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At least 1,639 records · Page 91

Design of a monolithic multichannel front-end readout ASIC for PET imaging based on scintillation crystals read out by photodetectors at both ends

This paper presents the design techniques of a monolithic multichannel front-end readout chip integrated with both high-accuracy TDC and high-resolution ADC for the PET using LYSO(Ce) crystals read out by MCP PMT at both ends. In the front-end readout chain, a regulated cascade (RGC) preamplifier is employed in every channel for amplifying the current signals generated from MCP detector. A gain-adjustment stage, an integrator and a pulse shaper are employed for pulse height analysis which changes the width of the pulses. A discriminator is placed after the preamplifier to generate triggers. These triggers are sent to a sub-nanosecond TDC for measurement and digitizing. The peak values of the shaped pulses are digitized by a multichannel time-based ADC for measurement. Three prototype chips are designed in AMS 0.35 {mu}m CMOS technology. In the front-end readout prototype chip, the dynamic range, the linearity, and the power dissipation are optimized. The input dynamic range from few fC to more than 100 pC can be achieved. The analog output range of the front-end readout circuits is from 1.2 V to 3.2 V. The shaping time is 280 ns and the power dissipation is reduced to less than 15 mW. In the TDC chip based on a DLL array, the RMS jitter and the peak-to-peak jitter of the used DLL are reduced to 7 ps and 21 ps, respectively. The bin size of the TDC has been reduced to 71 ps with a reference clock of 100 MHz. In the multichannel time-based ADC chip, a maximum resolution of 12 bits, a sampling rate of {approx}1 MS/s, and the power dissipation of 3 mW deg. 0.2 mW/channel are achieved. (authors)

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

System identification of the Large-Angle Magnetic Suspension Test Facility (LAMSTF)

The Large-Angle Magnetic Suspension Test Facility (LAMSTF), a laboratory-scale research project to demonstrate the magnetic suspension of objects over wide ranges of attitudes, has been developed. This system represents a scaled model of a planned Large-Gap Magnetic Suspension System (LGMSS). The LAMSTF system consists of a planar array of five copper electromagnets which actively suspend a small cylindrical permanent magnet. The cylinder is a rigid body and can be controlled to move in five independent degrees of freedom. Five position variables are sensed indirectly by using infra-red light-emitting diodes and light-receiving phototransistors. The motion of the suspended cylinder is in general nonlinear and hence only the linear, time-invariant perturbed motion about an equilibrium state is considered. One of the main challenges in this project is the control of the suspended element over a wide range of orientations. An accurate dynamic model plans an essential role in controller design. The analytical model of the LAMSTF system includes highly unstable real poles (about 10 Hz) and low-frequency flexible modes (about 0.16 Hz). Projection filters are proposed to identify the state space model from closed-loop test data in time domain. A canonical transformation matrix is also derived to transform the identified state space model into the physical coordinate. The LAMSTF system is stabilized by using a linear quadratic regulator (LQR) feedback controller. The rate information is obtained by calculating the back difference of the sensed position signals. The reference inputs contain five uncorrelated random signals. This control input and the system reponse are recorded as input/output data to identify the system directly from the projection filters. The sampling time is 4 ms and the model is fairly accurate in predicting the step responses for different controllers while the analytical model has a deficiency in the pitch axis.

Huang, Jen-Kuang↗

Quantum Theory of Surface Lattice Resonances

The collective interactions of nanoparticles arranged in periodic structures give rise to high‐ in‐plane diffractive modes known as surface lattice resonances. Although these resonances and their broader implications have been extensively studied within the framework of classical electrodynamics and linear response theory, a quantum optical theory capable of describing the dynamics of these structures, especially in the presence of material nonlinearities beyond ad hoc few‐mode approximations, is largely missing. To this end, we consider a lattice of metallic nanoparticles coupled to the electromagnetic field and derive the quantum input–output relations within the electric dipole approximation. As applications, we analyze coupling between the nanoparticle array and external quantum emitters, and show how the formalism extends to molecular optomechanics, where the high ‐factors of SLRs enable coupling to collective vibrational modes. We further consider arrays composed of saturable excitonic emitters, demonstrating how emitter nonlinearities can be used to switch the SLR condition between electronic transitions. Using a perturbative approach that accounts for population dynamics, we show how these effects can be probed in pump–probe experiments and give rise to nonlinear phase‐matching phenomena. Our work provides a microscopic framework for modeling SLRs interacting with quantum emitters without phenomenological descriptions of the electromagnetic environment.

molecular optomechanics↗

Remote synchronization of amplitudes across an experimental ring of non-linear oscillators

In this paper, the emergence of remote synchronization in a ring of 32 unidirectionally coupled non-linear oscillators is reported. Each oscillator consists of 3 negative voltage gain stages connected in a loop to which two integrators are superimposed and receives input from its preceding neighbour via a “mixing” stage whose gains form the main system control parameters. Collective behaviour of the network is investigated numerically and experimentally, based on a custom-designed circuit board featuring 32 field-programmable analog arrays. A diverse set of synchronization patterns is observed depending on the control parameters. While phase synchronization ensues globally, albeit imperfectly, for certain control parameter values, amplitudes delineate subsets of non-adjacent but preferentially synchronized nodes; this cannot be trivially explained by synchronization paths along sequences of structurally connected nodes and is therefore interpreted as representing a form of remote synchronization. Complex topology of functional synchronization thus emerges from underlying elementary structural connectivity. In addition to the Kuramoto order parameter and cross-correlation coefficient, other synchronization measures are considered, and preliminary findings suggest that generalized synchronization may identify functional relationships across nodes otherwise not visible. Further work elucidating the mechanism underlying this observation of remote synchronization is necessary, to support which experimental data and board design materials have been made freely downloadable.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

A HERSCHEL SURVEY OF THE [N II] 205 {mu}m LINE IN LOCAL LUMINOUS INFRARED GALAXIES: THE [N II] 205 {mu}m EMISSION AS A STAR FORMATION RATE INDICATOR

We present, for the first time, a statistical study of [N II] 205 {mu}m line emission for a large sample of local luminous infrared galaxies using Herschel Spectral and Photometric Imaging Receiver Fourier Transform Spectrometer (SPIRE FTS) data. For our sample of galaxies, we investigate the correlation between the [N II] luminosity (L{sub [N{sub II]}}) and the total infrared luminosity (L{sub IR}), as well as the dependence of L{sub [N{sub II]}}/L{sub IR} ratio on L{sub IR}, far-infrared colors (IRAS f{sub 60}/f{sub 100}), and the [O III] 88 {mu}m to [N II] luminosity ratio. We find that L{sub [N{sub II]}} correlates almost linearly with L{sub IR} for non-active galactic nucleus galaxies (all having L{sub IR} < 10{sup 12} L{sub Sun }) in our sample, which implies that L{sub [N{sub II]}} can serve as a star formation rate tracer which is particularly useful for high-redshift galaxies that will be observed with forthcoming submillimeter spectroscopic facilities such as the Atacama Large Millimeter/submillimeter Array. Our analysis shows that the deviation from the mean L{sub [N{sub II]}}-L{sub IR} relation correlates with tracers of the ionization parameter, which suggests that the scatter in this relation is mainly due to the variations in the hardness, and/or ionization parameter, of the ambient galactic UV field among the sources in our sample.

79 ASTRONOMY AND ASTROPHYSICS↗

TU-F-BRE-01: A High Resolution Micro Fiber Scintillator Detector Optimized for SRS and SBRT in Vivo Real Time Treatment Verification

Purpose: We have built a high resolution real time scintillating fiber detector prototype to determine in real time the accuracy of stereotactic radiosurgery (SRS) and stereotactic body radiotherapy (SBRT) treatments when only a fraction of the planned dose was delivered. The motivation of this work is to enhance dose delivery accuracy and to achieve error free radiosurgery. Methods: A high density array of scintillating fibers and a high speed photo detectors array were integrated to implement a high resolution real time dosimeter that can sample with high resolution pulsed SRS and SBRT beams cross sections. The high efficiency of the developed system allows to read each linac pulse in real time and to compute the accumulated dose and dose errors when only a fraction of the beam was delivered. The fibers are highly packed in a substrate that is directly coupled to two 128 pixel arrays with a pitch matching the fiber spacing to achieve accurate spatial localization. The small cross section of the fiber array allows stacking multiple fiber arrays to measure independent angular profiles that are digitally processed in parallel for real time dosimetry. Results: We implemented a high density array detector prototype with a pitch of 0.5 mm, readout speed of 1.2 msec, and a response time of 0.5 usec. The fast reading speed has the capability to determining the dose in flattening free filter beams. The detector can be installed in transmission mode at the output port of a micro-MLC. Treatment deviations smaller than 3% are detected when less than 1/100 of the planned dose was delivered. Conclusions: We built a prototype of a high resolution fiber scintillator array detector for SRS and SBRT in vivo dosimetry. Results show that the developed detector has the potential to assure error free SRS and SBRT treatments.

60 APPLIED LIFE SCIENCES↗

Quantum ghost imaging microscopy depth-of-field study

Quantum ghost imaging approaches have been proposed to enhance biological microscopy, for example, using 2D visible detectors to provide IR images or providing additional dimensions of spatial or spectral information. Toward the goal of making such imaging schemes practical, we compare image quality and depth-of-field between traditional images and ghost images at the same excitation levels. We measure how image quality and depth-of-field depend on the parameters of the entangled light produced using type-I spontaneous parametric down-conversion (SPDC). We use a pair of time-synchronized, photon-timing single-photon avalanche diode (SPAD) array detectors to capture two distinct microscope imaging paths simultaneously on a photon-pair-by-photon-pair basis: one in a traditional imaging pathway and the other a quantum ghost imaging pathway. We calculate the depth-of-field, resolution, contrast, and signal-to-noise ratio (SNR) through the parameter space of a β-Barium Borate (BBO) type-I bulk non-linear crystal length and angle. Our results provide a basis for choosing parameters for quantum ghost imaging with type-I SPDC sources.

47 OTHER INSTRUMENTATION↗

Neutron Capture and Transmission Measurements of 54 Fe at the RPI LINAC

54 Fe radiative capture cross section and transmission measurements were conducted at the Rensselaer Polytechnic Institute (RPI) Gaerttner Linear Accelerator (LINAC) Center using an enriched 54 Fe sample in the keV energy region. 54 Fe is a constituent of natural iron, which is present in a large variety of nuclear grade materials. Therefore, it is important to have an accurate understanding of the cross sections of 54 Fe, which can be measured experimentally. In the time-of-flight measurements conducted at the LINAC, an array of four C 6 D 6 detectors surrounded the sample and radiative capture data were collected using a digital data acquisition system. Additionally, a Li-glass detector was used to collect transmission data using an analog data acquisition system. The radiative capture yield of the 54 Fe measurements were normalized to saturated resonances observed in Au and Ta to obtain an absolute capture yield. The preliminary capture yield and preliminary transmission obtained can be compared to evaluations and existing experimental data. Some disagreements were observed in prominent d-wave capture resonances observed in 54 Fe in the low-keV neutron energy region. Both sets of experimental data along with pre-existing datasets will greatly enhance RPI’s ability to perform resonance evaluation for 54 Fe up to roughly 1 MeV.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Brighter-fatter Effect in Near-infrared Detectors—III. Fourier-domain Treatment of Flat Field Correlations and Application to WFIRST

Weak gravitational lensing has emerged as a leading probe of the growth of cosmic structure. However, the shear signal is very small and accurate measurement depends critically on our ability to understand how non-ideal instrumental effects affect astronomical images. The Wide-Field Infrared Survey Telescope (WFIRST) will fly a focal plane containing 18 Teledyne H4RG-10 near-infrared detector arrays, which present different instrument calibration challenges from previous weak lensing observations. Previous work [Paper I: Hirata & Choi, PASP, 132, 014501 (2020); and Paper II: Choi & Hirata, PASP, 132, 014502 (2020)] has shown that correlation functions of flat field images, including cross-correlations between different time slices that are enabled by the non-destructive read capability of the infrared detectors, are effective tools for disentangling linear and nonlinear inter-pixel capacitance (IPC) and the brighter-fatter effect (BFE). Here we present a Fourier-domain treatment of the flat field correlations, which allows us to expand the previous formalism to all orders in IPC, BFE, and classical nonlinearity. We show that biases in simulated flat field analyses in Paper I are greatly reduced through the use of this formalism. We then apply this updated formalism to flat field data from three WFIRST flight candidate detectors, and explore the robustness to variations in the analysis. We find that the BFE is present in all three detectors, and that its contribution to the flat field correlations dominates over the nonlinear IPC, in accordance with the results from Paper II on a development detector. The magnitude of the BFE is such that the effective area of a pixel is increased by (3.54 ± 0.03) × 10 -7 for every electron deposited in a neighboring pixel (sensor chip assembly [SCA] 20829, statistical error, not IPC-deconvolved). We compare IPC maps from flat field autocorrelation measurements to those obtained from the single pixel reset method and find a median difference of 0.113% for SCA 20829. After further diagnosis of this difference, we ascribe it largely to an additional source of cross-talk, the vertical trailing pixel effect, and recommend further work to develop a model for this effect. These results represent a significant step toward calibration of the non-ideal effects in WFIRST detectors.

79 ASTRONOMY AND ASTROPHYSICS↗

Formation of Imploding Plasma Liners for HEDP and MIF Application

Plasma jets with high density and velocity have a number of important applications in fusion energy and elsewhere, including plasma refueling, disruption mitigation in tokamaks, magnetized target fusion, injection of momentum into centrifugally confined mirrors, plasma thrusters, and high energy density plasmas (HEDP). In Magneto-Inertial Fusion (MIF), for example, an imploding material liner is used to compress a magnetized plasma to fusion conditions and to confine the resulting burning plasma inertially to obtain the necessary energy gain. The imploding shell may be solid, liquid, gaseous, or a combination of these states. The presence of the magnetic field in the target plasma suppresses thermal transport to the plasma shell, thus lowering the imploding power needed to compress the target to fusion conditions. This allows the required imploding momentum flux to be generated electromagnetically using off-the-shelf pulsed power technology. Practical schemes for standoff delivery of the imploding momentum flux are required and are open topics for research. One approach for accomplishing this, called plasma jet driven magneto-inertial fusion (PJMIF), uses a spherical array of pulsed plasma guns to create a spherically imploding shell of very high velocity, high momentum flux plasma. This approach requires development of plasma jet accelerators capable of achieving velocities of 50-200 km/s with very precise timing and density profiles, and with high total mass and density. Low-Z plasma jets would require the higher velocities, whereas very dense high-Z plasma shells could achieve the goal at velocities of only 50-100 km/s. In this report, we describe our work to develop the pulsed plasma gun technology needed for an experimental scientific exploration of the PJMIF concept, and also for the other applications mentioned earlier. The initial goal of a few hundred of hydrogen at 200 km/s was eventually replaced with accelerating 8000 μg of argon or xenon to 50 km/s for the Plasma Liner Experiment (PLX) at Los Alamos National Laboratory (LANL). Initial work used existing computational and analytical tools to develop and refine a specific plasma gun concept having a novel tapered coaxial electromagnetic accelerator contour with an array of symmetric ablative plasma injectors. The profile is designed to suppress the main barrier to success in coaxial guns, namely the blow-by instability in which the arc slips past and outruns the bulk of the plasma mass. Efforts to begin developing a set of annular non-ablative plasma injectors for the coaxial gun, in order to accelerate pure gases, resulted in development of linear parallel-plate MiniRailguns that turned out to work well as plasma guns in their own right and we subsequently chose them for an initial plasma liner experiment on the PLX facility at LANL. This choice was mainly driven by cost and schedule for that particular experiment, while longer term goals still projected use of coaxial guns for reactor-relevant applications for reasons of better symmetry, lower impurities, more compact plasma jet formation, and higher gun efficiency. Our efforts have focused mainly on 1) developing various plasma injection systems for both coax and linear railguns and ensuring they work reliably with the accelerator section, 2) developing a suite of plasma and gun diagnostics, 3) performing computational modeling to design and refine the plasma guns, 4) establishing a research facility dedicated to plasma gun development, and finally, 5) developing plasma guns and associated pulse power systems capable of achieving these goals and installing and testing the first two gun sets on the PLX facility at LANL. During the second funding cycle for this program, HyperV joined in a collaborative effort with LANL, the University of Alabama at Huntsville, and the University of New Mexico to perform a plasma liner experiment (PLX) to investigate the physics and technology of forming spherically imploding plasma liners. HyperV’s tasks focused on developing the plasma guns and associated pulse power systems required for the 30 gun experiment at LANL. Unfortunately, funding for the entire PLX collaborative project was terminated after only two years of the four year project due to program funding realignments which necessitated recompeting the project in midstream. Despite the loss of funding, HyperV installed two Mark1 guns and pulsed power systems on PLX, and jet characterization and merging experiments were subsequently successfully performed at LANL by the PLX Team. In parallel with those PLX experiments, HyperV continued its efforts to develop a plasma gun capable of meeting the PLX goal of 8 mg of argon at 50 km/s. HyperV was ultimately successful in this effort, demonstrating 10.8 mg at 52.8 km/s and 7.5 mg at 62.4 km/s with the Mark2 MiniRailgun.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Very long baseline interferometry observations of the RS Canum Venaticorum system HR 5110 at 8.4 GHz

The RS CVn binary system HR 5110 was observed with a well-calibrated four-element VLBI array at a frequency of 8.4 GHz. The total flux density, which was nearly constant at 32 + or - 2 mJy, was monitored throughout the experiment with a 20 km baseline interferometer allowing accurate visibilities to be calculated. The observed visibilities are consistent with a source unresolved on all the baselines. The maximum size of the equivalent Gaussian source is 1.4 milli-arcsec (FWHM), corresponding to a linear size of 1.1 x 10 to the 12th cm at 52 pc. This maximum size is comparable with the overall size of the binary system. The inferred lower limit of the brightness temperature is 4 x 10 to the 8th K, which is higher than the coronal temperature of 10 to the 7th K measured in a soft X-ray survey. This is consistent with a nonthermal mechanism for the radiation process of the moderate radio outburst observed.

Mutel, R. L.↗

High-angular resolution observations of stellar binary systems

A long-term program designed to investigate the spatial structure of centimetric radio emission from close binary systems using multistation VLBI array is discussed. Eleven binaries, including eight RS CVn systems, Algol, LSI 61 deg 303, and Cyg X-1, have been detected. The measured brightness temperatures vary from T(B) about 10 exp 8.5 K during periods of low activity to T(B) about 10 exp 10.5 K during flares. Extensive observation of a few sources has shown that the spatial structure is 'core-halo' with linear dimensions of about a stellar radius and the binary system, respectively. The observations are consistent with gyrosynchrotron emission of mildly relativistic electrons in magnetic fields of about 10 exp 1.5 + or - 0.5 gauss. The core sources appear to be optically thick, while the halo component is optically thin.

Lestrade, J.-F.↗

DUST CONTINUUM EMISSION AS A TRACER OF GAS MASS IN GALAXIES

We use a sample of 36 galaxies from the KINGFISH (Herschel IR), HERACLES (IRAM CO), and THINGS (Very Large Array H I) surveys to study empirical relations between Herschel infrared (IR) luminosities and the total mass of the interstellar gas (H{sub 2} + H I). Such a comparison provides a simple empirical relationship without introducing the uncertainty of dust model fitting. We find tight correlations, and provide fits to these relations, between Herschel luminosities and the total gas mass integrated over entire galaxies, with the tightest, almost linear, correlation found for the longest wavelength data (SPIRE 500). However, we find that accounting for the gas-phase metallicity (affecting the dust to gas ratio) is crucial when applying these relations to low-mass, and presumably high-redshift, galaxies. The molecular (H{sub 2}) gas mass is found to be better correlated with the peak of the IR emission (e.g., PACS160), driven mostly by the correlation of stellar mass and mean dust temperature. When examining these relations as a function of galactocentric radius, we find the same correlations, albeit with a larger scatter, up to a radius of r ∼ 0.7 r {sub 25} (containing most of a galaxy's baryonic mass). However, beyond that radius, the same correlations no longer hold, with increasing gas (predominantly H I) mass relative to the infrared emission. The tight relations found for the bulk of the galaxy's baryonic content suggest that total gas masses of disk-like (non-merging/ULIRG) galaxies can be inferred from far-infrared continuum measurements in situations where only the latter are available, e.g., in ALMA continuum observations of high-redshift galaxies.

79 ASTRONOMY AND ASTROPHYSICS↗

Onset of band structure in 70 Ga

Excited states in the odd-odd nucleus 70 Ga were studied using the 62 Ni( 14 C, αpn) fusion-evaporation reaction at the John D. Fox Superconducting Accelerator Laboratory at Florida State University with a 50 MeV beam. Depopulating γ rays were measured in coincidence with a Compton-suppressed Ge array consisting of three Clover detectors and seven single-crystal detectors. Analysis of γ–γ coincidences led to the addition of 16 new transitions to the 70 Ga level scheme, including transitions associated with the onset of a new positive-parity band structure likely based on the πg 9/2 ⊗ νg 9/2 configuration. Spins and parities were assigned using directional correlation of oriented nuclei (DCO) ratios and linear polarization measurements. Shell-model calculations with the JUN45 effective interaction reproduce the excitation energies of the positive-parity states reasonably well but predict negative-parity states that are typically 400–500 keV lower than observed. Furthermore, total Routhian surface calculations for the lowest positive-parity configuration with signature α = 0 indicate significant triaxiality (γ ≈ −20°) and the development of competing non-collective excitations at J = 8, corresponding to the experimentally observed onset of the positive-parity band. Similar features are found in the calculated surfaces for the lowest negative-parity states with α = 0.

59 ≤ A ≤ 89↗

Finite-frequency modeling of regional tropospheric infrasound using realistic atmospheres and terrain

Infrasonic waves have been observed to propagate to regional (greater than 15 km) distances through the troposphere. Infrasound propagation in the geometric acoustics approximation has shown that realistic terrain can scatter acoustic energy from tropospheric ducts; however, ray methods cannot intrinsically capture finite-frequency behavior such as diffraction. A two-dimensional finite-difference time-domain (FDTD) method has been developed to solve linearized equations for infrasound propagation with realistic terrain. Acoustic wave propagation over 100 km with both flat terrain and a Gaussian hill was first simulated in order to compare finite-frequency propagation with ray predictions. The effects of realistic terrain and atmospheres on infrasound signals from a 2012 surface explosion at the Utah Testing and Training Range are then investigated. Propagation through the troposphere is suggested by array processing results, but eigenrays are not predicted due to weak to nonexistent ducting conditions. FDTD modeling suggests that the inclusion of terrain and finite frequency effects helps explain much of the observed signal in a realistic scenario. Furthermore, these results suggest that geometric acoustics may underestimate propagation through the troposphere, and that recorded waveforms at regional distances may be noticeably affected by terrain.

58 GEOSCIENCES↗

Method Validation Summary for L16.2 AD-ISO-0015 for ISO-17025 / NFAC Applications

Methods for the analysis of semi-volatile organic compounds are employed at Savannah River National Laboratory (SRNL) for routine and non-routine samples from tank waste, process control, waste acceptance, and a wide array of other process and research samples. A method has been developed by SRNL, based on existing methods for semi-volatile analysis, for the analysis of nitroaromatic high explosives by gas chromatography / mass spectrometry in soils and sediments. Relative to past work performed at SRNL on nitroaromatic explosives, this developed, optimized, and validated method can achieve lower limits of detection and quantitation, greater precision, lower bias, higher linearity, and accuracy across a greater linear range.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

The Impact of Crosstalk in the X-IFU Instrument on Athena Science Cases

In this paper we present a first assessment of the impact of various forms of instrumental crosstalk on the science performance of the X-ray Integral Field Unit (X-IFU) on the Athena X-ray mission. This assessment is made using the SIXTE end-to-end simulator in the context of one of the more technically challenging science cases for the XIFU instrument. Crosstalk considerations may influence or drive various aspects of the design of the array of high-count-rate Transition Edge Sensor (TES) detectors and its Frequency Domain Multiplexed (FDM) readout architecture. The Athena X-ray mission was selected as the second L-class mission in ESA's Cosmic Vision 2015–25 plan, with alaunch foreseen in 2028, to address the theme ''Hot and Energetic Universe"1. One of the two instruments on boardAthena is the X-ray Integral Field Unit2 (X-IFU) which is based on an array of ~3800 Transition Edge Sensors (TES's)operated at a temperature of ~90 mK. The science cases pose an interesting challenge for this instrument, as they requirea combination of high energy resolution (2.5 eV FWHM or better), high spatial resolution (5 arcsec or better) and highcount rate capability (several tens of counts per second per detector for point sources as bright as 10 mCrab).The performance at the single sensor level has been demonstrated3, but the operation of such detectors in an array, usingmultiplexed readout, brings additional challenges, both for the design of the array in which the sensors are placed and forthe readout of the sensors. The readout of the detector array will be based on Frequency Domain Multiplexing (FDM)4.In this system of detectors and readout, crosstalk can arise through various mechanisms: on the TES array, neighboringsensors can couple through thermal crosstalk. Detectors adjacent in carrier frequency may suffer from electrical crosstalkdue to the finite width of the bandpass filters, and shared sources of impedance in their signal lines. The signals from theindividual detectors are summed and then amplified by a pair of SQUID amplifiers before being sent to warm front-endelectronics. The transfer function of the SQUID amplifiers is non-linear, which will give rise to higher harmonics ofcarriers and intermodulation products when multiple signal pulses are simultaneously present in the SQUID. Under highcount rate conditions this is another source of crosstalk. The effect of all these crosstalk sources is that parasitic pulseswill appear in the record of a signal pulse which will create a stochastic offset of the measured energy and thus adegradation of the energy resolution.

SIXTE↗

High-Level VSCF/VCI Calculations Decode the Vibrational Spectrum of the Aqueous Proton

We report that the hydrated excess proton is a common species in aqueous chemistry which complexes with water in a variety of structures. The infrared spectrum of the aqueous proton is particularly sensitive to this array of structures, which manifests as continuous IR absorption from 1000-3000 cm -1 known as the “proton continuum”. Because of the extreme breadth of the continuum and strong anharmonicity of the involved vibrational modes, this spectrum has eluded straightforward interpretation and simulation. Using protonated water hexamer clusters from reactive molecular dynamics trajectories, and focusing on their central H + (H 2 O) 2 structures’ spectral contribution, we reproduce the linear IR spectrum of the aqueous proton with a high-level local- monomer quantum method and highly accurate many-body potential energy surface. The accuracy of this approach is first verified in the vibrational spectra of the two isomers of the protonated water hexamer in the gas phase. We then apply this approach to 800 H + (H 2 O) 6 clusters, also written as [H + (H 2 O) 2 ](H 2 O) 4 , drawn from MS-EVB simulations of the bulk liquid to calculate the infrared spectrum of the aqueous proton complex. Incorporation of anharmonic effects to the vibrational potential and quantum mechanical treatment of the proton produce better agreement to the infrared spectrum compared to the double-harmonic approximation. We assess the correlation of the pro- ton stretching mode with different atomistic coordinates, finding the best correlation with $\langle$ROH$\rangle$, the expectation value of the proton-oxygen distance ROH. Finally, we also decompose the IR spectrum based on normal mode vibrations and $\langle$ROH$\rangle$ to provide insight on how different frequency regions in the continuum report on different configurations, vibrational modes, and mode couplings.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗