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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9

High-Frequency Focused Water-Coupled Ultrasound Used for Three-Dimensional Surface Depression Profiling

To interface with other solids, many surfaces are engineered via methods such as plating, coating, and machining to produce a functional surface ensuring successful end products. In addition, subsurface properties such as hardness, residual stress, deformation, chemical composition, and microstructure are often linked to surface characteristics. Surface topography, therefore, contains the signatures of the surface and possibly links to volumetric properties, and as a result serves as a vital link between surface design, manufacturing, and performance. Hence, surface topography can be used to diagnose, monitor, and control fabrication methods. At the NASA Glenn Research Center, the measurement of surface topography is important in developing high-temperature structural materials and for profiling the surface changes of materials during microgravity combustion experiments. A prior study demonstrated that focused air-coupled ultrasound at 1 MHz could profile surfaces with a 25-m depth resolution and a 400-m lateral resolution over a 1.4-mm depth range. In this work, we address the question of whether higher frequency focused water-coupled ultrasound can improve on these specifications. To this end, we employed 10- and 25-MHz focused ultrasonic transducers in the water-coupled mode. The surface profile results seen in this investigation for 25-MHz water-coupled ultrasound, in comparison to those for 1-MHz air-coupled ultrasound, represent an 8 times improvement in depth resolution (3 vs. 25 m seen in practice), an improvement of at least 2 times in lateral resolution (180 vs. 400 m calculated and observed in practice), and an improvement in vertical depth range of 4 times (calculated).

Roth, Don J.↗

Tribological Behavior of Electrochemically Etched AISI 316 Stainless Steel with a Textured Surface

In this work, AISI 316 stainless steel (316 SS) was electrochemically etched in four NaCl solutions (10, 15, 20, and 25 wt.%) to form textured surfaces. Surface morphologies, three-dimensional surface topographies, and surface profiles of the textured 316 SS samples were obtained by scanning electron microscopy (SEM) and laser scanning confocal microscope (LSCM). Sliding friction tests of the textured 316 SS samples were conducted in air and under grease lubrication. The results suggested that the variable degrees of microtextured surfaces after electrochemical etching in 10, 15, and 20 wt.% NaCl solutions. The 316 SS samples etched in 15 and 20 wt.% NaCl solutions showed more promising tribological performance than other samples, as reflected by their friction coefficients, mass loss per unit distance traveled (mg/m), and wear morphologies.

36 MATERIALS SCIENCE↗

Mechanical and chemical properties of PVD and cold spray Cr-coatings on Zircaloy-4

In this paper, accident-tolerant fuel (ATF) cladding materials aim to improve fuel reliability and safety during accident scenarios in water-cooled reactors. These ATF cladding should also perform comparable or better than the current zirconium alloy cladding under reactor normal operating conditions. Surface-modified Zircaloy-4 was produced by depositing a protective coating of chromium by two different coating techniques, Physical Vapor Deposition (PVD) and Cold Spray (CS). The coating thickness, structure, composition, and mechanical properties of the coated Zircaloy were assessed with advanced materials characterization techniques. Results showed a strengthening effect of the Cr-coating, along with ~83% higher hardness compared to that of the Zircaloy-4 substrate. Surface topography and surface chemistry of the Cr-coated Zircaloy-4 were assessed with contact profilometry, atomic force microscopy, contact angle goniometry, and X-ray photoelectron spectroscopy. Deposited Cr-coating significantly improved surface wettability compared to the substrate Zircaloy-4. The formation of surface oxides on the coatings by prolonged exposure to ambient air showed a further increase in the hydrophobic behavior. Surface parameters and surface chemistry after flow boiling critical heat flux tests, conducted at atmospheric pressure, evidenced a slight increase in surface roughness with notable changes in wettability associated with the formation of surface oxides.

36 MATERIALS SCIENCE↗

Nanocrystalline sol-gel TiO{sub 2}-SnO{sub 2} coatings: Preparation, characterization and photo-catalytic performance

Highlights: Black-Right-Pointing-Pointer SnO{sub 2} additive enhanced significantly photo-catalytic properties of TiO{sub 2} based thin film for remove of organic compounds. Black-Right-Pointing-Pointer Structural and optical properties are dependent on dopant concentration. Black-Right-Pointing-Pointer TiO{sub 2}-SnO{sub 2} nanocrystalline thin film is promising for photocatalytic properties in visible light. -- Abstract: In this study, preparation of SnO{sub 2} (0-30 mol% SnO{sub 2})-TiO{sub 2} dip-coated thin films on glazed porcelain substrates via sol-gel process has been investigated. The effects of SnO{sub 2} on the structural, optical, and photo-catalytic properties of applied thin films have been studied by X-ray diffraction, Raman spectroscopy, and scanning electron microscopy. Surface topography and surface chemical state of thin films were examined by atomic force microscopy and X-ray photoelectron spectroscopy. XRD patterns showed an increase in peak intensities of the rutile crystalline phase by increasing the SnO{sub 2} content. The prepared Sn doped TiO{sub 2} photo-catalyst films showed optical absorption in the visible light area exhibited excellent photo-catalytic ability for the degradation of methylene blue under visible light irradiation. Best photo-catalytic activity of Sn doped TiO{sub 2} thin films was measured in the TiO{sub 2}-15 mol% SnO{sub 2} sample by the Sn{sup 4+} dopants presented substitution Ti{sup 4+} into the lattice of TiO{sub 2} increasing the surface oxygen vacancies and the surface hydroxyl groups.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Adaptation of a general circulation model to ocean dynamics

A primitive-variable general circulation model of the ocean was formulated in which fast external gravity waves are suppressed with rigid-lid surface constraint pressires which also provide a means for simulating the effects of large-scale free-surface topography. The surface pressure method is simpler to apply than the conventional stream function models, and the resulting model can be applied to both global ocean and limited region situations. Strengths and weaknesses of the model are also presented.

Turner, R. E.↗

Fracture surface analysis in composite and titanium bonding: Part 1: Titanium bonding

Fractured lap shear Ti 6-4 adherends bonded with polyphenyquinoxaline (PPQ) and polysulfone were analyzed. The effects of adherend pretreatment, stress level, thermal aging, anodizing voltage, and modified adhesive of Ti 6-4 adherend bonded with PPQ on lap shear strength were studied. The effect of adherend pretreatment on lap shear strength was investigated for PS samples. Results of scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) used to study the surface topography and surface composition are also discussed.

Sanderson, K. A.↗

A View from Space: Evolution of the 1997-98 El Nino and La Nina

After the last extreme El Nino in 1982-1983, an extensive in situ observing system was deployed in the tropical Pacific Ocean in support of monitoring and predicting El Nino. Within the past ten years a series of ocean and atmosphere remote sensing satellites have been launched that serve to supplement and enhance the observations being taken at the surface, and at depth, in the equatorial Pacific Ocean. The 1997-1998 "El Nino Event of the Century" has been the best monitored El Nino on record. The 1997-1998 El Nino will be the first time a major El Nino event and subsequent La Nina will have been observed from start to finish from a combination of remotely-sensed measurements of sea surface temperature, sea surface topography, sea surface winds, ocean color, and precipitation. Among some of the lessons learned to date from the 1997-1998 event have been the need for global observations in addition to just those in the equatorial Pacific Ocean. In this presentation the evolution of the 1997-1998 El Nino will be depicted from the unique vantage point provided by these space-based observations as analyzed separately, and together as a representation of the coupled system. Comparisons and contrasts with the evolution 1982-1983 El Nino and how the in situ and space-based observations complement each other will be discussed.

Busalacchi, Antonio J.↗

A View from Space: Evolution of the 1997-1998 El Nino and La Nina

After the last extreme El Nino in 1982-1983, an extensive in situ observing system was deployed in the tropical Pacific Ocean in support of monitoring and predicting El Nino. Within the past ten years a series of ocean and atmosphere remote sensing satellites have been launched that serve to supplement and enhance the observations being taken at the surface, and at depth, in the equatorial Pacific Ocean. The 1997-1998 "El Nino Event of the Century" has been the best monitored El Nino on record. The 1997-1998 El Nino will be the first time a major El Nino event and subsequent La Nina will have been observed from start to finish from a combination of remotely-sensed measurements of sea surface temperature, sea surface topography, sea surface winds, ocean color, and precipitation. Among some of the lessons learned to date from the 1997-1998 event have been the need for global observations in addition to just those in the equatorial Pacific Ocean. In this presentation the evolution of the 1997-1998 El Nino will be depicted from the unique vantage point provided by these space-based observations as analyzed separately, and together as a representation of the coupled system. Comparisons and contrasts with the evolution 1982-1983 El Nino and how the in situ and space-based observations complement each other will be discussed.

Busalacchi, Antonio J.↗

Evolution of the 1997-98 El Nino and La Nina: the Role of Altimetry in ENSO Studies and Prediction

El Nino and the Southern Oscillation (ENSO) are known to be a quasi-periodic coupled ocean-atmosphere phenomenon occurring roughly every 3-7 years. Its largest oceanic manifestations are found in the equatorial Pacific, but it is of global climatic significance. During the flight of the TOPEX]Poseidon altimeter, the equatorial Pacific was in the midst of an unusual period of prolonged ENSO warming in the mid-1990's. In 1997, the tropical Pacific witnessed the development of a major El Nino event, rivaling in strength the 1982-83 El Nino. The intensity of this El Nino, and its rapid intensification early in the calendar year, caught the scientific community by surprise. None of the forecast models, statistical or dynamical, captured these features of the 1997 El Nino, although those models that assimilated in situ ocean observations did better than most in predicting that the event would occur in 1997. The onset of the El Nino coincided with the occurrence of several westerly wind events in the western Pacific rather than to delayed oscillator physics. However, western Pacific sea levels were anomalously elevated a year and a half prior to the onset, which may have helped precondition the system to a particularly strong ENSO episode. The coming of La Nina was foreshadowed by large-scale drops in sea level in the western tropical Pacific and cyclonic wind stress curl anomalies far beyond the +\- 8 degrees latitude bounds of the TAO mooring array. In past El Nino events, the evolution of the coupled system could only be studied from the perspective of in situ observations. The 1997-1998 El Nino event will be the first time a major El Nino event will have been observed from start to finish via remotely-sensed measurements of sea surface topography, sea surface temperature, sea surface winds, ocean color, and precipitation. These observations have considerable potential for advancing coupled climate forecasts on time scales from seasons to decades. This presentation will address questions along the lines of: (1) What are the scientific problems in ENSO that can benefit most from altimetry data? (2) Are there any precursors in the global ocean-atmosphere system for the 1997-98 extreme event? (3) Is there a unique role of altimetry in detecting potential precursors?(4) Has Topex/Poseidon data been adequately used to improve ENSO forecasts? Is there any firm evidence? (6) What is the status of the transition of El Nino into a La Nina?

Busalacchi, Antonio J.↗

A View From Space: Evolution of the 1997-1998 El Nino and La Nina

After the last extreme El Nino in 1982-1983, an extensive in situ observing system was deployed in the tropical Pacific Ocean in support of monitoring and predicting El Nino. Within the past ten years a series of ocean and atmosphere remote sensing satellites have been launched that serve to supplement and enhance the observations being taken at the surface, and at depth, in the equatorial Pacific Ocean. The 1997-1998 "El Nino Event of the Century" has been the best monitored El Nino on record. The 1997-1998 El Nino will be the first time a major El Nino event and subsequent La Nina will have been observed from start to finish from a combination of remotely-sensed measurements of sea surface temperature, sea surface topography, sea surface wind, ocean color, and precipitation, Among some of the lessons learned to date from the 1997-1998 event have been the need for global observation in addition to just those in the equatorial Pacific Ocean. In this presentation the evolution of the 1997-1998 El Nino will be depicted from the unique vantage point provided by these space-based observations as analyzed separately, and together as a representation of the coupled system. Comparisons and contrasts with the evolution 1982-1983 El Nino and how the in situ and space-based observations complement each other will be discussed.

Busalacchi, Antonio↗

Exploring Asteroid Interiors: The Deep Interior Mission Concept

Deep Interior is a mission to determine the geophysical properties of near-Earth objects, including the first volumetric image of the interior of an asteroid. Radio reflection tomography will image the 3D distribution of complex dielectric properties within the ~1 km rendezvous target and hence map structural, density or compositional variations. Laser altimetry and visible imaging will provide high-resolution surface topography. Smart surface pods culminating in blast experiments, imaged by the high frame rate camera and scanned by lidar, will characterize active mechanical behavior and structure of surface materials, expose unweathered surface for NIR analysis, and may enable some characterization of bulk seismic response. Multiple flybys en route to this target will characterize a diversity of asteroids, probing their interiors with non-tomographic radar reflectance experiments. Deep Interior is a natural follow-up to the NEARShoemaker mission and will provide essential guidance for future in situ asteroid and comet exploration. While our goal is to learn the interior geology of small bodies and how their surfaces behave, the resulting science will enable pragmatic technologies required of hazard mitigation and resource utilization.

Asphaug, E.↗

Measurements of Erosion Wear Volume Loss on Bare and Coated Polymer Matrix Composites

An investigation was conducted to examine the erosion behavior of uncoated and coated polymer matrix composite (PMC) specimens subjected to solid particle impingement using air jets. The PMCs were carbon-Kevlar (DuPont, Wilmington, DE) fiber-epoxy resin composites with a temperature capability up to 393 K (248 F). Tungsten carbide-cobalt (WC-Co) was the primary topcoat constituent. Bondcoats were applied to the PMC substrates to improve coating adhesion; then, erosion testing was performed at the University of Cincinnati. All erosion tests were conducted with Arizona road-dust (ARD), impinging at angles of 20 and 90 on both uncoated and two-layer coated PMCs at a velocity of 229 m/s and at a temperature of 366 K (200 F). ARD contains primarily 10-m aluminum oxide powders. Vertically scanning interference microscopy (noncontact, optical profilometry) was used to evaluate surface characteristics, such as erosion wear volume loss and depth, surface topography, and surface roughness. The results indicate that noncontact, optical interferometry can be used to make an accurate determination of the erosion wear volume loss of PMCs with multilayered structures while preserving the specimens. The two-layered (WC-Co topcoat and metal bondcoat) coatings on PMCs remarkably reduced the erosion volume loss by a factor of approximately 10. The tenfold increase in erosion resistance will contribute to longer PMC component lives, lower air friction, reduced related breakdowns, decreased maintenance costs, and increased PMC reliability. The decrease in the surface roughness of the coated vanes will lead to lower air friction and will subsequently reduce energy consumption. Eventually, the coatings could lead to overall economic savings.

Miyoshi, Kazuhisa↗

SPARROW: Steam Propelled Autonomous Retrieval Robot for Ocean Worlds

The Steam Propelled Autonomous Retrieval Robot (SPARROW) for Ocean Worlds was a Phase I mission concept study funded under the NASA NIAC program. This report represents the findings of that study and recommendations for future work. SPARROW, envisioned as a soccer ball-sized payload to a primary lander mission, is a propulsively hopping robot for the exploration of Europa's rugged, icy surface. A multi-thruster, passively gimballed robot within a protective, spherical shell, SPARROW is able to freely rotate, self-right, and tumble over chaotic terrains. Europa's abundant surface ice would be harvested as an in situ propellant source. The principal objective of SPARROW is to increase the science return of a Europa landed asset by enabling access to distal, spatially distributed geologic units. The design of mobility systems for Europa is challenging, due in part to its almost entirely unconstrained surface topography and strength. Images returned by Voyager and Galileo yielded resolutions on the order of hundreds of meters per pixel, with localized regions reaching 6 meters per pixel—still far larger than a typical rover. A key benefit of SPARROW's hopping, impact-tolerant design, is that it eliminates the need for a priori information regarding terrain topography and surface strength; no surface reaction forces are required for motion. In this context, SPARROW is believed to be entirely terrain agnostic. In this report we detail the results of three study objectives: i) to quantify the energy required to collect surface ice, change its phase, and maintain propellant temperature, ii) to identify control and estimation strategies that enable SPARROW to successfully reach, and return from, regions of scientific interest, and iii) to characterize the impact of SPARROW's range on likely science return. Five water-based propellant architectures are presented alongside their mass, power, and volume requirements. Monte Carlo simulations of SPARROW hopping and tumbling over 1 km of glacial ice are summarized, characterizing SPARROW's sensitivity to uncertainty in: initial pose, thrust profile, and vehicle-terrain interaction. A science traceability matrix is presented, which details the effect of sortie range on three science goals: constraining Europa's evolutionary morphology, assessing sub-surface ocean habitability, and searching for life and/or biosignatures.

Autonomous↗

SPARROW: A Steam Propelled Autonomous Retrieval Robot for Ocean Worlds

This paper presents the results of a NIAC Phase I study into the use of a propulsively hopping robot for the exploration of Europa’s rugged, icy surface. Named the“Steam Propelled Retrieval Robot for Ocean Worlds,” SPARROW is a multi-thruster robot passively gimballed within a protective, spherical shell, which enables it to freely rotate, self-right, and tumble over chaotic terrains. SPARROW is envisioned as a soccerball-sized payload to a primary lander mission. Europa’s abundant surface ice would be harvested as an in situ propellant source. The principal objective of SPARROW would be to increase the science return of a Europa landed asset by enabling access to distal, spatially distributed geologic units. The design of mobility systems for Europa is challenging, due in part to its almost entirely unconstrained surface topography and strength. Images returned by Voyager and Galileo yielded resolutions on the order of hundreds of meters per pixel, with localized regions reaching 6 meters per pixel—still far larger than a typical rover. A key benefit of SPARROW’s hopping, impact-tolerant design, is that it eliminates the need for a piori information on the terrain topography and surface strength; no surface reaction forces are required for motion. In this context, SPARROW is entirely terrain agnostic. In this paper we detail the results of three study objectives: i) to quantify the energy required to collect surface ice, change its phase, and maintain propellant temperature, ii) to identify control and estimation strategies that enable SPARROW to successfully reach, and return from, regions of scientific interest, and iii) to characterize the impact of SPARROW’s range on likely science return. Five water-based propellant architectures are presented alongside their mass, power, and volume requirements. Monte Carlo simulations of SPARROW hopping and tumbling over 1 km of glacial ice are summarized, characterizing SPARROW’s sensitivity to uncertainty in: initial conditions, thrust control, and cage-terrain interaction. Finally, a science traceability matrix is presented, which details the effect of sortie range on three science goals: constraining Europa’s evolutionary morphology, assessing sub-surface ocean habitability, and searching for life and/or biosignatures.

Phillips, Cynthia↗

A Study on the Surface Composition and Migration of Materials and Their Effect on Surface Microhardness during Micro-EDM of Ti-6Al-4V

This study aims to investigate the effect of machining parameters on the surface topography and composition of Ti-6Al-4V after micro-EDM as well as the effect of elemental composition on the surface microhardness. The surface topography has been studied in terms of quality of machined surface, crater sizes, and the presence of surface defects. Statistical analysis was carried out to study the influence of micro-EDM process parameters, i.e., voltage, capacitance, discharge energy, electrode rotational speed, and the electrode coating, on the elemental composition of the machined surface. It was found that the crater size, and hence the surface finish, was dependent on the electrical parameters only, with more pronounced effect of capacitance over voltage. The 60 V and 30 pF combination resulted in crater size as small as 1 µm, whereas crater size of 12 µm was obtained using a combination of 4700 pF and 112 V. Although smaller capacitance resulted in smaller crater sizes, it also increased the chances of defects or deposition of debris on the machined surface. There was migration of material from the tool electrode, dielectric oil, and atmosphere to the workpiece surface, which influenced the surface topography, crater sizes, and surface microhardness. The effects of non-electrical parameters on the relative percentage of various elements were found to be statistically insignificant. The surface microhardness was found to increase slightly due to the surface modification after EDM. The reason for increase in surface microhardness was identified as the migration of tungsten from the tool electrode and carbon from the dielectric. The maximum surface microhardness of 455 HV was obtained at a surface composition after micro-EDM containing 7.96% C and 9.69% W, where non-machined Ti-6Al-4V surface does not have any carbon or tungsten on the surface.

36 MATERIALS SCIENCE↗

Determination of the ocean circulation using Geosat altimetry

A spherical harmonic model of the sea surface topography complete to degree and order 10 and a model of the earth's geopotential field complete to degree and order 50 have been obtained in a simultaneous solution using Geosat altimeter data and tracking data from 14 different satellites. The sea surface topography model compares well with oceanographic models computed using hydrographic data and ship drift data. Currently, errors in the estimated gravity field model limit the determination of the spherical harmonic coefficients of the general ocean circulation to degrees 10 and lower, corresponding to a minimum wavelength of 4000 km. Error analysis indicates that the correlation between the geoid and the sea surface topography model is less than 0.2, indicating good separation of the geoid and the sea surface topography at wavelengths of 4000 km or longer. Estimates of the scale factor for the significant wave height (H1/3), which is used to compute the electromagnetic bias correction and the bias for the Geosat altimeter, are obtained. The estimate of the H1/3 correction is 3.6 + or - 1.5 percent, and the height bias estimate is zero.

Nerem, R. S.↗

Radar Sounding of Mars: A Focus on MARSIS

Radar has the unique capability of looking under the dry and cold surfaces of Mars. The depth of penetration of radio waves depends on a number of surface and subsurface parameters such as surface topography, subsurface geological structure, and surface and subsurface electromagnetic properties. Among these parameters, the surface topography is known best largely due to valuable data provided by Mars Global Surveyor's MOLA (Mars Orbiter Laser Altimeter) instrument. However, little information is available on the electromagnetic properties and subsurface characteristics of Mars. In addition to dispersion, the ionosphere will also attenuate the radio wave. The level of attenuation depends on the ionosphere's electron density and its profile shape and the electron-neutral collision frequency. Fortunately, information from past missions can provide some information on the expected level of attenuation. A figure shows expected total radio wave attenuation under three different ionospheric conditions. Additional information is contained in the original extended abstract.

Safaeinili, A.↗

Radar Sounding of Mars: A Focus on MARSIS

Radar has the unique capability of looking under the dry and cold surfaces of Mars. The depth of penetration of radio waves depends on a number of surface and subsurface parameters such as surface topography, subsurface geological structure and surface and subsurface electromagnetic properties. Among these parameters, the surface topography is known best largely due to valuable data provided by Mars Global Surveyor's MOLA instrument. However, little information is available on the electromagnetic properties and subsurface characteristics of Mars.

radar sounding↗