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At least 1,675 records · Page 93

Circular economy priorities for photovoltaics in the energy transition

Among the many ambitious decarbonization goals globally, the US intends grid decarbonization by 2035, requiring 1 TW of installed photovoltaics (PV), up from ~110 GW in 2021. This unprecedented global scale-up will stress existing PV supply chains with increased material and energy demands. By 2050, 1.75 TW of PV in the US cumulatively demands 97 million metric tonnes of virgin material and creates 8 million metric tonnes of life cycle waste. This analysis leverages the PV in Circular Economy tool (PV ICE) to evaluate two circular economy approaches, lifetime extension and closed-loop recycling, on their ability to reduce virgin material demands and life cycle wastes while meeting capacity goals. Modules with 50-year lifetimes can reduce virgin material demand by 3% through reduced deployment. Modules with 15-year lifetimes require an additional 1.2 TW of replacement modules to maintain capacity, increasing virgin material demand and waste unless >90% of module mass is closed-loop recycled. Currently, no PV technology is more than 90% closed-loop recycled. Glass, the majority of mass in all PV technologies and an energy intensive component with a problematic supply chain, should be targeted for a circular redesign. Our work contributes data-backed insights prioritizing circular PV strategies for a sustainable energy transition.

14 SOLAR ENERGY↗

Power Conversion with a Stirling Cycle for Venus Surface Mission

The light-filtering characteristic of the dense, mostly-CO2 atmosphere of Venus, combined with the high atmospheric cloud cover, relegates the surface mission use of photovoltaic power systems and beckons for the independence and reliability of a nuclear-powered energy source. A multi-faceted Venus mission study was completed at NASA GRC in December of 2003 that resulted in the preliminary design of a helium- charged, kinematic Stirling converter, which is powered by nuclear, General Purpose Heat Source (GPHS) modules. The kinematic, Stirling power converter is configured to drive an electronics and sensor cooler in addition to a generator for electrical power. This paper briefly describes the design process and also describes and summarizes key features of the Stirling power converter preliminary design concept. With an estimated total efficiency of 23.4%, the power converter drives the electronics and sensor cooler, and also produces 100 watts of electricity. The converter rejects waste heat at a hot sink temperature of 500 C.

Mellott, Ken↗

Solar and Storage Techno-Economic Analysis Tutorial for the IEEE Photovoltaic Specialist Conference (PVSC)

This tutorial will highlight the most recent efforts from the National Renewable Energy Laboratory (NREL) to track solar photovoltaic (PV) technology trends and manufacturing costs, project levelized cost of electricity (LCOE), and project levelized cost of solar plus storage (LCOSS) for systems across the globe. We will begin with an overview of the global PV supply chain and 2021 benchmark input data for NREL's crystalline silicon (c-Si) and thin film PV module manufacturing cost models. The framework that we follow and will review during this tutorial provides a methodology to prepare bottom-up manufacturing cost models including the items within the U.S. Generally Accepted Accounting Principles (GAAP) and the International Financial Reporting Standards (IFRS). For the polysilicon, wafer, cell conversion, and module assembly steps of the c-Si supply chain, and for thin film modules, we will review input data and methods useful for calculating the costs of goods sold (COGS); research and development (R&D) expenses; and sales, general, and business administration (S, G, &A) expenses. This 2021 benchmark analysis is compiled for state-of-the-art c-Si and thin film module manufacturing. We will also review methods for our 2021 system benchmark costs calculations and LCOE technoeconomic analysis of PV systems and solar plus storage systems. Next generation technologies that lower PV manufacturing and installation costs, reduce operations and maintenance (O&M) expenses, and improve system energy yield will also be highlighted. Techniques for comparing LCOE performance will also be reviewed. We look forward to sharing NREL's extensive work in these areas and discussing ideas for future directions.

cost models↗

Water Footprint of European Rooftop Photovoltaic Electricity based on Regionalised Life Cycle Inventories

The water use of photovoltaic (PV) electricity has been investigated in very few studies so far, which may be due to the low water demand of PV systems during operation. In this study, the water consumption and water withdrawal of electricity generated by PV systems were assessed by considering all life cycle stages and by taking account of country-level regional differences in water availability. The life cycle inventories of the manufacture of monocrystalline silicon (mono-Si) and cadmium telluride (CdTe) PV modules are based on data collected between 2010 and 2013 and take account of the shares of different countries in total global production. The water use in the life cycle inventories of European rooftop PV systems and conventional electricity generation technologies was regionalised to the country or region (such as continents, political or geographic entities of several countries) level and complemented by the share of water lost by evaporation. The AWARE (Available WAter REmaining) method was used to assess the water stress impact caused by water consumption and water withdrawal of electricity generation by European rooftop PV systems as well as by reservoir hydroelectric power plants and large-scale hard coal and nuclear power plants in Europe. The functional unit of this analysis is 1 kWh of alternating current (AC) electricity (at busbar). The life cycle inventories were linked to KBOB (Coordination Group for Construction and Property Services) life cycle inventory data DQRv2:2016, which are based on ecoinvent data v2.2 and contain updated life cycle inventory data in relevant economic sectors. This study was financed by the Swiss Federal Office of Energy (SFOE) and carried out in the framework of the Task 12 of the Photovoltaic Power Systems Programme (PVPS) of the International Energy Agency (IEA).

14 SOLAR ENERGY↗

Evaluation of the DC bus link capacitors and power transistor modules in the qualification testing of PV inverters

To achieve useful, fair, and cost-effective design qualification and type approval testing for PV inverters, two procedures were developed and demonstrated to evaluate the bus link capacitors and power transistor—and where applicable, its module—for long-term reliability. We evaluate the inverter under simulated use conditions with heat run tests to find the highest operating temperatures reached by these components. The procedures are demonstrated in this study with a 4-kVA class string inverter. The maximum temperature of the DC bus link capacitors was determined to be 76.4°C when the ambient temperature was at the inverter's maximum rated temperature of 60°C with derating occurring. On the other hand, the power transistor module's maximum temperature using the heat sink temperature as the index, 92.6°C, occurred in an ambient of 40.8°C when derating was not occurring. The conditions found for upper temperatures exhibited by these components are, respectively, proposed for implementation in the dry heat and thermal cycling tests in the IEC 62093 “Power conversion equipment for photovoltaic systems – Design qualification testing” international standard draft so that the levels applied in the tests are in proportion to those experienced in the field. Finally as a result, fairer evaluation of inverter reliability is realized.

14 SOLAR ENERGY↗

Scalable fabrication of perovskite solar cells

Perovskite materials use earth-abundant elements, have low formation energies for deposition and are compatible with roll-to-roll and other high-volume manufacturing techniques. These features make perovskite solar cells (PSCs) suitable for terawatt-scale energy production with low production costs and low capital expenditure. Demonstrations of performance comparable to that of other thin-film photovoltaics (PVs) and improvements in laboratory-scale cell stability have recently made scale up of this PV technology an intense area of research focus. Here, we review recent progress and challenges in scaling up PSCs and related efforts to enable the terawatt-scale manufacturing and deployment of this PV technology. We discuss common device and module architectures, scalable deposition methods and progress in the scalable deposition of perovskite and charge-transport layers. We also provide an overview of device and module stability, module-level characterization techniques and techno-economic analyses of perovskite PV modules.

14 SOLAR ENERGY↗

Addressing Soiling: From Interface Chemistry to Practicality

Natural soiling has reduced the energy output of photovoltaic (PV) systems since the technology was first used. Projecting even a small average annual soiling loss translates to billions of dollars in annual lost revenue worldwide. Production losses due to soiling can be very high in some locations, substantially increasing the levelized cost of electricity (LCOE) due to lost power production, increased operating and maintenance costs, and/or increased finance cost due to the uncertainty. Furthermore, although soiling has been discussed in the literature for more than 70 years, solutions to many problems are still needed. The National Renewable Energy Laboratory (NREL) is working with the PV industry to develop the tools/knowledge so that the effects of soiling can be predicted for different environmental conditions and cost-effective mitigation can be implemented. For this project, NREL performed a number of research and development tasks/subtasks in the following general areas to 1) predict PV module soiling losses based on environmental factors at a PV installation and from its energy production data, 2) quantitatively measure the adhesion forces to understand the physics enabling soiling, and 3) develop related standards on PV module coatings and artificial soiling. At the inception of the project, the PV industry considered these efforts to be the most important and immediate soiling issues that we could address to have the highest impact on LCOE. These focused efforts have led to outstanding accomplishments that have been communicated and very well received by the community.

14 SOLAR ENERGY↗

Two-dimensional electron gas in a modulation-doped SrTiO{sub 3}/Sr(Ti, Zr)O{sub 3} heterostructure

A two-dimensional electron gas (2DEG) in SrTiO{sub 3} is created via modulation doping by interfacing undoped SrTiO{sub 3} with a wider-band-gap material, SrTi{sub 1−x}Zr{sub x}O{sub 3}, which is doped n-type with La. All layers are grown using hybrid molecular beam epitaxy. Using magnetoresistance measurements, we show that electrons are transferred into the SrTiO{sub 3}, and a 2DEG is formed. In particular, Shubnikov-de Haas oscillations are shown to depend only on the perpendicular magnetic field. Experimental Shubnikov-de Haas oscillations are compared with calculations that assume multiple occupied subbands.

36 MATERIALS SCIENCE↗

A Circularity Assessment for Silicon Solar Panels Based on Dynamic Material Flow Analysis: Preprint

Solar photovoltaics (PV) are the fastest growing renewable energy technology for clean, inexpensive, and sustainable electricity generation. Along with numerous technical roadmaps to improve system cost, performance and reliability, the PV industry should also plan to handle large volumes of silicon panel waste, which is initially estimated to be ~13 million metric tons (MT) by 2050 in the U.S. alone. Understanding the magnitude of material needs and how material flows throughout the PV panel life cycle could respond to design, operational and different end-of-life (EOL) circular pathways will help transition into a circular, resource-conserving economy. Herein, we introduce a dynamic material flow analysis (DMFA) framework based on electricity generation to quantify time-series stocks and flows of bulk PV materials (e.g., solar glass and aluminum frames) throughout the life cycles of utility-scale silicon PV systems in the U.S. in the period 2000-2100. We apply the model to a range of scenarios to understand how material demands depend on selected PV-related parameters, different material circularity strategies, and recent module design trends (e.g., bifacial, frameless). We found that float glass and aluminum in PV installations would likely reach 100 million MT and 12 million MT by 2100, respectively, in the baseline scenario. The most influential parameters for PV installation and subsequent waste reduction are found to be module lifetime, module efficiency, annual degradation, and material reduction. Module recycling and component remanufacturing were found to be the most effective material circularity strategies for waste minimization. Panel reuse has negligible savings on waste under current module efficiencies compared to replacements with newer generations with higher efficiency. Ongoing trends to produce larger power frameless modules could save 10 million MT of glass and ~9 million MT of aluminum. Our results enable advanced planning for future materials needs and provide insight into potential opportunities to minimize waste.

circular economy↗

In-Situ Measurement of Crystalline Silicon Modules Undergoing Potential-Induced Degradation in Damp Heat Stress Testing for Estimation of Low-Light Power Performance

The extent of potential-induced degradation of crystalline silicon modules in an environmental chamber is estimated using in-situ dark I-V measurements and applying superposition analysis. The dark I-V curves are shown to correctly give the module power performance at 200, 600 and 1,000 W/m 2 irradiance conditions, as verified with a solar simulator. The onset of degradation measured in low light in relation to that under one sun irradiance can be clearly seen in the module design examined; the time to 5% relative degradation measured in low light (200 W/m 2 ) was 28% less than that of full sun (1,000 W/m 2 irradiance). The power of modules undergoing potential-induced degradation can therefore be characterized in the chamber, facilitating statistical analyses and lifetime forecasting.

14 SOLAR ENERGY↗

In Situ Exploration of Dipole Field Effects on Weak Hysteresis in 3D/2D Perovskites

This research delves into the effects of 2D layers on the functionality of 3D perovskite using lock-in amplifier-based in situ surface photovoltage (SPV) and its phase spectroscopy, with an emphasis on elucidating the connection between the tuning of dipole moments and the photocurrent hysteresis. Conventionally, the SPV of a perovskite/hole transport layer is observed to diminish as positive bias escalates. However, this trend is reversed in the case of 3D perovskite samples, where an augmentation in SPV is noted under positive bias. Notably, 3D/2D perovskite structures initially show a decrease, then an increase in SPV as bias intensifies, a phenomenon more pronounced with larger dipole moments in 2D. However, there is no linear relationship between the dipole moment and the hysteresis factor. Furthermore, using in situ light-chopping-frequency-modulated SPV and Kelvin Probe Force Microscopy, it is revealed that the dipole fields of 2D layers can hinder ion migration. This leads to efficient hole transfer and minimal photocurrent hysteresis in 3D/2D perovskites, providing strong evidence for the underlying cause of hysteresis. Additionally, these findings suggest intricate interplays among the external electric field, interface dipole moments, and surface photovoltaics, offering significant insights into perovskite optoelectronics.

3D/2D perovskite↗

Chemical Vapor Deposition for Ultra-lightweight Thin-film Solar Arrays for Space

The development of thin-film solar cells on flexible, lightweight, space-qualified substrates provides an attractive cost solution to fabricating solar arrays with high specific power, (W/kg). The use of a polycrystalline chalcopyrite absorber layer for thin film solar cells is considered as the next generation photovoltaic devices. A key technical issues outlined in the 2001 U.S. Photovoltaic Roadmap, is the need to develop low cost, high throughput manufacturing for high-efficiency thin film solar cells. At NASA GRC we have focused on the development of new single-source-precursors (SSPs) and their utility to deposit the chalcopyrite semi-conducting layer (CIS) onto flexible substrates for solar cell fabrication. The syntheses and thermal modulation of SSPs via molecular engineering is described. Thin-film fabrication studies demonstrate the SSPs can be used in a spray CVD process, for depositing CIS at reduced temperatures, which display good electrical properties, suitable for PV devices.

Hepp, Aloysius F.↗

Switching coordination of distributed dc-dc converters for highly efficient photovoltaic power plants

A distributed photovoltaic (PV) power plant includes a plurality of distributed dc-dc converters. The dc-dc converters are configured to switch in coordination with one another such that at least one dc-dc converter transfers power to a common dc-bus based upon the total system power available from one or more corresponding strings of PV modules. Due to the coordinated switching of the dc-dc converters, each dc-dc converter transferring power to the common dc-bus continues to operate within its optimal efficiency range as well as to optimize the maximum power point tracking in order to increase the energy yield of the PV power plant.

14 SOLAR ENERGY↗

Evaluating the causes of photovoltaics cost reduction: Why is PV different?

The goals of this project were to quantify sources of cost reduction in photovoltaics (PV), improve theories of technological evolution, develop new analytical methods, and formu- late guidelines for continued cost reduction in photovoltaics. A number of explanations have been suggested for why photovoltaics have come down in cost rapidly over time, including increased production rates, significant R&D expenditures, heavy patenting ac- tivity, decreasing material and input costs, scale economies, reduced plant construction costs, and higher conversion efficiencies. We classified these proposed causes into low- level factors and high-level drivers. Low-level factors include technical characteristics, such as module efficiency or wafer area, which are easily posed in terms of variables of a cost equation. High-level factors include scale economies, research and development (R&D), and learning-by-doing.

14 SOLAR ENERGY↗

Summary of NREL's FY13-FY15 Photovoltaic Subprogram

In this report, you will find summaries of the completed FY13-FY15 Photovoltaic projects that were funded within NREL. The summaries describe the initial motivation for the project; significant achievements, including publications, intellectual property, and collaborations; and remaining challenges. Among the NREL projects, you will find research of almost every major PV technology - from the next generation of silicon PV to relatively new organic PVs - as well as projects advancing PV module durability and characterization. Each of these projects was designed to support SunShot's goals, putting the United States one step closer to widespread use of low-cost, clean electricity.

14 SOLAR ENERGY↗

LiNbO{sub 3}: A photovoltaic substrate for massive parallel manipulation and patterning of nano-objects

The application of evanescent photovoltaic (PV) fields, generated by visible illumination of Fe:LiNbO{sub 3} substrates, for parallel massive trapping and manipulation of micro- and nano-objects is critically reviewed. The technique has been often referred to as photovoltaic or photorefractive tweezers. The main advantage of the new method is that the involved electrophoretic and/or dielectrophoretic forces do not require any electrodes and large scale manipulation of nano-objects can be easily achieved using the patterning capabilities of light. The paper describes the experimental techniques for particle trapping and the main reported experimental results obtained with a variety of micro- and nano-particles (dielectric and conductive) and different illumination configurations (single beam, holographic geometry, and spatial light modulator projection). The report also pays attention to the physical basis of the method, namely, the coupling of the evanescent photorefractive fields to the dielectric response of the nano-particles. The role of a number of physical parameters such as the contrast and spatial periodicities of the illumination pattern or the particle deposition method is discussed. Moreover, the main properties of the obtained particle patterns in relation to potential applications are summarized, and first demonstrations reviewed. Finally, the PV method is discussed in comparison to other patterning strategies, such as those based on the pyroelectric response and the electric fields associated to domain poling of ferroelectric materials.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Assessing Machine Learning as a Tool to Explain Variance in Deployed Photovoltaic (PV) System Degradation

Degradation remains a large uncertainty in forecasting production for PV plants, creating significant risk for developers and financiers. This study aims to quantify the distribution and drivers of degradation across 10,000 PV systems deployed for distributed or utility generation by training a machine learning model to predict year-over-year degradation rates from metadata characteristics. A combination of K-Means clustering and random forest regressor were found to associate multiple metadata features as potential drivers of degradation, including module characteristics, system design, and climate features. From this, it is inferred that if machine learning is able to find complex patterns between metadata features and system performance loss, such methods can be employed to help developers and financiers make data-informed decisions when estimating long-term energy production forecasts in financial models.

Dunn, Jimmy C.↗

Reliability and Geographic Trends of 50,000 Photovoltaic Systems in the USA: Preprint

This paper presents performance and reliability data from nearly 50,000 photovoltaic (PV) systems totaling 1.7 gigawatts installed capacity in the USA from 2009 to 2012 and their geographic trends. About 90% of the normal systems and about 85% of all systems, including systems with known issues, performed to within 10% or better of expected performance. Although considerable uncertainty may exist due to the nature of the data, hotter climates appear to exhibit some degradation not seen in the more moderate climates. Special causes of underperformance and their impacts are delineated by reliability category. Hardware-related issues are dominated by inverter problems (totaling less than 0.5%) and underperforming modules (totaling less than 0.1%). Furthermore, many reliability categories show a significant decrease in occurrence from year 1 to subsequent years, emphasizing the need for higher-quality installations but also the need for improved standards development. The probability of PV system damage because of hail is below 0.05%. Singular weather events can have a significant impact such as a single lightning strike to a transformer or the impact of a hurricane. However, grid outages are more likely to have a significant impact than PV system damage when extreme weather events occur.

14 SOLAR ENERGY↗