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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,639 records · Page 91
All sourcesNASA NTRSDOE OSTI
NASA NTRS1999

Validation of Satellite Retrieved Land Surface Variables

The effective use of satellite observations of the land surface is limited by the lack of high spatial resolution ground data sets for validation of satellite products. Recent large scale field experiments include FIFE, HAPEX-Sahel and BOREAS which provide us with data sets that have large spatial coverage and long time coverage. It is the objective of this paper to characterize the difference between the satellite estimates and the ground observations. This study and others along similar lines will help us in utilization of satellite retrieved data in large scale modeling studies.

Lakshmi, Venkataraman↗
DOE OSTI2021

Improved performance of a near-field thermophotovoltaic device by a back gapped reflector

Various spectral control techniques can be applied to improve the performance of a thermophotovoltaic (TPV) device. For example, a back surface reflector (BSR) is a common structure to improve the performance of TPV devices. A conventional metal BSR structure enhances the photogeneration rate by increasing the absorption probability of photons via back surface reflections, affording a second chance for absorption. However, the effects of surface passivation and external luminescence introduced by BSR structures have been previously ignored, which potentially decreases the performance of TPV devices. Recently, a back gapped reflector (BGR) structure was proposed to greatly improve the performance of far-field TPV devices by reducing imperfect reflections at the semiconductor-metal interface. In the present work, the performance improvement on a thin-film, near-field InAs TPV device with a BGR is investigated, comparing its performance to that with a conventional metal BSR. Surface passivation conditions are also investigated to further improve the performance of TPV devices with back reflectors. Further, the output power and efficiency are calculated using an iterative model combining fluctuational electrodynamics and the full drift diffusion model. For the well-passivated condition, when the BSR is replaced by the BGR, the calculated conversion efficiency of the near-field TPV was improved from 16.4% to 21% and the output power was increased by 10%. Finally, the absorption of the back reflectors and external luminescence loss are analyzed to explain the performance improvement.

external luminescence↗
DOE OSTI2021

Large Eddy Simulation of the Southern Ocean

The data set contains seven Large Eddy Simulations (LES) at the Southern Ocean Flux Site for studies of deep turbulent ocean boundary layers, with and without surface wave effects, and with both idealized and observed forcing by wind, surface buoyancy flux and Stokes drift profiles. There are 20 days of hourly statistics computed every half-hour of turbulence quantities; namely, the vertical fluxes of buoyancy (temperature) and momentum, buoyancy and velocity variances, and the turbulent kinetic energy, its production terms and its dissipation.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1976

Influence of surface roughness and waviness on film thickness and pressure distribution in elastohydrodynamic contacts

The Christensen theory of a stochastic model for hydrodynamic lubrication of rough surfaces was extended to elastohydrodynamic lubrication between two rollers. Solutions for the reduced pressure at the entrance as a function of the ratio of the average nominal film thickness to the rms surface roughness, were obtained numerically. Results were obtained for purely transverse as well as purely longitudinal surface roughness for cases with or without slip. The reduced pressure was shown to decrease slightly by considering longitudinal surface roughness. The same approach was used to study the effect of surface roughness on lubrication between rigid rollers and lubrication of an infinitely wide slider bearing. Using the flow balance concept, the perturbed Reynolds equation, was derived and solved for the perturbed pressure distribution. In addition, Cheng's numerical scheme was modified to incorporate a single two-dimensional elastic asperity on the stationary surface. The perturbed pressures obtained by these three different models were compared.

Chow, L. S. H.↗
NASA NTRS1988

Development of a torsion balance for adhesion measurements

A new torsion balance for study of adhesion in ceramics is discussed. A torsion wire and a linear variable differential transformer are used to monitor load and to measure pull-off force (adhesion force). The investigation suggests that this torsion balance is valuable in studying the interfacial properties of ceramics in controlled environments such as in ultrahigh vacuum. The pull-off forces measured in dry, moist, and saturated nitrogen atmosphere demonstrate that the adhesion of silicon nitride contacts remains low at humidities below 80 percent but rises rapidly above that. The adhesion at saturation is 10 times or more greater than that below 80 percent relative humidity. The adhesion in a saturated atmosphere arises primarily from the surface tension effects of a thin film of water adsorbed on the surface. The surface tension of the water film was 58 x 10 to the minus 5 to 65 x 10 to the minus 5 power. The accepted value for water is 72.7 x 10 to the minus 5 power N/cm. Adhesion characteristics of silicon nitride in contact with metals, like the friction characteristics of silicon carbide to metal contacts, can be related to the relative chemical activity of metals in ultrahigh vacuum. The more active the metal, the higher the adhesion.

Miyoshi, Kazuhisa↗
NASA NTRS1988

Stagnation flow field analysis for an aeroassist flight experiment vehicle

Continuum methods are used to analyze the stagnation flow field of the aeroassist flight experiment (AFE) vehicle. For the lower altitude portion of an AFE trajectory, the viscous shock-layer equations are employed. At higher altitudes, the full Navier-Stokes equations with chemical nonequilibrium and surface slip are used. Particular attention is given to the effect of surface catalyticity on surface heating, electron number density, and flow field structure.

Gupta, Roop N.↗
NASA NTRS1991

Further evaluation of the constrained least squares electromagnetic compensation method

Technologies exist for construction of antennas with adaptive surfaces that can compensate for many of the larger distortions caused by thermal and gravitational forces. However, as the frequency and size of reflectors increase, the subtle surface errors become significant and degrade the overall electromagnetic performance. Electromagnetic (EM) compensation through an adaptive feed array offers means for mitigation of surface distortion effects. Implementation of EM compensation is investigated with the measured surface errors of the NASA 15 meter hoop/column reflector antenna. Computer simulations are presented for: (1) a hybrid EM compensation technique, and (2) evaluating the performance of a given EM compensation method when implemented with discretized weights.

Smith, William T.↗
NASA NTRS1992

An experimental study of heat transfer in a large-scale turbine rotor passage

An experimental study of the heat transfer distribution in a turbine rotor passage was conducted in a large-scale, ambient temperature, rotating turbine model. Heat transfer was measured for both the full-span suction and pressure surfaces of the airfoil as well as for the hub endwall surface. The objective of this program was to document the effects of flow three-dimensionality on the heat transfer in a rotating blade row (vs a stationary cascade). Of particular interest were the effects of the hub and tip secondary flows, tip leakage and the leading-edge horseshoe vortex system. The effect of surface roughness on the passage heat transfer was also investigated. Midspan results are compared with both smooth-wall and rough-wall finite-difference two-dimensional heat transfer predictions. Contour maps of Stanton number for both the rotor airfoil and endwall surfaces revealed numerous regions of high heat transfer produced by the three-dimensional flows within the rotor passage. Of particular importance are regions of local enhancement (as much as 100 percent over midspan values) produced on the airfoil suction surface by the secondary flows and tip-leakage vortices and on the hub endwall by the leading-edge horseshoe vortex system.

Blair, Michael F.↗
NASA NTRS2003

Lifetime Predictions of a Titanium Silicate Glass with Machined Flaws

A dynamic fatigue study was performed on a Titanium Silicate glass to assess its susceptibility to delayed failure and to compare the results with those of a previous study. Fracture mechanics techniques were used to analyze the results for the purpose of making lifetime predictions. The material strength and lifetime was seen to increase due to the removal of residual stress through grinding and polishing. Influence on time-to-failure is addressed for the case with and without residual stress present. Titanium silicate glass otherwise known as ultra-low expansion (ULE)* glass is a candidate for use in applications requiring low thermal expansion characteristics such as telescope mirrors. The Hubble Space Telescope s primary mirror was manufactured from ULE glass. ULE contains 7.5% titanium dioxide which in combination with silica results in a homogenous glass with a linear expansion coefficient near zero. delayed failure . This previous study was based on a 230/270 grit surface. The grinding and polishing process reduces the surface flaw size and subsurface damage, and relieves residual stress by removing the material with successively smaller grinding media. This results in an increase in strength of the optic during the grinding and polishing sequence. Thus, a second study was undertaken using samples with a surface finish typically achieved for mirror elements, to observe the effects of surface finishing on the time-to-failure predictions. An allowable stress can be calculated for this material based upon modulus of rupture data; however, this does not take into account the problem of delayed failure, most likely due to stress corrosion, which can significantly shorten lifetime. Fortunately, a theory based on fracture mechanics has been developed enabling lifetime predictions to be made for brittle materials susceptible to delayed failure. Knowledge of the factors governing the rate of subcritical flaw growth in a given environment enables the development of relations between lifetime, applied stress and failure probability for the material under study. Dynamic fatigue is one method of obtaining the necessary information to develop these relationships. In this study, the dynamic fatigue method was used to construct a time-to-failure diagram for polished ULE glass.

Tucker, Dennis S.↗
DOE OSTI2017

Kinetics and Mechanism of Methanol Conversion over Anatase Titania Nanoshapes

The kinetics and mechanism of methanol dehydration, redox, and oxidative coupling were explored at 300 °C under dilute oxygen concentration over anatase TiO 2 nanoplates and truncated-bipyramidal nanocrystals in order to understand the surface structure effect of TiO 2 . The two TiO 2 nanoshapes displayed both (001) and (101) facets, with a higher fraction of the (001) facet exposed on the nanoplates, while truncated-bipyramidal nanocrystals were dominated by the (101) facet. A kinetic study using in situ titration with ammonia reflects that the active sites for methanol dehydration are acidic and nonequivalent in comparison to redox and oxidative coupling. In situ FTIR spectroscopy reveals that adsorbed methoxy is the dominant surface species for all reactions, while the observed methanol dimer is found to be a spectator species through isotopic methanol exchange, supporting the dissociative mechanism for methanol dehydration via surface methoxy over TiO 2 surfaces. Density functional theory calculations show that the formation of dimethyl ether involves the C–H bond dissociation of an adsorbed methoxy, followed by coupling with another surface methoxy on the 5-fold-coordinated Ti cations on the (101) surface, similar to the mechanism reported on the (001) surface. Kinetic isotope effects are observed for dimethyl ether, formaldehyde, and methyl formate in the presence of deuterated methanol (CD 3 OH and CD 3 OD), confirming that the cleavage of the C–H bond is the rate-limiting step for the formation of these products. A comparison between estimated kinetic parameters for methanol dehydration over various TiO 2 nanocrystals suggests that (001) has a higher dehydration reactivity in comparison to (101), but the surface density of active sites could be limited by the presence of residual fluorine atoms originating from the synthesis. The (001) surface of TiO 2 is also more active than the (101) surface in redox and oxidative coupling of methanol, which is due to the reactive surface oxygen on (001) in comparison to the (101) surface.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1988

Effective radii of annuli in surface photometry

When surface photometry is done in concentric annuli, there is a tendency toward distortion of the true profile because of the finite widths of the annuli. This distortion can be avoided by choosing an effective radius for the annulus such that the actual surface brightness at that radius is equal to the average surface brightness over the annulus. This effective radius depends on the shape of the radial profile, but its calculation can be performed in an iterative way. Formulas for the effective radius are given for some typical profile shapes.

King, Ivan R.↗
NASA NTRS1990

Photovoltaic effects in photoemission studies of Schottky barrier formation

It is shown here that much of the recent photoelectron spectroscopy literature describing the onset of pinning in adsorbate-semiconductor systems at low temperature must be reinterpreted in light of surface photovoltaic effects. Two sources of surface charging are discussed, both of which are strongly enhanced at low temperature. The surface photovoltage resulting from separation of electron-hole pairs by the electric field in the depletion region is usually the dominant source of surface potential shifts, and causes flattening of the semiconductor bands. In addition, surface charging due to photoemission into the vacuum may reverse bias a p-type diode at low temperatures, causing increase band bending.

Hecht, M. H.↗
NASA NTRS1990

The effects of g-jitter and surface tension induced convection on float zones

The effects of g-jitter on nonencapsulated and encapsulated liquid bridges were investigated numerically, using fluid characteristics and parameters from three fluid systems: a silicone oil bridge, a methanol bridge, and a silicon melt. Results showed that complex flow patterns can arise in g-jitter environment which significantly modify the heat-transfer characteristics of the system. It was found that the nonencapsulated liquid bridges and float zone melts were dominated by surface-tension driven convection, with very little impact on the flows by residual and g-jitter accelerations. Zone encapsulation resulted in a sizeable drop in the maximum fluid velocities. The g-jitter computations on the encapsulated float zones resulted in significant augmentation of the maximum velocities and heat transfer, with the silicon melt being the least sensitive to g-jitter acceleration.

Ramachandran, N.↗
NASA NTRS1984

Separation processes during binary monotectic alloy production

Observation of microgravity solidification processes indicates that outside of sedimentation, at least two other important effects can separate the phases: critical-point wetting and spreading; and thermal migration of second-phase droplets due to interfacial tension gradients. It is difficult to study these surface tension effects while in a unit gravity field. In order to investigate the processes occurring over a temperature range, i.e., between a consolute point and the monotectic temperature, it is necessary to use a low-gravity environment. The MSFC drop tube (and tower), the ballistic trajectory KC-135 airplane, and the Space Shuttle are ideal facilities to aid formation and testing of hypotheses. Much of the early work in this area focuses on transparent materials so that process dynamics may be studied by optical techniques such as photography for viewing macro-processes; holography for studying diffusional growth; spinodal decomposition and coalescence; ellipsometry for surface wetting and spreading effects; and interferometry and spectroscopy for small-scale spatial resolution of concentration profiles.

Frazier, D. O.↗
NASA NTRS1972

Remote sensing of atmospheric and surface temperatures with microwaves.

Solids, liquids, and gases emit at microwave wavelengths measurable amounts of black-body thermal radiation. Receiver sensitivities readily approach 0.01 K, and permit accurate measurements of land, sea, and atmospheric temperatures. Sea and land temperature measurements must be corrected for the effects of surface emissivity, but these effects can often be measured or estimated. Observations near the 5 mm wavelength 02 resonances can yield atmospheric temperature profiles with an approximate accuracy of 2 K for altitudes 0-80 km. Such measurements from balloons and aircraft suggest that the planned earth-orbital satellite experiments will yield data valuable for numerical weather prediction. Ground-based radio telescopes and planetary-probes have yielded similar information about the surfaces and atmospheres of other planets.

Staelin, D. H.↗
NASA NTRS1983

Surface analysis of graphite fiber reinforced polyimide composites

Several techniques have been used to establish the effect of different surface pretreatments on graphite-polyimide composites. Composites were prepared from Celion 6000 graphite fibers and the polyimide LARC-160. Pretreatments included mechanical abrasion, chemical etching and light irradiation. Scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) were used in the analysis. Contact angle of five different liquids of varying surface tensions were measured on the composites. SEM results showed polymer-rich peaks and polymer-poor valleys conforming to the pattern of the release cloth used durng fabrication. Mechanically treated and light irradiated samples showed varying degrees of polymer peak removal, with some degradation down to the graphite fibers. Minimal changes in surface topography were observed on concentrations of surface fluorine even after pretreatment. The light irradiation pretreatment was most effective at reducing surface fluorine concentrations whereas chemical pretreatment was the least effective. Critical surface tensions correlated directly with the surface fluorine to carbon ratios as calculated from XPS.

Messick, D. L.↗
DOE OSTI2020

Pd3Ag(111) as a Model System for Hydrogen Separation Membranes: Combined Effects of CO Adsorption and Surface Termination on the Activation of Molecular Hydrogen

Abstract The co-adsorption of hydrogen and carbon monoxide on Pd 3 Ag(111) alloy surfaces has been studied as a model system for Pd-Ag alloys in membrane and catalysis applications using periodic density functional theory calculations (PW91-GGA). We explored the effects of Pd–Ag surface composition, since segregation of silver towards and away from the surface has been suggested to explain the experimentally observed changes in H 2 activation, CO inhibition and reactivity. We found that CO pre-adsorbed on the surface weakens the adsorption of H on Pd 3 Ag(111) alloy surfaces irrespective of whether the surface termination corresponds to the bulk Pd 3 Ag composition, or is purely Pd-terminated. A higher coverage of H with CO present is obtained for the Pd-terminated surface; this surface also exhibits a larger range of chemical potentials for co-adsorbed hydrogen and CO. The barrier for H 2 activation increases with increasing CO coverage, but the surface composition has the largest impact on H 2 activation at intermediate CO coverage. The results imply that Pd-based membranes with typically ~ 23 wt% Ag are less prone to CO poisoning if the surface becomes Pd-terminated.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗