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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,657 records · Page 92
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

The effects of g-jitter and surface tension induced convection on float zones

The effects of g-jitter on nonencapsulated and encapsulated liquid bridges were investigated numerically, using fluid characteristics and parameters from three fluid systems: a silicone oil bridge, a methanol bridge, and a silicon melt. Results showed that complex flow patterns can arise in g-jitter environment which significantly modify the heat-transfer characteristics of the system. It was found that the nonencapsulated liquid bridges and float zone melts were dominated by surface-tension driven convection, with very little impact on the flows by residual and g-jitter accelerations. Zone encapsulation resulted in a sizeable drop in the maximum fluid velocities. The g-jitter computations on the encapsulated float zones resulted in significant augmentation of the maximum velocities and heat transfer, with the silicon melt being the least sensitive to g-jitter acceleration.

Ramachandran, N.↗
NASA NTRS1984

Separation processes during binary monotectic alloy production

Observation of microgravity solidification processes indicates that outside of sedimentation, at least two other important effects can separate the phases: critical-point wetting and spreading; and thermal migration of second-phase droplets due to interfacial tension gradients. It is difficult to study these surface tension effects while in a unit gravity field. In order to investigate the processes occurring over a temperature range, i.e., between a consolute point and the monotectic temperature, it is necessary to use a low-gravity environment. The MSFC drop tube (and tower), the ballistic trajectory KC-135 airplane, and the Space Shuttle are ideal facilities to aid formation and testing of hypotheses. Much of the early work in this area focuses on transparent materials so that process dynamics may be studied by optical techniques such as photography for viewing macro-processes; holography for studying diffusional growth; spinodal decomposition and coalescence; ellipsometry for surface wetting and spreading effects; and interferometry and spectroscopy for small-scale spatial resolution of concentration profiles.

Frazier, D. O.↗
NASA NTRS1972

Remote sensing of atmospheric and surface temperatures with microwaves.

Solids, liquids, and gases emit at microwave wavelengths measurable amounts of black-body thermal radiation. Receiver sensitivities readily approach 0.01 K, and permit accurate measurements of land, sea, and atmospheric temperatures. Sea and land temperature measurements must be corrected for the effects of surface emissivity, but these effects can often be measured or estimated. Observations near the 5 mm wavelength 02 resonances can yield atmospheric temperature profiles with an approximate accuracy of 2 K for altitudes 0-80 km. Such measurements from balloons and aircraft suggest that the planned earth-orbital satellite experiments will yield data valuable for numerical weather prediction. Ground-based radio telescopes and planetary-probes have yielded similar information about the surfaces and atmospheres of other planets.

Staelin, D. H.↗
NASA NTRS1983

Surface analysis of graphite fiber reinforced polyimide composites

Several techniques have been used to establish the effect of different surface pretreatments on graphite-polyimide composites. Composites were prepared from Celion 6000 graphite fibers and the polyimide LARC-160. Pretreatments included mechanical abrasion, chemical etching and light irradiation. Scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) were used in the analysis. Contact angle of five different liquids of varying surface tensions were measured on the composites. SEM results showed polymer-rich peaks and polymer-poor valleys conforming to the pattern of the release cloth used durng fabrication. Mechanically treated and light irradiated samples showed varying degrees of polymer peak removal, with some degradation down to the graphite fibers. Minimal changes in surface topography were observed on concentrations of surface fluorine even after pretreatment. The light irradiation pretreatment was most effective at reducing surface fluorine concentrations whereas chemical pretreatment was the least effective. Critical surface tensions correlated directly with the surface fluorine to carbon ratios as calculated from XPS.

Messick, D. L.↗
DOE OSTI2020

Pd3Ag(111) as a Model System for Hydrogen Separation Membranes: Combined Effects of CO Adsorption and Surface Termination on the Activation of Molecular Hydrogen

Abstract The co-adsorption of hydrogen and carbon monoxide on Pd 3 Ag(111) alloy surfaces has been studied as a model system for Pd-Ag alloys in membrane and catalysis applications using periodic density functional theory calculations (PW91-GGA). We explored the effects of Pd–Ag surface composition, since segregation of silver towards and away from the surface has been suggested to explain the experimentally observed changes in H 2 activation, CO inhibition and reactivity. We found that CO pre-adsorbed on the surface weakens the adsorption of H on Pd 3 Ag(111) alloy surfaces irrespective of whether the surface termination corresponds to the bulk Pd 3 Ag composition, or is purely Pd-terminated. A higher coverage of H with CO present is obtained for the Pd-terminated surface; this surface also exhibits a larger range of chemical potentials for co-adsorbed hydrogen and CO. The barrier for H 2 activation increases with increasing CO coverage, but the surface composition has the largest impact on H 2 activation at intermediate CO coverage. The results imply that Pd-based membranes with typically ~ 23 wt% Ag are less prone to CO poisoning if the surface becomes Pd-terminated.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1987

Detection of reflector surface error from near-field data: Effect of edge diffracted field

The surface accuracy of large reflector antennas must be maintained within certain tolerances if high gain/low sidelobe performance is to be achieved. Thus the measurement of the surface profile is an important part of the quality control procedure when constructing antennas of this type. An efficient method for surface profile measurement has been proposed, i.e., the reflector surface is calculated from the measured near-field phase data using the theory of geometric optics. For a surface profile calculation of this kind, it is necessary to know the margin of error built into the method of calculation. This will enable a specification of the tolerance from which the surface profile can be determined. When calculating the surface profile from near-field phase data, there are two main sources of error. The first is the measurement error in near-field phase data. The second arises from the edge diffracted fields that are superimposed on the reflected fields in the measured near-field data. The error in the calculated surface profile produced by the edge diffracted fields is examined.

Cherrette, Alan R.↗
NASA NTRS1979

Effect of mid- and high-spatial frequencies on optical performance

In many of today's telescopes the effects of surface errors on image quality and scattered light are very important. The influence of optical fabrication surface errors on the performance of an optical system is discussed. The methods developed by Hopkins (1957) for aberration tolerancing and Barakat (1972) for random wavefront errors are extended to the examination of mid- and high-spatial frequency surface errors. The discussion covers a review of the basic concepts of image quality, an examination of manufacturing errors as a function of image quality performance, a demonstration of mirror scattering effects in relation to surface errors, and some comments on the nature of the correlation functions. Illustrative examples are included.

Noll, R. J.↗
NASA NTRS1999

Reflight of the Solid Surface Combustion Experiment: Flame Radiation Near Extinction

In flame spreading in quiescent and low-velocity opposing flows, effects of surface reradiation and flame radiation are important in establishing the spread rate and whether the flame, once ignited, survives to steady spread or extinguishes after a time long compared to the ignition event. A reflight of the Solid Surface Combustion Experiment (SSCE), supported by modelling, demonstrates that for thick, flat fuels, the ultimate fate of the flame is extinction rather than steady spread. A mismatch between the thermal scale in the gas, driven by radiation, and the species diffusion scale, driven by mass diffusion, develops such that the high temperature regions of the flame are ultimately located in a region to which oxygen cannot be supplied at a sufficient rate to sustain reaction, and extinction occurs. Results of the experiment conducted on Space Shuttle mission STS 85 on 9 August 1997 are reviewed. For the flat surface geometry, while the hydrodynamic phenomena associated with opposed-flow flame spread may be treated two dimensionally, the radiative effects are three dimensional, and so modelling the radiative processes, with the mismatch in dimensionality, is difficult. The cylindrical geometry at least one long compared to the radius, provides a configuration in which the radiative processes for spread in the axial direction are two dimensional, thus simplifying the modelling. The cylindrical geometry allows for the development of more sophisticated radiative models without the complication of dimensionality concerns, e.g., discrete transfer, which is discussed in detail by Bundy (1998). Additionally, the cylindrical geometry results in a "focussing" of the heat transfer to the surface and may allow for steady spread for radii that for thick fuels of the same half-thickness there is no steady spread.

Altenkirch, R. A.↗
DOE OSTI2023

Direct Numerical Simulation of Transitional and Turbulent Flows Over Multi-Scale Surface Roughness—Part II: The Effect of Roughness on the Performance of a High-Pressure Turbine Blade

Abstract Turbine blades generally present surface roughness introduced in the manufacturing process or caused by in-service degradation, which can have a significant impact on aero-thermal performance. A better understanding of the fundamental physical mechanisms arising from the interaction between the roughness and the turbine flow at engine-relevant conditions can provide insights for the design of blades with improved efficiency and longer operational life. To this end, a high-fidelity numerical framework combining a well-validated solver for direct numerical simulation and a second-order accurate immersed boundary method is employed to predict roughness-induced aero-thermal effects on an LS89 high-pressure turbine (HPT) blade at engine-relevant conditions. Different amplitudes and distributions of surface roughness are investigated and a reference smooth-blade simulation under the same flow conditions is conducted for comparison. Roughness of increasing amplitude progressively shifts the blade suction side boundary layer transition upstream, producing larger values of the turbulent kinetic energy and higher total wake losses. The on-surface data-capturing capabilities of the numerical framework provide direct measurements of the heat flux and the skin friction coefficient, hence offering quantitative information between the surface topology and engineering-relevant performance parameters. This work may provide a benchmark for future numerical studies of turbomachinery flows with roughness.

Engineering↗
DOE OSTI2019

The Effects of Carburization on the Fatigue Crack Growth Behaviors of Local Surface Cracks in Cylindrical Bars

In this study, a series of fatigue tests were conducted on C45 steel specimens with local surface cracks. The effects of carburizing treatment with different case depths were discussed under cyclic tensile and torsional loading. Moreover, the surface crack extension paths and crack propagation rates were discussed. In addition, the effects of additional static torsion under cyclic tensile loading and additional static tension under cyclic torsional loading were analyzed, and comparisons were made between the results of the carburized materials and those of the uncarburized materials. Some conclusions show that carburization can effectively retard crack extension and improve fatigue life. However, the improvement provided by the case depth on the fatigue life is limited to a certain range, and extensive case depths might decrease the fatigue strengths of materials. For the studied material, carburization had a more direct influence on the crack growth under cyclic tensile loading than cyclic torsional loading.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Chemistry in confined space through the eyes of surface science—2D porous materials

There are a rapidly growing number of studies showing exciting new opportunities in the way confinement effects on surfaces affect the properties of materials and their chemistry. These effects have been observed recently under two-dimensional (2D) van der Waals materials such as a graphene and boron nitride and for the case of supported 2D-porous oxides, including silicates, aluminosilicates and zeolite nanosheets. This review summarizes the current state of the art in this area of research and how confinement effects in 2D systems relate to those found in 3D porous and layered materials. The focus of this review is put in 2D-materials with inherent porosity, such as 2D-porous oxides. An outlook is also given for the future of this exciting emerging area.

36 MATERIALS SCIENCE↗
NASA NTRS1983

Space Shuttle heating analysis with variation in angle of attack and surface condition

The effects of variations in the angle of attack and surface catalycity condition on the Space Shuttle surface heating along the windward centerline are evaluated. Further, the time history of the nonequilibrium-to-equilibrium surface heating ratio and the boundary edge quantities are analyzed. Results show that a + or - 5% change in the angle of attack does not appreciably influence either the nonequilibrium heating or the nonequilibrium-to-equilibrium heat transfer ratio at higher (75 km) or lower (48 km) altitudes. The variation in the recombination rate parameter is found to affect the surface heating most at an altitude of about 75 km for the STS-2 flight. A maximum reduction of 49% in heating due to nonequilibrium chemistry is obtained at about a 75 km altitude in the nose region of the Orbiter for the STS-2 flight data. In addition, the nonequilibrium effects at the boundary layer edge are found to become less significant for altitudes less than 65 km even though the boundary layer flow may still be in nonquilibrium.

Gupta, R. N.↗
DOE OSTI2016

A leaf-molded transparent triboelectric nanogenerator for smart multifunctional applications

Transparent, flexible and highly efficient portable power sources are essential components of the next generation electronics and optoelectronic devices. However, complicated technology, expensive cost, environmental pollution and low-efficient output have limited its development. Herein, based on periodic contact/separation between human skin and the microstructured polydimethylsiloxane (PDMS) film, we demonstrate a transparent flexible triboelectric nanogenerator (TENG) through a relatively simple, low-cost, environmental-friendly and high-efficient method. For the first time, the natural leaves with rich surface textures were introduced to make microstructures on PDMS films as effective friction surface in the TENG. Furthermore, long silver nanowires (200 µm in length at least) through novel synthesis were assembled as high-performance electrode, resulting in the entirely flexible and transparent TENG. Owing to the unique design, the transparent flexible TENG was eventually obtained with an enhanced output (Voc=56 V; Isc=3.1 μA) and remarkable transparency (88%). Owing to compelling features of the TENG, a self-powered user-interactive wearable system was successfully established by integrating a flexible electrochromic device (ECD). The remarkable color-tunable ability via mechanical control of our system, highly inspired by chameleons, is potentially useful in military camouflage, monitoring human activity visually, as well as replacing performance of face change in Sichuan Opera. Therefore, this research is a substantial advancement toward the construction of transparent nanogenerator and its multifunctional applications in energy conversation, wearable electronics, healthcare, culture experience, and even environmental protection.

42 ENGINEERING↗
DOE OSTI2019

An interface stabilized perovskite solar cell with high stabilized efficiency and low voltage loss

Stabilization of the crystal phase of inorganic/organic lead halide perovskites is critical for their high performance optoelectronic devices. However, due to the highly ionic nature of perovskite crystals, even phase stabilized polycrystalline perovskites can undergo undesirable phase transitions when exposed to a destabilizing environment. While various surface passivating agents have been developed to improve the device performance of perovskite solar cells, conventional deposition methods using a protic polar solvent, mainly isopropyl alcohol (IPA), results in a destabilization of the underlying perovskite layer and an undesirable degradation of device properties. We demonstrate the hidden role of IPA in surface treatments and develop a strategy in which the passivating agent is deposited without destabilizing the high quality perovskite underlayer. This strategy maximizes and stabilizes device performance by suppressing the formation of the perovskite δ-phase and amorphous phase during surface treatment, which is observed using conventional methods. Our strategy also effectively passivates surface and grain boundary defects, minimizing non-radiative recombination sites, and preventing carrier quenching at the perovskite interface. This results in an open-circuit-voltage loss of only ~340 mV, a champion device with a power conversion efficiency of 23.4% from a reverse current–voltage scan, a device with a record certified stabilized PCE of 22.6%, and enhanced operational stability. In addition, our perovskite solar cell exhibits an electroluminescence external quantum efficiency up to 8.9%.

14 SOLAR ENERGY↗
NASA NTRS1972

Practical method for diffusion welding of steel plate in air.

Description of a simple and easily applied method of diffusion welding steel plate in air which does not require a vacuum furnace or hot press. The novel feature of the proposed welding method is that diffusion welds are made in air with deadweight loading. In addition, the use of an autogenous (self-generated) surface-cleaning principle (termed 'auto-vac cleaning') to reduce the effects of surface oxides that normally hinder diffusion welding is examined. A series of nine butt joints were diffusion welded in thick sections of AISI 1020 steel plate. Diffusion welds were attempted at three welding temperatures (1200, 1090, and 980 C) using a deadweight pressure of 34,500 N/sq m (5 psi) and a two-hour hold time at temperature. Auto-vac cleaning operations prior to welding were also studied for the same three temperatures. Results indicate that sound welds were produced at the two higher temperatures when the joints were previously fusion seal welded completely around the periphery. Also, auto-vac cleaning at 1200 C for 2-1/2 hours prior to diffusion welding was highly beneficial, particularly when subsequent welding was accomplished at 1090 C.

Moore, T. J.↗
NASA NTRS1974

Influence of mixer nozzle velocity decay characteristics on CTOL-OTW jet noise shielding

Jet noise shielding benefits for CTOL engine-over-the-wing configurations were obtained with model scale multitube and lobed mixer nozzles and various shielding surface geometries. Spectral data were obtained with jet velocities from 585 to 1110 ft/sec. Correlation equations for predicting jet noise shielding benefits with single conical nozzle installations were modified to correlate the mixer nozzle data. The modification included consideration of the number of nozzle elements and the peak axial velocity decay in the flow field adjacent to the shielding surface. The effect of forward velocity on jet noise attenuation by a shielding surface is discussed.

Vonglahn, U.↗
NASA NTRS1975

Influence of mixer nozzle velocity decay characteristics on CTOL-OTW jet noise shielding

Jet noise shielding benefits for CTOL engine-over-wing configurations were obtained with model-scale multitube and lobed mixer nozzles and various shielding surface geometries. Spectral data were obtained with jet velocities from 585 to 1110 ft/sec. Correlation equations for predicting jet noise shielding benefits with single conical nozzle installations were modified to correlate the mixer nozzle data. The modification included consideration of the number of nozzle elements and the peak axial velocity decay in the flow field adjacent to the shielding surface. The effect of forward velocity on jet noise attenuation by a shielding surface is discussed.

Von Glahn, U.↗