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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,621 records · Page 90
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Investigation into the Role of Surface Modification of Cellulose Nanocrystals with Succinic Anhydride in Dye Removal

Herein, the effect of surface modification of cellulose nanocrystals (CNC) on the sorption of dyes from waste textile effluent (methylene blue as a model) was achieved. The esterification of the isolated CNC from wood sawdust by acid hydrolysis was performed through melting with succinic anhydride (SA). At using 1:3–1:9 as the feeding ratios of CNC to SA, the succinylated CNC (CNC-SA) was obtained with degree of substitution of 1.6–2.2 and carboxylic content of 286.8–381.7 mmol/kg. Both of diameter size and zeta potential of the prepared CNC-SA were gradually enlarged by increasing the reactant feed ratio, indicating the successful modification of CNC surface with highly stable particles via increasing the negative charges on the outer surface. FTIR and XRD affirmed the change in the chemical structure as well as crystallinity of CNC after succinylation reaction. The prepared succinylated CNC was applied in the removal of methylene blue (MB) dye and the data showed that the sorption capacity is a direct proportional linear relation with the contents of carboxylic group. Within 120 min contact time, the sorption capacity was enlarged from 64.1 mg/g for CNC to 84.1 mg/g for CNC-SA3. The sorption data was fitted well to the first order kinetic model. Due to the esterification, the rate of sorption reaction is accelerated by double factor. These findings will maximize the benefit of esterified CNC in water treatment.

36 MATERIALS SCIENCE↗
NASA NTRS2020

Hexcomb Pattern Roughness Effects on Blunt Body Transition and Heating

An experimental investigation of hexcomb pattern surface roughness effects on boundary-layer transition and convective heating has been performed. Two representative entry vehicle geometries, a spherical-cap aeroshell and a sphere-cone aeroshell, were considered. Multiple cast ceramic models of each geometry were fabricated with various roughness pattern densities and depths that simulated an ablated hexcomb-structure thermal protection system. Wind tunnel testing was performed at Mach 6 over a range of Reynolds numbers sufficient to produce laminar, transitional, and turbulent flow. Aeroheating and boundary-layer transition onset data were obtained using global phosphor thermography. The experimental heating data are presented herein, as are comparisons to laminar and turbulent smooth-wall heat transfer distributions from computational flow field simulations. The experimental data were used to develop a unified boundary-layer transition correlation for both sandgrain distributed roughness and hexcomb pattern roughness.

Brian R Hollis↗
DOE OSTI2019

The Effects of Hydrogen Iodide Back Surface Treatment on CdTe Solar Cells

An appropriate electrical back contact in CdTe solar cells is crucial to achieving high power conversion efficiency. In this work, we develop a facile back surface treatment method for CdTe solar cells using hydroiodic acid (HI) and investigate the effects of HI etching on the CdTe surfaces. The electrical properties of the CdTe absorber and interfaces are characterized by current-voltage, capacitance-voltage, admittance spectroscopy, and complex capacitance spectroscopy measurements. Here, the HI-etched devices show slightly higher apparent carrier concentrations than the control devices, suggesting an increased copper doping in the CdTe absorber. The potential barrier height of the back contact is reduced from 0.430 to 0.368 eV after the HI-treatment, accompanied by reduced contact resistance and carrier recombination. Additionally, the HI-treatment eliminates a defect signature at 0.409 eV. All of these HI-treatment effects lead to improved power conversion efficiency of CdTe solar cells through enhancement of the fill factor, the short circuit current, and open circuit voltage in order of significance.

14 SOLAR ENERGY↗
NASA NTRS1975

Analysis of ground reflection of jet noise obtained with various microphone arrays over an asphalt surface

Ground reflection effects on the propagation of jet noise over an asphalt surface are discussed for data obtained using a 33.02-cm diameter nozzle with microphones at several heights and distances from the nozzle axis. Ground reflection effects are analyzed using the concept of a reflected signal transfer function which represents the influence of both the reflecting surface and the atmosphere on the propagation of the reflected signal in a mathematical model. The mathematical model used as a basis for the computer program was successful in significantly reducing the ground reflection effects. The range of values of the single complex number used to define the reflected signal transfer function was larger than expected when determined only by the asphalt surface. This may indicate that the atmosphere is affecting the propagation of the reflected signal more than the asphalt surface. The selective placement of the reinforcements and cancellations in the design of an experiment to minimize ground reflection effects is also discussed.

Miles, J. H.↗
NASA NTRS1975

Analysis of ground reflection of jet noise obtained with various microphone arrays over an asphalt surface

Ground reflection effects on the propagation of jet noise over an asphalt surface are discussed for data obtained using a 33.02 cm (13-in.) diameter nozzle with microphones at several heights and distances from the nozzle axis. Analysis of ground reflection effects is accomplished using the concept of a reflected signal transfer function which represents the influence of both the reflecting surface and the atmosphere on the propagation of the reflected signal in a mathematical model. The mathematical model used as a basis for the computer program was successful in significantly reducing the ground reflection effects. The range of values of the single complex number used to define the reflected signal transfer function was larger than expected when determined only by the asphalt surface. This may indicate that the atmosphere is affecting the propagation of the reflected signal more than the asphalt surface. Also discussed is the selective placement of the reinforcements and cancellations in the design of an experiment to minimize ground reflection effects.

Miles, J. H.↗
DOE OSTI2018

Effect of Mica and Hematite (001) Surfaces on the Precipitation of Calcite

The substrate effect of mica and hematite on the nucleation and crystallization of calcite was investigated using scanning electron microscope (SEM), X-ray diffraction (XRD), and electron backscatter diffraction (EBSD) methods. On mica, we found, in the absence of Mg 2+ , the substrates’ (001) surfaces with hexagonal and pseudo-hexagonal two-dimensional (2-D) structure can affect the orientation of calcite nucleation with calcite (001) ~// mica (001) and calcite (010) ~// mica (010) to be the major interfacial relationship. On hematite, we did not observe frequent twinning relationship between adjacent calcite gains, but often saw preferentially nucleation of calcite at surface steps on hematite substrate. We suggest that calcite crystals initially nucleate from the Ca 2+ layers adsorbed on the surfaces. The pseudo-hexagonal symmetry on mica (001) surface also leads to the observed calcite (001) twinning. A second and less common orientation between calcite {104} and mica (001) was detected but could be due to local structure damage of the mica surface. Results in the presence of Mg 2+ show that the substrate surfaces can weaken Mg toxicity to calcite nucleation and lead to a higher level of Mg incorporation into calcite lattice.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Low-temperature Leidenfrost-like jumping of sessile droplets on microstructured surfaces

The Leidenfrost effect—the levitation and hovering of liquid droplets on hot solid surfaces—generally requires a sufficiently high substrate temperature to activate liquid vaporization. Here, in this paper, we report the modulation of Leidenfrost-like jumping of sessile water microdroplets on micropillared surfaces at a relatively low temperature. Compared to traditional Leidenfrost effect occurring above 230 °C, the fin-array-like micropillars enable water microdroplets to levitate and jump off the surface within milliseconds at a temperature of 130 °C by triggering the inertia-controlled growth of individual vapour bubbles at the droplet base. We demonstrate that droplet jumping, resulting from momentum interactions between the expanding vapour bubble and the droplet, can be modulated by tailoring of the thermal boundary layer thickness through pillar height. This enables regulation of the bubble expansion between the inertia-controlled mode and the heat-transfer-limited mode. The two bubble-growth modes give rise to distinct droplet jumping behaviours characterized by constant velocity and constant energy regimes, respectively. This heating strategy allows the straightforward purging of wetting liquid droplets on rough or structured surfaces in a controlled manner, with potential applications including the rapid removal of fouling media, even when located in surface cavities.

42 ENGINEERING↗
NASA NTRS1975

The effects of environmental exposure on reusable surface insulation for space shuttle

Coated specimens of reusable surface insulation (RSI) were exposed to alternate radiant heating and atmospheric exposure cycles to study the effects of surface contamination on the RSI coating. Different methods of heating were employed on clean and artificially contaminated specimens to determine the contributions of heating conditions to coating devitrification.

Ransone, P. O.↗
NASA NTRS1976

Classifying and monitoring water quality by use of satellite imagery

A technique is developed to eliminate the atmosphere and surface noise effects on Landsat signals of water bodies by manipulating the total signal from Landsat in such a way that only the volume reflectance is left as a residual. With the Landsat signal from a lake and the known volume reflectance for its clear water it is possible to eliminate the surface and atmospheric effects and have residual signals that are indicative only of the type and concentration of the material in other lakes. Laboratory values are more precise than field values because in the field one must contend with indirect skylight and wave action which can be removed in the laboratory. The volume reflectance of distilled water or a very clear lake approaching distilled water was determined in the laboratory by the use of the Bendix radiant power measuring instrument. The Bendix multispectral data analysis system provided a color categorized image of several hundred lakes in a Wisconsin area. These lakes were categorized for tannin and nontannin waters and for the degrees of algae, silt, weeds, and bottom effects present.

Scherz, J. P.↗
NASA NTRS1982

Investigation of surface tension phenomena using the KC-135 aircraft

The microgravity environment of the KC-135 aircraft was utilized in three experiments designed to determine the following: (1) the feasibility of measuring critical wetting temperatures; (2) the effectiveness of surface tension as a means of keeping the cushioning heat transfer liquid in the furnace during ampoule translation; and (3) whether a non-wetting fluid would separate from the ampoule wall under low gravity conditions. This trio of investigations concerning surface phenomena demonstrates the effectiveness of the KC-135 as a microgravity research environment for small-scale, hand-held experiments.

Alter, W. S.↗
DOE OSTI2021

The influence of surface heat fluxes on the growth of idealized monsoon depressions

This study explores the effect of surface sensible and latent heat fluxes on monsoon depressions using a series of idealized convection-permitting simulations. Each experiment is initialized with a small-amplitude wave that is allowed to grow within an environment representative of the South Asian monsoon. Comparing experiments with and without interactive surface heat fluxes, it is found that these fluxes enhance the growth of the simulated vortices. Without interactive surface fluxes, the strengthening period is short and the vortices fail to reach intensities characteristic of stronger monsoon depressions. Using a large set of experiments in which the vertical and meridional shear are systematically varied, it is found that surface heat fluxes enhance intensity the most when the upper-level shear is weak, the lower-level shear and associated moist static energy (MSE) gradient are sufficiently steep, and the lower-level meridional shear is strong. Here, these experiments reveal two different regimes of convection-coupled monsoon depression growth: one in which convection is driven by MSE advection and one in which it is driven by surface heat fluxes and quasigeostrophic forcing for ascent. Both regimes require sufficiently strong meridional shear to achieve initial growth by barotropic instability.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1987

The behavior of surface tension on steady-state rotating fluids in the low gravity environments

The effect of surface tension on steady-state rotating fluids in a low gravity environment is studied. All the values of the physical parameters used in these calculations, except in the low gravity environments, are based on the measurements carried out by Leslie (1985) in the low gravity environment of a free-falling aircraft. The profile of the interface of two fluids is derived from Laplace's equation relating the pressure drop across an interface to the radii of curvature which has been applied to a low gravity rotating bubble that contacts the container boundary. The interface shape depends on the ratio of gravity to surface tension forces, the ratio of centrifugal to surface tension forces, the contact radius of the interface to the boundary, and the contact angle. The shape of the bubble is symmetric about its equator in a zero-gravity environment. This symmetry disappears and gradually shifts to parabolic profiles as the gravity environment becomes non-zero. The location of the maximum radius of the bubble moves upward from the center of the depth toward the top boundary of the cylinder as gravity increases. The contact radius of interface to the boundary r0 at the top side of cylinder increases and r0 at the bottom side of the cylinder decreases as the gravity environment increases from zero to 1 g.

Hung, R. J.↗
NASA NTRS1994

Transonic flight test of a laminar flow leading edge with surface excrescences

A flight experiment, conducted at NASA Dryden Flight Research Center, investigated the effects of surface excrescences, specifically gaps and steps, on boundary-layer transition in the vicinity of a leading edge at transonic flight conditions. A natural laminar flow leading-edge model was designed for this experiment with a spanwise slot manufactured into the leading-edge model to simulate gaps and steps like those present at skin joints of small transonic aircraft wings. The leading-edge model was flown with the flight test fixture, a low-aspect ratio fin mounted beneath an F-104G aircraft. Test points were obtained over a unit Reynolds number range of 1.5 to 2.5 million/ft and a Mach number range of 0.5 to 0.8. Results for a smooth surface showed that laminar flow extended to approximately 12 in. behind the leading edge at Mach number 0.7 over a unit Reynolds number range of 1.5 to 2.0 million/ft. The maximum size of the gap-and-step configuration over which laminar flow was maintained consisted of two 0.06-in. gaps with a 0.02-in. step at a unit Reynolds number of 1.5 million/ft.

Zuniga, Fanny A.↗
DOE OSTI2023

Exchange-Driven Intermixing of Bulk and Topological Surface States by Chiral Excitons in Bi 2 Se 3

Topological surface states (TSS) in the prototypical topological insulator (TI) Bi 2 Se 3 are frequently characterized using optical probes, but electron-hole interactions and their effect on surface localization and optical response of the TSS remain unexplored. Here, we use ab initio calculations to understand excitonic effects in the bulk and surface of Bi 2 Se 3 . We identify multiple series of chiral excitons that exhibit both bulk and TSS character, due to exchange-driven mixing. Further, our results address fundamental questions about the degree to which electron-hole interactions can relax the topological protection of surface states and dipole selection rules for circularly polarized light in TIs by elucidating the complex intermixture of bulk and surface states excited in optical measurements and their coupling to light.

42 ENGINEERING↗
NASA NTRS1999

Validation of Satellite Retrieved Land Surface Variables

The effective use of satellite observations of the land surface is limited by the lack of high spatial resolution ground data sets for validation of satellite products. Recent large scale field experiments include FIFE, HAPEX-Sahel and BOREAS which provide us with data sets that have large spatial coverage and long time coverage. It is the objective of this paper to characterize the difference between the satellite estimates and the ground observations. This study and others along similar lines will help us in utilization of satellite retrieved data in large scale modeling studies.

Lakshmi, Venkataraman↗
NASA NTRS1999

Validation of Satellite Retrieved Land Surface Variables

The effective use of satellite observations of the land surface is limited by the lack of high spatial resolution ground data sets for validation of satellite products. Recent large scale field experiments include FIFE, HAPEX-Sahel and BOREAS which provide us with data sets that have large spatial coverage and long time coverage. It is the objective of this paper to characterize the difference between the satellite estimates and the ground observations. This study and others along similar lines will help us in utilization of satellite retrieved data in large scale modeling studies.

Lakshmi, Venkataraman↗