Electronically Tunable Mirror with Surface Plasmons
Surface plasmon tunable filter is a new technology under development at the Jet Propulsion Laboratory. This technology can be used to build a tunable mirror.
Surface↗
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Kinetically Tunable, Active Auxetic, and Variable Recruitment Active Textiles from Hierarchical Assemblies
Multifunctional textiles with programmable, multi-axial, distributed, and scalable actuation are highly desirable and presently unrealized. 1D torque-unbalanced active yarns within 2D textile structures are exploited to produce soft and scalable active textiles that exhibit tunable displacements, forces, stiffnesses, and kinematic deformations. Through a textile hierarchy spanning active material composition, yarn construction, textile geometry, and system architecture, these active textiles accomplish kinetic tunability, variable recruitment behaviors, and auxetic effects without mechanical contact, called active auxetic effects. New modes of pre-programmed multi-axial performance are enabled by geometrically manipulating—specifically pre-stressing and constraining—active filaments in torsion and leveraging their structural elastic instability within a textile geometry. The new kinematic motion afforded by torque-unbalanced active yarns enhances the performance of active textiles, which accomplish tensile strokes over 40%, generated blocked forces up to 308 N m−1, and specific work over 0.4. kJ kg−1. Advances in active textiles are demonstrated through multifunctional 3D applications, including a variable constriction pump that exhibits sequential actuation, a wearable that conforms multi-axially around the body, and a soft exoskeleton that performs assistive motions and on-body anchoring simultaneously. By harnessing the capabilities of active materials within a textile hierarchy, advances in the potentiality of multifunctional textiles are presented.
Active auxetic effects↗
Tunable Laser Spectrometers for Planetary Science
Distinguishing planetary formation and evolution pathways and understanding the origins of volatiles on planetary bodies requires determination of relative abundances and isotope ratios in the noble gases, and also of the isotope ratios in C, H, N, O and S at high precisions. Traditional planetary mass spectrometers uniquely provide excellent survey capability including the noble gas relative abundances and their isotope ratios. However, to distinguish planetary evolution models for the outer planets, stable isotope ratios in C and O require precisions of ∼10 or better, readily achievable with a tunable laser spectrometer (TLS). As demonstrated on the Mars Curiosity rover, and as planned for a now-selected NASA Venus mission, tunable laser spectrometers play a unique role synergistic with the capabilities of planetary mass spectrometers. The TLS technique of recording infrared absorption spectra at ultrahigh resolution (resolving power λ/δλ ∼ 5 million) provides unambiguous detection of a wide variety of gases such as H2O, H2O2, H2CO, HOCl, NO, NO2, HNO3, N2O, O3, CO, CO2, NH3, N2H4, PH3, H2S, SO2, OCS, HCl, HF, O2, HCN, and CH4, C2H2, C2H4, C2H6 at parts-per-billion levels. Through line-depth or line-area ratio comparisons of adjacent spectral lines, planetary TLS instruments can achieve isotope ratio measurements in C, H, N, O, and S molecules at precisions of ∼1–2, including for the triple isotope components of O and S. Expected performance of TLS instruments for Venus, Saturn, Enceladus and Uranus will be described as constrained by actual measurements reported at Mars on the Curiosity rover.
Planetary↗
Formation of tunable diamond micro- and nanopillars for field effect enhancement applications
Here, we developed a process for the fabrication of tunable single crystal diamond micro- and nanopillars, with tip widths ranging from 40 to 460 nm, densities ranging from 0.5 to 53.5 pillars/μm 2 , and heights greater than 4.5 μm. A self-assembled Au nanodot ensemble etch mask was formed from an annealed Au thin film. The nanodot diameter and density can be tuned using the initial film thickness. The pillars were etched from the nanodot mask using an RIE O 2 plasma, which has infinite selectivity for the diamond when applied at low RF powers (50 W). Finally, the pillars can be sharpened to ~40 nm tip widths by annealing in air at 650 °C. These pillars can be used for applications such as field effect enhancement of diamond photocathode devices, enhancement of optical emission from N-V centers, and antireflective coatings.
36 MATERIALS SCIENCE↗
Dynamically tunable membrane metasurfaces for infrared spectroscopy and strong light-matter interactions
Mid-infrared spectroscopy enables biochemical sensing by identifying vibrational molecular fingerprints, but it faces limitations in instrumentation portability and analytical sensitivity. Optical metasurfaces with strong mid-infrared photonic resonances provide an attractive solution towards on-chip spectrometry and sensitive molecular detection, yet their static nature hinders their anticipated impact. Here, we introduce and demonstrate dynamically tunable silicon membrane metasurfaces exhibiting high-Q transmissive resonances in the fingerprint region. By harnessing silicon’s thermo-optical properties, we achieve continuous modulation of coupling-induced transparency (CIT) modes that emerge upon the interference of quasi-bound states in the continuum (q-BICs) and surface lattice modes (SLMs). We measure a spectral tuning rate of 0.06 cm −1 K −1 by continuously sweeping the sharp CIT resonances over a 23.5 cm −1 spectral range across a temperature range of 300–700 K. In the current proof‑of‑concept implementation, the dynamic transmission control enables non-contact chemical analysis of polymer films by detecting characteristic absorption bands of polystyrene (1450 and 1492 cm −1 ) and poly(methyl methacrylate) (1730 cm −1 ) without requiring conventional spectrometers. When analyte molecules fill the metasurface-generated photonic cavities, we demonstrate vibrational strong coupling between the poly(methyl methacrylate)’s carbonyl band and the CIT mode, manifested in a Rabi splitting of ~43 cm −1 . Our results establish a new photonic platform that unites spectral precision, strong field enhancement, and reconfigurability, offering diverse potential for compact mid-infrared spectroscopy, molecular sensing, and programmable polaritonic photonics.
74 ATOMIC AND MOLECULAR PHYSICS↗
Ten-valley excitonic complexes in charge-tunable monolayer WSe 2
Excitons dominate the optical response of two-dimensional (2D) semiconductors. Strong interactions produce peculiar excitonic complexes, which provide a testing ground for exciton and quantum many-body theories. Here, we report a hitherto unobserved many-body exciton that emerges upon filling both the K and Q valleys of WSe 2 . We optically probe the exciton landscape using charge-tunable devices with unusually thin dielectrics that facilitate doping up to several 10 13 cm −2 . We observe the emergence of the thermodynamically stable complex when 10 valleys are electrostatically filled. We gain insight into its physics using magneto-optical measurements. Our results are well-described by a model where the number of distinguishable Fermi seas interacting with the photoexcited electron-hole pair defines the complex’s behavior. In addition to expanding the repertoire of excitons in 2D semiconductors, this complex could probe the limit of exciton models and answer open questions about screened Coulomb interactions in 2D semiconductors.
M exciton↗
A 10GHz optoelectronic oscillator with continuous frequency tunability and low phase noise
A 10GHz optoelectronic oscillator (OEO) with continuous frequency tunability and low phase noise is presented.
optoelectronic oscillator frequency tunability↗
Tunable Diode Laser (TDL) Development for Trace Gas Spectroscopy and Metrology Systems
The current status of tunable diode lasers (TDLs) for spectroscopy and metrology systems is reviewed.
Trace Gas Spectroscopy tunable diode lasers(TDLs) ↗
Development of a Compact Imaging Spectrometer Using Liquid Crystal Tunable Filter Technology
Liquid crystal tunable filters are useful in building compact multi-spectral instruments. The system is portable and adaptable for use in a variety of fields of study in the visible and near-infrared regions of the spectrum.We will present data from calibration targets and some applications, results of the spectral calibration of a spectrometer system, and results of environmental (vibration, radiation, shock, and thermal) testing. Data acquisition and system design are also discussed.
spectrometers imaging↗
Tunable Infrared Lasers: Preparing for Expanded use in Environmental Monitoring
The literature on the use of tunable infrared lasers, for atmospheric trace gas detection and monitoring is about 25 years of age. However, this field, whith its myriad of potential application areas, has always been driven by the available laser technology. As new or improved laser devices become available, with characteristics which lend themselves to operation in compact, nearly autonomous instruments, their application to atmospheric science and environmental measurements expands.
tunable infrared lasers↗
High-Order Tunable Filters Based on a Chain of Coupled Crystalline Whispering Gallery-Mode Resonators
We demonstrate experimentally a tunable third-order optical filter fabricated from the three voltage-controlled lithium niobate whispering gallery-mode resonators. The filter operates at 1550 nm with 30-MHz bandwidth and can be electrooptically tuned by 12 GHz in the linear regime with approximately 80-MHz/V tuning rate. With this filter, we have demonstrated 6-dB fiber-to-fiber insertion loss and 30-ns tuning speed, limited by the resonator buildup time.
optical resonators↗
Miniature Tunable Laser Spectrometers for Quantifying Atmospheric Trace Gases, Water Resources, Earth Back-Contamination, and In Situ Resource Utilization
The Tunable Laser Spectrometers (TLS) technique has seen wide applicability in gas measurement and analysis for atmospheric analysis, industrial, commercial and health monitoring and space applications. In Earth science using balloons and aircraft over 2 decades, several groups (JPL, NASA Langley & Ames, NOAA, Harvard U., etc) have demonstrated the technique for ozone hole studies, lab kinetics measurements, cloud physics and transport, climate change in the ice record. The recent availability of high-power (mW) room temperature lasers (TDL, IC, QC) has enabled miniaturized, high-sensitivity spectrometers for industry and space (1) Mars, Titan, Venus, Saturn, Moon (2) Commercial isotope ratio spectrometers are replacing bulkier, complex isotope ratio mass spectrometers.
Tunable laser spectrometers (TLS)↗
Surface Plasmon Tunable Filter and Flat Panel Display Device
Now a prototype of surface plasmon tunable filter has been fabricated at JPL, and the experiment measurement will be discussed in this paper.
surface↗
Surface Plasmon Tunable Filter and Spectrometer-on-a-Chip
Surface plasmon tunable filter (SPTF) is a new technology invented in Jet Propulsion Lab. When a white light is incident on a metal/air/metal structure, in certain condition, surface plasmon waves can be excited at one metal/air material interface; those photons in surface plasmon resonances wavelength range will be converted into the energy of free electrons in the metal than coupled into the other metal film, and re-radiate out the color light.
Surface↗
Electronically Tunable Color Filter with Surface Plasmon Waves
Last year, I had reported a novel phenomenon of voltage-induced color-selective absorption with surface plasmons (Appl. Phys. Lett. 67, 2749)...A prototype ( of a tunable notch filter) has been built using liquid crystal as the EO material.
Surface↗
Thermoplastic Elastomers and Their Physical Gels Electrospun into Tunable Microfibrous Nonwoven Mats: Structure Formation and Property Enhancement
Abstract Thermoplastic elastomers (TPEs) based on styrenic block copolymers constitute excellent examples of self‐networking macromolecules that are employed in a wide range of contemporary technologies as molded parts. In such applications, these TPEs exist as dense (nonporous) films or other shapes. Here, it is first demonstrated that a series of commercial TPEs possessing comparable compositions can be electrospun from solution to form microfibers that are arranged into nonwoven mats that are breathable. An important consideration for microfiber formation is the copolymer molecular weight, which regulates i) the viscosity of the parent solution prior to electrospinning, ii) the ability of these copolymers to self‐assemble during electrospinning, iii) the microfiber morphology, and iv) the mechanical properties of the resultant microfibers. The addition of a midblock‐selective aliphatic oil to these TPEs yields thermoplastic elastomer gels (TPEGs), wherein the copolymer morphology and mechanical properties become highly composition‐tunable. Electrospinning TPEGs from a binary oil+solvent solution introduces a micelle inversion mechanism that begins with an oil‐rich micellar core and ends with a styrene‐rich micellar core, required for network stabilization, as the solvent dries during microfiber solidification. This work has implications for the production of controllably low‐modulus microfibrous materials possessing modestly improved toughness but exceptional extensibility and enhanced optical transparency.
Shamsi, Mohammad↗
Tunable Anomalous Hall Effect in a Kagomé Ferromagnetic Weyl Semimetal
Emerging from the intricate interplay of topology and magnetism, the giant anomalous Hall effect (AHE) is the most known topological property of the recently discovered kagomé ferromagnetic Weyl semimetal Co 3 Sn 2 S 2 with the magnetic Co atoms arranged on a kagomé lattice. Here it is reported that the AHE in Co 3 Sn 2 S 2 can be fine-tuned by an applied magnetic field orientated within ≈2° of the kagomé plane, while beyond this regime, it stays unchanged. Particularly, it can vanish in magnetic fields parallel to the kagomé plane and even decrease in magnetic fields collinear with the spin direction. This tunable AHE can be attributed to local spin switching enabled by the geometrical frustration of the magnetic kagomé lattice, revealing that spins in a kagomé ferromagnet change their switching behavior as the magnetic field approaches the kagomé plane. Furthermore, these results also suggest a versatile way to tune the properties of a kagomé magnet.
anomalous Hall effect↗
Tackling P3HT:Y‐Series Miscibility Through Advanced Processing for Tunable Aggregation
Abstract Polymer and small molecule blend thin films are of strong interest for organic electronics and particularly organic solar cells. The high miscibility in blends of ordinary P3HT and state‐of‐the‐art Y‐series non‐fullerene acceptors (NFAs) suppresses phase separation and aggregation challenging successful charge separation and transport. In a recent work, current‐induced doping (CID) is introduced, a method to precisely control the aggregation of Poly(3‐hexylthiophene) (P3HT) in solution. The highly ordered pre‐aggregation in solution is used here to control the P3HT aggregation in neat films and blends with Y12 (BTP‐4F‐12). This results in a 25‐fold increase in hole mobility in P3HT organic field‐effect transistor (OFET) devices and tunability of the P3HT aggregate quality in the presence of Y12 over large ranges. At the same time, particularly the Y12 long‐range ordering is heavily suppressed by increasing P3HT aggregation. However, solvent vapor annealing (SVA) leads to an extraordinarily high Y12 ordering, changes in the crystal orientation of Y12, and a further improvement of P3HT aggregation. A broad range of different degrees of aggregation of both materials can therefore be obtained in the final thin films solely by changing processing parameters without changing the composition of the material system.
Chemistry↗