozone number density and column abundance. Just the reverse is experienced by air ascending along isentropics surfaces. Together, these mechanisms provide an explanation for ozone "mini-hole" phenomenon, which punctuates the circulation of the Southern Hemisphere.

Salby, Murry L.↗
NASA NTRS2018

Impact Study of the Assimilation of Surface Sensitive Microwave Radiances in the GEOS

The aim of this study is to investigate the feasibility of assimilating low frequency microwave observations from different satellite Microwave radiometers such as the Advanced Microwave Sounding Unit-A (AMSU-A). These observations are relevant to the description of air temperature, humidity, and surface parameters such as ocean surface temperature. Their assimilation into Goddard Earth Observing System (GEOS) modeling and assimilation system helps better constrain models in regions where very few observations are assimilated. In recent years, Channels 1–4 and 15 have not been assimilated in GEOS because of their large sensitivities to uncertain surface parameters such as emissivity and skin temperature. Here, the impact of using different channels will be discussed. Also we investigate the validity of the emissivity model in these channels over ocean and sea ice.Radiative transfer calculations necessary for the assimilation of satellite radiances are performed using the Community Radiative Transfer Model (CRTM). The CRTM performs forward radiative transfer calculations of brightness temperature from atmospheric profiles (temperature, moisture, and ozone) and surface characteristics. Additionally, the CRTM calculates the Jacobians of brightness temperature with respect to the input . The Jacobians are for the inversion of these radiances within the Gridpoint Statistical Interpolation (GSI) analysis system. Here, For direct assimilation of the radiance observations, the interface between GSI and CRTM, is slightly modified. Finally, we validate the assimilation results, and discuss the impact of each channels in detail.

Ebrahimi, Hamideh↗
NASA NTRS1981

The albedo of snow for partially cloudy skies

The albedo of snow is defined as the ratio of reflected to incident solar energy, and it is an important parameter in the earth's radiation budget analysis and in the study of snowpack's thermal conditions. An approximate model for calculating the incident spectral flux for partially cloudy skies is presented. The input parameters for the calculation are atmospheric precipitable water, turbidity, ozone content, surface pressure, the optical thickness of clouds, and the grain size of snow crystals. The spectral snow reflectance model considers both specular surface reflection and volumetric multiple scattering. The surface reflection is calculated by using a crystal-shape-dependent bidirectional reflectance distribution function; the volumetric multiple scattering is calculated by using a crystal-size-dependent approximate solution in the radiative transfer equation. The model yields spectral and integrated solar flux and snow reflectance as a function of solar elevation and fractional cloud-cover. The illustrative insolation and albedo values were obtained from spectral reflectance and incident flux for representative parameters of Antarctic coastal regions. A simple relationship between grain size and the overcast albedo was obtained. For a set of grain size and shape, the albedo as a function of solar elevation and fractional cloud cover was tabulated.

Choudhury, B. J.↗
NASA NTRS1990

A numerical method for parameterization of atmospheric chemistry - Computation of tropospheric OH

An efficient and stable computational scheme for parameterization of atmospheric chemistry is described. The 24-hour-average concentration of OH is represented as a set of high-order polynomials in variables such as temperature, densities of H2O, CO, O3, and NO(t) (defined as NO + NO2 + NO3 + 2N2O5 + HNO2 + HNO4) as well as variables determining solar irradiance: cloud cover, density of the overhead ozone column, surface albedo, latitude, and solar declination. This parameterization of OH chemistry was used in the three-dimensional study of global distribution of CH3CCl3. The proposed computational scheme can be used for parameterization of rates of chemical production and loss or of any other output of a full chemical model.

Spivakovsky, C. M.↗
NASA NTRS1992

SeaWiFS calibration and validation plan, volume 3

The Sea-viewing Wide Field-of-view Sensor (SeaWiFS) will be the first ocean-color satellite since the Nimbus-7 Coastal Zone Color Scanner (CZCS), which ceased operation in 1986. Unlike the CZCS, which was designed as a proof-of-concept experiment, SeaWiFS will provide routine global coverage every 2 days and is designed to provide estimates of photosynthetic concentrations of sufficient accuracy for use in quantitative studies of the ocean's primary productivity and biogeochemistry. A review of the CZCS mission is included that describes that data set's limitations and provides justification for a comprehensive SeaWiFS calibration and validation program. To accomplish the SeaWiFS scientific objectives, the sensor's calibration must be constantly monitored, and robust atmospheric corrections and bio-optical algorithms must be developed. The plan incorporates a multi-faceted approach to sensor calibration using a combination of vicarious (based on in situ observations) and onboard calibration techniques. Because of budget constraints and the limited availability of ship resources, the development of the operational algorithms (atmospheric and bio-optical) will rely heavily on collaborations with the Earth Observing System (EOS), the Moderate Resolution Imaging Spectrometer (MODIS) oceans team, and projects sponsored by other agencies, e.g., the U.S. Navy and the National Science Foundation (NSF). Other elements of the plan include the routine quality control of input ancillary data (e.g., surface wind, surface pressure, ozone concentration, etc.) used in the processing and verification of the level-0 (raw) data to level-1 (calibrated radiances), level-2 (derived products), and level-3 (gridded and averaged derived data) products.

Hooker, Stanford B.↗
NASA NTRS1990

Comparisons between TOMS, TOVS and DOBSON observations - Satellite and surface views of total column ozone

The reliability of the ozone retrievals by the TIROS-N Operational Vertical Sounder (TOVS) calculated with the newly developed physical algorithm is investigated by comparing the quality of the TOVS total ozone soundings to the corresponding values obtained by the Nimbus-7 TOMS and by the ground-based DOBSON network. The three-way comparison concentrates on observations during the last 4 months of 1987, the period of the great Antarctic 'ozone hole'. It is shown that each instrument has characteristic strengths and weaknesses, and that each of the three systems makes serious errors under some conditions.

Chesters, Dennis↗
NASA NTRS2000

Total Ozone Mapping Spectrometer (TOMS) Level-3 Data Products User's Guide

Data from the TOMS series of instruments span the time period from November 1978, through the present with about a one and a-half year gap from January 1994 through July 1996. A set of four parameters derived from the TOMS measurements have been archived in the form of daily global maps or Level-3 data products. These products are total column ozone, effective surface reflectivity, aerosol index, and erythermal ultraviolet estimated at the Earth surface. A common fixed grid of I degree latitude by 1.25 degree longitude cells over the entire globe is provided daily for each parameter. These data are archived at the Goddard Space Flight Center Distributed Active Archive Center (DAAQ in Hierarchical Data Format (HDF). They are also available in a character format through the TOMS web site at http://toms.gsfc.nasa.gov. The derivations of the parameters, the mapping algorithm, and the data formats are described. The trend uncertainty for individual TOMS instruments is about 1% decade, but additional uncertainty exists in the combined data record due to uncertainty in the relative calibrations of the various TOMS.

McPeters, Richard D.↗
NASA NTRS2012

Overview of US AID-World Bank-NASA Collaboration to Address Water Management Issues in the MENA Region

The World Bank, USAID and NASA have recently established a joint project to study multiple issues pertaining to water related applications in the Middle East North Africa (MENA) region. The main concentration of the project is on utilization of remote sensing data and hydrological models to address crop irrigation and mapping, flood mapping and forecasting, evapotranspiration and drought problems prevalent in this large geographic area. Additional emphases are placed on understanding the climate impact on these areas as well. Per IPCC 2007 report, by the end of this century MENA region is projected to experience an increase of 3 C to 5 C rise in mean temperatures and a 20% decline in precipitation. This poses a serious problem for this geographic zone especially when majority of the hydrological consumption is for the agriculture sector and the remaining amount is for domestic consumption. The remote sensing data from space is one of the best ways to study such complex issues and further feed into the decision support systems. NASA's fleet of Earth Observing satellites offer a great vantage point from space to look at the globe and provide vital signs necessary to maintain healthy and sustainable ecosystem. These observations generate multiple products such as soil moisture, global precipitation, aerosols, cloud cover, normalized difference vegetation index, land cover/use, ocean altimetry, ocean salinity, sea surface winds, sea surface temperature, ozone and atmospheric gases, ice and snow measurements, and many more. All of the data products, models and research results are distributed-via the Internet freely through out the world. This project will utilize several NASA models such as global Land Data Assimilation System (LDAS) to generate hydrological states and fluxes in near real time. These LDAS products will then be further compared with other NASA satellite observations (MODIS, VIIRS, TRMM, etc.) and other discrete models to compare and optimize evapotranspiration, soil moisture and crop irrigation, droUght assessment and water balance. The floods being a critical disaster in many of the MENA countries, NASA's global flood mapping and modeling framework (CREST) will be customized for country specific needs and delivered to the remote sensing organizations for their future use. Finally, capacity building is a critical part of this project and NASA will assist in this effort as well.

Habib, Shahid↗
NASA NTRS2012

Customizing NASA's Earth Science Research Products for addressing MENA Water Challenges

As projected by IPCC 2007 report, by the end of this century the Middle East North Mrica (MENA) region is projected to experience an increase of 3 C to 5 C rise in mean temperatures and a 20% decline in precipitation. This poses a serious problem for this geographic zone especially when majority of the hydrological consumption is for the agriculture sector and the remaining amount is for domestic consumption. In late 2011, the World Bank, USAID and NASA have joined hands to establishing integrated, modem, up to date NASA developed capabilities for various countries in the MENA region for addressing water resource issues and adapting to climate change impacts for improved decision making for societal benefits. The main focus of this undertaking is to address the most pressing societal issues which can be modeled and solved by utilizing NASA Earth Science remote sensing data products and hydrological models. The remote sensing data from space is one of the best ways to study such complex issues and further feed into the decision support systems. NASA's fleet of Earth Observing satellites offer a great vantage point from space to look at the globe and provide vital signs necessary to maintain healthy and sustainable ecosystem. NASA has over fifteen satellites and thirty instruments operating on these space borne platforms and generating over 2000 different science products on a daily basis. Some of these products are soil moisture, global precipitation, aerosols, cloud cover, normalized difference vegetation index, land cover/use, ocean altimetry, ocean salinity, sea surface winds, sea surface temperature, ozone and atmospheric gasses, ice and snow measurements, and many more. All of the data products, models and research results are distributed via the Internet freely through out the world. This project will utilize several NASA models such as global Land Data Assimilation System (LDAS) to generate hydrological states and fluxes in near real time. These LDAS products will then be further compared with other NASA satellite observations (MODIS, VIIRS, TRMM, etc.) and other discrete models to compare and optimize evapotranspiration, soil moisture and crop irrigation, drought assessment and water balance. The floods being a critical disaster in many of the MENA countries, NASA's global flood mapping and modeling framework (CREST) will be customized for country specific needs and delivered to the remote sensing organizations for their future use. Training is an important component under this activity and adequate level of training will be offered to build basic capacity to work with NASA provided data products, models for their future use. This paper provides a comprehensive introduction to NASA's Earth Science mission for understanding the behavior of our home Planet, projecting its health for future generations and applying research results solving societal issues.

Habib, Shahid↗
NASA NTRS2012

Assess Calibration Consistency of MODIS and AVHRR Thermal Infrared Bands Using SNO Observations Corrected for Atmospheric Effects

Monitoring environmental changes from space requires extremely well-calibrated observations to achieve the necessary high accuracy and stability. The calibration differences between the Moderate Resolution Imaging Spectroradiometer (MODIS) and the Advanced Very High Resolution Radiometer (AVHRR) thermal bands provide a valuable quality assessment of the instrument performance. This letter compares the calibration differences between the Aqua MODIS and NOAA-18 AVHRR bands at 11.0 and 12.0 /Lm using simultaneous nadir overpass observations obtained in nearly parallel orbits. Impacts due to the relative spectral-response differences between the two sensors are estimated by MODTRAN simulations with real-time atmospheric profiles of temperature, water vapor, atmospheric pressure and ozone, and surface skin temperatures. Results show that the temperature difference after the removal of atmospheric impacts is within 0.30 K (or 0.40% in radiance) across the effective calibration range (or the 1l.0 l'm band/channel. For the 12.0 pm band, the differences are OAO K (or 0.50%) at the typical radiance and up to 0.70 K (or 0.90%) close to the maximum radiance, indicating an excellent calibration consistency between MODIS and AVHRR for both bands.

Wu, Aisheng↗
NASA NTRS2020

The California Baseline Ozone Transport Study (CABOTS)

Ozone is one of the six “criteria” pollutants identified by the U.S. Clean Air Act Amendment of 1970 as particularly harmful to human health. Concentrations have decreased markedly across the United States over the past 50 years in response to regulatory efforts, but continuing research on its deleterious effects have spurred further reductions in the legal threshold. The South Coast and San Joaquin Valley Air Basins of California remain the only two “extreme” ozone nonattainment areas in the United States. Further reductions of ozone in the West are complicated by significant background concentrations whose relative importance increases as domestic anthropogenic contributions decline and the national standards continue to be lowered. These background concentrations derive largely from uncontrollable sources including stratospheric intrusions, wildfires, and intercontinental transport. Taken together the exogenous sources complicate regulatory strategies and necessitate a much more precise understanding of the timing and magnitude of their contributions to regional air pollution. The California Baseline Ozone Transport Study was a field campaign coordinated across Northern and Central California during spring and summer 2016 aimed at observing daily variations in the ozone columns crossing the North American coastline, as well as the modification of the ozone layering downwind across the mountainous topography of California to better understand the impacts of background ozone on surface air quality in complex terrain.

Ian C. Faloona↗
DOE OSTI2023

Modelling the coupled mercury-halogen-ozone cycle in the central Arctic during spring

Near-surface mercury and ozone depletion events occur in the lowest part of the atmosphere during Arctic spring. Mercury depletion is the first step in a process that transforms long-lived elemental mercury to more reactive forms within the Arctic that are deposited to the cryosphere, ocean, and other surfaces, which can ultimately get integrated into the Arctic food web. Depletion of both mercury and ozone occur due to the presence of reactive halogen radicals that are released from snow, ice, and aerosols. In this work, we added a detailed description of the Arctic atmospheric mercury cycle to our recently published version of the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem 4.3.3) that includes Arctic bromine and chlorine chemistry and activation/recycling on snow and aerosols. The major advantage of our modelling approach is the online calculation of bromine concentrations and emission/recycling that is required to simulate the hourly and daily variability of Arctic mercury depletion. We used this model to study coupling between reactive cycling of mercury, ozone, and bromine during the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) spring season in 2020 and evaluated results compared to land-based, ship-based, and remote sensing observations. The model predicts that elemental mercury oxidation is driven largely by bromine chemistry and that particulate mercury is the major form of oxidized mercury. The model predicts that the majority (74%) of oxidized mercury deposited to land-based snow is re-emitted to the atmosphere as gaseous elemental mercury, while a minor fraction (4%) of oxidized mercury that is deposited to sea ice is re-emitted during spring. Our work demonstrates that hourly differences in bromine/ozone chemistry in the atmosphere must be considered to capture the springtime Arctic mercury cycle, including its integration into the cryosphere and ocean.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1988

Antarctic ozone depletion chemistry - Reactions of N2O5 with H2O and HCl on ice surfaces

In a study concerning Antarctic ozone depletion, reactions of dinitrogen pentoxide with water and hydrochloric acid were studied on ice surfaces in a Knudsen cell flow reactor. The N2O5 reacted on ice at 185 K to form condensed-phase nitric acid (HNO3). This reaction may provide a sink for odd nitrogen, NO(x), during the polar winter, a requirement in nearly all models of Antarctic ozone depletion. The reaction of N2O5 on HCl-ice surfaces at 185 K produced gaseous nitryl chloride (ClNO2) and condensed-phase HNO3 and proceeded until all of the HCl within the ice was depleted. The ClNO2 which did not react or condense on ice at 185 K, can be readily photolyzed in the Antarctic spring to form atomic chlorine for catalytic ozone destruction cycles. The other photolysis product, gaseous nitrogen dioxide may be important in the partitioning of NO(x) between gaseous and condensed phases in the Antarctic winter.

Tolbert, Margaret A.↗