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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,621 records · Page 90
All sourcesNASA NTRSDOE OSTI
DOE OSTI2015

Numerical investigation on transverse heat transfer properties in cross section of full size Nb{sub 3}Sn CICC ITER conductor

The contact mechanical characteristics in the cross section of the Nb{sub 3}Sn cable are sensitive to the cryogenic cooling and cyclic transverse electromagnetic loads, which may affect the cable’s performance. In this paper, based on a proposed discrete dynamic model (DEM), where the contact heat transfer among strands and the convective heat transfer in liquid helium are taken into account, the cooling process under two heat transfer mechanisms is performed. Simulation results show that the temperature variation of Poloidal Field Insert Sample (PFIS) cable with time agrees well with the existing experimental results, and the role of contact heat transfer cannot be neglected during cryogenic cooling. It is obtained from the further analysis that the effect of contact heat transfer becomes more prominent with the decrease of mass flow rate of liquid helium, which leads to the stress status within cable changed significantly. With the temperature boundary condition imposed on the cable radial direction, the effective thermal conductivity (ETC) of cable can be obtained. It can be found that the ETC increases with increasing the transverse loads and is sensitive to the low temperature environment, while it is not affected by load cycles basically. These results may provide the guide for the design and application of the future CICC conductors.

36 MATERIALS SCIENCE↗
NASA NTRS1991

Comparison of spectroscopic properties of Tm and Ho in YAG and YLF crystals

The paper compares the cross-relaxation, energy transfer and loss processes in Tm- and Ho-doped YAG and YLF as a function of temperature, Tm concentration, and excitation power. Significant differences in the behavior of Tm and Tm,Ho in YAG and YLF crystals were found. The cross-relaxation rates of Tm(6 pct) are faster in YLF (about 5 microsec) than YAG (about 10 microsec). The energy transfer rates between Tm and Ho are faster in YLF than YAG. The time it takes for the maximum intensity of 1.7-micron emission to drop 10 percent is 25 microsec for YLF:Tm(6 pct),Ho(0.6 pct) and 65 microsec YAG:Tm(6 pct),Ho(0.5 pct). The losses occurring with increasing pump power for 2.1-micron emission of the above samples are 30 percent less in YLF than YAG. These qualitative differences point to YLF as a valuable 2-micron laser host material.

Armagan, G.↗
NASA NTRS1994

A realistic model of evaporation for a liquid droplet

An intuitive delineation along with dimensional considerations and experimental evidences are presented to show that in a general case, the evaporation of a liquid droplet undergoes three regimes through the process. Initially, the heat transfer inside the evaporating droplets is conduction controlled; then, in the second stage, convective heat transfer may take over; finally, the convections subside, and the process returns to conduction controlled mode.

Chai, An-Ti↗
DOE OSTI2020

A Dose Assessment Model for Radioactive Waste Exposed by Gully Erosion at West Valley - 20513

The Western New York Nuclear Service Center (WNYNSC), located approximately 48 km south of Buffalo, New York, is the site of a former nuclear fuel reprocessing and radioactive waste disposal facility. Spent nuclear fuel was processed there from 1966 to 1972, leaving behind radioactive and chemical wastes in two disposal areas and a waste tank farm. Site operations also resulted in releases of radioactivity to site soils, groundwater, and to surface waters draining the site. The New York State Energy Research and Development Authority (NYSERDA) and the U.S. Department of Energy (DOE) are collaborating in a process of decision making for decommissioning those facilities remaining at the WNYNSC following the completion of Phase 1 decommissioning. Neptune and Company, Inc. (Neptune) was contracted to develop a probabilistic performance assessment (PPA) computer model to assist the agencies in this process. The PPA Model includes a contaminant transport component focusing on the movement of contaminants within and among environmental media including groundwater and surface water transport, contaminant translocation by plants and animals, diffusion, and erosion. The model also includes evaluation of potential exposure and health effects for a Resident Farmer exposure scenario, where the Resident Farmer represents a critical group, described as that group of individuals reasonably expected to receive the greatest exposure to residual radioactivity for any applicable set of circumstances. The West Valley Site is located in the glaciated Allegheny Plateau region of western New York State. The waste reprocessing and disposal areas were constructed on a relatively fat area of plateau dissected by drainages of Buttermilk Creek, including Erdman Brook, Franks Creek, and Quarry Creek. An important aspect of the contaminant transport component of the PPA model is consideration of erosive processes such as slumping of the stream slopes and the advance of gullies from these streams. These erosion processes remove material from the plateau, growing the size of the creek valleys and making them wider and deeper. Of particular interest for the impact of erosion is radioactive waste contained in the Nuclear Regulatory Commission (NRC)-Licensed Disposal Area (NDA), the New York State-Licensed Disposal Area (SDA), and residual radiological inventory in the underground storage tanks at the Waste Tank Farm (WTF). The PPA Model is organized around geographically-defined facilities which were constructed upon the plateau, including the NDA, SDA, and WTF. Ongoing stream erosion processes will potentially transfer radioactive waste and residual inventory from these facilities to the ground surface on adjacent hillslope areas where erosion has breached the facility. Hence, it is important to evaluate the consequences of potential exposures to a Resident Farmer on the hillslopes below a breached facility. Two interrelated aspects of the dose assessment model related to hillslope exposure are discussed: 1) representation of the physical processes related to transport of radionuclides from facilities onto the hillslopes, and from the hillslopes into adjoining creeks where contaminated material migrates downstream with surface water and sediment, and; 2) adaptation of the activities associated with the Resident Farmer scenario to assess potential exposures to contamination in the hillslope areas. This discussion will cover the conceptual basis of the hillslope exposure and transport models, and also implementation in the PPA computer model. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2015

Groundwork for Universal Canister System Development

The mission of the United States Department of Energy’s Office of Environmental Management is to complete the safe cleanup of the environmental legacy brought about from five decades of nuclear weapons development and government-sponsored nuclear energy research. Some of the wastes that that must be managed have been identified as good candidates for disposal in a deep borehole in crystalline rock (SNL 2014a). In particular, wastes that can be disposed of in a small package are good candidates for this disposal concept. A canister-based system that can be used for handling these wastes during the disposition process (i.e., storage, transfers, transportation, and disposal) could facilitate the eventual disposal of these wastes. This report provides information for a program plan for developing specifications regarding a canister-based system that facilitates small waste form packaging and disposal and that is integrated with the overall efforts of the DOE’s Office of Nuclear Energy Used Fuel Disposition Campaign's Deep Borehole Field Test. Wastes to be considered as candidates for the universal canister system include capsules containing cesium and strontium currently stored in pools at the Hanford Site, cesium to be processed using elutable or nonelutable resins at the Hanford Site, and calcine waste from Idaho National Laboratory. The initial emphasis will be on disposal of the cesium and strontium capsules in a deep borehole that has been drilled into crystalline rock. Specifications for a universal canister system are derived from operational, performance, and regulatory requirements for storage, transfers, transportation, and disposal of radioactive waste. Agreements between the Department of Energy and the States of Washington and Idaho, as well as the Deep Borehole Field Test plan provide schedule requirements for development of the universal canister system. Future work includes collaboration with the Hanford Site to move the cesium and strontium capsules into dry storage, collaboration with the Deep Borehole Field Test to develop surface handling and emplacement techniques and to develop the waste package design requirements, developing universal canister system design options and concepts of operations, and developing system analysis tools. Areas in which further research and development are needed include material properties and structural integrity, in-package sorbents and fillers, waste form tolerance to heat and postweld stress relief, waste package impact limiters, sensors, cesium mobility under downhole conditions, and the impact of high pressure and high temperature environment on seals design.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2017

Synergies between Unsaturated Zn/Cu Doping Sites in Carbon Dots Provide New Pathways for Photocatalytic Oxidation

Unsaturated metal species (UMS) confined in nanomaterials play important roles for electron transfer in a wide range of catalytic reactions. However, the limited fabrication methods of UMS restrict their wider catalytic applications. Here in this paper, we report on the synergy of unsaturated Zn and Cu dopants confined in carbon dots (ZnCu-CDs) to produce enhanced electron transfer and photooxidation processes in the doped CDs. The Zn/Cu species chelate with the carbon matrix mainly through Cu-O(N)-Zn-O(N)-Cu complexes. Within this structure, Cu 2+ acts as a mild oxidizer that facilely increases the unsaturated Zn content and also precisely tunes the unsaturated Zn valence state to Zn d+ , where d is between 1 and 2, instead of Zn. With the help of UMS, electron-transfer pathways are produced, enhancing both the electron donating (7.0 times) and-accepting (5.3 times) abilities relative to conventional CDs. Because of these synergistic effects, the photocatalytic efficiency of CDs in photooxidation reactions is shown to improve more than 5-fold.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2020

Thermodynamic and kinetic hydricity of transition metal hydrides

The prevalence of transition metal-mediated hydride transfer reactions in chemical synthesis, catalysis, and biology has inspired the development of methods for characterizing the reactivity of transition metal hydride complexes. Thermodynamic hydricity represents the free energy required for heterolytic cleavage of the metal–hydride bond to release a free hydride ion, H - , as determined through equilibrium measurements and thermochemical cycles. Kinetic hydricity represents the rate of hydride transfer from one species to another, as measured through kinetic analysis. This tutorial review describes the common methods for experimental and computational determination of thermodynamic and kinetic hydricity, including advice on best practices and precautions to help avoid pitfalls. The influence of solvation on hydricity is emphasized, including opportunities and challenges arising from comparisons across several different solvents. Connections between thermodynamic and kinetic hydricity are discussed, and opportunities for utilizing these connections to rationally improve catalytic processes involving hydride transfer are highlighted.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

An Assessment of the Materials of Construction for the Transfer Lines and Unit Operations Equipment Associated with the Recycle Diversion Process

The Defense Waste Processing Facility (DWPF) processes and vitrifies radioactive waste that it receives from the Concentration, Storage, and Transfer Facility (CSTF) and Salt Waste Processing Facility (SWPF). As a result of the evaporation of water during both the melter feed preparation and the melter feed vitrification steps in DWPF, a recycle waste stream is generated, neutralized, and sent back to the CSTF. The recycle waste is a dilute water stream originating from the collection of condensate liquids containing some minor sludge and frit solids and other waste components primarily resulting from entrainment into the condensate during foam-over events. The recycle stream volume is significant and is expected to approach 3 million gallons per year once the SWPF reaches full operation. Diverting the bulk of the recycle waste stream from the CSTF is essential for the eventual closure of the waste tanks, and hence the completion of the SRS liquid waste mission.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2025

Isotope-dependent Tafel analysis probes proton transfer kinetics during electrocatalytic water splitting

Proton transfer plays an important role in both hydrogen and oxygen evolution reactions during electrocatalytic water splitting to produce green hydrogen. However, directly adapting the conventional proton/deuterium kinetic isotope effect to study proton transfer in heterogeneous electrocatalytic processes is challenging. Here we propose using the shift in the Tafel slope between protic and deuteric electrolytes, or the Tafel slope isotope effect, as an effective probe of proton transfer characteristics. Comparison of the Tafel slope isotope effect for diverse hydrogen and oxygen evolution reaction electrocatalysts in different pH environments reveals that proton transfer is both pH and structure dependent. Using ruthenium oxide as an example, we show that local structure modification can change the rate-determining step from an electrochemical, concerted proton–electron transfer step to a chemical step and improve the oxygen evolution activity in acid. The isotope-dependent Tafel analysis will facilitate a better understanding of the proton transfer behaviours during electrocatalytic processes and provide guidance for designing efficient electrocatalysts.

Chemistry↗
DOE OSTI2015

Complex software dedicated for design and simulation of LPCE process for heavy water detritiation

The main purpose of this paper is to present a comprehensive software, SICA, designed to be used in water-hydrogen liquid phase catalytic exchange process (LPCE). The software calculates the water-gas catalytic isotopic exchange process, following the transfer of any H, D or T isotope from water to gas and vice versa. This software is useful for both design and laboratory-based research; the type of the catalytic filling (ordered or random) can be defined for any of these 2 cases, the isotopic calculation being specific to the package type. For the laboratory-based research, the performance of a catalytic packing can be determined by knowing the type and by using experimental results. Performance of the mixed catalytic packing is defined by mass transfer constants for each catalytic and hydrophilic package in that specific arrangement, and also for the isotope whose transfer is studied from one phase to another. Also, it has been established a link between these constants and commonly used parameters for the fillings performance defined by HETP (Height Equivalent of Theoretical Plate). To demonstrate the performance of the software, we present a comparative analysis of water-gas catalytic isotopic exchange on a column equipped with 3 types of filling: successive layers, random and structured (ordered package filled with catalyst). The program can be used for the LPCE process calculation, process used at detritiation facilities for CANDU reactors or fusion reactors. (authors)

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2018

Mechanical properties of Al/ω-Al-Cu-Fe composites synthesized by the SPS technique

Highlights: • For the first time, Al/ω-Al-Cu-Fe composites are produced by Spark Plasma Sintering. • Cu diffusion in Al matrix leads to precipitation of θ′-Al{sub 2}Cu. • The σ{sub 0.2%} drop at around 523 K is due to coarsening of θ′-Al{sub 2}Cu precipitates. • At high temperature, load transfer is the main strengthening mechanism. • At low temperature, SPS Al/ω composites have higher σ{sub 0.2%} than HIP Al/ω composites. - Abstract: Al/40 vol%ω-Al-Cu-Fe composites were produced from Al powder and i-Al-Cu-Fe quasi-crystalline particles using spark plasma sintering (SPS) technique. The mechanical properties of the composite were evaluated over the temperature range 293 K–823 K by performing compression tests at constant strain rate. The temperature dependence of the σ{sub 0,2%} yield stress gives evidence of two temperature regimes with a transition in the range 473 K–523 K. The decrease of σ{sub 0,2%} with increasing temperature, more pronounced in the low temperature regime, indicates that the two temperature regimes correspond to two different thermally activated deformation mechanisms. Based on microstructural analyses of the Al matrix, where plastic deformation takes place, the different strengthening contributions are discussed and the results are finally compared to those obtained for composites produced by hot isostatic pressing (HIP), for which the σ{sub 0,2%} temperature dependence is similar. In the low temperature regime, the σ{sub 0.2%} stress of the SPS composites is higher than that of the HIP composites. In this temperature regime, the stress difference is mainly ascribed to the different reinforcement phases present in the Al matrix. In the high temperature regime, the temperature dependence of σ{sub 0.2%} is comparable for the two composites whatever the processing route: load transfer is thus the main strengthening mechanism, which is similar for the two Al/ω-Al-Cu-Fe composites, the temperature dependence being ascribed to cross slip and climb processes.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Effect of a redox-mediating ligand shell on photocatalysis by CdS quantum dots

Semiconductor quantum dots (QDs) are efficient organic photoredox catalysts due to their high extinction coefficients and easily tunable band edge potentials. Despite the majority of the surface being covered by ligands, our understanding of the effect of the ligand shell on organic photocatalysis is limited to steric effects. We hypothesize that we can increase the activity of QD photocatalysts by designing a ligand shell with targeted electronic properties, namely, redox-mediating ligands. Herein, we functionalize our QDs with hole-mediating ferrocene (Fc) derivative ligands and perform a reaction where the slow step is hole transfer from QD to substrate. Surprisingly, we find that a hole-shuttling Fc inhibits catalysis, but confers much greater stability to the catalyst by preventing a build-up of destructive holes. We also find that dynamically bound Fc ligands can promote catalysis by surface exchange and creation of a more permeable ligand shell. Finally, we find that trapping the electron on a ligand dramatically increases the rate of reaction. Furthermore, these results have major implications for understanding the rate-limiting processes for charge transfer from QDs and the role of the ligand shell in modulating it.

Chemistry↗
DOE OSTI2021

Understanding Melting and Freezing/Solidification and the Associated Effects on Heat Transfer

Phase change (solid/liquid or liquid/vapor) is a process that enables a large heat transfer capacity for a broad range of engineering applications, such as steam generators, condensers, thermal energy storage, thermosyphons, and heat pipes. Water has been the most usable phase-change cooling medium. Advanced applications are proposing alkali metals (e.g., sodium, potassium, lithium) to increase the total heat transfer rate for moderate and high-temperature applications. Sodium and potassium have the advantage of relatively low melting temperatures (98 and 64°C, respectively) make them suitable for high-temperature applications (700–1100 K). At too high of temperatures (above 1200 K), lithium is an excellent choice as a working fluid because of its high latent heat vaporization and high-surface tension. The low vapor pressure of alkali metals makes them candidates for closed spaces applications, such as thermosyphons and heat pipes. Lithium has the lowest vapor pressure than potassium and sodium, which can work at a much higher temperature without over-pressurizing the container.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2017

A single-composition CaSi{sub 2}O{sub 2}N{sub 2}:RE (RE=Ce{sup 3+}/Tb{sup 3+}, Eu{sup 2+}, Mn{sup 2+}) phosphor nanofiber mat: Energy transfer, luminescence and tunable color properties

CaSi{sub 2}O{sub 2}N{sub 2}:RE (RE = Ce{sup 3+}/Tb{sup 3+}, Eu{sup 2+}, Mn{sup 2+}) phosphor nanofiber mat has been prepared via the electrospinning process and further annealing treatment. The diameter of nanofiber precursors are generally in a range of 400–600 nm, which exhibits smooth and uniform surface morphology. After removing the polymer template by high temperature treatment, the fabricated mats have been transformed into a phosphor film and maintain uniform nanofiber network microstructures. Photoluminescence (PL) properties of CaSi{sub 2}O{sub 2}N{sub 2} phosphor nanofiber mat have been activated by Ce{sup 3+}/Tb{sup 3+}, Eu{sup 2+} and Mn{sup 2+}. The emission color of CaSi{sub 2}O{sub 2}N{sub 2}:Ce{sup 3+}/Tb{sup 3+}, Eu{sup 2+}, Mn{sup 2+} phosphor mats can be adjusted by modifying the concentration of doped Tb{sup 3+}/Mn{sup 2+}/Eu{sup 2+} and the resultant energy transfer process. Owing to the energy transfer of Ce{sup 3+}-Tb{sup 3+}, the emitting color of the phosphor mat can be changed from blue to green. Meanwhile, we still found that the switching of emitting colors from blue to red and blue to yellow can be achieved via the energy transfer of Ce{sup 3+}-Mn{sup 2+} and Ce{sup 3+}-Eu{sup 2+}, respectively. We demonstrated a white light emission phosphor nanofiber mat by using CaSi{sub 2}O{sub 2}N{sub 2} system, which exhibited promising applications for near-UV WLEDs. - Graphical abstract: CIE chromaticity coordinates of CaSi{sub 2}O{sub 2}N{sub 2}:Ce{sup 3+}/Tb{sup 3+}, Eu{sup 2+}, Mn{sup 2+} samples. The lighting optical images with a drive current of 100 mA: three LEDs with nanofiber mats of CaSi{sub 2}O{sub 2}N{sub 2}: 0.02Ce{sup 3+}, 0.03Tb{sup 3+}(b), CaSi{sub 2}O{sub 2}N{sub 2}: 0.02Ce{sup 3+}, 0.01Eu{sup 2+}(c) and CaSi{sub 2}O{sub 2}N{sub 2}: 0.02Ce{sup 3+}, 0.12Mn{sup 2+}(d). Display Omitted.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2005

Bacillus subtilis spore survival and expression of germination-induced bioluminescence after prolonged incubation under simulated Mars atmospheric pressure and composition: implications for planetary protection and lithopanspermia

Bacterial endospores in the genus Bacillus are considered good models for studying interplanetary transfer of microbes by natural or human processes. Although spore survival during transfer itself has been the subject of considerable study, the fate of spores in extraterrestrial environments has received less attention. In this report we subjected spores of a strain of Bacillus subtilis, containing luciferase resulting from expression of an sspB-luxAB gene fusion, to simulated martian atmospheric pressure (7-18 mbar) and composition (100% CO(2)) for up to 19 days in a Mars simulation chamber. We report here that survival was similar between spores exposed to Earth conditions and spores exposed up to 19 days to simulated martian conditions. However, germination-induced bioluminescence was lower in spores exposed to simulated martian atmosphere, which suggests sublethal impairment of some endogenous spore germination processes.

Mars↗
NASA NTRS2017

A Overview of New Technologies Driving Innovation in the Airborne Science Community

Following a more than a century of scientific aircraft and ballooning there is a sense that a renaissance of sorts is at hand in the aviation industry. The advent of incredibly miniaturized autopilots, inertial navigation systems, GPS antennae, and payloads has sparked a revolution in manned and unmanned aircraft. Improved SATCOM and onboard computing has enabled realtime data processing and improved transfer of data on and off the aircraft, making flight planning and data collection more efficient and effective. Electric propulsion systems are scaling up to larger and larger vehicles as evidenced by the NASA GL-10, which is leading to a new X-plane and is leading to renewed interest in personal air vehicles. There is also significant private and government investments in the development of High Altitude, Long Endurance (HALE) aircraft. This presentation will explore how such developments are likely to improve our ability to observe earth systems processes from aircraft by providing an overview of current NASA Airborne Science capabilities, followed by a brief discussion of new technologies being applied to Airborne Science missions, and then conclude with an overview of new capabilities on the horizon that are likely to be of interest to the Earth Science community.

airborne science↗
NASA NTRS2017

An Overview of New Technologies Driving Innovation in the Airborne Science Community

Following a more than a century of scientific aircraft and ballooning there is a sense that a renaissance of sorts is at hand in the aviation industry. The advent of incredibly miniaturized autopilots, inertial navigation systems, GPS antennae, and payloads has sparked a revolution in manned and unmanned aircraft. Improved SATCOM and onboard computing has enabled realtime data processing and improved transfer of data on and off the aircraft, making flight planning and data collection more efficient and effective. Electric propulsion systems are scaling up to larger and larger vehicles as evidenced by the NASA GL-10, which is leading to a new X-plane and is leading to renewed interest in personal air vehicles. There is also significant private and government investments in the development of High Altitude, Long Endurance (HALE) aircraft. This presentation will explore how such developments are likely to improve our ability to observe earth systems processes from aircraft by providing an overview of current NASA Airborne Science capabilities, followed by a brief discussion of new technologies being applied to Airborne Science missions, and then conclude with an overview of new capabilities on the horizon that are likely to be of interest to the Earth Science community.

airborne science↗