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At least 1,621 records · Page 90

Structure Sensitivity of Acrolein Hydrogenation by Platinum Nanoparticles on Ba x Sr 1- x TiO 3 Nanocuboids

The structure sensitivity of Pt nanoparticles (Pt N ) for gas-phase acrolein (AC) hydrogenation was probed for Pt N on Ba x Sr 1- x TiO 3 nanocuboid supports with (0 0 1) facets in a combined theoretical and experimental study. The in situ selectivity for allyl alcohol increased with the increase of the Sr concentration in the support, which corresponds to modifications in the stable Winterbottom shape and lattice strain of the Pt nanoparticles as a result of the interfacial energy between Pt and the Ba x Sr 1- x TiO 3 supports. “Local model” nanofacets of the Pt surface, edge, and corner morphologies were developed as compact representations of adsorption and reaction sites. DFT was used as the primary modeling tool for the equilibrium adsorption states. We argue that adsorption on edge sites is critically important for the overall allyl alcohol selectivity of Pt N catalysts. A simple model was developed to represent Pt N strain effects caused by its interaction with the substrate. Bader topological atom, spherical volume averaging charge, and modified bond valence sum analyses were used to understand the bonding structure. Density of states analysis was performed for the structures of Pt N , adsorbed AC, and intermediate products to examine adsorbate–particle interactions. The simulated hydrogenation of AC on Pt N nanofacets was compared to the in situ hydrogenation of AC by Pt N on Ba x Sr 1- x TiO 3 to examine the effects of facet, edge, and corner sites on the overall selectivity.

bio-inspired↗

Communications Transceivers for Venus Surface Missions

The high temperature of the surface of Venus poses many difficulties. Previous Venus landers have only operated for short durations before succumbing to the heat. NASA Glenn Research Center conducted a study on communications for long duration Venus surface missions. I report the findings in this presentation. Current technology allows production of communications transceivers that can operate on the surface of Venus, at temperatures above 450 C and pressures of over 90 atmospheres. While these transceivers would have to be relatively simple, without much of the advanced signal processing often used in modern transceivers, since current and near future integrated circuits cannot operate at such high temperatures, the transceivers will be able to meet the requirements of proposed Venus Surface mission. The communication bands of interest are High Frequency or Very High Frequency (HFNHF) for communication between Venus surface and airborne probes (including surface to surface and air to air), and Ultra High Frequency (UHF) to Microwave bands for communication to orbiters. For HFNHF, transceivers could use existing vacuum tube technology. The packaging of the vacuum tubes may need modification, but the internal operating structure already operates at high temperatures. Using metal vacuum structures instead of glass, allows operation at high pressure. Wide bandgap transistors and diodes may be able to replace some of the thermionic components. VHF communications would be useful for line-of- sight operations, while HF would be useful for short-wave type communications using the Venusian ionosphere. UHF and microwave communications use magnetically focused thermionic devices, such as traveling wave tubes (TWTs), magnetron (M-type) amplifiers, and klystrons for high power amplifiers, and backward wave oscillators (BWOs) and reflex klystrons for oscillators. Permanent magnets are already in use in industry that can operate at 500 C. These magnets could focus electron beam tubes on the surface of Venus. While microwave windows will need to be designed for the high pressure, diamond windows have already been demonstrated, so high-pressure microwave windows can be designed and built. Thus, all of these devices could be useful for Venus surface missions. Current electronic power conditioners to supply the high voltages used in these microwave devices cannot operate at high temperatures, but earlier electronic power conditioners that used vacuum tubes can be modified to work at high temperature. Evaluating the various devices in this study, the M-type traveling wave tube (where a traveling wave structure is used in a crossed-field device, similar to the Amplitron used on the Apollo missions) stood out for the high power amplifier since it requires a single high voltage, simplifying the power supply design. Since the receiver amplifier is a low power amplifier, the loss of efficiency in linear beam devices without a depressed collector (and thus needing a single high voltage) is not important; a low noise TWT is a possible solution. Before solid-state microwave amplifiers were available, such TWTs were built with a 1-2 dB noise figure. A microwave triode or transistor made from a wide bandgap material may be preferable, if available. Much of the development work needed for Venusian communication devices will need to focus on the packaging of the devices, and their connections, but the technology is available to build transceivers that can operate on the surface of Venus indefinitely.

Force, Dale A.↗

The Flexible Lunar Architecture for Exploration (FLARE): Designed for the Artemis-3 Moon 2024 Mission and Beyond

The Flexible Lunar Architecture for Exploration (FLARE) is a concept to deliver four crew to the lunar surface for 7 to 14 days and then return them safely to Earth by 2024. This meets NASA’s internal 2024 lunar landing deadline directed by President Trump (Trump, 2017) and the “5-year” goal set forth by Vice President Pence (Pence, 2019). FLARE is an alternative to NASA’s Human Landing System reference architecture from the Design Analysis Cycle (DAC) #2 (NASA, 2019b). The minimum FLARE concept uses one Space Launch System launch, one Orion, one European Service Module (ESM), and one human lander to deliver four crew to the Moon for a minimum surface duration of 7 days and return them to Earth. FLARE adds a new capability, called the SpaceTug, based upon the mature and successful United Launch Alliance “Common” Centaur Upper Stage vehicle, with modifications. In FLARE, the SpaceTug provides propulsion needed to return the Orion+ESM from the Moon to Earth. The SpaceTug also provides propulsion to deliver the human lander Descent Element (DE) and Ascent Element (AE) separately to lunar orbit. The Orion+ESM then completes a rendezvous with the mated DE+AE in lunar orbit. FLARE also offers optional phases to the Moon 2024 mission. The SpaceTug can also deliver components of the planned Gateway - including the Power and Propulsion Element and the Habitation and Logistics Outpost - to lunar orbit; however, the planned FLARE destination is a Low Lunar Frozen Polar Orbit unlike the NASA DAC2 plan for a Near Rectilinear Halo Orbit. FLARE also provides an option to deliver precursor equipment - including a habitation module, crew mobility devices and an In-Situ Resource Utilization demonstration - to the lunar surface for enhanced crew exploration and science with the extended 14-day surface mission.

Commercial Launch Vehicles (CLV)↗

A Package of Momentum and Heat Transfer Coefficients for the Stable Surface Layer Extended by New Coefficients over Sea Ice

The bulk transfer coefficients of momentum, heat, and humidity belong to the main ingredients of numerical weather prediction and climate models. They are needed for the calculation of turbulent fluxes in the surface layer and often rely on the Monin–Obukhov similarity theory requiring universal stability functions. The problem of a derivation of transfer coefficients based on different stability functions has been considered by many researchers over the years but it remains to this day. In this work, dedicated to the memory of S.S. Zilitinkevich, we also address this task, and obtain transfer coefficients from three pairs of theoretically derived stability functions suggested by Zilitinkevich and co-authors for stable conditions. Additionally, we construct non-iterative parametrizations of these transfer coefficients based on earlier work. Results are compared with state-of-the-art coefficients for land, ocean, and sea ice. The combined parametrizations form a package in a universal framework relying on a semi-analytical solution of the Monin-Obukhov similarity theory equations. A comparison with data of the Surface Heat Budget of the Arctic Ocean campaign (SHEBA) over sea ice reveals large differences between the coefficients for land conditions and the measurements over sea ice. However, two schemes of Zilitinkevich and co-authors show, after slight modification, good agreement with SHEBA although they had not been especially developed for sea ice. One pair of the modified transfer coefficients is superior and is compatible to earlier SHEBA-based parametrizations. Finally, an algorithm for practical use of all transfer coefficients in climate models is given.

54 ENVIRONMENTAL SCIENCES↗

Role of Boron in Enhancing the Catalytic Performance of Supported Platinum Catalysts for the Nonoxidative Dehydrogenation of n -Butane

Platinum-based supported catalysts for hydrocarbon conversion are among the most effective for selective dehydrogenation and isomerization processes. However, high process temperatures and the possibility of coke formation require catalyst modifications to mitigate such effects. One of the emerging approaches to prevent platinum catalyst deactivation is the use of boron additives that have been proposed to prevent coking. Despite such a valuable property of boron, the mechanisms for extending the catalyst lifetime and the decrease in coke formation based on this method are still poorly understood. The type and transformations of boron species on silica surface were investigated as a function of boron introduction, platinum addition, catalyst activation, and catalytic reactivity by a combination of X-ray photoelectron spectroscopy, electron microscopy, solid-state nuclear magnetic resonance spectroscopy, and density functional theory calculations to uncover the possible role of boron modification in improving the catalytic performance. Catalytic nonoxidative dehydrogenation of n-butane revealed that incorporation of boron improved the catalytic activity (similar to 3x) and stability of Pt/SiO 2 . The role of boron in enhancing catalytic performance was attributed to facilitating the migration of alkyl groups from platinum catalytic centers to tetrahedrally coordinated boron sites.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Experimental studies of the effects of atomic ordering in epitaxial Ga{sub x}In{sub 1–x}P alloys on their structural and morphological properties

The properties of epitaxial Ga{sub x}In{sub 1–x}P alloys with an ordered arrangement of atoms in the crystal lattice are studied by a number of structural and microscopic methods. The alloys are grown by metal-organic chemical vapor deposition onto single-crystal GaAs(100) substrates. It is shown that, under conditions for the coherent growth of an ordered Ga{sub x}In{sub 1–x}P alloy on a GaAs(100) substrate, atomic ordering results in radical modifications of the structural properties of the semiconductor compared to the properties of disordered alloys. Among these modifications are a change in the crystal-lattice parameter and, as a consequence, lowering of the crystal symmetry and the formation of two different types of surface nanorelief. With consideration for elastic strains, the parameters of Ga{sub x}In{sub 1–x}P alloys with ordering as functions of the order parameter are calculated for the first time. It is shown that all experimental data are in good agreement with the developed theoretical concepts.

36 MATERIALS SCIENCE↗

Calibrating the Galactic Cepheid Period–Luminosity Relation from the Maximum-likelihood Technique

We present a realization of the maximum-likelihood technique, which is one of the latest modifications of the Baade–Becker–Wesselink method. Our approach is based on nonlinear calibrations of the effective temperature and bolometric correction, which take into account metallicity and surface gravity. It allows one to estimate the key Cepheid parameters, the distance modulus, and the interstellar reddening, combining photometric and spectroscopic data (including the effective temperature data). This method is applied to a sample of 44 Galactic Cepheids for which multiphase temperature measurements are available. The additional data correction is performed to subtract the impact of the component in binary/multiple systems. We also study the effect of shock waves, whose presence in the stellar atmosphere distorts the observational data and leads to systematic errors in the obtained parameters. We determine the optimal restriction on the input data to eliminate this effect. This restriction provides accurate period–radius and period–luminosity relations that are consistent with the results in previous studies. We found the following relations: log R = (0.68 ± 0.03) · log P + (1.14 ± 0.03), M {sub v} = − (2.67 ± 0.16) · (log P − 1) − (4.14 ± 0.05).

79 ASTRONOMY AND ASTROPHYSICS↗

Development and testing of the ultraviolet spectrometer for the Mariner Mars 1971 spacecraft

The Mariner Mars 1971 ultraviolet spectrometer is an Ebert-Fastie type of the same basic design as the Mariner Mars 1969 instrument. Light enters the instrument and is split into component wavelengths by a scanning reflection diffraction grating. Two monochrometer exit slits allow the use of two independent photomultiplier tube sensors. Channel 1 has a spectral range of 1100 to 1692 A with a fixed gain, while Channel 2 has a spectral range of 1450 to 3528 A with an automatic step gain control, providing a dynamic range over the expected atmosphere and surface brightness of Mars. The scientific objectives, basic operation, design, testing, and calibration for the Mariner Mars 1971 ultraviolet spectrometer are described. The design discussion includes those modifications that were necessary to extend the lifetime of the instrument in order to accomplish the Mariner Mars 1971 mission objectives.

Farrar, J. W.↗

The 727 airplane side inlet low-speed performance confirmation model test for refanned JT8D engines

The results of a low-speed wind tunnel test of a 0.3 scale model 727 airplane side inlet for JT8D-100 engines are presented. The objectives of the test were to develop lines for a full-scale flightworthy inlet, to evaluate inlet total pressure recovery and steady-state total pressure distortion, and to obtain model-scale distortion data which can be used in the assessment of the compatibility of the inlet with the JT8D-100 series engines. A secondary objective was to obtain internal/external cowl static pressures for the determination of nacelle loads. Two basic inlet models were tested at static, forward speed, angle-of-attack (inflow angle), and cross-wind conditions. One model was with and one without an acoustic ring. Two modifications to the models were also tested, one with the ring closer to the inlet throat and one with a larger lip. Test measurements consisted of inlet surface static pressure, engine face total pressure, inlet airflow, tunnel total pressure, tunnel total temperature and tunnel velocity. Total pressure traverses were taken directly behind the ring and strut. No dynamic measurements were taken.

Schuehle, A. L.↗

Thrust-vectored differential turns

Barrier surface construction in the joint space of the differential turning game for thrust-vectored vs. conventional aircraft is discussed. Differential-turn studies are based on modifications of existing computer programs including an energy-turn program, and one which generates hodograph data. Optimal turning flight in energy approximation is discussed for the conventional aircraft configurations. It is concluded that any advantages realized from thrust-vectoring are minor, unless hover is possible, where advantages would be major at low energies, and affect tactics at high energies as well.

Kelley, H. J.↗

Automated mixed traffic vehicle design AMTV 2

The design of an improved and enclosed Automated Mixed Traffic Transit (AMTT) vehicle is described. AMTT is an innovative concept for low-speed tram-type transit in which suitable vehicles are equipped with sensors and controls to permit them to operate in an automated mode on existing road or walkway surfaces. The vehicle chassis and body design are presented in terms of sketches and photographs. The functional design of the sensing and control system is presented, and modifications which could be made to the baseline design for improved performance, in particular to incorporate a 20-mph capability, are also discussed. The vehicle system is described at the block-diagram-level of detail. Specifications and parameter values are given where available.

Johnston, A. R.↗

Nimbus-7 total ozone algorithm

The total ozone algorithm used for the processing of Nimbus-4 BUV measurements is modified to account for off-nadir viewing of the Total Ozone Mapping Spectrometer onboard Nimbus-7 satellite. TOMS is a cross-track scanning instrument with a 50 x 50-km field of view, increasing to 150 x 150 km at the extreme off-nadir angle of 51 deg and six spectral bands in the 310-380-nm region. Consideration is given to the determination of the pressure at the reflecting surface and profile selection scheme at very high solar zenith angles. The algorithm is also applicable to the Solar Backscattered UV Experiment aboard the same satellite. The modifications provide for a better cloud height, snow correction, and improved retrievals near the terminator.

Bhartia, P. K.↗

Overview of numerical codes developed for predicted electrothermal deicing of aircraft blades

An overview of the deicing computer codes that have been developed at the University of Toledo under sponsorship of the NASA-Lewis Research Center is presented. These codes simulate the transient heat conduction and phase change occurring in an electrothermal deicier pad that has an arbitrary accreted ice shape on its surface. The codes are one-dimensional rectangular, two-dimensional rectangular, and two-dimensional with a coordinate transformation to model the true blade geometry. All modifications relating to the thermal physics of the deicing problem that have been incorporated into the codes will be discussed. Recent results of reformulating the codes using different numerical methods to increase program efficiency are described. In particular, this reformulation has enabled a more comprehensive two-dimensional code to run in much less CPU time than the original version. The code predictions are compared with experimental data obtained in the NASA-Lewis Icing Research Tunnel with a UH1H blade fitted with a B. F. Goodrich electrothermal deicer pad. Both continuous and cyclic heater firing cases are considered. The major objective in this comparison is to illustrate which codes give acceptable results in different regions of the airfoil for different heater firing sequences.

Keith, Theo G.↗

Wind-Wave-Current Tank Research Facility usage and status

This summary is to provide information as to: (1) research activities, and (2) facilities status of the wind-wave-current tank research facility located at the GSFC/WFF. Research Activities include: (1) Wave-Turbulence Interaction; (2) Velocity Structure Below Waves; (3) Short-Wave Modification by Long-Waves; (4) Wind-Wave Generation Time Scale; (5) Wave-Current Interaction; (6) Rain Effects on Microwave Scattering from the Sea-Surface; and (7) Gas Exchange Rates versus Scatterometer Power.

Bliven, L. F.↗

A Wind-Tunnel Investigation of a Transonic-Transport Configuration Utilizing Drag-Reducing Devices at Mach Numbers from 0.20 to 1.03

The static longitudinal stability and control and lateral characteristics of a transonic-transport model, incorporating recent drag-reducing devices, has been investigated in the Langley 8-foot transonic pressure tunnel. The wing was cambered, had a thickened root and a taper ratio of 0.3. Wing sweepback angles of 45 degrees and 40 degrees were investigated with corresponding aspect ratios of 7 and 8, respectively. Modifications to the model for reducing the drag were: a forward fuselage addition and special bodies (four big enough to house jet engines) added to the upper surface of the wing. Other components and changes investigated included an empennage, a wing-tip body, wing fences, wing trailing-edge flaps, horizontal-tail settings, and wing dihedral angle. The investigation covered the Mach number range from 0.20 to 1.03 for the angle-of-attack range from -5 degrees to 15.4 degrees, and a sideslip angle of -5 degrees, in the Reynolds number range from 0.52 times 10(exp 6) to 1.94 times 10(exp 6) based on the wing mean aerodynamic chord. The various fuselage and wing additions delayed the drag-rise Mach number and greatly reduced the drag beyond the drag rise. The wing bodies markedly alleviated unstable pitch tendencies throughout the test Mach number range. At low landing speeds, the wing bodies exhibited little interference with the ability of trailing-edge flaps to increase the lift near maximum lift coefficient; and the use of fences greatly reduced the severe longitudinal instability trend at landing attitudes. The model with a 6 degree dihedral angle exhibited positive lateral and directional stability characteristics in the presence of the fuselage and wing additions. An increase in drag-rise Mach number associated with the fuselage and wing additions on the 40 degree sweptback wing combination was similar to that for the comparable 45 degree combination. These additions did, however, reduce the drag of the 40 degree sweptback configurations more than the 45 degree configurations in the transonic speed range.

Loving, Donald L.↗

Dynamical Masses for a Complete Census of Local Dwarf Galaxies

The 2020s are poised to continue the past two decades of significant advances based on observations of dwarf galaxies in the nearby universe. Upcoming wide-field photometric surveys will probe substantially deeper than previous data sets, pushing the discovery frontier for new dwarf galaxies to fainter magnitudes, lower surface brightnesses, and larger distances. These dwarfs will be compelling targets for testing models of galaxy formation and cosmology, including the properties of dark matter and possible modifications to gravity. However, most of the science that can be extracted from nearby dwarf galaxies relies on spectroscopy with large telescopes. We suggest that maximizing the scientific impact of near-future imaging surveys will require both major spectroscopic surveys on 6-10m telescopes and multiplexed spectroscopy with even larger apertures.

79 ASTRONOMY AND ASTROPHYSICS↗

Modulating the Pseudoelastic Response of Nitinol Using Ion Implantation

This work explores whether ion beam modification can be used to modulate the austenite to martensite phase transformation in Nickel-Titanium (NiTi), thereby achieving novel or localized transformation properties in near-surface regions. We report this could provide alternatives to laser shot peening or other surface treatment methods and possibly expand applications in biomedical, aerospace, and other fields. Irradiation induces defects and internal stress that can serve as nucleation and/or pinning sites for the phase transformation. Thus, it can augment more convention- al approaches, including alloying, severe mechanical work, grain size reduction, and precipitation of coherent precipitates. A range of outcomes is possible in principle, including a shift of the critical stress or temperature for onset of the transformation, linearization, reduction of hysteresis, stabilization, and extent of transformation strain.

36 MATERIALS SCIENCE↗

Effect of Ti Modification on Microstructures and Properties of Carbidic Austempered Ductile Iron

In this paper, we investigated the effect of titanium modification on microstructures and properties of carbidic austempered ductile iron (CADI) containing 3.72 wt.% C, 2.77 wt.% Si, and 0.51 wt.% Mn. The results showed that with the addition of 0.1 wt.% Ti, TiC particles were formed, and distributed in carbides and matrix. Microstructural observation indicated that the maximum diameter of graphite nodules decreased from 58 to 40 μm, and the shape of carbides transformed from network to fragmentation, which was related to the nucleation of the eutectic structure (γ + (Fe, Cr){sub 3}C) where TiC particles act as the nucleus. After isothermal quenching at 300 °C, the hardness of Ti-bearing CADI was 3.5 HRC higher than ordinary CADI, and the impact toughness was increased by 14.3%. Additionally, due to the decrease in exfoliation, the wear loss of Ti-bearing CADI was 14.8% lower than ordinary CADI during the block-on-ring wear test at the surface load of 300 N.

36 MATERIALS SCIENCE↗