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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,639 records · Page 91
All sourcesNASA NTRSDOE OSTI
DOE OSTI2013

THE FORMATION OF IRIS DIAGNOSTICS. II. THE FORMATION OF THE Mg II h and k LINES IN THE SOLAR ATMOSPHERE

NASA's Interface Region Imaging Spectrograph (IRIS) small explorer mission will study how the solar atmosphere is energized. IRIS contains an imaging spectrograph that covers the Mg II h and k lines as well as a slit-jaw imager centered at Mg II k. Understanding the observations requires forward modeling of Mg II h and k line formation from three-dimensional (3D) radiation-magnetohydrodynamic (RMHD) models. This paper is the second in a series where we undertake this modeling. We compute the vertically emergent h and k intensity from a snapshot of a dynamic 3D RMHD model of the solar atmosphere, and investigate which diagnostic information about the atmosphere is contained in the synthetic line profiles. We find that the Doppler shift of the central line depression correlates strongly with the vertical velocity at optical depth unity, which is typically located less than 200 km below the transition region (TR). By combining the Doppler shifts of the h and k lines we can retrieve the sign of the velocity gradient just below the TR. The intensity in the central line depression is anti-correlated with the formation height, especially in subfields of a few square Mm. This intensity could thus be used to measure the spatial variation of the height of the TR. The intensity in the line-core emission peaks correlates with the temperature at its formation height, especially for strong emission peaks. The peaks can thus be exploited as a temperature diagnostic. The wavelength difference between the blue and red peaks provides a diagnostic of the velocity gradients in the upper chromosphere. The intensity ratio of the blue and red peaks correlates strongly with the average velocity in the upper chromosphere. We conclude that the Mg II h and k lines are excellent probes of the very upper chromosphere just below the TR, a height regime that is impossible to probe with other spectral lines. They also provide decent temperature and velocity diagnostics of the middle chromosphere.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2026

Thermal cycling-driven microstructural changes of eutectic Al–Si phase change materials in SS304 containers revealed by multi-modal imaging

Aluminum-based Al–Si alloys are widely used as phase change materials (PCMs) in thermal energy storage (TES) systems owing to their high volumetric latent heat and superior thermal conductivity. However, their long-term reliability is limited by degradation processes that remain insufficiently understood. In this work, we employ a multimodal, correlative characterization framework to systematically resolve the degradation behavior of eutectic Al–Si PCMs in contact with SS304 containers under repeated thermal cycling. By integrating high-resolution electron microscopy, three-dimensional X-ray fluorescence (3D XRF) imaging, and differential scanning calorimetry (DSC), we directly link spatially resolved compositional and microstructural evolution to changes in thermophysical properties. The correlative analysis reveals that elemental leaching of Fe, Cr, and Ni from the stainless-steel container into the PCM drives the formation of intermetallic compounds (IMCs) both at the interface and within the bulk PCM, leading to pronounced compositional heterogeneity. These interfacial reactions and diffusion-induced transformations progressively destabilize the Al–Si eutectic, reducing the effective phase-transforming fraction. Consistent with these observations, DSC measurements show a decrease in melting temperature and latent heat of fusion with thermal cycling. These results underscore the critical influence of interfacial reactions and material compatibility on the stability, durability, and overall performance of Al–Si-based TES systems.

25 ENERGY STORAGE↗
DOE OSTI2020

4D imaging of lithium-batteries using correlative neutron and X-ray tomography with a virtual unrolling technique

The temporally and spatially resolved tracking of lithium intercalation and electrode degradation processes are crucial for detecting and understanding performance losses during the operation of lithium-batteries. Here, high-throughput X-ray computed tomography has enabled the identification of mechanical degradation processes in a commercial Li/MnO 2 primary battery and the indirect tracking of lithium diffusion; furthermore, complementary neutron computed tomography has identified the direct lithium diffusion process and the electrode wetting by the electrolyte. Virtual electrode unrolling techniques provide a deeper view inside the electrode layers and are used to detect minor fluctuations which are difficult to observe using conventional three dimensional rendering tools. Moreover, the 'unrolling' provides a platform for correlating multi-modal image data which is expected to find wider application in battery science and engineering to study diverse effects e.g. electrode degradation or lithium diffusion blocking during battery cycling.

25 ENERGY STORAGE↗
NASA NTRS1997

Measured Spacecraft Dynamic Effects on Atmospheric Science Instruments

On September 1991, NASA launched the Upper Atmosphere Research Satellite. In addition to its atmospheric science mission, spacecraft dynamic effects on science measurements were analyzed. The investigation included two in-flight experiments to determine how each on-board instrument, subsystem and environmental disturbance contributed to the spacecraft dynamic response and how these disturbances affected science measurements. Three case studies are presented which show the impact of spacecraft dynamic response on science measurements. In the first case, correlation of independent atmospheric meridional wind measurements taken by two instruments with the spacecraft dynamic response demonstrated that excessive vibration (exceeding instrument pointing requirements) resulted in wind measurement disagreement. In the second case, solar array disturbances produced a spacecraft response signature on radiometer measurements. The signature explicitly demonstrated that if an instrument has sufficient spatial and temporal resolution, spacecraft dynamic response could impact measurements. In the final case, correlation of an instrument's fine sun sensor data and CO2 measurements demonstrated the effect of temporal and spatial sampling resolution and active pointing control on science measurements. The sun sensor had a frequency modulated characteristic due to spacecraft vibration and the periodic scanning of another instrument which was not present on the CO2 measurements.

Woodard, Stanley E.↗
NASA NTRS1990

Real-time optical correlator using photorefractive GaAs

A real-time optical correlator based on GaAs and liquid-crystal TV (LCTV) is demonstrated. The demonstrated system has a video-frame rate limited by the speed of the LCTVs; if faster spatial-light modulators are used, the potential frame rate of a GaAs-based correlator can be as fast as 1000 frames/sec under experimental conditions. Comparisons are made between VanderLugt and joint transform and between degenerate and nondegenerate four-wave mixing. The edge-enhancement effect and the Bragg diffraction effect are discussed.

Liu, Duncan T. H.↗
NASA NTRS2015

Composite Characterization Using Laser Doppler Vibrometry and Multi-Frequency Wavenumber Analysis

NASA has recognized the need for better characterization of composite materials to support advances in aeronautics and the next generation of space exploration vehicles. An area of related research is the evaluation of impact induced delaminations. Presented is a non-contact method of measuring the ply depth of impact delamination damage in a composite through use of a Scanning Laser Doppler Vibrometer (SLDV), multi-frequency wavenumber analysis, and a wavenumber-ply correlation algorithm. A single acquisition of a chirp excited lamb wavefield in an impacted composite is post-processed into a numerous single frequency excitation wavefields through a deconvolution process. A spatially windowed wavenumber analysis then extracts local wavenumbers from the wavefield, which are then correlated to theoretical dispersion curves for ply depth determination. SLDV based methods to characterize as-manufactured composite variation using wavefield analysis will also be discussed.

Juarez, Peter↗
DOE OSTI2020

Thermal Pressure in the Laser‐Heated Diamond Anvil Cell: A Quantitative Study and Implications for the Density Versus Mineralogy Correlation of the Mantle

Abstract Thermal pressure is an inevitable thermodynamic consequence of heating a volumetrically constrained sample in the diamond anvil cell. Its possible influences on experimentally determined density‐mineralogy correlations are widely appreciated, yet the effect itself has never been experimentally measured. We present here the first quantitative measurements of the spatial distribution of thermal pressure in a laser‐heated diamond anvil cell (LHDAC) in both olivine and AgI. The observed thermal pressure is strongly localized and closely follows the distribution of the laser hotspot. The magnitude of the thermal pressure is of the order of the thermodynamic thermal pressure ( αK T Δ T ) with gradients between 0.5 and 1.0 GPa/10 μm. Remarkably, we measure a steep gradient in thermal pressure even in a sample that is heated close to its melting line. This generates consequences for pressure determinations in pressure‐volume‐temperature (PVT) equation of state measurements when using an LHDAC. We show that an incomplete account of thermal pressure in PVT experiments can lead to biases in the coveted depth versus mineralogy correlation. However, the ability to spatially resolve thermal pressure in an LHDAC opens avenues to measure difficult‐to‐constrain thermodynamic derivative properties, which are important for comprehensive thermodynamic descriptions of the interior of planets.

Yen, Connor Ethan↗
DOE OSTI2026

Correlation-aware binning for small-angle neutron scattering via Gaussian-process inference

Binning in small-angle neutron scattering (SANS) is typically performed empirically, with fixed parameters chosen for convenience rather than statistical optimality. Such practices often fail to balance statistical precision and spatial resolution, leading to inconsistencies across instruments and datasets. Here we establish a correlation-aware framework that determines the optimal bin width from first principles by extending the classical Freedman–Diaconis (FD) rule to account for inter-bin correlations with a Gaussian process. In this formulation, the scattering intensity is treated as a smooth stochastic field whose statistical coherence is described by a covariance matrix. Analytical expressions of errors derived from this model yield closed-form criteria that separate the total deviation into contributions from counting noise, aliasing distortion and curvature-dependent correlation effects. Expressed in reduced variables, the resulting dimensionless error surface reveals a continuous transition from the uncorrelated FD regime to the correlation-dominated limit, providing a unified description of noise suppression and resolution control. Because the formulation depends only on the profile characteristics of scattering intensity I(Q), specifically its average intensity and first- and second-order derivatives, it applies generally to any SANS measurement regardless of sample, instrument or geometry. Experimental validation using small- and ultra-small-angle neutron scattering data confirms the predicted scaling behavior, demonstrating that correlation-aware inference systematically reduces mean-squared error and enables information-efficient reproducible data reduction across materials and instruments.

Tung, Chi-Huan [ORNL] (ORCID:0000000221972074)↗
NASA NTRS1993

Functional patterns in an annual grassland during an AVIRIS overflight

This study relates Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) imagery to ground measurements of vegetation distribution, physiology, and productivity at Stanford University's Jasper Ridge Biological Preserve. Primary efforts focused on a 9-ha region of annual grassland where we completed a detailed ground-based study in conjunction with a 15 May 1991 AVIRIS overflight. Spectral mixture analysis and the normalized difference vegetation index (NDVI) calculated from AVIRIS data were used to evaluate spatial patterns of vegetation type, productivity, and potential physiological activity. Concurrent ground sampling revealed a high degree of correlation between NDVI and estimates of canopy chemistry, structure, productivity, and CO2 flux, supporting the use of imaging spectrometry to estimate spatial and temporal trends in vegetation physiology and productivity in this relatively simple grassland ecosystem. Geostatistical analyses of both ground and AVIRIS data supported the conclusion that the AVIRIS pixel size was suitable for describing the influence of major landscape features in this grassland and that spatial detail would be lost at slightly larger pixel sizes typical of other imaging spectrometers.

Gamon, John A.↗
DOE OSTI2023

Thermodynamic behavior of correlated electron-hole fluids in van der Waals heterostructures

Abstract Coupled two-dimensional electron-hole bilayers provide a unique platform to study strongly correlated Bose-Fermi mixtures in condensed matter. Electrons and holes in spatially separated layers can bind to form interlayer excitons, composite Bosons expected to support high-temperature exciton condensates. The interlayer excitons can also interact strongly with excess charge carriers when electron and hole densities are unequal. Here, we use optical spectroscopy to quantitatively probe the local thermodynamic properties of strongly correlated electron-hole fluids in MoSe 2 /hBN/WSe 2 heterostructures. We observe a discontinuity in the electron and hole chemical potentials at matched electron and hole densities, a definitive signature of an excitonic insulator ground state. The excitonic insulator is stable up to a Mott density of ~0.8 × 10 12 cm −2 and has a thermal ionization temperature of ~70 K. The density dependence of the electron, hole, and exciton chemical potentials reveals strong correlation effects across the phase diagram. Compared with a non-interacting uniform charge distribution, the correlation effects lead to significant attractive exciton-exciton and exciton-charge interactions in the electron-hole fluid. Our work highlights the unique quantum behavior that can emerge in strongly correlated electron-hole systems.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2014

Spatially-resolved mapping of history-dependent coupled electrochemical and electronical behaviors of electroresistive NiO

Bias-induced oxygen ion dynamics underpins a broad spectrum of electroresistive and memristive phenomena in oxide materials. Although widely studied by device-level and local voltage-current spectroscopies, the relationship between electroresistive phenomena, local electrochemical behaviors, and microstructures remains elusive. Here, the interplay between history-dependent electronic transport and electrochemical phenomena in a NiO single crystalline thin film with a number of well-defined defect types is explored on the nanometer scale using an atomic force microscopy-based technique. A variety of electrochemically-active regions were observed and spatially resolved relationship between the electronic and electrochemical phenomena was revealed. The regions with pronounced electroresistive activity were further correlated with defects identified by scanning transmission electron microscopy. Using fully coupled mechanical-electrochemical modeling, we illustrate that the spatial distribution of strain plays an important role in electrochemical and electroresistive phenomena. In conclusion, these studies illustrate an approach for simultaneous mapping of the electronic and ionic transport on a single defective structure level such as dislocations or interfaces, and pave the way for creating libraries of defect-specific electrochemical responses.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1989

Achromatical Optical Correlator

Signal-to-noise ratio exceeds that of monochromatic correlator. Achromatical optical correlator uses multiple-pinhole diffraction of dispersed white light to form superposed multiple correlations of input and reference images in output plane. Set of matched spatial filters made by multiple-exposure holographic process, each exposure using suitably-scaled input image and suitable angle of reference beam. Recording-aperture mask translated to appropriate horizontal position for each exposure. Noncoherent illumination suitable for applications involving recognition of color and determination of scale. When fully developed achromatical correlators will be useful for recognition of patterns; for example, in industrial inspection and search for selected features in aerial photographs.

Chao, Tien-Hsin↗
NASA NTRS1992

IRAS and the Boston University Arecibo Galactic H I Survey: A catalog of cloud properties

The Infrared Astronomy Satellite (IRAS) Galactic Plane Surface Brightness Images were used to identify infrared emission associated with cool, diffuse H I clouds detected by the Boston University-Arecibo Galactic H I Survey. These clouds are associated with galactic star clusters, H II regions, and molecular clouds. Using emission-absorption experiments toward galactic H II regions, we determined the H I properties of cool H I clouds seen in absorption against the thermal continuum, including their kinematic distances. Correlations were then made between IRAS sources and these H II regions, thus some of the spatial confusion associated with the IRAS fields near the galactic plane was resolved since the distances to these sources was known. Because we can also correlate the BU-Arecibo clouds with existing CO surveys, these results will allow us to determine the intrinsic properties of the gas (neutral and ionized atomic as well as molecular) and dust for interstellar clouds in the inner galaxy. For the IRAS-identified H II region sample, we have established the far infrared (FIR) luminosities and galactic distribution of these sources.

Bania, Thomas M.↗
DOE OSTI2016

Exciton Correlations in Intramolecular Singlet Fission

We have synthesized a series of asymmetric pentacene-tetracene heterodimers with a variable-length conjugated bridge that undergo fast and efficient intramolecular singlet fission (iSF). These compounds have distinct singlet and triplet energies, which allow us to study the spatial dynamics of excitons during the iSF process, including the significant role of exciton correlations in promoting triplet pair generation and recombination. We demonstrate that the primary photoexcitations in conjugated dimers are delocalized singlets that enable fast and efficient iSF. However, in these asymmetric dimers, the singlet becomes more localized on the lower energy unit as the length of the bridge is increased, slowing down iSF relative to analogous symmetric dimers. We resolve the recombination kinetics of the inequivalent triplets produced via iSF, and find that they primarily decay via concerted processes. By identifying different decay channels, including delayed fluorescence via triplet-triplet annihilation, we can separate transient species corresponding to both correlated triplet pairs and uncorrelated triplets. Recombination of the triplet pair proceeds rapidly despite our experimental and theoretical demonstration that individual triplets are highly localized and unable to be transported across the conjugated linker. In this class of compounds, the rate of formation and yield of uncorrelated triplets increases with bridge length. Overall, these constrained, asymmetric systems provide a unique platform to isolate and study transient species essential for singlet fission, which are otherwise difficult to observe in symmetric dimers or condensed phases.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2013

Electron nongyrotropy in the context of collisionless magnetic reconnection

Collisionless magnetized plasmas have the tendency to isotropize their velocity distribution function around the local magnetic field direction, i.e., to be gyrotropic, unless some spatial and/or temporal fluctuations develop at the particle gyroscales. Electron gyroscale inhomogeneities are well known to develop during the magnetic reconnection process. Nongyrotropic electron velocity distribution functions have been observed to play a key role in the dissipative process breaking the field line connectivity. In this paper, we present a new method to quantify the deviation of a particle population from gyrotropy. The method accounts for the full 3D shape of the distribution and its analytical formulation allows fast numerical computation. Regions associated with a significant degree of nongyrotropy are shown, as well as the kinetic origin of the nongyrotropy and the fluid signature it is associated with. Using the result of 2.5D Particle-In-Cell simulations of magnetic reconnection in symmetric and asymmetric configurations, it is found that neither the reconnection site nor the topological boundaries are generally associated with a maximized degree of nongyrotropy. Nongyrotropic regions do not correspond to a specific fluid behavior as equivalent nongyrotropy is found to extend over the electron dissipation region as well as in non-dissipative diamagnetic drift layers. The localization of highly nongyrotropic regions in numerical models and their correlation with other observable quantities can, however, improve the characterization of spatial structures explored by spacecraft missions.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2020

Markovian transport processes in a heterogeneous, variably saturated watershed: A multi-domain spatial Markov model

Transport processes in watersheds remain challenging to describe accurately with upscaled models because of their intricate complexities at multiple scales that can lead to multi-modal, non-Fickian breakthrough curves. One of the recent advances in solute transport modeling has been the Lagrangian spatial Markov model (SMM), which describes transport using velocity increments and models the correlated transitions between them. The method has been applied previously to saturated porous media and fractured media, but these successful applications suggest it may be useful for describing watershed scale processes as well. An existing, 3-D, heterogeneous variably saturated model of a headwaters catchment and classical random walk particle tracking were used to generate a forward simulation and the resulting transport was analyzed with a spatial Markov framework. Existing SMM methods were used to analyze the transport paths through the complex, unconfined domain and we found that the vadose zone plays an important role in the correlation structure. As such, a new kind of SMM is proposed, termed a multi-domain SMM (MD-SMM), that uses separate correlation models for auto-transitions in the vadose zone and the saturated zone, and for the cross-transitions between them. The MD-SMM improves representation of transport relative to the single domain model and can naturally delineate times when a particle is in the vadose zone or the saturated zone, adding an additional degree of realism to the upscaled model. Lastly, we show that the transition probability matrix for transport in the saturated portion of this unconfined system is approximately Markovian, which is an important validation of the proposed framework.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2015

The spatial distribution of satellite galaxies within halos: Measuring the very small scale angular clustering of SDSS galaxies

We measure the angular clustering of galaxies from the Sloan Digital Sky Survey (SDSS) Data Release 7 in order to probe the spatial distribution of satellite galaxies within their dark matter halos. Specifically, we measure the angular correlation function on very small scales (7″–320″) in a range of luminosity threshold samples (absolute r-band magnitudes from −18 up to −21) that are constructed from the subset of SDSS that has been spectroscopically observed more than once (the so-called plate overlap region). We choose to measure angular clustering in this reduced survey footprint in order to minimize the effects of fiber collision incompleteness, which are otherwise substantial on these small scales, and we discuss the possible impact that fiber collisions have on our measurements. We model our clustering measurements using a fully numerical halo model that populates dark matter halos in N-body simulations to create realistic mock galaxy catalogs. The model has free parameters that specify both the number and spatial distribution of galaxies within their host halos. We adopt a flexible density profile for the spatial distribution of satellite galaxies that is similar to the dark matter Navarro–Frenk–White (NFW) profile, except that the inner slope is allowed to vary. We find that the angular clustering of our most luminous samples (M{sub r} < −20 and −21) suggests that luminous satellite galaxies have substantially steeper inner density profiles than NFW. Lower-luminosity samples are less constraining, however, and are consistent with satellite galaxies having shallow density profiles. Our results confirm the findings of Watson et al. while using different clustering measurements and modeling methodology.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS2014

Asymmetries in Core-Collapse Supernovae from Maps of Radioactiver 44Ti in Cassiopeia A

Asymmetry is required by most numerical simulations of stellar core-collapse explosions, but the form it takes differs significantly among models. The spatial distribution of radioactive 44Ti, synthesized in an exploding star near the boundary between material falling back onto the collapsing core and that ejected into the surroundingmedium1, directly probes the explosion asymmetries. Cassiopeia A is a young2, nearby3, core-collapse4 remnant from which 44Ti emission has previously been detected5-8 but not imaged. Asymmetries in the explosion have been indirectly inferred from a high ratio of observed 44Ti emission to estimated 56Ni emission9, from optical light echoes10, and from jet-like features seen in the X-ray11 and optical12 ejecta. Here we report spatial maps and spectral properties of the 44Ti in Cassiopeia A. This may explain the unexpected lack of correlation between the 44Ti and iron X-ray emission, the latter being visible only in shock-heated material. The observed spatial distribution rules out symmetric explosions even with a high level of convective mixing, as well as highly asymmetric bipolar explosions resulting from a fast-rotating progenitor. Instead, these observations provide strong evidence for the development of low-mode convective instabilities in core-collapse supernovae.

stellarcore-collapse explosions↗