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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
NASA NTRS1987

Effect of storage and LEO cycling on manufacturing technology IPV nickel-hydrogen cells

Yardney Manufacturing Technology (MANTECH) 50 A-hr space weight individual pressure vessel nickel-hydrogen cells were evaluated. This consisted of investigating: the effect of storage and charge/discharge cycling on cell performance. For the storage test the cells were precharged with hydrogen, by the manufacturer, to a pressure of 14.5 psia. After undergoing activation and acceptance tests, the cells were discharged at C/10 rate (5A) to 0.1 V or less. The terminals were then shorted. The cells were shipped to NASA Lewis Research Center where they were stored at room temperature in the shorted condition for 1 year. After storage, the acceptance tests were repeated at NASA Lewis. A comparison of test results indicate no significant degradation in electrical performance due to 1 year storage. For the cycle life test the regime was a 90 minute low earth orbit at deep depths of discharge (80 and 60 percent). At the 80 percent DOD the three cells failed on the average at cycle 741. Failure for this test was defined to occur when the cell voltage degraded to 1 V prior to completion of the 35 min discharge. The DOD was reduced to 60 percent. The cycle life test was continued.

Smithrick, John J.↗
NASA NTRS1991

Performance of a Dual Anode Nickel-Hydrogen Cell

Nickel-hydrogen batteries are presently being used for energy storage on satellites in low Earth orbit and in geosynchronous orbit, and have also been selected for use on the proposed Space Station Freedom. Development continues on the cell technology in order to improve the specific energy and lengthen the cycle life. An experimental study was conducted to compare the voltage performance of a nickel-hydrogen cell containing a dual anode with the standard cell design which uses a single hydrogen electrode. Since the principle voltage loss in a nickel-hydrogen cell is attributed to the mass transport and resistive polarization parameters of the nickel electrode, addition of a hydrogen electrode on the other side of the nickel electrode should reduce the electrochemical polarizations by a factor of two. A 3.5 in. diameter boilerplate cell with a single 30 mils thick nickel electrode was cycled under various current conditions to evaluate its performance with a single anode and then with a double anode. A layered separator consisting of one Zircar cloth separator and one radiation-grafted polyethylene separator were used between the electrodes. The electrolyte was 26% KOH, and the tests were done at room temperature. The discharge voltage characteristics were determined as a function of current and depth-of-discharge. At the 4C discharge rate and 50% DOD, the voltage of the dual anode cell was 100 mV higher than the single anode cell. At 75% DOD the dual anode cell voltage was about 130 mV higher than the standard cell design. Resistances of the two c ell designs obtained from the slope of the mid-discharge voltages plotted against various currents indicated that the dual anode cell resistance was one-half of the state-of-the-art cell.

Gahn, Randall F.↗
NASA NTRS1997

Arc burst pattern analysis fault detection system

A method and apparatus are provided for detecting an arcing fault on a power line carrying a load current. Parameters indicative of power flow and possible fault events on the line, such as voltage and load current, are monitored and analyzed for an arc burst pattern exhibited by arcing faults in a power system. These arcing faults are detected by identifying bursts of each half-cycle of the fundamental current. Bursts occurring at or near a voltage peak indicate arcing on that phase. Once a faulted phase line is identified, a comparison of the current and voltage reveals whether the fault is located in a downstream direction of power flow toward customers, or upstream toward a generation station. If the fault is located downstream, the line is de-energized, and if located upstream, the line may remain energized to prevent unnecessary power outages.

Russell, B. Don↗
NASA NTRS1981

Synthetic battery cycling

The trend in energy storage is toward systems with high-voltage and high-power outputs. These conditions accentuate the cumulative effects of small differences in characteristics from cell to cell in any large multicell battery. These considerations are of particular concern with a number of emerging electrochemical concepts where convenient overcharge reactions do not exist. The use of interactive computer graphics is suggested as an aid in battery system development. Mathematical representations of simplistic but fully representative functions of many electrochemical concepts of current practical interest will permit battery-level charge and discharge phenomena to be analyzed in a qualitative manner prior to the assembly and testing of actual hardware. This technique will be a useful addition to the variety of tools available to the battery system designer as he bridges the gap between interesting single-cell life test data and reliable energy storage subsystems.

Thaller, L. H.↗
NASA NTRS1997

NiH2 Battery Reconditioning for LEO Applications

This paper summarizes reasons for and benefits of reconditioning nickel-hydrogen (NiH2) batteries used for Low Earth Orbit (LEO) applications. NiH2 battery cells do not have the classic discharge voltage problems more commonly associated with nickel-cadmium (NiCd) cells. This is due, in part, to use of hydrogen electrodes in place of cadmium electrodes. The nickel electrode, however, does have a similar discharge voltage signature for both cell designs. This can have an impact on LEO applications where peak loads at higher relative depths of discharge can impact operations. Periodic reconditioning provides information which can be used for analyzing long term performance trends to predict usable capacity to a specified voltage level. The reconditioning process described herein involves discharging NiH2 batteries at C/20 rates or less, to an average cell voltage of 1.0 volts or less. Recharge is performed at nominal C/5 rates to specified voltage/temperature (V/T) charge levels selected to restore required capacity with minimal overcharge. Reconditioning is a process of restoring reserve capacity lost on cycling, which is commonly called the memory effect in NiCd cells. This effect is characterized by decreases in the discharge voltage curve with operational life and cycling. The end effect of reconditioning NiH2 cells may be hidden in the versatility, of that design over the NiCd cell design and its associated negative electrode fading problem. The process of deep discharge at lower rates by way of reconditioning tends to redistribute electrolyte and water in the NiH2 cell electrode stack, while improving utilization and charge efficiency. NiH2 battery reconditioning effects on life are considered beneficial and may, in fact. extend life based on NiCd experience. In any case, usable capacity data obtained from reconditioning is required for performance evaluation and trend analysis. Characterization and life tests have provided the historical data base used to determine the need for reconditioning in most battery applications. The following sections briefly describe the background of NiH2 battery reconditioning and testing at Lockheed Martin Missiles & Space (LMMS) and other aerospace companies.

Armantrout, J. D.↗
NASA NTRS1969

Transformer regulated self-stabilizing chopper

A self-stabilizing voltage regulator is described. Direct current voltage regulation employing a series transistor rendered conductive during various portions of a cycle is controlled by saturation of an autotransformer. The constant volt-second capacity of the transformer provides conduction time inverse to the input voltage whereby average output voltage is maintained constant. Conduction commenced in response to short gate signals, and resistor feedback for degenerative turn-off of the transistor was after transformer saturation. Standard output filters are also included.

Raposa, F. L.↗
NASA NTRS2010

Performance and Safety Tests of Lithium-Ion Cells Arranged in a Matrix Design Configuration

Matrix Packs display large variations in cell bank voltages at the charge and discharge current (C/2) used in this test program. The voltage difference is larger at the end of discharge than at the end of charge under the conditions studied. Disconnection of a cell from the pack leads to a larger voltage difference during discharge (greater than 2.0 V) between the bank that has one less cell and the other banks. Thermal profile does not show any significant changes or increase in temperature after one cell was disconnected from the bank in spite of falling to very low voltages at the end of discharge. All tests on the matrix pack with the HAM displayed lower max in general due to the placement of thermocouple on the outside of the HAM rather than on the cells. Disconnection of cells has almost no influence on the performance of the packs and does not show any abnormal thermal changes for the 100 cycles obtained in this test program. Longer cycle life may influence the performance especially if the low voltage cell goes into reversal. Overcharge leads to CID activation of cells. If the matrix configuration has a larger number of cells in series, (more than 5 S configuration), the limitations of protective devices may manifest itself irrespective of it being in a matrix configuration. External short circuit causes a fire with expulsion of content from some cells. The fire does not propagate itself laterally, but if there was cell module stacking, then the fire would cause the cells above it to also go into flames/thermal runaway. Limitations of protective devices are observed in this case as the PTCs in the cells did not protect under this abusive condition. Matrix configurations seem to provide protection against lateral propagation of fire and flame. Matrix pack configuration seems to provide good performance in spite of losing cell connections; at least for the configuration tested under this program.

Jeevarajan, Judith↗
NASA NTRS1996

Single battery power subsystems: On-line reconditioning

The effect of on-line reconditioning (deep discharge) on a single, Nickel-Hydrogen spacecraft battery in GEO and LEO is considered. A life cycle test was performed in both GEO and LEO to study the effect of reconditioning on the battery's end of discharge voltage (EODV). The results of these tests show that: LEO on-line reconditioning increased the EODV (by approximately 15 cycles to maximum EODV) and the EODV lasted for approximately 300 cycles, but GEO on-line reconditioning decreased the EODV slightly during the first six days and increases significantly after the seventh day. Based on the available data from the life cycle test, it has been concluded that a long life and stable voltage is realizable with the baseline architecture (single battery, single bus) without the need for reconditioning.

Tobias, R. F.↗
NASA NTRS2006

Li-ion rechargeable batteries on Mars Exploration Rovers

Lithium-ion batteries have contributed significantly to the success of NASA's Mars Rovers, Spirit and Opportunity that have been exploring the surface of Mars for the last two years and performing astounding geological studies to answer the ever-puzzling questions of life beyond Earth and the origin of our planets. Combined with the triple-junction solar cells, the lithium-ion batteries have been powering the robotic rovers, and assist in keeping the rover electronics warm, and in supporting nighttime experimentation and communications. The use of Li-ion batteries has resulted in significant benefits in several categories, such as mass, volume, energy efficiency, self discharge, and above all low temperature performance. Designed initially for the primary mission needs of 300 cycles over 90 days of surface operation, the batteries have been performing admirably, over the last two years. After about 670 days of exploration and at least as many cycles, there is little change in the end-of discharge (EOD) voltages or capacities of these batteries, as estimated from the in-flight data and corroborated by ground testing. Aided by such impressive durability from the Li-ion batteries, both from cycling and calendar life stand point, these rovers are poised to extend their exploration well beyond two years. In this paper, we will describe the performance characteristics of these batteries during launch, cruise phase and on the surface of Mars thus far.

litium ion batteries↗
NASA NTRS1987

Comparator with noise suppression

An apparatus for generating a single pulse the first time only that a noisy cyclic signal exceeds a reference level during a half-cycle is disclosed. For the positive half of a cycle of the noisy cyclic signal, a comparator and a multivibrator produce a fixed voltage output when the noisy cyclic signal first exceeds the reference level. A multivibrator stops the production of the fixed voltage output when the noisy cyclic signal next passes the zero voltage level in the negative direction. Consequently, a single pulse is generated indicating that the signal exceeded the reference level during that half-cycle. The comparator and multi-vibrator produce pulses whenever the noisy cyclic signal exceeds the reference level during the negative half-cycle.

Batts, Colossie N.↗
NASA NTRS1997

Effect of Storage on Performance of Super Nickel-Cadmium Cells

A study was undertaken to examine the capacity maintenance features of SUPER nickel-cadmium cells when stored for extended periods to determine whether the features change when the same kinds of positive plates as that used in nickel-hydrogen cells are used, The cells maintained their capacity when stored at 0 C in the discharged state and at 0 C in the charged state by continuously trickle charging. There was a capacity loss when stored in the open-circuit condition at 28 C. A cycling test at 17% depth of discharge for 2400 cycles using cells stored at various conditions showed that cells maintained good end of discharge voltage regardless of their storage history. However, the EOD voltages of stored cells were lower by 10 mV compared to those of fresh cells. The capacity at the end of the cycling test decreased for the stored cells by 2-7 Ah. The storage related capacity loss is lower for SUPER Ni-Cd cells compared to that of Ni-H2 cells containing a hydrogen precharge. The results suggest the pivotal role of hydrogen pressure in the capacity loss phenomenon.

Vaidyanathan, Hari↗
NASA NTRS1970

Thermionic triode generates ac power

Electrostatic grid controls conduction cycle of thermionic diode to convert low dc output voltages to high ac power without undesirable power loss. An ac voltage applied to the grid of this new thermionic triode enables it to convert heat directly into high voltage electrical power.

Kniazzeh, A. G. F.↗
NASA NTRS1980

Advanced electric propulsion system concept for electric vehicles. Addendum 1: Voltage considerations

The two electric vehicle propulsion systems that best met cost and performance goals were examined to assess the effect of battery pack voltage on system performance and cost. A voltage range of 54 to 540 V was considered for a typical battery pack capacity of 24 k W-hr. The highest battery specific energy (W-hr/kg) and the lowest cost ($/kW-hr) were obtained at the minimum voltage level. The flywheel system traction motor is a dc, mechanically commutated with shunt field control, and due to the flywheel the traction motor and the battery are not subject to extreme peaks of power demand. The basic system uses a permanent-magnet motor with electronic commutation supplied by an ac power control unit. In both systems battery cost were the major factor in system voltage selection, and a battery pack with the minimum voltage of 54 V produced the lowest life-cycle cost. The minimum life-cycle cost for the basic system with lead-acid batteries was $0.057/km and for the flywheel system was $0.037/km.

Raynard, A. E.↗
NASA NTRS2002

Optimal Charging of Nickel-Hydrogen Batteries for Life Extension

We are exploring the possibility of extending the cycle life of battery systems by using a charging profile that minimizes cell damage. Only nickel-hydrogen cells are discussed at this time, but applications to lithium-ion cells are being considered. The process first requires the development of a fractional calculus based nonlinear dynamic model of the specific cells being used. The parameters of this model are determined from the cell transient responses. To extend cell cycle life, an instantaneous damage rate model is developed. The model is based on cycle life data and is highly dependent on cell voltage. Once both the cell dynamic model and the instantaneous damage rate model have been determined, the charging profile for a specific cell is determined by numerical optimization. Results concerning the percentage life extension for different charging strategies are presented. The overall procedure is readily adaptable to real-time implementations where the charging profile can maintain its minimum damage nature as the specific cell ages.

Hartley, Tom T.↗
NASA NTRS2001

Chemical State of Surface Oxygen on Carbon and Its Effects on the Capacity of the Carbon Anode in a Lithium-Ion Battery Investigated

In a lithium-ion battery, the lithium-storage capacity of the carbon anode is greatly affected by a surface layer formed during the first half cycle of lithium insertion and release into and out of the carbon anode. The formation of this solid-electrolyte interface, in turn, is affected by the chemistry of the carbon surface. A study at the NASA Glenn Research Center examined the cause-and-effect relations. Information obtained from this research could contribute in designing a high-capacity lithium-ion battery and, therefore, small, powerful spacecraft. In one test, three types of surfaces were examined: (1) a surface with low oxygen content (1.5 at.%) and a high concentration of active sites, (2) a surface with 4.5 at.% -OH or -OC type oxygen, and (3) a surface with 6.5 at.% O=C type oxygen. The samples were made from the same precursor and had similar bulk properties. They were tested under a constant current of 10 mA/g in half cells that used lithium metal as the counter electrode and 0.5 M lithium iodide in 50/50 (vol%) ethylene carbonate and dimethyl carbonate as the electrolyte. For the first cycle of the electrochemical test, the graph describes the voltage of the carbon anode versus the lithium metal as a function of the capacity (amount of lithium insertion or release). From these data, it can be observed that the surface with low oxygen and a high concentration of active sites could result in a high irreversible capacity. Such a high irreversible capacity could be prevented if the active sites were allowed to react with oxygen in air, producing -OH or -OC type oxygen. The O=C type oxygen, on the other hand, could greatly reduce the capacity of lithium intercalation and, therefore, needs to be avoided during battery fabrication.

Hung, Ching-Cheh↗
NASA NTRS2018

Description of Simulated Small Satellite Operation Data Sets

A set of two BP930 batteries (Identified as PK31 and PK35) were operated continuously for a simulated satellite operation profile completion for single cycle. The battery packs were charged to an initial voltage of around 8.35 V for 100% SOC before the experiment was started. This document explains the structure of the battery data sets. Please cite this paper when using this dataset: Z. Cameron, C. Kulkarni, A. Guarneros, K. Goebel, S. Poll, "A Battery Certification Testbed for Small Satellite Missions", IEEE AUTOTESTCON 2015, Nov 2-5, 2015, National Harbor, MA

Kulkarni, Chetan S.↗