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At least 1,621 records · Page 90

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NASA NTRS1987

Tropical and extratropical forcing of the large-scale circulation - A diagnostic study

Seasonal anomalies in the large-scale circulation are studied in relation to seasonal-mean tropical forcing and extratropical transient-eddy forcing using nine years of tropical-wind and outgoing-longwave-radiation (OLR) data. Results show that in the interannual time scale, extreme swings in anomalous convection over the maritime continent of Indonesia/Borneo and the equatorial central Pacific are linked, respectively, by an east-west seesaw or a dipole pattern, identified with major fluctuations of the Pacific Walker circulation. It is found that extratropical circulation anomalies are related to the fluctuation of this dipole heat source. The overall extratropical circulation seems to be more responsive to the dipole heating with enhanced convection over the maritime continent. While the characteristics of the transient eddies, especially near the exit region of the East Asia jet stream, change substantially between maximum or minimum convection episodes, these transient eddies (defined as transients from the seasonal mean) appear to be unimportant in forcing the seasonal mean circulation anomalies.

Lau, K. M.↗

NASA NTRS1987

The magnetic field of the equatorial magnetotail - AMPTE/CCE observations at R less than 8.8 earth radii

The MPTE/CCE magnetic field experiment has been used to obtain a quantitative evaluation of the frequency and extent of magnetic field distortion in the near-tail region at less than 8.8 earth radii. The variation of this distortion with Kp, radial distance, longitude, and near-equatorial latitude is reported. It has been found that taillike distortions from the dipole field direction may reach 80 deg near the MPTE/CE apogee of 8.8 earth radii. The Bz field component in dipole coordinates was always positive within 0.5 earth radii of the equatorial current sheet, indicating the neutral lines were never seen inside of 8.8 earth radii. Fields were most taillike near midnight and during times of high Kp. At 8.5 earth radii the equatorial field magnitude depressions were roughly half the dipole field strength of 51 nT. These depressions are larger at lesser distances, reaching -40 nT at 3.4 earth radii for Kp of 2- or less and -80 nT and Kp of 3+ and greater.

Fairfield, D. H.↗

NASA NTRS1987

Beaming of Uranian kilometric radiation and implications for the planetary magnetic field

Radio waves from Uranus at 481.2 kHz detected by Voyager 2 show a strong beaming effect. When the data are analyzed according to the magnetic latitude of the observer in an offset tilted dipole field model, a sharply defined emission beam extending from 25 to 55 deg latitude is evident consistent with a source over the south magnetic pole. The lack of prominent emission from the north magnetic pole can be attributed to the large spatial offset of the magnetic dipole resulting in much lower source frequencies. For proper alignment of the beam, an advance of the dipole axis longitude by 23 deg from the standard model is required. This phase shift is interpreted as the result of higher order magnetic moments producing a skew of the field lines at low altitudes in the polar source region. This conclusion further substantiates models of the interior of Uranus which predict a complex intrinsic field with significant nondipolar contributions to the surface magnetic field.

Barbosa, D. D.↗

NASA NTRS1987

How important is correlation in the description of the Ni-H2O interaction

Using very large basis sets, which can accurately describe the polarizability of Ni and H2O and the dipole moment of H2O, the dipole-induced-dipole interaction is shown to be more than 50 percent of the about 4.8 kcal/mole bonding. Dispersion is found to account for the remainder of the bonding; this is significantly less than in previous estimates. The superposition error at the SCF level is essentially zero, and only 0.5 kcal/mole at the SDCI level, and the binding energy has been corrected for this error.

Bauschlicher, Charles W., Jr.↗

NASA NTRS1989

Low frequency oscillations in total ozone measurements

Low frequency oscillations with periods of approximately one to two months are found in eight years of global grids of total ozone data from the Total Ozone Mapping Spectrometer (TOMS) satellite instrument. The low frequency oscillations corroborate earlier analyses based on four years of data. In addition, both annual and seasonal one-point correlation maps based on the 8-year TOMS data are presented. The results clearly show a standing dipole in ozone perturbations, oscillating with 35 to 50 day periods over the equatorial Indian Ocean-west Pacific region. This contrasts with the eastward moving dipole reported in other data sets. The standing ozone dipole appears to be a dynamical feature associated with vertical atmospheric motions. Consistent with prior analyses based on lower stratospheric temperature fields, large-scale standing patterns are also found in the extratropics of both hemispheres, correlated with ozone fluctuations over the equatorial west Pacific. In the Northern Hemisphere, a standing pattern is observed extending from the tropical Indian Ocean to the north Pacific, across North America, and down to the equatorial Atlantic Ocean region. This feature is most pronounced in the NH summer.

Gao, X. H.↗

NASA NTRS1988

Full configuration-interaction study of the ionic-neutral curve crossing in LiF

Full configuration-interaction (FCI) calculations are used to assess the relative ability of methods for truncating the n-particle expansion in describing the ionic-neutral curve crossing between the two lowest Sigma(+) states of LiF. While the FCI calculations yield a smooth dipole moment function, MRCI calculations based on CASSCF orbitals optimized for the lowest state at all r values yield a discontinuous dipole moment function. However, when the orbitals are optimized using a state-averaged CASSCF procedure, with equal weights for the ionic and neutral solutions, both the CASSCF and MRCI dipole moment functions are smooth and in reasonable agreement with the FCI. No single-reference-based method is found to work satisfactorily. Potential curves for the lowest two Sigma(+) states are determined in both the adiabatic and diabatic representations using a large atomic natural orbit Gaussian basis set and a state-averaged CASSCF/MRCI treatment of electron correlation.

Bauschlicher, Charles W., Jr.↗

NASA NTRS1988

The determination of absolute ro-vibrational intensities for radical diatomic molecules

Ro-vibrational transition intensities of radical and/or chemically reactive molecular species are difficult to determine. A number of methods which might be used to provide information on matrix elements of the electric dipole moment function and the construction of the dipole moment function from the information these methods provide are discussed. The derived dipole moment function represents an optimum choice and allows a calculation (with estimable errors) of the line intensities for a large number of ro-vibrational transitions.

Chackerian, C., Jr.↗

NASA NTRS1988

Coronal magnetic fields produced by photospheric shear

The magnetofrictional method for computing force-free fields is used to examine the evolution of the magnetic field of a line dipole, when there is relative shearing motion between the two polarities. It is found that the energy of the sheared field can be arbitrarily large compared with the potential field. It is also found that it is possible to fit the magnetic energy, as a function of shear amplitude, by a simple functional form. The fit parameters depend only on the distribution of normal field in the photosphere and the form of the shearing displacement. They show that the energy is relatively more enhanced if the shear occurs: (1) where the normal field is strongest; and/or (2) in the inner region of the dipole, near the axis; and/or (3) over a large fraction of the dipole area.

Klimchuk, J. A.↗

NASA NTRS1989

Application of satellite visible band data to high latitude oceans

Freshwater discharge in the Northeast Pacific contains very fine sediments that can be detected using Landsat Thematic Mapper (TM) and Multi-spectral Scanner (MSS) imagery. From the TM data, several new coastal circulation features were discovered in the northern Gulf of Alaska. Flow around a coastal island produces a myriad of dipole eddies which are important to the cross-shelf transport of salt and heat. They also serve as sites to test numerical models to allow a better understanding of coastal flows and eddy formation elsewhere. Detection of these dipole eddies from their sediment distributions has allowed the comparison of different spectral bands from six imaging satellite sensors for their abilities to describe these features. It is concluded that, in addition to the TM sensor's capability, the sediments can be detected with MSS and CZCS sensors, but not with AVHRR or DMSP. As a consequence of this comparison of satellite visible data, it is confirmed that the dipole eddies here exist under low flow conditions (less than 1000 cu m/sec).

Ahlnas, Kristina↗

NASA NTRS1990

Barotropic instability with divergence - Theory and applications to Venus

IR images of Venus reveal a curious double-lobed hot spot in the polar region. Elson (1982) has suggested that this dipole represents a barotropic instability associated with a high-latitude jet. Unfortunately, the classical theory of barotropic instability cannot predict temperature variations. This paper generalizes the theory to include horizontal divergence, vertical motions, and temperature variations, and applies it to the stratosphere of Venus. The fastest-growing barotropic instability in the nominal model matches the observed dipole in period and horizontal temperature pattern. The accompanying wind variations are comparable to the speed of the mean jet, indicating strong nonlinear effects. It is concluded that the Venus dipole may represent the self-limited stage of a barotropic instability with divergence.

Dobrovolskis, Anthony R.↗

NASA NTRS1990

Low-frequency oscillations in total ozone measurements

Gao, X. H.↗

NASA NTRS1991

Is interstellar detection of higher members of the linear radicals CnCH and CnN feasible?

Rotational constants and dipole moments for linear-chain radicals CnCH and CnN are estimated using a combinatiaon of ab initio molecular orbital calculations and observed data on the starting members of the series. CnCH with n = 0-5 have been observed by radioastronomy in carbon-rich interstellar clouds; higher members of the series have 2Pi ground states with large dipole moments and are strong candidates for observation. CN and C3N have also been observed by radioastronomy; higher members of the series, with the possible exception of C5N, have 2Pi ground states with near-zero dipole moments making their interstellar detection hopeless under present observational conditions. C5N can be a strong candidate only if it has a 2Sigma ground state, and best computations so far indicate that this is not the case.

Pauzat, F.↗

NASA NTRS1992

Equilibrium properties of transition-metal ion-argon clusters via simulated annealing

The geometrical structures of M(+) (Ar)n ions, with n = 1-14, have been studied by the minimization of a many-body potential surface with a simulated annealing procedure. The minimization method is justified for finite systems through the use of an information theory approach. It is carried out for eight potential-energy surfaces constructed with two- and three-body terms parametrized from experimental data and ab initio results. The potentials should be representative of clusters of argon atoms with first-row transition-metal monocations of varying size. The calculated geometries for M(+) = Co(+) and V(+) possess radial shells with small (ca. 4-8) first-shell coordination number. The inclusion of an ion-induced-dipole-ion-induced-dipole interaction between argon atoms raises the energy and generally lowers the symmetry of the cluster by promoting incomplete shell closure. Rotational constants as well as electric dipole and quadrupole moments are quoted for the Co(+) (Ar)n and V(+) (Ar)n predicted structures.

Asher, Robert L.↗

NASA NTRS1993

Theoretical characterization of the reaction CH3 +OH yields CH3OH yeilds products: The (1)CH2 + H2O, H2 + HCOH, and H2 + H2CO channels

The potential energy surface (PES) for the CH3OH system has been characterized for the (1)CH2 + H2O, H2 + HCOH, and H2 + H2CO product channels using complete-active-space self-consistent-field (CASSCF) gradient calculations to determine the stationary point geometries and frequencies followed by CASSCF/internally contracted configuration-interaction (CCI) calculations to refine the energetics. The (1)CH2 + H2O channel is found to have no barrier. The long range interaction is dominated by the dipole-dipole term, which orients the respective dipole moments parallel to each other but pointing in opposite directions. At shorter separations there is a dative bond structure in which a water lone pair donates into the empty a" orbital of CH2. Subsequent insertion of CH2 into an OH bond of water have barriers located at -5.2 kcal/mol and 1.7 kcal/mol, respectively, with respect to CH3 + OH. From comparison of the computed energetics of the reactants and products to known thermochemical data it is estimated that the computed PES is accurate to plus or minus 2 kcal/mol.

Walch, Stephen P.↗

NASA NTRS1992

Interpreting asteroid photometry and polarimetry using a model of shadowing and coherent backscattering

The shadow-hiding models for the opposition effect and negative polarization of atmosphereless solar system bodies do not explain some experimental findings, such as the enhancing opposition effect and negative polarization with decreasing particle size down to wavelength scales. The enhancement for laboratory photometric and polarimetric data on artificial glass samples with different particle size is shown. These results are in agreement with the so-called coherent backscattering or interference mechanism proposed for the interpretation of the opposition effect and negative polarization. Two different approaches for describing the opposition effect and negative polarization produced by the shadow-interference mechanism were developed. One is based on exact electromagnetic solutions for simple scattering systems that include dipole-dipole and dipole-surface coupling; The other is based on a point-scatterer approximation characterized by model photometric and polarimetric phase functions, and the mutual shadowing effect is derived using virtual volumes associated with the point-scatterers. Both approaches yield qualitatively similar results, although neither is entirely satisfactory. We regard them as prototypes for a future unified model of shadowing and coherent backscattering. The sharp opposition effect of 44 Nysa and the asteroid albedo-polarization rule are here explained using the point-scatterer approach.

Shkuratov, Y. G.↗

NASA NTRS1993

The magnetic field configurations of AM Herculis binaries

We have considered equilibrium configurations of a white dwarf and a red dwarf companion in AM Herculis type binary system where the red dwarf is assumed to have an intrinsic centered dipole field, and the white dwarf an offset dipole or a centered dipole plus a quadrupole field, and the interaction is purely magnetic. The restoring torque, due to the system being perturbed from its stable equilibrium configuration, is compared with the accretion torque. The results are used to show that the observed alignment of the main cyclotron emission region relative to the red star can be explained quite simply by these models without having to invoke gravitational torques. We also provide a possible explanation of the observation that the more strongly accreting pole has the weaker field strength in the few systems where fields have been determined at both poles.

Wu, Kinwah↗

NASA NTRS1993

Theoretical characterization of the reaction CH3 + OH yields CH3OH yields products - The (1)CH2 + H2O, H2 + HCOH, and H2 + H2CO channels

The potential energy surface (PES) for the CH3OH system has been characterized for the (1)CH2 + H2O, H2 + HCOH, and H2 + H2CO product channels using complete-active-space self-consistent-field (CASSCF) gradient calculations to determine the stationary point geometries and frequencies followed by CASSCF/internally contracted configuration-interaction (CCI) calculations to refine the energetics. The (1)CH2 + H2O channel is found to have no barrier. The long range interaction is dominated by the dipole-dipole term, which orients the respective dipole moments parallel to each other but pointing in opposite directions. At shorter separations there is a dative bond structure in which a water lone pair donates into the empty 'a' orbital of CH2. Subsequent insertion of CH2 into an OH bond of water have barriers located at -5.2 kcal/mol and 1.7 kcal/mol, respectively, with respect to CH3 + OH. From comparison of the computed energetics of the reactants and products to known thermochemical data it is estimated that the computed PES is accurate to plus or minus 2 kcal/mol.

Walch, Stephen P.↗

NASA NTRS1993

On the latitude and solar cycle dependence of the interplanetary magnetic field strength

Twenty years of solar magnetograph and in-ecliptic IMF measurements are used to verify that the radial IMF component (B sub r) can be approximated by a superposition of the sun's inclined magnetic dipole moment and a current sheet normal to the dipole axis. The net field is found to be about three times stronger along the dipole axis than near the current sheet. Over the sunspot cycle, the absolute value of B sub r should undergo the least modulation near the heliographic equator and the greatest modulation above the sun's poles, where, at 1 AU, it varies systematically between about 10 nT near sunspot minimum and about 1 nT near sunspot maximum. The latitudinal gradients in the absolute value of B sub r are expected to be steepest around sunspot minimum and flattest near sunspot maximum. It is predicted that Ulysses will encounter very strong fields when it flies over the solar poles during the declining phase of sunspot cycle 22.

Wang, Y.-M.↗