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At least 163 records · Page 9

Covariant C and O Isotope Trends in Arctic Carbonate Crusts and ALH 84001: Potential Biomarker or Indicator of Cryogenic Formation Environment?

This work seeks to use the chemical, isotopic, and mineralogical characteristics of secondary carbonate minerals produced during brief aqueous events to identify the conditions of the aqueous environment in which they formed. Liquid water near the surface of Mars is subject to either rapid freezing and/or evaporation. These processes are also active on Earth, and produce secondary minerals that have complex chemical, mineralogical, and isotopic textures and compositions that can include covariant relationships between Delta C-13 (sub VPDB) and delta O-18 (sub VSMOW). The extremely well studied four billion year old carbonates preserved in martian meteorite ALH 84001 also show covariant delta C-13 and delta O-18 compositions, but these variations are manifested on a micro-scale in a single thin section while the variation observed so far in terrestrial carbonates is seen between different hand samples.

Socki, Richard A.↗

Laser Heterodyne Radiometer for Sensitive Detection of CO2 and CH4

We propose to develop an inexpensive, miniaturized, passive laser heterodyne radiometer (LHR) using commercially available telecommunications laser components to measure two significant carbon cycle gases in the atmospheric column: carbon dioxide (CO2) and methane (CH4). This instrument would operate in tandem with the passive aerosol sensor currently used in AERONET (an established network of more than 450 ground aerosol monitoring instruments worldwide). Because aerosols induce a radiative effect that influences terrestrial carbon exchange, simultaneous detection of aerosols with these key carbon cycle gases offers a uniquely comprehensive measurement approach that supports the Decadal Survey. Laser heterodyne radiometry is a technique for detecting weak signals that was adapted from radio receiver technology. In a radio receiver, a weak input signal from a radio antenna is mixed with a stronger local oscillator signal. The mixed signal (beat note, or intermediate frequency) has a frequency equal to the difference between the input signal and the local oscillator. The intermediate frequency is amplified and sent to a detector that extracts the audio from the signal. In a laser heterodyne radiometer, the weak input signal is light that has undergone absorption by a trace gas. The local oscillator is a laser at a near-by frequency - in this case a low-cost distributed feedback (DFB) telecommunications laser. These two light waves are superimposed in either a beamsplitter or in a fiber coupler (as is the case in this design). The signals are mixed in the detector, and the RF beat frequency is extracted. Changes in concentration of the trace gas are realized through analyzing changes in the beat frequency amplitude. A schematic of the progression of the LHR development project is shown in the figure below. At the center (within the dashed line), light from the local oscillator is superimposed upon light that has undergone absorption by a trace gas, in a single mode fiber coupler. Superimposed light is mixed in a fast photoreceiver, and the beat signal is analyzed for changes in absorption. The left portion of the figure depicts a progression of light sources that pass through the trace gas, increasing in complexity in the downward direction. On the right side of the figure, RF signal processing progresses from a commercially available spectrum analyzer to a RF receiver, and finally to an RF filter bank to deconvolute portions of the beat frequency more heavily weighted for different altitudes.

Wilson, Emily L.↗

Global distribution, formation and fate of mineral‐associated soil organic matter under a changing climate: A trait‐based perspective

Abstract Soil organic matter (SOM) is the largest actively cycling reservoir of terrestrial carbon (C), and the majority of SOM in Earth's mineral soils (~65%) is mineral‐associated organic matter (MAOM). Thus, the formation and fate of MAOM can exert substantial influence on the global C cycle. To predict future changes to Earth's climate, it is critical to mechanistically understand the processes by which MAOM is formed and decomposed, and to accurately represent this process‐based understanding in biogeochemical and Earth system models. In this review, we use a trait‐based framework to synthesize the interacting roles of plants, soil micro‐organisms, and the mineral matrix in regulating MAOM formation and decomposition. Our proposed framework differentiates between plant and microbial traits that influence total OM inputs to the soil (‘feedstock traits’) versus traits that influence the proportion of OM inputs that are ultimately incorporated into MAOM (‘MAOM formation traits’). We discuss how these feedstock and MAOM formation traits may be altered by warming, altered precipitation and elevated carbon dioxide. At a planetary scale, these feedstock and MAOM formation traits help shape the distribution of MAOM across Earth's biomes, and modulate biome‐specific responses of MAOM to climate change. We leverage a global synthesis of MAOM measurements to provide estimates of the total amount of MAOM‐C globally (~840–1540 Pg C; 34%–51% of total terrestrial organic C), and its distribution across Earth's biomes. We show that MAOM‐C concentration is highest in temperate forests and grasslands, and lowest in shrublands and savannas. Grasslands and croplands have the highest proportion of soil organic carbon (SOC) in the MAOM fraction (i.e. the MAOM‐C:SOC ratio), while boreal forests and tundra have the lowest MAOM‐C:SOC ratio. Drawing on our trait framework, we then review experimental data and posit the effects of climate change on MAOM pools in different biomes. We conclude by discussing how MAOM is integrated into soil C models, and how feedstock and MAOM formation traits may be included in these models. We also summarize the projected fate of MAOM under climate change scenarios (Representative Concentration Pathways 4.5 and 8.5) and discuss key model uncertainties. Read the free Plain Language Summary for this article on the Journal blog.

54 ENVIRONMENTAL SCIENCES↗

Biologically mediated isotope fractionations - Biochemistry, geochemical significance and preservation in the earth's oldest sediments

Preferential metabolization of isotopically light carbon and sulfur has resulted in a fractionation of the stable isotopes of these elements on a global scale, with the light species (C-12, S-32) markedly concentrated in biogenic materials. Since the biological effects are basically retained when carbon and sulfur are incorporated in sediments, the respective fractionations are propagated into the rock section of the geochemical cycle, this having consequently caused a characteristic bipartition of both elements between 'light' and 'heavy' crustal reservoirs. Preservation of the biological isotope effects in sedimentary rocks makes it possible to trace the underlying biochemical processes back over most of the geological record. According to the available evidence, biological (autotrophic) carbon fixation arose prior to 3.5(if not 3.8) billion years ago, while the emergence of dissimilatory sulfate reduction antedates the appearance of the oldest presumably bacteriogenic sulfur isotope patterns in rocks between 2.7 and 2.8 billion years old. Hence, biological control of the terrestrial carbon and sulfur cycles has been established very early in the earth's history.

Schidlowski, M.↗

Diffuse Radiation Forcing Constraints on Gross Primary Productivity and Global Terrestrial Evapotranspiration

Abstract The diffuse radiation fertilization effect—the increase in plant productivity in the presence of higher diffuse radiation ( K ↓,d )—is an important yet understudied aspect of atmosphere‐biosphere interactions and can modify the terrestrial carbon, energy, and water budgets. The K ↓,d fertilization effect links the carbon cycle with clouds and aerosols, all of which are large sources of uncertainties for our current understanding of the Earth system and for future climate projections. Here we establish to what extent observational and modeling uncertainty in sunlight's diffuse fraction ( k d ) affects simulated gross primary productivity (GPP) and terrestrial evapotranspiration ( λE ). We find only 48 eddy covariance sites with simultaneous sufficient measurements of K ↓,d with none in the tropical climate zone, making it difficult to constrain this mechanism globally using observations. Using a land modeling framework based on the latest version of the Community Land Model, we find that global GPP ranges from 114 Pg C year −1 when using k d forcing from the Modern‐Era Retrospective analysis for Research and Applications, version 2 reanalysis to a ∼7% higher value of 122 Pg C year −1 when using the Clouds and the Earth's Radiant Energy System satellite product, with especially strong differences apparent over the tropical region (mean increase ∼9%). The differences in λE , although smaller (−0.4%) due to competing changes in shaded and sunlit leaf transpiration, can be greater than regional impacts of individual forcing agents like aerosols. Our results demonstrate the importance of comprehensively and systematically validating the simulated k d by atmosphere modules as well as the response to differences in k d within land modules across Earth System Models.

54 ENVIRONMENTAL SCIENCES↗

The potential land requirements and related land use change emissions of solar energy

Although the transition to renewable energies will intensify the global competition for land, the potential impacts driven by solar energy remain unexplored. In this work, the potential solar land requirements and related land use change emissions are computed for the EU, India, Japan and South Korea. A novel method is developed within an integrated assessment model which links socioeconomic, energy, land and climate systems. At 25–80% penetration in the electricity mix of those regions by 2050, we find that solar energy may occupy 0.5–5% of total land. The resulting land cover changes, including indirect effects, will likely cause a net release of carbon ranging from 0 to 50 gCO 2 /kWh, depending on the region, scale of expansion, solar technology efficiency and land management practices in solar parks. Hence, a coordinated planning and regulation of new solar energy infrastructures should be enforced to avoid a significant increase in their life cycle emissions through terrestrial carbon losses.

14 SOLAR ENERGY↗

Miniaturized Laser Heterodyne Radiometer (LHR) for Measurements of Greenhouse Gases in the Atmospheric Column

This passive laser heterodyne radiometer (LHR) instrument simultaneously measures multiple trace gases in the atmospheric column including carbon dioxide (CO2) and methane (CH4), and resolves their concentrations at different altitudes. This instrument has been designed to operate in tandem with the passive aerosol sensor currently used in AERONET (an established network of more than 450 ground aerosol monitoring instruments worldwide). Because aerosols induce a radiative effect that influences terrestrial carbon exchange, simultaneous detection of aerosols with these key carbon cycle gases offers a uniquely comprehensive measurement approach. Laser heterodyne radiometry is a technique for detecting weak signals that was adapted from radio receiver technology. In a radio receiver, a weak input signal from a radio antenna is mixed with a stronger local oscillator signal. The mixed signal (beat note, or intermediate frequency) has a frequency equal to the difference between the input signal and the local oscillator. The intermediate frequency is amplified and sent to a detector that extracts the audio from the signal. In the LHR instrument described here, sunlight that has undergone absorption by the trace gas is mixed with laser light at a frequency matched to a trace gas absorption feature in the infrared (IR). Mixing results in a beat signal in the RF (radio frequency) region that can be related to the atmospheric concentration. For a one-second integration, the estimated column sensitivities are 0.1 ppmv for CO2, and <1 ppbv for CH4. In addition to producing a standalone ground measurement product, this instrument could be used to calibrate/validate four Earth observing missions: ASCENDS (Active Sensing of CO2 Emissions over Nights, Days, and Seasons), OCO-2 (Orbiting Carbon Observatory), OCO-3, and GOSAT (Greenhouse gases Observational SATellite). The only network that currently measures CO2 and CH4 in the atmospheric column is TCCON (Total Carbon Column Observing Network), and only two of its 16 operational sites are in the United States. TCCON data is used for validation of GOSAT data, and will be used for OCO-2 validation. While these Fourier-transform spectrometers (FTS) can measure the largest range of trace gases, the network is severely limited due to the high cost and extreme size of these instruments (these occupy small buildings and require personnel for operation). The LHR/AERONET instrument offers a significantly smaller (carry-on luggage size) autonomous instrument that can be incorporated into AERONET s much larger (450 instruments) global network.

Steel, Emily↗

Low-Cost Miniaturized Laser Heterodyne Radiometer for Highly Sensitive Detection of CO2 and CH4 in the Atmospheric Column

We present a new passive ground-network instrument capable of measuring carbon dioxide (CO2) at 1.57 microns and methane (CH4) at 1.62 microns -- key for validation of OCO-2, ASCENDS, OCO-3, and GOSAT. Designed to piggy-back on an AERONET sun tracker (AERONET is a global network of more than 450 aerosol sensing instruments), this instrument could be rapidly deployed into the established AERONET network of ground sensors. Because aerosols induce a radiative effect that influences terrestrial carbon exchange, this simultaneous measure of aerosols and carbon cycle gases offers a uniquely comprehensive approach. This instrument is a variation of a laser heterodyne radiometer (LHR) that leverages recent advances in telecommunications lasers to miniaturize the instrument (the current version fits in a carry-on suitcase). In this technique, sunlight that has undergone absorption by the trace gas is mixed with laser light at a frequency matched to a trace gas absorption feature in the infrared (IR). Mixing results in a beat signal in the RF (radio frequency) region that can be related to the atmospheric concentration. By dividing this RF signal into a filter bank, concentrations at different altitudes can be resolved. For a one second integration, we estimate column sensitivities of 0.1 ppmv for CO2, and <1 ppbv for CH4.

Wilson, Emily L.↗

Carbon-14 activities in recently fallen meteorites and Antarctic meteorites

This paper reports C-14 measurements in meteorites using an extraction method which employs RF melting of samples as small as 0.1 g. A study of extraction of cosmic-ray-produced C-14 in samples of Bruderheim gave C-14 levels between 38 and 60 dpm/kg for samples which had been preheated in air between 250 and 700 C, with a mean value of 46.8 + or - 1.4 dpm/kg. A range of values between 35 and 59 dpm/kg was found for other falls of saturated meteorites preheated to 500 C. The preheating step is shown to be effective in removing terrestrial carbon contamination. A series of samples previously dated by Kr-81 as having ages of 120-310 kyr gave C-14 levels of between less than 0.16 and 0.37 + or - 0.10 dpm/kg. These levels are consistent with levels of in situ production by cosmic rays at the earth's surface.

Jull, A. J. T.↗

Seasonal stabilization effects slowed the greening of the Northern Hemisphere over the last two decades

Rising atmospheric CO₂ and warming spring temperatures increase vegetation growth and the terrestrial carbon sink. However, drought, heat stress, phenology, and resource limitations may stabilize or limit theses projected increases. We investigate the balance between these amplifying and stabilizing ecological factors by asking whether enhanced early-season growth leads to continued late-season growth. Using the Moderate Resolution Imaging Spectroradiometer (MODIS) leaf area index (LAI) dataset, we identify three seasonal growth patterns based on early- and peak-season positive LAI anomalies: (1) amplification, where late-season LAI anomalies exceed earlier ones; (2) weak stabilization, where late-season anomalies remain similar or slightly lower; and (3) strong stabilization, where late-season anomalies become negative. Weak and strong stabilization events dominate across 67% and 26% of Northern Hemisphere ecosystems above 30°N, respectively. The absence of any trend in amplifying or stabilizing events suggests stabilizing factors seasonally offset CO₂ and temperature-induced spring greening. Terrestrial biosphere models underestimate strong stabilization and overestimate amplification events. This inconsistency arises from the models’ underestimation late-season LAI sensitivity to precipitation in water-limited regions; overlook negative legacy effects of early enhanced LAI on late-season soil moisture via evapotranspiration losses in energy-limited regions. Our findings suggest water/heat stress and resource limitations limit greening and the land carbon sink.

Zhang, Wen↗

A survey of carbon monoxide emission in dark clouds

Results are reported of a CO and (C-13)O survey of 68 dark clouds from the Lynds catalog. CO was detected in 63 of the 64 sources in which it was searched for, and the (C-13)O line was seen in 52 of 55 clouds. There is a rather narrow distribution of CO peak line radiation temperatures about a mean of 6 K; this may reflect the presence of a roughly uniform kinetic temperature of 9.5 K in the sources. Despite the probably subthermal excitation temperature of the (C-13)O transition observed, derived (C-13)O column densities are most likely good to within a factor of 2. Typical CO column densities for the clouds surveyed are 5 x 10 to the 17-th power per sq cm, assuming a terrestrial carbon isotope ratio. All 68 clouds have previously been studied by Dieter in 6-cm H2CO absorption; a comparison of line widths shows the (C-13)O lines to generally be wider than their formaldehyde counterparts. Possible explanations of this fact in terms of internal cloud motions are discussed.

Dickman, R. L.↗

Warming Response of Deep Soil Carbon (LDRD Final Report)

The overarching objective of this LDRD project was to determine the vulnerability of deep soil organic carbon (SOC) to warming in the Sierra Nevada region. Deep soils (>30 cm) store more than 70% of global SOC, and increased SOC decomposition and CO 2 emissions caused by warming are potentially large climate change feedbacks. According to the Intergovernmental Panel on Climate Change, temperatures are expected to increase by 4°C by the year 2100, warming the land and underlying soil, and making understanding of how warming will influence deep SOC storage and persistence critical to projecting the land carbon sink. However, uncertainty remains in our process-level understanding and ability to quantify how projected warming will impact the stability of carbon in deep soils. We investigated warming effects on deep (up to 16 m) SOC stability across climate, vegetation, and soil mineralogy gradients in California. We sampled soils from the surface to bedrock (down to 16 meters) at four sites representing vastly different ecosystems across the Northern and Southern Sierra Nevada mountains. This study quantified the response of SOC concentration, distribution, and vulnerability to warming using a soil incubation experiment to warm the whole soil profile and radiocarbon and stable isotopes to assess which pools are vulnerable to loss under warming. Our results refine our understanding of the terrestrial carbon cycle by revealing the vulnerability of deep SOC to future changes in climate and how minerology may influence that vulnerability.

58 GEOSCIENCES↗

Differential Radiometers Using Fabry-Perot Interferometric Technique for Remote Sensing Determination of Various Atmospheric Trace Gases

New type of remote sensing instrument based upon the Fabry-Perot inte rferometric technique has been developed at NASA's Goddard Space Flight Center. Fabry-Perot interferometry (FPI) is a well known, powerful spectroscopic technique and one of its many applications is to be use d to measure greenhouse gases and also some harmful species in the at mosphere. With this technique, absorption of particular species is me asured and related to its concentration. A solid Fabry-Perot etalon is used as a frequency filter to restrict the measurement to particular absorption bands of the gas of interest. With adjusting the thicknes s of the etalon that separation (in frequency) of the transmitted fri nges can be made equal to the almost constant separation of the gas a bsorption lines. By adjusting the temperature of the etalon, which changes the index of refi-action of its material, the transmission fring es can be brought into nearly exact correspondence with absorption li nes of the particular species. With this alignment between absorption lines and fringes, changes in the amount of a species in the atmosph ere strongly affect the amount of light transmitted by the etalon and can be related to gas concentration. The instrument that we have dev eloped detects the absorption of various atmospheric trace gases in d irect or reflected sunlight. Our instrument employing Fabry-Perot interferometer makes use of two features to achieve high sensitivity. The first is high spectral resolution enabling one to match the width of an atmospheric absorption feature by the instrumental band pass. The second is high optical throughput enabled by using multiple spectral lines simultaneously. For any species that one wishes to measure, thi s first feature is available while the use of multiple spectral features can be employed only for species with suitable spectra and freedom from interfering species in the same wavelength region. We have deve loped an instrument for use as ground based, airborne and satellite s ensor for gases such as carbon dioxide (1570 nm), oxygen (762 nm and 768 nm lines sensitive to changes in oxygen pressure and oxygen temper ature) and water vapor (940 nm). Our current goal is to develop an ul tra precise, inexpensive, ground based device suitable for wide deplo yment as a validation instrument for the Orbiting Carbon Observatory (OCO) satellite. We show sensitivity measurements for CO2, 02, and H2 O, compare our measurements to those obtained using other types of sensors and discuss some of the peculiarities that must be addressed in order to provide the very high quality column detection required for solving problems about global distribution of greenhouse gases and cl imatological models. In another area of research we are interested in developing a small-size channel for CO2 capable of doing simultaneous measurements with the AERONET (Aerosol Robotic Network) at NASA, God dard to study the hypothesis that atmospheric aerosols affect the reg ional terrestrial carbon cycle. We present recent data from our groun d based measurements of O2, CO2, H2O and (13)CO2 and discuss extensio n of the technique to new species and applications.

Georgieva, E. M.↗

A general framework for nitrogen deposition effects on soil respiration in global forests

Since the Industrial Revolution, human activities have altered atmospheric nitrogen (N) deposition to global forests, affecting carbon dioxide emissions from soils (soil respiration or SR) – one of the largest land-atmosphere carbon fluxes. However, experimental studies have demonstrated both positive and negative effects of N deposition on SR in global forests, leading to debates on how N deposition increases or decreases SR. We developed a framework for generalizing SR responses to N deposition using synthesized data from 168 N addition experiments worldwide and observed SR across the global natural N deposition gradient. The findings indicate that N deposition decreased SR in 2.9% of global forested areas, particularly in eastern China, western Europe, and the eastern USA. However, the net effect of N deposition increased the global forest SR by ~5% (1.7 ± 0.1 PgC yr –1 ). If N pollution could be effectively controlled, global forest SR would decrease, potentially contributing to a reduction in the terrestrial carbon emissions.

Cen, Xiaoyu [National Forestry and Grassland Admin↗

Origin of Chlorobenzene Detected by the Curiosity Rover in Yellowknife Bay: Evidence for Martian Organics in the Sheepbed Mudstone?

The Sample Analysis at Mars (SAM) instrument on the Curiosity rover is designed to determine the inventory of organic and inorganic volatiles thermally evolved from solid samples using a combination of evolved gas analysis (EGA), gas chromatography mass spectrometry (GCMS), and tunable laser spectroscopy. The first solid samples analyzed by SAM, a scoop of windblown dust and sand at Rocknest (RN), revealed chlorinated hydrocarbons derived primarily from reactions between a martian oxychlorine phase (e.g. perchlorate) and terrestrial carbon from N-methyl-N-(tert-butyldimethylsilyl)-trifluoroacetamide (MTBSTFA) vapor present in the SAM instrument background. Chlorobenzene (CBZ) was also identified by SAM GCMS at RN at trace levels (approx.0.007 nmol) and was attributed to the reaction of chlorine with the Tenax polymers used in the hydrocarbon traps. After the RN analyses, Curiosity traveled to Yellowknife Bay and drilled two separate holes designated John Klein (JK) and Cumberland (CB). Analyses of JK and CB by both SAM and the CheMin x-ray diffraction instrument revealed a mudstone consisting of approx.20 wt% smectite clays, which on Earth are known to aid the concentration and preservation of organic matter. In addition, higher abundances and a more diverse suite of chlorinated hydrocarbons in CB compared to RN suggests that martian or meteoritic organic sources may be preserved in the mudstone. Here we discuss the SAM EGA and GCMS measurements of volatiles released from the Sheepbed mudstone. We focus primarily on the elevated CBZ detections at CB and laboratory analog experiments conducted to help determine if CBZ is derived from primarily terrestrial, martian, or a combination of sources.

origin of↗

Calculating Soil Wetness, Evapotranspiration and Carbon Cycle Processes Over Large Grid Areas Using a New Scaling Technique

Soil wetness typically shows great spatial variability over the length scales of general circulation model (GCM) grid areas (approx 100 km ), and the functions relating evapotranspiration and photosynthetic rate to local-scale (approx 1 m) soil wetness are highly non-linear. Soil respiration is also highly dependent on very small-scale variations in soil wetness. We therefore expect significant inaccuracies whenever we insert a single grid area-average soil wetness value into a function to calculate any of these rates for the grid area. For the particular case of evapotranspiration., this method - use of a grid-averaged soil wetness value - can also provoke severe oscillations in the evapotranspiration rate and soil wetness under some conditions. A method is presented whereby the probability distribution timction(pdf) for soil wetness within a grid area is represented by binning. and numerical integration of the binned pdf is performed to provide a spatially-integrated wetness stress term for the whole grid area, which then permits calculation of grid area fluxes in a single operation. The method is very accurate when 10 or more bins are used, can deal realistically with spatially variable precipitation, conserves moisture exactly and allows for precise modification of the soil wetness pdf after every time step. The method could also be applied to other ecological problems where small-scale processes must be area-integrated, or upscaled, to estimate fluxes over large areas, for example in treatments of the terrestrial carbon budget or trace gas generation.

Sellers, Piers↗

Does Terrestrial Drought Explain Global CO2 Flux Anomalies Induced by El Nino?

The El Nino Southern Oscillation is the dominant year-to-year mode of global climate variability. El Nino effects on terrestrial carbon cycling are mediated by associated climate anomalies, primarily drought, influencing fire emissions and biotic net ecosystem exchange (NEE). Here we evaluate whether El Nino produces a consistent response from the global carbon cycle. We apply a novel bottom-up approach to estimating global NEE anomalies based on FLUXNET data using land cover maps and weather reanalysis. We analyze 13 years (1997-2009) of globally gridded observational NEE anomalies derived from eddy covariance flux data, remotely-sensed fire emissions at the monthly time step, and NEE estimated from an atmospheric transport inversion. We evaluate the overall consistency of biospheric response to El Nino and, more generally, the link between global CO2 flux anomalies and El Nino-induced drought. Our findings, which are robust relative to uncertainty in both methods and time-lags in response, indicate that each event has a different spatial signature with only limited spatial coherence in Amazonia, Australia and southern Africa. For most regions, the sign of response changed across El Nino events. Biotic NEE anomalies, across 5 El Nino events, ranged from -1.34 to +0.98 Pg Cyr(exp -1, whereas fire emissions anomalies were generally smaller in magnitude (ranging from -0.49 to +0.53 Pg C yr(exp -1). Overall drought does not appear to impose consistent terrestrial CO2 flux anomalies during El Ninos, finding large variation in globally integrated responses from 11.15 to +0.49 Pg Cyr(exp -1). Despite the significant correlation between the CO2 flux and El Nino indices, we find that El Nino events have, when globally integrated, both enhanced and weakened terrestrial sink strength, with no consistent response across events

Schwalm. C. R.↗