Search NASA⌕ Search

SEARCH · Search NASA

Results for “thermochemical”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
NASA NTRS1974

Oxidative vaporization kinetics of chromium (III) oxide in oxygen from 1270 to 1570 K

Rates of oxidative vaporization of Cr2O3 on preoxidized resistively heated chromium were determined in flowing oxygen at 0.115 torr for temperatures from 1270 to 1570 K. Reaction controlled rates were obtained from experimental rates by a gold calibration technique. These rates were shown to agree with those predicted by thermochemical analysis. The activation energy obtained for the oxidative vaporation reaction corresponded numerically with the thermochemical enthalpy of the reaction. A theoretical equation is given for calculating the rate from thermodynamic data by using boundary layer theory.

Stearns, C. A.↗
NASA NTRS1973

Magnetic hysteresis in natural materials

Magnetic hysteresis loops and the derived hysteresis ratios R sub H and R sub I are used to classify the various natural dilute magnetic materials. R sub I is the ratio of saturation isothermal remanence (I sub R) to saturation (I sub S) magnetization, and R sub H is the ratio of remanent coercive force (H sub R) to coercive force (H sub C). The R sub H and R sub I values depend on grain size, the characteristics of separate size modes in mixtures of grains of high and low coercivity, and the packing characteristics. Both R sub H and R sub I are affected by thermochemical alterations of the ferromagnetic fraction. Hysteresis loop constriction is observed in lunar samples, chondrite meteorites, and thermochemically altered basaltic rocks, and is due to mixtures of components of high and low coercivity. Discrete ranges of R sub H and R sub I for terrestrial and lunar samples and for chondrite meteorites provide for a classification of these natural materials based on their hysteresis properties.

Wasilewski, P. J.↗
NASA NTRS1974

Computational procedure for evaluation of space shuttle TPS requirements

The rudiments of a computational procedure are presented for predicting heat transfer rates to the windward pitchplane of a shuttle vehicle under conditions of nonequilibrium flow. The procedure involves computations in three regions of the flow field, namely, the stagnation region, inviscid flow region, and boundary layer region. The thermochemical state in the inviscid flow was calculated with the aid of correlations developed from shadowgraphs of shuttle configurations. The flow in the boundary layer and stagnation regions was computed with a nonequilibrium viscous layer code. For boundary layers, the outer edge thermochemical state was determined by matching the mass flow in the boundary layer with the mass flow represented by each inviscid streamline. Typical solutions are presented to show the effects of surface pressure, catalycity, and homogeneous chemical reactions on flow field variables and surface heat transfer rates.

Tong, H.↗
NASA NTRS1974

Oxidative vaporization kinetics of Cr2O3 in oxygen from 1000 to 1300 C

Rates of oxidative vaporization of Cr2O3 on preoxidized resistively heated chromium were determined in flowing oxygen at a pressure of 0.115 Torr for temperatures from 1000 to 1300 C. Reaction controlled rates were obtained from experimental rates by a gold calibration technique, and these rates were shown to agree with those predicted by thermochemical analysis. The activation energy obtained for the oxidative vaporization reaction corresponded numerically with the thermochemical enthalpy of the reaction. A theoretical equation is given for calculating the rate from thermodynamic data using boundary-layer theory.

Stearns, C. A.↗
NASA NTRS1975

The NATA code: Theory and analysis, volume 1

A computer program for calculating quasi-one-dimensional gas flow in axisymmetric and two-dimensional nozzles and rectangular channels is presented. Flow is assumed to start from a state of thermochemical equilibrium at a high temperature in an upstream reservoir. The program provides solutions based on frozen chemistry, chemical equilibrium, and nonequilibrium flow with finite reaction rates. Electronic nonequilibrium effects can be included using a two-temperature model. An approximate laminar boundary layer calculation is given for the shear and heat flux on the nozzle wall. Boundary layer displacement effects on the inviscid flow are considered also. Chemical equilibrium and transport property calculations are provided by subroutines. The code contains precoded thermochemical, chemical kinetic, and transport cross section data for high-temperature air, CO2-N2-Ar mixtures, helium, and argon. It provides calculations of the stagnation conditions on axisymmetric or two-dimensional models, and of the conditions on the flat surface of a blunt wedge. The primary purpose of the code is to describe the flow conditions and test conditions in electric arc heated wind tunnels.

Bade, W. L.↗
NASA NTRS1975

Analytic and experimental evaluation of flowing air test conditions for selected metallics in a shuttle TPS application

A detailed experimental and analytical evaluation was performed to define the response of TD nickel chromium alloy (20 percent chromium) and coated columbium (R512E on CB-752 and VH-109 on WC129Y) to shuttle orbiter reentry heating. Flight conditions important to the response of these thermal protection system (TPS) materials were calculated, and test conditions appropriate to simulation of these flight conditions in flowing air ground test facilities were defined. The response characteristics of these metallics were then evaluated for the flight and representative ground test conditions by analytical techniques employing appropriate thermochemical and thermal response computer codes and by experimental techniques employing an arc heater flowing air test facility and flat face stagnation point and wedge test models. These results were analyzed to define the ground test requirements to obtain valid TPS response characteristics for application to flight. For both material types in the range of conditions appropriate to the shuttle application, the surface thermochemical response resulted in a small rate of change of mass and a negligible energy contribution. The thermal response in terms of surface temperature was controlled by the net heat flux to the surface; this net flux was influenced significantly by the surface catalycity and surface emissivity. The surface catalycity must be accounted for in defining simulation test conditions so that proper heat flux levels to, and therefore surface temperatures of, the test samples are achieved.

Schaefer, J. W.↗
NASA NTRS1975

Hydrogen production from solar energy

Three alternatives for hydrogen production from solar energy have been analyzed on both efficiency and economic grounds. The analysis shows that the alternative using solar energy followed by thermochemical decomposition of water to produce hydrogen is the optimum one. The other schemes considered were the direct conversion of solar energy to electricity by silicon cells and water electrolysis, and the use of solar energy to power a vapor cycle followed by electrical generation and electrolysis. The capital cost of hydrogen via the thermochemical alternative was estimated at $575/kW of hydrogen output or $3.15/million Btu. Although this cost appears high when compared with hydrogen from other primary energy sources or from fossil fuel, environmental and social costs which favor solar energy may prove this scheme feasible in the future.

Eisenstadt, M. M.↗
NASA NTRS1975

An analysis of hydrogen production via closed-cycle schemes

A thermodynamic analysis and state-of-the-art review of three basic schemes for production of hydrogen from water: electrolysis, thermal water-splitting, and multi-step thermochemical closed cycles is presented. Criteria for work-saving thermochemical closed-cycle processes are established, and several schemes are reviewed in light of such criteria. An economic analysis is also presented in the context of energy costs.

Chao, R. E.↗
NASA NTRS1975

Fire dynamics of modern aircraft from a materials point of view

A general approach for selecting polymers to increase fire safety in aircraft is described. It is shown that polymer flammability and thermal protection capability are related to the molecular structure of the polymer and its thermochemical properties. These criteria are used to develop advanced fire-resistant materials which can achieve increased survivability in both post-crash and in-flight fires. The degree of fire hardening of materials depends greatly on the available heat load and fire threat present. It is shown that improvements in fire safety can be achieved by the use of polymers possessing certain basic thermochemical parameters such as high char yield.

Parker, J. A.↗
NASA NTRS1975

Ispra Mark-10 water splitting process

A thermochemical water splitting process, the Ispra Mark-10 chemical reaction cycle, was chosen for examining the possibility of using water to produce hydrogen on a large scale for fuel and major industrial chemical uses. The assumed energy source for the process is an HTGR (helium cooled). A process flow diagram, a material balance, and an energy balance were developed for the thermochemical reaction cycle. Principal reactions which constitute the cycle are included.

Source record↗
NASA NTRS1975

Fire dynamics of modern aircraft from a materials point of view

A general approach for selecting polymers to increase fire safety in aircraft is described. It is shown that polymer flammability and thermal protection capability are related to the molecular structure of the polymer and its thermochemical properties. These criteria are used to develop advanced fire-resistant materials that can achieve increased survivability in both post-crash and in-flight fires. The degree of fire hardening of materials depends greatly on the available heat load and fire threat present. It is shown that improvements in fire safety can be achieved by the use of polymers possessing certain basic thermochemical parameters such as high char yield.

Parker, J. A.↗
NASA NTRS1975

Hydrogen as an energy vector

The feasibility of utilizing hydrogen as an energy vector is considered, with special attention given to means of hydrogen production. The state-of-the-art in thermochemical processes is reviewed, and criteria for the technical and economic feasibility of large-scale thermochemical water splitting processes are presented. The production of hydrogen from coal and from photolysis of water is discussed.

Powers, W. D.↗
NASA NTRS1976

Hydrogen as an energy medium

Coal, though abundant in certain geographical locations of the USA poses environmental problems associated with its mining and combustion. Also, nuclear fission energy appears to have problems regarding safety and radioactive waste disposal that are as yet unresolved. The paper discusses hydrogen use and market projection along with energy sources for hydrogen production. Particular attention is given to hydrogen production technology as related to electrolysis and thermochemical water decomposition. Economics of hydrogen will ultimately be determined by the price and availability of future energy carriers such as electricity and synthetic natural gas. Thermochemical methods of hydrogen production appear to offer promise largely in the efficiency of energy conversion and in capital costs over electrolytic methods.

Cox, K. E.↗
NASA NTRS1976

Nuclear driven water decomposition plant for hydrogen production

The conceptual design of a hydrogen production plant using a very-high-temperature nuclear reactor (VHTR) to energize a hybrid electrolytic-thermochemical system for water decomposition has been prepared. A graphite-moderated helium-cooled VHTR is used to produce 1850 F gas for electric power generation and 1600 F process heat for the water-decomposition process which uses sulfur compounds and promises performance superior to normal water electrolysis or other published thermochemical processes. The combined cycle operates at an overall thermal efficiency in excess of 45%, and the overall economics of hydrogen production by this plant have been evaluated predicated on a consistent set of economic ground rules. The conceptual design and evaluation efforts have indicated that development of this type of nuclear-driven water-decomposition plant will permit large-scale economic generation of hydrogen in the 1990s.

Parker, G. H.↗
NASA NTRS1978

Hydrogen from the solar photolysis of water

Developments related to the study of photosynthesis are examined and aspects of photosensitization by solids are considered. It is pointed out that solids photosensitization for solar photochemical fuel formation is now an extremely active research area as a consequence of the promising results obtained with semiconductor photoelectrodes. The investigation of water decomposition schemes involving heterogeneous reactions is likely to be a productive area. As is the case for photosynthesis, the known examples of water decomposition by solids photosensitization involve charge separation processes immediately following light absorption. Homogeneous photoredox reactions are also discussed, taking into account thermochemical and photochemical cycles leading to the formation of a photooxidized ion, hydrogen quantum yields in the photo-oxidation aqueous ions, and thermochemical and photochemical cycles leading to the formation of a photoreduced ion.

Ryason, P. R.↗
NASA NTRS1979

Effects of Impurities and Processing on Silicon Solar Cells, Phase 3

Results of the 14th quarterly report are presented for a program designed to assess the effects of impurities, thermochemical processes and any impurity process interactions on the performance of terrestrial silicon solar cells. The Phase 3 effort encompasses: (1) potential interactions between impurities and thermochemical processing of silicon; (2) impurity-cell performance relationships in n-base silicon; (3) effect of contaminants introduced during silicon production, refining or crystal growth on cell performance; (4) effects of nonuniform impurity distributions in large area silicon wafers; and (5) a preliminary study of the permanence of impurity effects in silicon solar cells.

Hopkins, R. H.↗
NASA NTRS1980

The SERI solar energy storage program

In support of the DOE thermal and chemical energy storage program, the solar energy storage program (SERI) provides research on advanced technologies, systems analyses, and assessments of thermal energy storage for solar applications in support of the Thermal and Chemical Energy Storage Program of the DOE Division of Energy Storage Systems. Currently, research is in progress on direct contact latent heat storage and thermochemical energy storage and transport. Systems analyses are being performed of thermal energy storage for solar thermal applications, and surveys and assessments are being prepared of thermal energy storage in solar applications. A ranking methodology for comparing thermal storage systems (performance and cost) is presented. Research in latent heat storage and thermochemical storage and transport is reported.

Copeland, R. J.↗
NASA NTRS1982

Spallation of the Galileo probe heat shield

The Galileo probe heat shield will encounter severe radiative and convective heating during entry into Jupiter's atmosphere. The shield is made of two different carbon phenolic composites; one is chopped-molded, and the other is tape-wrapped, both of which tend to spall under intense heating conditions. To characterize this phenomenon, an experimental program, using a gasdynamic laser, was initiated. Tests were performed at a variety of radiation intensities, and both the total and spallation mass-loss rates were measured and correlated with intensity. These correlations were then applied to calculated flight heating conditions for two model atmospheres. Entry of a 310-kg probe into the nominal atmosphere would result in a spallation mass loss of 6.3 kg, or 7.4% of the expected thermochemical mass loss. Similarly, entry of that probe into the cool-dense atmosphere would result in 11.9 kg of spallation, or about 10% of the expected thermochemical mass loss.

Lundell, J. H.↗