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At least 1,621 records · Page 90

Modifying the Soil and Water Assessment Tool to Simulate Cropland Carbon Flux: Model Development and Initial Evaluation

Climate change is one of the most compelling modern issues and has important implications for almost every aspect of natural and human systems. The Soil and Water Assessment Tool (SWAT) model has been applied worldwide to support sustainable land and water management in a changing climate. However, the inadequacies of the existing carbon algorithm in SWAT limit its application in assessing impacts of human activities on CO2 emission, one important source of greenhouse gases (GHGs) that traps heat in the earth system and results in global warming. In this research, we incorporate a revised version of the CENTURY carbon model into SWAT to describe dynamics of soil organic matter (SOM)- residue and simulate land-atmosphere carbon exchange.

Zhang, Xuesong↗

Surface structure of α-Cr2O3(0001) after activated oxygen exposure

The surface structure of a-Cr2O3(0001) before and after exposure to activated oxygen from an ECR plasma source was investigated by x-ray photoelectron spectroscopy (XPS) and x-ray photoelectron diffraction (XPD). Epitaxial Cr2O3(0001) thin films were deposited on Al2O3(0001) substrates by oxygen-plasma-assisted molecular beam epitaxy (OPA-MBE). When cooled or annealed in vacuum, strong evidence for a Cr-Cr-O3- termination was obtained by comparing the Cr3+ XPD azimuthal scan to single scattering simulations. However, after plasma exposure, a high binding energy feature was observed in the Cr 2p XPS spectrum that possesses an ordered structure distinct from the underlying Cr3+ of Cr2O3, which remains Cr-Cr-O3-like. Investigation of this new surface structure with simulations of various candidate structures tentatively rules out CrO2-like configurations. The high binding energy feature likely arises from a higher oxidation state of Cr. One possibility is the oxidation of the surface layer of Cr to Cr6- with a double chromyl structure (O=Cr=O).

Environmental Molecular Sciences Laboratory↗

Arginine starvation in colorectal carcinoma cells: Sensing, impact on translation control and cell cycle distribution

Tumor cells rely on a continued exogenous nutrient supply in order to maintain a high proliferative activity. Although a strong dependence of some tumor types on exogenous arginine sources has been reported, the mechanisms of arginine sensing by tumor cells and the impact of changes in arginine availability on translation and cell cycle regulation are not fully understood. The results presented herein state that human colorectal carcinoma cells rapidly exhaust the internal arginine sources in the absence of exogenous arginine and repress global translation by activation of the GCN2-mediated pathway and inhibition of mTOR signaling. Tumor suppressor protein p53 activation and G{sub 1}/G{sub 0} cell cycle arrest support cell survival upon prolonged arginine starvation. Cells with the mutant or deleted TP53 fail to stop cell cycle progression at defined cell cycle checkpoints which appears to be associated with reduced recovery after durable metabolic stress triggered by arginine withdrawal. - Highlights: • Arginine withdrawal causes a rapid and dramatic drop of its intracellular level. • Starvation for arginine activates GCN2 and decreases mTOR cellular signaling. • Response to arginine starvation depends on p53 status of the cells.

60 APPLIED LIFE SCIENCES↗

Chemical-damage MINE: A database of curated and predicted spontaneous metabolic reactions

Spontaneous reactions between metabolites are often neglected in favor of emphasizing enzyme-catalyzed chemistry because spontaneous reaction rates are assumed to be insignificant under physiological conditions. However, synthetic biology and engineering efforts can raise natural metabolites' levels or introduce unnatural ones, so that previously innocuous or nonexistent spontaneous reactions become an issue. Problems arise when spontaneous reaction rates exceed the capacity of a platform organism to dispose of toxic or chemically active reaction products. While various reliable sources list competing or toxic enzymatic pathways' side-reactions, no corresponding compilation of spontaneous side-reactions exists, nor is it possible to predict their occurrence. We addressed this deficiency by creating the Chemical Damage (CD)-MINE resource. First, we used literature data to construct a comprehensive database of metabolite reactions that occur spontaneously in physiological conditions. We then leveraged this data to construct 148 reaction rules describing the known spontaneous chemistry in a substrate-generic way. We applied these rules to all compounds in the ModelSEED database, predicting 180,891 spontaneous reactions. The resulting (CD)-MINE is available at https://minedatabase.mcs.anl. gov/cdmine/#/home and through developer tools. We also demonstrate how damage-prone intermediates and end products are widely distributed among metabolic pathways, and how predicting spontaneous chemical damage helps rationalize toxicity and carbon loss using examples from published pathways to commercial products. We explain how analyzing damage-prone areas in metabolism helps design effective engineering strategies. Finally, we use the CD-MINE toolset to predict the formation of the novel damage product N-carbamoyl proline, and present mass spectrometric evidence for its presence in Escherichia coli.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Using naturally occurring radionuclides to determine drinking water age in a community water system

Drinking water quality in a community water system is closely linked to the age of water from initial treatment to time of delivery. However, water age is difficult to measure with conventional chemical tracers; particularly in stagnant water, where the relationship between disinfectant decay, microbial growth, and water age is poorly understood. Using radionuclides that were naturally present in source water, we found that measured activity ratios of 90 Y/ 90 Sr and 234 Th/ 238 U in discrete drinking water samples of known age accurately estimated water age up to 9 days old (σ est : ± 3.8 h, P < 0.0001, r 2 = 0.998, n = 11) and 25 days old (σ est : ± 13.3 h, P < 0.0001, r 2 = 0.996, n = 12), respectively. Moreover, 90 Y-derived water ages in a community water system (6.8 × 10 4 m 3 d –1 capacity) were generally consistent with water ages derived from an extended period simulation model. Radionuclides differ from conventional chemical tracers in that they are ubiquitous in distribution mains and connected premise plumbing. The ability to measure both water age and an analyte (e.g., chemical or microbe) in any water sample at any time allows for new insight into factors that control drinking water quality.

54 ENVIRONMENTAL SCIENCES↗

Disentangling the Impact of the COVID‐19 Lockdowns on Urban NO 2 From Natural Variability

Abstract TROPOMI satellite data show substantial drops in nitrogen dioxide (NO 2 ) during COVID‐19 physical distancing. To attribute NO 2 changes to NO x emissions changes over short timescales, one must account for meteorology. We find that meteorological patterns were especially favorable for low NO 2 in much of the United States in spring 2020, complicating comparisons with spring 2019. Meteorological variations between years can cause column NO 2 differences of ~15% over monthly timescales. After accounting for solar angle and meteorological considerations, we calculate that NO 2 drops ranged between 9.2% and 43.4% among 20 cities in North America, with a median of 21.6%. Of the studied cities, largest NO 2 drops (>30%) were in San Jose, Los Angeles, and Toronto, and smallest drops (<12%) were in Miami, Minneapolis, and Dallas. These normalized NO 2 changes can be used to highlight locations with greater activity changes and better understand the sources contributing to adverse air quality in each city.

54 ENVIRONMENTAL SCIENCES↗

Structural basis of G-quadruplex unfolding by the DEAH/RHA helicase DHX36

Guanine-rich nucleic acid sequences challenge the replication, transcription, and translation machinery by spontaneously folding into G-quadruplexes, the unfolding of which requires forces greater than most polymerases can exert. Eukaryotic cells contain numerous helicases that can unfold G-quadruplexes. The molecular basis of the recognition and unfolding of G-quadruplexes by helicases remains poorly understood. DHX36 (also known as RHAU and G4R1), a member of the DEAH/RHA family of helicases, binds both DNA and RNA G-quadruplexes with extremely high affinity, is consistently found bound to G-quadruplexes in cells, and is a major source of G-quadruplex unfolding activity in HeLa cell lysates. DHX36 is a multi-functional helicase that has been implicated in G-quadruplex-mediated transcriptional and post-transcriptional regulation, and is essential for heart development, haematopoiesis, and embryogenesis in mice. Here we report the co-crystal structure of bovine DHX36 bound to a DNA with a G-quadruplex and a 3' single-stranded DNA segment. Furthermore, we show that the N-terminal DHX36-specific motif folds into a DNA-binding-induced α-helix that, together with the OB-fold-like subdomain, selectively binds parallel G-quadruplexes. Comparison with unliganded and ATP-analogue-bound DHX36 structures, together with single-molecule fluorescence resonance energy transfer (FRET) analysis, suggests that G-quadruplex binding alone induces rearrangements of the helicase core; by pulling on the single-stranded DNA tail, these rearrangements drive G-quadruplex unfolding one residue at a time.

59 BASIC BIOLOGICAL SCIENCES↗

Fermi -LAT follow-up observations in seven years of real-time high-energy neutrino alerts

The realtime program for high-energy neutrino track events detected by the IceCube South Pole Neutrino Observatory releases alerts to the astronomical community with the goal of identifying electromagnetic counterparts to astrophysical neutrinos. Gamma-ray observations from theFermi-Large Area Telescope (LAT) enabled the identification of the flaring gamma-ray blazar TXS 0506+056 as a likely counterpart to the neutrino event IC-170922A. By continuously monitoring the gamma-ray sky,Fermi-LAT plays a key role in the identification of candidate counterparts to realtime neutrino alerts. In this paper, we present theFermi-LAT strategy for following up high-energy neutrino alerts applied to seven years of IceCube data. Right after receiving an alert, a search is performed in order to identify gamma-ray activity from known and newly detected sources that are positionally consistent with the neutrino localization. In this work, we study the population of blazars found in coincidence with high-energy neutrinos and compare them to the full population of gamma-ray blazars detected byFermi-LAT. We also evaluate the relationship between the neutrino and gamma-ray luminosities, finding different trends between the two blazar classes BL Lacs and flat-spectrum radio quasars.

Astronomy & Astrophysics↗

TRIGA MARK-II source term

ORIGEN 2.2 are employed to obtain data regarding γ source term and the radio-activity of irradiated TRIGA fuel. The fuel composition are specified in grams for use as input data. Three types of fuel are irradiated in the reactor, each differs from the other in terms of the amount of Uranium compared to the total weight. Each fuel are irradiated for 365 days with 50 days time step. We obtain results on the total radioactivity of the fuel, the composition of activated materials, composition of fission products and the photon spectrum of the burned fuel. We investigate the differences of results using BWR and PWR library for ORIGEN. Finally, we compare the composition of major nuclides after 1 year irradiation of both ORIGEN library with results from WIMS. We found only minor disagreements between the yields of PWR and BWR libraries. In comparison with WIMS, the errors are a little bit more pronounced. To overcome this errors, the irradiation power used in ORIGEN could be increased a little, so that the differences in the yield of ORIGEN and WIMS could be reduced. A more permanent solution is to use a different code altogether to simulate burnup such as DRAGON and ORIGEN-S. The result of this study are essential for the design of radiation shielding from the fuel.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Powerloads on the front end components and the duct of the heating and diagnostic neutral beam lines at ITER

The heating and current drive beam lines (HNB) at ITER are expected to deliver ∼16.7 MW power per beam line for H beams at 870 keV and D beams at 1 MeV during the H-He and the DD/DT phases of ITER operation respectively. On the other hand the diagnostic neutral beam (DNB) line shall deliver ∼2 MW power for H beams at 100 keV during both the phases. The path lengths over which the beams from the HNB and DNB beam lines need to be transported are 25.6 m and 20.7 m respectively. The transport of the beams over these path lengths results in beam losses, mainly by the direct interception of the beam with the beam line components and reionisation. The lost power is deposited on the surfaces of the various components of the beam line. In order to ensure the survival of these components over the operational life time of ITER, it is important to determine to the best possible extent the operational power loads and power densities on the various surfaces which are impacted by the beam in one way or the other during its transport. The main factors contributing to these are the divergence of the beamlets and the halo fraction in the beam, the beam aiming, the horizontal and vertical misalignment of the beam, and the gas profile along the beam path, which determines the re-ionisation loss, and the re-ionisation cross sections. The estimations have been made using a combination of the modified version of the Monte Carlo Gas Flow code (MCGF) and the BTR code. The MCGF is used to determine the gas profile in the beam line and takes into account the active gas feed into the ion source and neutraliser, the HNB-DNB cross over, the gas entering the beamline from the ITER machine, the additional gas atoms generated in the beam line due to impacting ions and the pumping speed of the cryopumps. The BTR code has been used to obtain the power loads and the power densities on the various surfaces of the front end components and the duct modules for different scenarios of ITER operation. The gas profile and the magnetic field distribution for each scenario has been considered in these evaluations. The worst case power loads and power densities for each surface have been used to study their thermo-mechanical behaviour and manufacturing feasibility. The details of these calculations and results obtained are presented and discussed.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Control of an average output power of a CuBr laser

We have studied the pump parameters of a CuBr laser (pulse repetition rate of 14 kHz) with an independent heating of the active medium and an additional excitation source, providing an operational control of the radiation parameters in a given time interval. We have fabricated an experimental setup that makes it possible to change the average output power by applying a control pulse which is ahead of the main pulse by 0.12 - 20 {mu}s. It is shown that to ensure the effective control of the laser power, the voltage amplitude of the additional excitation pulse should be within 12 % - 28 % of the main pulse amplitude. In this case, the proposed control regime allows a 2.5-fold decrease in the time delay between the control and main excitation pulses due to a higher energy of the additional pulse compared to self-heating regime of the laser operation.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Free energy change of a dislocation due to a Cottrell atmosphere

The free energy reduction of a dislocation due to a Cottrell atmosphere of solutes is computed using a continuum model. In this work, we show that the free energy change is composed of near-core and far-field components. The far-field component can be computed analytically using the linearized theory of solid solutions. Near the core the linearized theory is inaccurate, and the near-core component must be computed numerically. The influence of interactions between solutes in neighbouring lattice sites is also examined using the continuum model. We show that this model is able to reproduce atomistic calculations of the nickel–hydrogen system, predicting hydride formation on dislocations. The formation of these hydrides leads to dramatic reductions in the free energy. Lastly, the influence of the free energy change on a dislocation’s line tension is examined by computing the equilibrium shape of a dislocation shear loop and the activation stress for a Frank–Read source using discrete dislocation dynamics.

42 ENGINEERING↗

EXTENDED TAILS FROM SGR 1806-20 BURSTS

In 2004, SGR 1806-20 underwent a period of intense and long-lasting burst activity that included the giant flare of 2004 December 27-the most intense extra-solar transient event ever detected at Earth. During this active episode, we routinely monitored the source with Rossi X-ray Timing Explorer and occasionally with Chandra. During the course of these observations, we identified two relatively bright bursts observed with Konus-Wind in hard X-rays that were followed by extended X-ray tails or afterglows lasting hundreds to thousands of seconds. Here, we present detailed spectral and temporal analysis of these events observed about 6 and 1.5 months prior to the 2004 December 27 giant flare. We find that both X-ray tails are consistent with a cooling blackbody of constant radius. These spectral results are qualitatively similar to those of the burst afterglows recorded from SGR 1900+14 and recently from SGR 1550-5418. However, the latter two sources exhibit significant increase in their pulsed X-ray intensity following the burst, while we did not detect any significant changes in the rms pulsed amplitude during the SGR 1806-20 events. Moreover, we find that the fraction of energy partitioned to the burst (prompt energy release) and the tail (afterglow) differs by an order of magnitude between SGR 1900+14 and SGR 1806-20. We suggest that such differences can be attributed to differences in the crustal heating mechanism of these neutron stars combined with the geometry of the emitting areas.

79 ASTRONOMY AND ASTROPHYSICS↗

DISK MASS-TO-LIGHT RATIO DISTRIBUTION FROM STELLAR POPULATION SYNTHESIS: APPLICATION TO ROTATION CURVE DECOMPOSITION OF NGC 5278 (KPG 390 A)

In this work we extend the study on the mass distribution of the spiral galaxy NGC 5278, performing 1D and 2D (GALFIT) bulge-disk decomposition to determine which components constitute the baryonic mass in this galaxy. Our analysis does not detect any bulge; instead we find a bright source probably related to the central active galactic nucleus and an exponential disk. We fix the stellar disk contribution to the rotation curve (RC) with broadband photometric observations and population synthesis models, to obtain the 2D mass distribution of the stellar disk. In the particular case of NGC 5278, we find that the typical assumption of considering the mass-to-luminosity ratio (M/L) of the disk as constant along the galactocentric radius is not valid. We also extract a baryonic RC from the mass profile to determine the inability of this baryonic RC and also the baryonic RC with more than and less than 30% disk mass (in order to consider the disk mass errors) to fit the entire RC. We perform the RC decomposition of NGC 5278 by considering the baryonic RC and four types of dark matter (DM) halo: Hernquist, Burkert, Navarro, Frenk, and White, and Einasto. Our results determine that the Hernquist DM halo better models our observed RC in the case of disk mass M{sub d} = 5.6 Multiplication-Sign 10{sup 10} M {sub Sun} and also with less than 30% disk mass. In the case of more than 30% disk mass, the cored Einasto (n < 4) DM halo is the best-fitting model.

79 ASTRONOMY AND ASTROPHYSICS↗

The beaming pattern of external Compton emission from relativistic outflows: The case of anisotropic distribution of electrons

The beaming pattern of radiation emitted by a relativistically moving source, such as jets in microquasars, active galactic nuclei, and gamma-ray bursts, is a key issue for understanding acceleration and radiation processes in these objects. In this paper, we introduce a formalism based on a solution of the photon transfer equation to study the beaming patterns for emission produced by electrons accelerated in the jet and the upscattering photons of low-energy radiation fields of external origin (the so-called external Compton scenario). The formalism allows us to treat non-stationary, non-homogeneous, and anisotropic distributions of electrons, but assuming homogeneous/isotropic and non-variable target photon fields. We demonstrate the non-negligible impact of the anisotropy in the electron distribution on angular and spectral characteristics of the EC radiation.

79 ASTRONOMY AND ASTROPHYSICS↗

A multi-wavelength view of the central kiloparsec region in the luminous infrared galaxy NGC 1614

The Luminous Infrared Galaxy NGC 1614 hosts a prominent circumnuclear ring of star formation. However, the nature of the dominant emitting mechanism in its central ∼100 pc is still under debate. We present sub-arcsecond angular resolution radio, mid-infrared, Paα, optical, and X-ray observations of NGC 1614, aimed at studying in detail both the circumnuclear ring and the nuclear region. The 8.4 GHz continuum emission traced by the Very Large Array and the Gemini/T-ReCS 8.7 μm emission, as well as the Paα line emission, show remarkable morphological similarities within the star-forming ring, suggesting that the underlying emission mechanisms are tightly related. We used a Hubble Space Telescope/NICMOS Paα map of similar resolution to our radio maps to disentangle the thermal free-free and non-thermal synchrotron radio emission, from which we obtained the intrinsic synchrotron power law for each individual region within the central kiloparsec of NGC 1614. The radio ring surrounds a relatively faint, steep-spectrum source at the very center of the galaxy, suggesting that the central source is not powered by an active galactic nucleus (AGN), but rather by a compact (r ≲ 90 pc) starburst (SB). Chandra X-ray data also show that the central kiloparsec region is dominated by SB activity, without requiring the existence of an AGN. We also used publicly available infrared data to model-fit the spectral energy distribution of both the SB ring and a putative AGN in NGC 1614. In summary, we conclude that there is no need to invoke an AGN to explain the observed bolometric properties of the galaxy.

79 ASTRONOMY AND ASTROPHYSICS↗

An ALMA survey of submillimeter galaxies in the extended Chandra deep field south: The redshift distribution and evolution of submillimeter galaxies

We present the first photometric redshift distribution for a large sample of 870 μm submillimeter galaxies (SMGs) with robust identifications based on observations with ALMA. In our analysis we consider 96 SMGs in the Extended Chandra Deep Field South, 77 of which have 4-19 band photometry. We model the SEDs for these 77 SMGs, deriving a median photometric redshift of z {sub phot} = 2.3 ± 0.1. The remaining 19 SMGs have insufficient photometry to derive photometric redshifts, but a stacking analysis of Herschel observations confirms they are not spurious. Assuming that these SMGs have an absolute H-band magnitude distribution comparable to that of a complete sample of z ∼ 1-2 SMGs, we demonstrate that they lie at slightly higher redshifts, raising the median redshift for SMGs to z {sub phot} = 2.5 ± 0.2. Critically we show that the proportion of galaxies undergoing an SMG-like phase at z ≥ 3 is at most 35% ± 5% of the total population. We derive a median stellar mass of M {sub *} = (8 ± 1) × 10{sup 10} M {sub ☉}, although there are systematic uncertainties of up to 5 × for individual sources. Assuming that the star formation activity in SMGs has a timescale of ∼100 Myr, we show that their descendants at z ∼ 0 would have a space density and M{sub H} distribution that are in good agreement with those of local ellipticals. In addition, the inferred mass-weighted ages of the local ellipticals broadly agree with the look-back times of the SMG events. Taken together, these results are consistent with a simple model that identifies SMGs as events that form most of the stars seen in the majority of luminous elliptical galaxies at the present day.

79 ASTRONOMY AND ASTROPHYSICS↗

SHORT-TIMESCALE MONITORING OF THE X-RAY, UV, AND BROAD DOUBLE-PEAK EMISSION LINE OF THE NUCLEUS OF NGC 1097

Recent studies have suggested that the short-timescale (≲ 7 days) variability of the broad (∼10,000 km s{sup –1}) double-peaked Hα profile of the LINER nucleus of NGC 1097 could be driven by a variable X-ray emission from a central radiatively inefficient accretion flow. To test this scenario, we have monitored the NGC 1097 nucleus in X-ray and UV continuum with Swift and the Hα flux and profile in the optical spectrum using SOAR and Gemini-South from 2012 August to 2013 February. During the monitoring campaign, the Hα flux remained at a very low level—three times lower than the maximum flux observed in previous campaigns and showing only limited (∼20%) variability. The X-ray variations were small, only ∼13% throughout the campaign, while the UV did not show significant variations. We concluded that the timescale of the Hα profile variation is close to the sampling interval of the optical observations, which results in only a marginal correlation between the X-ray and Hα fluxes. We have caught the active galaxy nucleus in NGC 1097 in a very low activity state, in which the ionizing source was very weak and capable of ionizing just the innermost part of the gas in the disk. Nonetheless, the data presented here still support the picture in which the gas that emits the broad double-peaked Balmer lines is illuminated/ionized by a source of high-energy photons which is located interior to the inner radius of the line-emitting part of the disk.

79 ASTRONOMY AND ASTROPHYSICS↗