Search NASA⌕ Search

SEARCH · Search NASA

Results for “Layered Structures”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,639 records · Page 91
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Reversible Fuel Cell Stacks with Integrated Water Management

Regenerative fuel cell/electrolyzers have long held promise as energy storage devices. Due to their small footprint and their ability to separately size the power and storage functions, they have many advantages over batteries, particularly for remote or deployable systems. A unitized regenerative fuel cell is proposed that takes advantage of three new technologies. The first is a H 2 /O 2 unitized regenerative stack that Giner, Inc. (Giner) has developed that combines a fuel cell and electrolyzer stack, eliminating one of the electrochemical stacks, the most expensive component in regenerative fuel cell systems. The second is an oxygen catalyst with low PGM loadings generated through Reactive Spray Deposition Technology (RSDT). The third is an amphiphilic microporous layer (AMPL) structure to greatly aid water management in both operational modes.

08 HYDROGEN↗
DOE OSTI2024

Using interfaces to: create strongly-coupled magnetic-ferroelectrics

Starting at the level of electrons and atoms our long-term goal is to rationally design complex oxide heterostructures and interface-materials with targeted emergent behaviors. This is not a matter of simply optimizing material parameters, but rather begins with understanding a mechanism to control the interplay between the diverse microscopic degrees of freedom prevalent in complex oxides in order to create targeted macroscopic phenomena and ends with the design of new material realizations. These realizations are in turn created with atomic-layer precision, structurally assessed to see that they are the intended realization, and finally their relevant properties are measured. During this program we have developed the scientific ideas necessary to apply this materials-by-design paradigm to the creation of materials offering electrical control of magnetism. At the heart of our approach lies a partnership between theory, synthesis, and characterization. These are the areas of expertise of the three co-PIs, who have worked closely together since their arrival at Cornell. During this project bold ideas on where to put the atoms to provide electrical control of magnetism were met with the latest methods of synthesis science and electron microscopy in an attempt create targeted new multiferroics. Our work applying this materials-by-design methodology to multiferroics has enjoyed multiple successes. The Co-PIs have invented new mechanisms for multiferroics, which provide strong coupling between polarization and magnetism, and reduced them to practice. Specifically, we pioneered multiferroics based on spin-phonon coupling, rotation-driven multiferroicity, and novel geometric multiferroics. Importantly, the latter two of these mechanisms enable the deterministic switching of magnetism by an applied electric field, which is key to the application of multiferroics to future device technologies. Most recently, we performed detailed theoretical analysis on a system involving the combination of magnetoelectric and colossal magnetoresistance behaviors and predict that electrical control of a metal-insulator transition is possible in appropriately strained SmBaMn2O6. The research enabled by this grant led to 63 publications in leading refereed journals including Nature, Nature Materials, Physical Review Letters, and Advanced Materials demonstrating a materials-by-design paradigm to the creation of materials offering electrical control of magnetism.

36 MATERIALS SCIENCE↗
DOE OSTI2018

The Impact of Cloud Radiative Effects on the Tropical Tropopause Layer Temperatures

A single-column radiative-convective model (RCM) is a useful tool to investigate the physical processes that determine the tropical tropopause layer (TTL) temperature structures. Previous studies on the TTL using the RCMs, however, omitted the cloud radiative effects. In this study, we examine the impact of cloud radiative effects on the simulated TTL temperatures using an RCM. We derive the cloud radiative effects based on satellite observations, which show heating rates in the troposphere but cooling rates in the stratosphere. We find that the cloud radiative effect warms the TTL by as much as 2 K but cools the lower stratosphere by as much as -1.5 K, resulting in a thicker TTL. With (without) considering cloud radiative effects, we obtain a convection top of ≈167 hPa (≈150 hPa) with a temperature of ≈213 K (≈209 K), and a cold point at ≈87 hPa (≈94 hPa) with a temperature of ≈204 K (≈204 K). Therefore, the cloud radiative effects widen the TTL by both lowering the convection-top height and enhancing the cold-point height. We also examine the impact of TTL cirrus radiative effects on the RCM-simulated temperatures. We find that the TTL cirrus warms the TTL with a maximum temperature increase of ≈1.3 K near 110 hPa.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Titanium Nitride as an Intermetallic Diffusion Barrier for Hydrogen Permeation in Palladium–Vanadium Composite Membranes

Hydrogen purification is a critical industrial process, and there are ongoing efforts to develop low-cost alternatives to palladium foil membranes. Titanium nitride (TiN) is studied as an interdiffusion barrier to enable hydrogen permeation in composite palladium–vanadium membranes. TiN was deposited via reactive sputtering, and films with the desired (200) orientation were obtained in the metallic regime at 400 °C under a 200 V bias to the substrate. The permeability of thin-film TiN was determined with palladium-based sandwich structures. TiN layers up to 10 nm resulted in a minimal decrease in flux (~20%) relative to a freestanding PdCu foil, which was attributed to the interfacial resistance. At greater thicknesses, the TiN layer was rate-limiting, and it was found that the effective permeability of the sputtered TiN thin films was ~6 × 10−12 mol s−1 m−1 Pa−0.5. Composite Pd|TiN|V|TiN|Pd membranes exhibited permeability values up to three times greater than pure palladium, exhibiting stability at 450 °C for over 100 h, with the lack of intermetallic diffusion and alloy formation being confirmed with XRD. The membranes were unstable at 500 °C, which was attributed to the instability of the thin Pd layer and loss of catalytic activity.

Biochemistry & Molecular Biology↗
DOE OSTI2017

A Three-dimensional View of Turbulence: Constraints on Turbulent Motions in the HD 163296 Protoplanetary Disk Using DCO{sup +}

Gas kinematics are an important part of the planet formation process. Turbulence influences planetesimal growth and migration from the scale of submicron dust grains through gas-giant planets. Radio observations of resolved molecular line emission can directly measure this non-thermal motion and, taking advantage of the layered chemical structure of disks, different molecular lines can be combined to map the turbulence throughout the vertical extent of a protoplanetary disk. Here we present ALMA observations of three molecules (DCO{sup +}(3-2), C{sup 18}O(2-1) and CO(2-1)) from the disk around HD 163296. We are able to place stringent upper limits (v {sub turb} < 0.06c {sub s}, <0.05c {sub s}, and <0.04c {sub s} for CO(2-1), C{sup 18}O(2-1), and DCO{sup +}(3-2) respectively), corresponding to α ≲ 3 × 10{sup −3}, similar to our prior limit derived from CO(3-2). This indicates that there is little turbulence throughout the vertical extent of the disk, contrary to theoretical predictions based on the magnetorotational instability and gravitoturbulence. In modeling the DCO{sup +} emission, we also find that it is confined to three concentric rings at 65.7 ± 0.9 au, 149.9{sub −0.7}{sup +0.5} au, and 259 ± 1 au, indicative of a complex chemical environment.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Insights of warm-cloud biases in Community Atmospheric Model 5 and 6 from the single-column modeling framework and Aerosol and Cloud Experiments in the Eastern North Atlantic (ACE-ENA) observations

There has been a growing concern that most climate models predict precipitation that is too frequent, likely due to lack of reliable subgrid variability and vertical variations in microphysical processes in low-level warm clouds. In this study, the warm-cloud physics parameterizations in the singe-column configurations of NCAR Community Atmospheric Model version 6 and 5 (SCAM6 and SCAM5, respectively) are evaluated using ground-based and airborne observations from the Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Aerosol and Cloud Experiments in the Eastern North Atlantic (ACE-ENA) field campaign near the Azores islands during 2017–2018. The 8-month single-column model (SCM) simulations show that both SCAM6 and SCAM5 can generally reproduce marine boundary layer cloud structure, major macrophysical properties, and their transition. The improvement in warm-cloud properties from the Community Atmospheric Model 5 and 6 (CAM5 to CAM6) physics can be found through comparison with the observations. Meanwhile, both physical schemes underestimate cloud liquid water content, cloud droplet size, and rain liquid water content but overestimate surface rainfall. Modeled cloud condensation nuclei (CCN) concentrations are comparable with aircraft-observed ones in the summer but are overestimated by a factor of 2 in winter, largely due to the biases in the long-range transport of anthropogenic aerosols like sulfate. We also test the newly recalibrated autoconversion and accretion parameterizations that account for vertical variations in droplet size. Compared to the observations, more significant improvement is found in SCAM5 than in SCAM6. This result is likely explained by the introduction of subgrid variations in cloud properties in CAM6 cloud microphysics, which further suppresses the scheme's sensitivity to individual warm-rain microphysical parameters. The predicted cloud susceptibilities to CCN perturbations in CAM6 are within a reasonable range, indicating significant progress since CAM5 which produces an aerosol indirect effect that is too strong. The present study emphasizes the importance of understanding biases in cloud physics parameterizations by combining SCM with in situ observations.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2026

Improving the Confidence in Retrievals of Vertical Distributions of Cloud Condensation Nuclei Number Concentration from ARM Supported by Aircraft In Situ Observations

Accurate quantification of the vertical distribution of cloud condensation nuclei (CCN) number concentrations is critical for improving our understanding of aerosol–cloud interactions. Ground-based Raman lidars operated by the Atmospheric Radiation Measurement (ARM) program, together with surface CCN measurements, are used to retrieve vertically resolved CCN number concentrations (Retrieved Number concentration of CCN, RNCCN). These retrievals rely on several assumptions, including that aerosol composition is vertically homogeneous. To assess this assumption, we developed and tested a framework to infer the dominant aerosol classes/types at different altitudes. This was done by applying a k-Nearest-Neighbors (kNN) algorithm to lidar ratio and linear depolarization ratio measurements from Raman lidar. We evaluated the framework using aircraft aerosol and CCN measurements from the ARM Holistic Interactions of Shallow Clouds, Aerosols, and Land Ecosystems (HI-SCALE) field campaign. The results show that RNCCN performance degrades as vertical aerosol complexity increases, i.e., RNCCN agrees with the aircraft CCN in vertically homogeneous conditions, but closure decreases in layered aerosol structures. To generalize beyond individual examples, we introduce a metric (heterogeneity index) that quantifies the vertical complexity by assessing the variation of inferred aerosol classes/types. Case-level statistics show a tendency for RNCCN and aircraft differences to increase with this metric. By detecting retrievals that are likely compromised by aerosol vertical heterogeneity, the proposed framework improves the interpretability and effective use of RNCCN used for long-term evaluation of models and aerosol–cloud interactions.

Tian, Jingjing↗
NASA NTRS1970

Swept-frequency UHF radiometer for deep probes of earth - A concept

Radiometer, developed for use on moon or planets, could be used to - determine layering and structure as deep as 100 feet below earth surface, determine physical properties of subsurface by variation of dielectric constants, identify types of materials including ore bodies and oil, and locate subsurface deposits of moisture.

Koppl, W.↗
NASA NTRS1972

On the structure of hypersonic turbulent boundary layers.

Extensive hot-wire auto- and cross-correlation measurements obtained in a fully developed compressible turbulent boundary layer are presented. A tentative mechanism of turbulence production and growth in hypersonic flow suggested by these measurements is developed. This flow model is consistent with previous observations in incompressible flows. Detailed measurements of the mean properties of the hypersonic turbulent boundary layer are also presented and compared with results from various transformation and finite-difference prediction methods. It is shown that none of the theories predict all the properties of the hypersonic turbulent boundary layer and that additional measurements are needed to provide more adequate physics of turbulent processes for use in the various theories.

Owen, F. K.↗
NASA NTRS1974

Measurement and correlation of aerodynamic heating to surface corrugation stiffened structures in thick turbulent boundary layers

The flow conditions for which heating distributions were measured on corrugated surfaces and wavy walls in turbulent boundary layers are shown, along with the ratio of the displacement thickness to the roughness height versus the local edge Mach number for an equivalent smooth surface. The present data are seen to greatly extend the range of data available on corrugated surfaces in turbulent boundary layers. These data were obtained by testing fullscale corrugation roughened panels in the wall boundary layer of a supersonic and hypersonic wind tunnel. The experimental program used to obtain the data is described. The data are analyzed and correlated in terms of the pertinent flow and geometric parameters. The developed correlations are compared with the available thin boundary layer data, as well as with previously published correlation techniques.

Brandon, H. J.↗
NASA NTRS1974

On the inlet vortex system

The flow field of a jet engine with an inlet vortex, which can pick up heavy debris from the ground and damage the engine, was simulated in a small water tunnel by means of the hydrogen bubble technique. It was found that the known engine inlet vortex is accompained by a vortex system, consisting of two inlet vortices (the ground based and the trailing one), secondary vortices, and ground vortices. Simulation of the ground effect by an inlet image proved that the inlet vortex feeds on free stream vorticity and can exist without the presence of a ground boundary layer. The structural form of the inlet vortex system was explained by a simple potential flow model, which showed the number, location, and the importance of the stagnation points. A retractable horizontal screen or an up-tilt of the engine is suggested as countermeasure against debris ingestion.

Bissinger, N. C.↗
NASA NTRS1974

Evaluation of a new jet flap propulsive-lift system for turbofan-powered STOL transports

A large-scale STOL transport model with a new jet flap propulsive-lift system was subject to wind-tunnel testing. Aerodynamically, this IBF system combines the benefits of the jet flap and the mechanical flap with boundary layer control. Structurally, it creates its own spanwise air duct with the deflection of the mechanical flap. An additional short-chord control flap, located at the jet-flap exit, provides a powerful means for flight path and lateral controls. The results show that the overall effectiveness of this flap system compares well with other jet flap propulsive-lift systems. A preliminary study based on the wind-tunnel data was made on a medium-size IBF STOL jet transport configuration for a typical-military mission. This study showed that the IBF results in a configuration with a relatively low T/W ratio, making the system an attractive candidate for future designs.

Chin, Y. T.↗
NASA NTRS1974

Fine-scale structure of a cold hydrogen layer

Neutral-hydrogen absorption-line interferometer observations are reported for five continuum radio sources situated behind an extensive layer of cold interstellar H I gas. In contrast to low-spatial-resolution emission-line observations reported earlier which show the large-scale uniformity of the layer, the high-spatial-resolution absorption-line observations reveal variations in the velocity and density within the layer. The new results together with the old indicate the apparent coexistence of a large-scale mechanism for triggering the formation of cold hydrogen and an instability mechanism leading to small-scale irregularities.

Baker, P. L.↗
NASA NTRS1975

Aerodynamic heating to corrugation stiffened structures in thick turbulent boundary layers

The results of an experimental program to evaluate heat transfer and pressure distributions on corrugation roughened flat plates in thick turbulent boundary layers are presented. The experimental program consisted of tests in the tunnel wall boundary layers of the Langley Unitary Plan Wind Tunnel (UPWT) and Continuous Flow Hypersonic Tunnel (CFHT) at freestream Mach numbers of 2.5, 3.5, 4.5, and 10.3. Tests in the UPWT were conducted at a freestream Reynolds number/m of 10,800,000 and in the CFHT, at Reynolds numbers/m of 1,300,000 to 5,800,000. The test configurations consisted of 50.8 x 50.8 cm panels with corrugated beads of two different peak amplitudes, 0.61 and 0.29 cm. The angle of the corrugated beads relative to the flow direction was varied between 0 (aligned) and 90 deg (normal). The measured peak and average heat transfer are analyzed and correlated in terms of the bulk boundary layer, internal boundary layer, and geometric parameters.-

Brandon, H. J.↗