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At least 163 records · Page 9

System for Thermal Imaging of Hot Moving Objects

The High Altitude/Re-Entry Vehicle Infrared Imaging (HARVII) system is a portable instrumentation system for tracking and thermal imaging of a possibly distant and moving object. The HARVII is designed specifically for measuring the changing temperature distribution on a space shuttle as it reenters the atmosphere. The HARVII system or other systems based on the design of the HARVII system could also be used for such purposes as determining temperature distributions in fires, on volcanoes, and on surfaces of hot models in wind tunnels. In yet another potential application, the HARVII or a similar system would be used to infer atmospheric pollution levels from images of the Sun acquired at multiple wavelengths over regions of interest. The HARVII system includes the Ratio Intensity Thermography System (RITS) and a tracking subsystem that keeps the RITS aimed at the moving object of interest. The subsystem of primary interest here is the RITS (see figure), which acquires and digitizes images of the same scene at different wavelengths in rapid succession. Assuming that the time interval between successive measurements is short enough that temperatures do not change appreciably, the digitized image data at the different wavelengths are processed to extract temperatures according to the principle of ratio-intensity thermography: The temperature at a given location in a scene is inferred from the ratios between or among intensities of infrared radiation from that location at two or more wavelengths. This principle, based on the Stefan-Boltzmann equation for the intensity of electromagnetic radiation as a function of wavelength and temperature, is valid as long as the observed body is a gray or black body and there is minimal atmospheric absorption of radiation.

Weinstein, Leonard↗

Coastal Changes in Temperature and Salinity Observed during Hurricane Isaac Recorded and Downloaded by NASA DRIFTERs Moored in Heron Bay and at Half Moon Island, Louisiana

Major changes in salinity (approx.14 ppt.) and temperature (approx.40C) were continuously registered by two prototype NASA DRIFTERs, surface moored floaters, that NASA's Applied Science and Technology Project Office (ASTPO) has developed. The DRIFTER floating sensor module is equipped with an Arduino open-source electronics prototyping platform and programming language (http://www.arduino.cc), a GPS (Global Positioning System) module with antenna, a cell phone SIM (Subscriber Identity Module) card and a cellular antenna which is used to transmit data, and a probe to measure temperature and conductivity (from which salinity can be derived). The DRIFTER is powered by a solar cell panel and all the electronic components are mounted and sealed in [ waterproof encasement. Position and measurement data are transmitted via short message service (SMS) messaging to a Twitter site (DRIFTER 002@NASADRIFTER_002 and DRIFTER 004@NASADRIFTER_004), which provides a live feed. These data are the imported into a Google spreadsheet where conductivity is converted to salinity, and graphed in real-time. The spreadsheet data will be imported into a webpage maintained by ASTPO, where it will be displayed available for dO\\1lload.

Kalcic, Maria↗

Studies on magnetocaloric effect of Tb 2 Ni 0.90 Si 2.94 compound

A comparative study has been carried out on the magnetocaloric properties of as-cast and annealed Tb 2 Ni 0.90 Si 2.94 intermetallic compound. While the as-cast material exhibits ferromagnetic cluster-glass behaviour below 9.9 K coexisting with antiferromagnetic (AFM) interaction, the annealed system shows AFM ordering below 13.5 K and spin freezing occurs below 4 K. The compound exhibits moderate magnetocaloric performance with maximum isothermal entropy changes (–ΔS M ) 8.8 and 10.9 J kg –1 K –1 , relative cooling power (RCP) 306 and 365 J kg –1 , along with adiabatic temperature change (ΔT ad ) 5.5 and 8.15 K for 70 kOe magnetic field change in as-cast and annealed forms, respectively. The estimated magnetic entropy change is found to be larger for annealed sample in comparison to that of as-cast analogue. However, the full width at half maxima (FWHM) of –ΔS M (T) behaviour is larger in as-cast compound due to the presence of inherent structural disorder which reduces with thermal annealing. A positive isothermal entropy change (–ΔS M ) and adiabatic temperature change (ΔT ad ) is observed for the as-cast compound in the measured field and temperature region. In contrast, the annealed system exhibits inverse magnetocaloric effect in the low field and temperature region where AFM interactions dominate. Magnetocaloric effect (MCE) is used as a tool to establish a subtle correlation between the observed magnetocaloric effect and the reported magnetic properties of the system.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Disentangling the chemistry and transport impacts of the quasi-biennial oscillation on stratospheric ozone

The quasi-biennial oscillation (QBO) in tropical winds perturbs stratospheric ozone throughout much of the atmosphere via changes in transport of ozone and other trace gases, as well as via temperature changes, both of which alter ozone chemistry. Attributing these causes of QBO–ozone variability may provide insights into model-to-model differences that contribute to ozone simulation. Here we develop a novel metric of steady-state ozone (SSO) to separate these effects: SSO calculates the local steady-state response of ozone due to the changes in temperature, chemical species, and overhead ozone column; the response due to circulation change is presumed when SSO shows no response. It is applied to the nudged Department of Energy's Energy Exascale Earth System Model version 2 (E3SMv2) with interactive ozone chemistry to demonstrate its validity. The E3SMv2 simulations nudged to reanalysis data produced reasonable wind and ozone patterns, especially in the tropics. Consistent with previous studies, we find clear demarcations with pressure. Ozone perturbations in the upper stratosphere (<6 hPa) are predicted by temperature changes; those between 6 and 20 hPa are predicted by NO y changes, and those in the lower stratosphere show no temperature or NO y response and are presumably driven by circulation changes. These results are important for diagnosing model-to-model discrepancy in QBO–ozone response and enhancing the reliability of ozone projections.

Xie, Jinbo [Lawrence Livermore National Laboratory↗

Dynamic variability of column ozone

A first-order, analytic estimate of the dynamical change in column ozone density is given as a function of temperature change in the lower stratosphere. It is found that, for each 1 percent (about 2 C) cooling averaged over the lower stratosphere, the column ozone density can be expected to decrease by approximately 7 percent, if it can be assumed that such a temperature change is induced by changes in wave transports.

Tung, Ka Kit↗

Ratcheting of climate pledges needed to limit peak global warming

We report the new and updated emission reduction pledges submitted by countries ahead of the Twenty-Sixth Conference of Parties represent a meaningful strengthening of global ambition compared to the 2015 Paris pledges. Yet, limiting global warming below 1.5 °C this century will require countries to ratchet ambition for 2030 and beyond. Here, we explore a suite of emissions pathways to show that ratcheting near-term ambition through 2030 will be crucial to limiting peak temperature changes. Delaying ratcheting ambition to beyond 2030 could still deliver end-of-century temperature change of less than 1.5 °C but would result in higher temperature overshoot over many decades with the potential for adverse consequences. Ratcheting near-term ambition would also deliver benefits from enhanced non-CO2 mitigation and facilitate faster transitions to net-zero emissions systems in major economies.

54 ENVIRONMENTAL SCIENCES↗

Mesospheric temperature and circulation response to the Hunga Tonga-Hunga-Ha'apai volcanic eruption

The Hunga Tonga Hunga-Ha'apai (HTHH) volcanic eruption on 15 January 2022 injected water vapor and SO 2 into the stratosphere. Several months after the eruption, significantly stronger westerlies, and a weaker Brewer-Dobson circulation developed in the stratosphere of the Southern Hemisphere and were accompanied by unprecedented temperature anomalies in the stratosphere and mesosphere. In August 2022, the Sounding of the Atmosphere using Broadband Emission Radiometry (SABER) satellite instrument observed record-breaking temperature anomalies in the stratosphere and mesosphere that alternate signs with altitude. Ensemble simulations carried out with the Whole Atmosphere Community Climate Model (WACCM6) indicate that the strengthening of the stratospheric westerlies explains the mesospheric temperature changes. The stronger westerlies cause stronger westward gravity wave drag in the mesosphere. Although the enhanced gravity wave drag is partly balanced by a weakening of planetary wave forcing, the net result is an acceleration of the mesospheric mean meridional circulation. The stronger mesospheric circulation, in turn, plays a dominant role in driving the changes in mesospheric temperatures. This study highlights the impact of large volcanic eruptions on middle atmospheric dynamics and provides insight into their long-term effects in the mesosphere. On the other hand, we could not discern a clear mechanism for the observed changes in stratospheric circulation. In fact, an examination of the WACCM ensemble reveals that not every member reproduces the large changes observed by SABER. We conclude that there is a stochastic component to the stratospheric response to the HTHH eruption.

58 GEOSCIENCES↗

Directional Cooling-Induced Fracturing Westerly Granite Test Results

Directional Cooling-Induced Fracturing (DCIF) experiments were conducted on a short, cylindrical sample of Westerly granite (diameter = 4 inches, height ~ 2 inches). Liquid nitrogen was poured in a copper cup attached to the top of the sample, and the resulting acoustic emissions (AEs) and temperature changes on the surface of the sample were monitored. The obtained AEs were used to determine the microcracking source locations and amplitude, and the associated moment tensors. Included in this submission is an animation of the AEs, a graphic displaying the temperature changes, and the measured data.

15 GEOTHERMAL ENERGY↗

Solar Forcing of Regional Climate Change During the Maunder Minimum

We examine the climate response to solar irradiance changes between the late 17th century Maunder Minimum and the late 18th century. Global average temperature changes are small (about 0.3 to 0.4 C) in both a climate model and empirical reconstructions. However, regional temperature changes are quite large. In the model, these occur primarily through a forced shift toward the low index state of the Arctic Oscillation/North Atlantic Oscillation. This leads to colder temperatures over the Northern Hemisphere continents, especially in winter (1 to 2 C), in agreement with historical records and proxy data for surface temperatures.

Shindell, Drew T.↗

Toward efficient elastocaloric systems: Predicting material thermal properties with high fidelity

A critical need to accurately model thermal behaviors of materials that exhibit strong elastocaloric effects, including predicting the effects themselves at varying stresses and temperatures, has been addressed using a simple and versatile physics-based approach. The key factor leading to the high precision is approximating the underlying elastic phase transition as a smooth modification of lattice entropy between coexisting phases. Once the phase transformation entropy is modeled to match experimentally measured strain as a function of temperature and applied stress, estimating the heat capacity, entropy, and isothermal entropy and adiabatic temperature changes in temperature-stress coordinates becomes straightforward. This approach provides insight into how thermal properties of elastocaloric materials vary through the transition based on strain measurements that are simple to perform and interpret. In addition to aiding in the rapid evaluation of new and existing elastocaloric materials, this advance is expected to prove invaluable for accurate heat transfer modeling aimed at designing efficient regenerative elastocaloric cooling devices.

36 MATERIALS SCIENCE↗

Disruption of acyl-acyl carrier protein (acyl-ACP) synthetase in cyanobacteria impairs lipid remodeling as revealed by acyl-ACP measurements

Free fatty acid (FFA) production in bacteria is a key target for metabolic engineering. The knockout of the acyl-ACP synthetase (AAS) prevents reincorporation of FFA into the fatty acid biosynthetic cycle and is widely used to enhance their secretion. However, the role of AAS in membrane lipid remodeling under environmental stress, such as altered temperature, remains poorly understood. In cyanobacteria, temperature shifts are known to affect fatty acid desaturation and membrane fluidity, yet it is unclear whether AAS contributes to these adaptive responses through re-esterification of membrane-released acyl chains. We elucidated unique aspects of fatty acid metabolism in response to temperature changes in biotechnologically relevant microbes with the development of an efficient method for quantifying acyl-ACP intermediates using anion exchange chromatography (AEX). In Escherichia coli, which performs desaturation during fatty acid biosynthesis, we detected saturated and unsaturated acyl-ACPs that confirm biosynthetic pathway operation. In the cyanobacteria, Picosynechococcus sp. PCC 7002 and the Δaas strain, changes between two temperatures were interpreted with support from proteomic and lipidomic analyses and indicated that the AAS is tied to membrane lipid remodeling. Further, polyunsaturated acyl-ACPs were detected in the Δaas strain, which was unexpected because fatty acid synthesis does not produce polyunsaturates in cyanobacteria, suggesting the presence of alternative acyl-activating enzymes or unknown acyl-ACP desaturases. This study highlights the possible link between acyl chain recycling and lipid remodeling in cyanobacteria and demonstrates the utility of AEX-based acyl-ACP profiling in dissecting fatty acid metabolism.

59 BASIC BIOLOGICAL SCIENCES↗

Elastocaloric effect in vanadium (IV) oxide

Elastocaloric cooling utilizes the latent heat associated with stress-induced reversible phase transformations to achieve cooling. Currently, the key barrier to this technology is its prohibitive cost due to the high elastocaloric material cost and the large stress required to drive the cooling cycle. Vanadium (IV) oxide (VO 2 ) is a good candidate, and it is relatively cheap. Our calorimetry study shows it exhibits a reversible phase transformation with a large latent heat of 31.5 J/g, as well as excellent functional stability. Its transformation temperature and latent heat are tunable via heat treatment. We demonstrated that VO 2 powders can be cyclically compressed in a steel tube using a steel plunger to drive the elastocaloric effect. The application of relatively low stress of 300 MPa is sufficient to result in a reversible temperature change of 0.5 °C on the powder compact. Further improvement of reversible temperature change to 1.6 °C under 300MPa is achieved by adding conductive copper powders. Future efforts should focus on improving material properties such as heat capacity and thermal conductivity for candidate ceramic oxides to maximize elastocaloric effects.

36 MATERIALS SCIENCE↗

Consideration of materials for aircraft brakes

A study has been made of the frictional behavior of several aircraft brake materials using a simple high-temperature Falex-type apparatus. Tests were run at velocities of seven ft/minute; loads to 600 pounds and temperatures to 700 C. The data for these brake materials sliding against a variety of steels and other materials indicate a large reduction in friction due to surface oxidation in the temperature range 250 to 300 C. It also was found that the retention of this oxide was a function of the temperature changes. With increasing temperature the oxide was removed, while with reducing temperature it was retained. Frictional behavior was more characteristic of the steel than the brake material.

Peterson, M. B.↗

Compartmentalization in proteinoid microspheres

Proteinoid microspheres with stable internal compartments and internal structure are made from acidic proteinoid and basic proteinoid with calcium. The populations of microspheres are characterized by a wide diversity of structure. A model of primitive intracellular communication is suggested by the observed movement of internal particles between compartments of a multicompartmentalized unit. Differential response to pH change and to temperature change has been demonstrated within one population and suggests one mode of adaptive selection among primordial cell populations.

Brooke, S.↗

Transverse shear stresses and their sensitivity coefficients in multilayered composite panels

A computational procedure is presented for the accurate determination of transverse shear stresses and their sensitivity coefficients in flat multilayered composite panels subjected to mechanical and thermal loads. The sensitivity coefficients measure the sensitivity of the transverse shear stresses to variations in the different lamination and material parameters of the panel. The panel is discretized by using either a three-field mixed finite element model based on a two-dimensional first- order shear deformation plate theory or a two-field degenerate solid element with each of the displacement components having a linear variation throughout the thickness of the laminate. The evaluation of transverse shear stresses can be conveniently divided into two phases. The first phase consists of using a superconvergent recovery technique for evaluating the in-plane stresses in the different layers. In the second phase, the transverse shear stresses are evaluated by using piecewise integration, in the thickness direction, of the three-dimensional equilibrium equations. The same procedure is used for evaluating the sensitivity coefficients of the transverse shear stresses. The effectiveness of the computational procedure is demonstrated by means of numerical examples of multilayered cross-ply panels subjected to transverse loading, uniform temperature change, and uniform temperature gradient through the thickness of the panel. In each case the standard of the comparison is taken to be the exact solution of the three dimensional thermoelasticity equations of the panel.

Noor, Ahmed K.↗

Material Outgassing, Identification and Deposition, MOLIDEP System

The outgassing tests are performed employing a modified vacuum operated Cahn analytical microbalance, identified as the MOLIDEP system. The test measures under high vacuum, the time varying Molecular mass loss of a material sample held at a chosen temperature; it Identifies the outgassing molecular components using an inline SRS 300 amu Residual Gas Analyzer (RGA) and employs a temperature controlled 10 MHz Quartz Crystal Microbalance (QCM) to measure the condensable DEPosits. Both the QCM and the RGA intercept within the conductive passage the outgassing products being evacuated by a turbomolecular pump. The continuous measurements of the mass loss, the rate of loss, the sample temperature, the rate of temperature change, the QCM temperature and the QCM recorded condensable deposits or rate of deposits are saved to an Excel spreadsheet. A separate computer controls the RGA.

Scialdone, John J.↗