Search NASA⌕ Search

SEARCH · Search NASA

Results for “Solar diffuser”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,675 records · Page 93
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

The anisotropic nature of singlet fission in single crystalline organic semiconductors

The escalating global energy predicament implores for a revolutionary resolution—one that converts sunlight into electricity—holding the key to supreme conversion efficiency. This comprehensive review embarks on the exploration of the principle of generating multiple excitons per absorbed photon, a captivating concept that possesses the potential to redefine the fundamental confines of conversion efficiency, albeit its application remains limited in photovoltaic devices. At the nucleus of this phenomenon are two principal processes: multiple exciton generation (MEG) within quantum-confined environments, and singlet fission (SF) inside molecular crystals. The process of SF, characterized by the cleavage of a single photogenerated singlet exciton into two triplet excitons, holds promise to potentially amplify photon-to-electron conversion efficiency twofold, thereby laying the groundwork to challenge the detailed balance limit of solar cell efficiency. Our discourse primarily dissects the complex nature of SF in crystalline organic semiconductors, laying special emphasis on the anisotropic behavior of SF and the diffusion of the subsequent triplet excitons in single-crystalline polyacene organic semiconductors. We initiate this journey of discovery by elucidating the principles of MEG and SF, tracing their historical genesis, and scrutinizing the anisotropy of SF and the impact of quantum decoherence within the purview of functional mode electron transfer theory. We present an overview of prominent techniques deployed in investigating anisotropic SF in organic semiconductors, including femtosecond transient absorption microscopy and imaging as well as stimulated Raman scattering microscopies, and highlight recent breakthroughs linked with the anisotropic dimensions of Davydov splitting, Herzberg–Teller effects, SF, and triplet transport operations in single-crystalline polyacenes. Through this comprehensive analysis, our objective is to interweave the fundamental principles of anisotropic SF and triplet transport with the current frontiers of scientific discovery, providing inspiration and facilitating future ventures to harness the anisotropic attributes of organic semiconductor crystals in the design of pioneering photovoltaic and photonic devices.

Chemistry↗
NASA NTRS1977

"Solar ponds"

Array uses low-cost materials and heavy construction methods to make collection and storage of solar energy economical on large scale required for commercial operation. Series of long trenches are dug side by side over an area large in comparison to heat diffusivity of soil.

Miller, C. G.↗
NASA NTRS1977

Bright X-ray arcs and the emergence of solar magnetic flux

The Skylab S-056 and S-082A experiments and ground-based magnetograms have been used to study the role of bright X-ray arcs and the emergence of solar magnetic flux in the McMath region 12476. The S-056 X-ray images show a system of one or sometimes two bright arcs within a diffuse emitting region. The arcs seem to directly connect regions of opposite magnetic polarity in the photosphere. Magnetograms suggest the possible emergence of a magnetic flux. The width of the main arc is approximately 6 arcsec when most clearly defined, and the length is approximately 30-50 arcsec. Although the arc system is observed to vary in brightness over a period exceeding 24 hours, it remains fixed in orientation. The temperature of the main arc is approximately 3 x 10 to the 6th K. It is suggested that merging magnetic fields may provide the primary energy source, perhaps accompanied by resistive heating from a force-free current.

Chapman, G. A.↗
NASA NTRS1979

X-ray studies of quasars with the Einstein Observatory

Results of an investigation of the X-ray properties of quasars conducted using the Einstein Observatory (HEAO 2) are reported. The positions, fluxes and luminosities of 35 known quasars were observed by the Einstein high-resolution imaging detector and the imaging proportional counter. Assuming optical redshifts as valid distance indicators, 0.5-4.5 keV X-ray luminosities ranging from 10 to the 43rd to 10 to the 47 ergs/sec are obtained, with evidence of very little cold gas absorption. Flux variability on a time scale of less than 10,000 sec is observed for the quasar OX 169, which implies a mass between 8 x 10 to the 5th and 2 x 10 to the 8th solar masses for the black hole assumed to be responsible for the emission. Preliminary results of the quasar survey also indicate that quasars contribute significantly to the diffuse X-ray background.

Tananbaum, H.↗
NASA NTRS1983

The cool DC white dwarf Stein 2051B

Visual scans from the Kitt-Peak 2.1-m telescope and UV spectra from the IUE satellite are combined in a spectroscopic study of the bright DC white dwarf, Stein 2051B. With a cooling age near 2 billion years, and a resulting atmospheric mass of hydrogen of the order of 6 x 10 to the 17th g, the accretion rate over the star's lifetime is less than 2 x 10 to the -25th solar masses/year. This is far below the predictions of standard accretion theories, and requires unreasonably strong suppression of hydrogen accretion in this star if the accretion-diffusion theory is to account for the carbon abundance found. It is suggested that the carbon may have been brought to the surface by convective mixing.

Wegner, G.↗
NASA NTRS1984

IRAS observations of cometary dust

It is pointed out that solid material present in the coma and tail of a comet is revealed by the scattering of sunlight and thermal emission of absorbed solar radiation. The large beam size and low background of the cold Infrared Astronomy Satellite (IRAS) telescope make it extremely well suited to the measurement of faint diffuse thermal emission from solid grains associated with comets. The IRAS project was conducted jointly by the Netherlands, the United Kingdom, and the U.S. Its basic objective involved a survey of the sky in four wavelength regions centered on 12, 25, 60, and 100 microns. The present paper is mainly concerned with IRAS observations of the coma-nucleus regions as defined by the maximum in the intensity distribution. Attention is given to circumstances of comet observations, dust production rates, and a discussion of the results.

Walker, R. G.↗
NASA NTRS1987

Energy diffusion of pickup ions upstream of comets

A steady state model of pickup ion energization upstream of a cometary bow wave is presented in order to investigate the effects of quasi-linear energy diffusion in the turbulence there. The model assumes that the ions are immediately isotropized at pickup, and it includes the effects of adiabatic acceleration in the slowing solar wind and of continual pickup of ions as the comet is approached. By taking all physical quantities to fall off as power laws with distance from the comet, an analytical expression is obtained for the distribution function of pickup ions in the reference frame moving with the solar wind. To illustrate the application of this model, the model results are compared to the observations of pickup ions at comet Giacobini-Zinner. At present, this is the only cometary encounter for which sufficient quantitative information is available. The model does not compare well with these observations, but it is not clear whether the differences are due to artificial problems in the model or the data analysis or to the action of other energization processes at this comet. Preliminary results from the Halley encounters appear to agree more closely with this model.

Isenberg, Philip A.↗
NASA NTRS1988

Downstream energetic proton and alpha particles during quasi-parallel interplanetary shock events

This paper considers the energetic particle populations in the downstream region of three quasi-parallel interplanetary shock events, which was explored using the ISEE 3 Ultra Low Energy Charge Analyzer sensor, which unambiguously identifies protons and alpha particles using the electrostatic deflection versus residual energy technique. The downstream particles were found to exhibit anisotropies due largely to convection in the solar wind. The spectral indices of the proton and the alpha-particle distribution functions were found to be remarkably constant during the downstream period, being generally insensitive to changes in particle flux levels, magnetic field direction, and solar wind densities. In two of the three events, the proton and the alpha spectra were the same throughout the entire downstream period, supporting the prediction of diffusive shock acceleration theory.

Tan, L. C.↗
DOE OSTI2020

Tandem particle-slurry batch reactors for solar water splitting (Final Scientific/Technical Report)

Economically, particle slurry reactors are projected to be one of the most promising technologies for solar photoelectrochemical hydrogen production, according to a 2009 techno-economic analysis commissioned by the US DOE and performed by Directed Technologies, Inc. The Fuel Cell Technologies Office’s Multi-Year Research, Development and Demonstration (MYRD&D) goals and targets are to reduce the cost of H 2 produced from renewable sources at the plant gate (i.e. not including delivery, dispensing, or storage) to < $2.00/gge, equivalent to ~$2.00/kg H 2 . Research results from our techno-economic modeling research suggest that this target could be met using particle slurry reactors assuming STH efficiencies in the range of 5 – 10%, materials lifetimes of < 1 year, and nanoparticles that cost up to 20 times more than projected costs of TiO 2 -coated Fe 2 O 3 nanoparticles. Although most large worldwide research efforts directed at solar photoelectrochemical hydrogen production focus on wafer-based designs, the projected lower cost for a particle slurry reactor at these disparate projected STH efficiencies clearly suggests that particle slurry reactors could be a scalable and deployable technology, assuming several challenges are overcome. These major technological challenges include the demonstration of a vertically-stacked-vessel architecture that is capable of operating sustainably while mostly relying on diffusion and natural convection to mix the redox shuttles between the vessels, and the demonstration that photocatalyst particles can operate at an overall 1% STH efficiency or larger when incorporated into this two-vessel design. Our research adds to the understanding of photocatalytic reactors for solar water splitting through numerical modeling results and experimental results. Numerical models were developed to simulate relevant device physics including particle and reactor dimensions which affect optical, transport, and rheological properties, electrocatalytic and photovoltaic properties of particles at various temperatures, and properties of redox shuttles and separators. Moreover, theoretical maximum solar-to-hydrogen efficiencies for ensembles of particles like in photocatalyst reactors were modeled and simulated and shown to equal or exceed those of photoelectrochemical designs under most scenarios. These results help determine constraints on the reactor that will enable more optimal designs for future prototypes. In parallel, experiments were performed to identify the most effective redox shuttles and to empirically validate the numerical models and simulations. Toward the latter, state-of-the-art light-absorbing particles and electrocatalysts were synthesized and characterized physically and photoelectrochemically for water electrolysis and redox chemistry with redox shuttles in the form factor of mesoporous electrodes and free-floating particles. The most promising materials candidates were used in a suspension reactor to evaluate performance toward photocatalytic H 2 production and results from the two measurements were compared. Predominantly, state-of-the-art cocatalyst-modified Rh-doped SrTiO 3 and BiVO 4 particles were further characterized to assess for their ability to perform visible-light-driven H 2 and O 2 evolution, respectively, and results were similar to those reported for the state-of-the-art in the peer-reviewed literature. Outcomes from this work inform the public of the effectiveness and promise of solar photocatalytic water splitting for clean and renewable hydrogen production. This work may also help increase research interest and funding for photocatalysis projects, which will accelerate development of a technology that will benefit the public by generating fuel while emitting few greenhouse gases and pollutants.

08 HYDROGEN↗
NASA NTRS1981

Correlation of the cosmic-ray intensity with solar-terrestrial parameters

Results are presented of numerical simulations of cosmic ray drift due to perturbations in the interplanetary medium affecting solar-terrestrial parameters. Computations were performed for a model spherical heliosphere of radius 25 AU, with an interplanetary magnetic field in the shape of an Archimedean spiral with magnitude of 5 gamma at 1 AU, corresponding to a wind velocity of 400 km/sec, and diffusion coefficients corresponding to the assumption that the parallel mean free path is somewhat larger han the cyclotron radius at earth orbit, and its spatial dependence is proportional to the gyroradius. It is found that perturbations in the heliospheric equatorial regions affect galactic cosmic rays more effectively when the Northern Hemisphere heliospheric magnetic field is directed inward rather than outward, with perturbations in the parallel drift coefficient more effective than perturbations in solar wind velocity or perpendicular drift velocity. Results are consistent with the observed variation of the correlation between the geomagnetic aa index and the neutron monitor counting rate on Mt. Washington with the solar cycle.

Jokipii, J. R.↗
NASA NTRSDate not supplied

The Hourly GHI, DHI and DNI: Intercomparison of the CERES-Based Data and the NSRDB Data through Comparison with the Ground-Based BSRN Data

The NASA Clouds and the Earth’s Radiant Energy System (CERES) SYN1deg(Ed4.1) provides hourly global horizontal irradiance (GHI), diffuse horizontal irradiance (DHI) and direct horizontal irradiance (DirHI) at 1-degree latitude by 1-degree longitude resolution, and the time span is from March 2000 to near present. While the GHI agrees well with the ground-based Baseline Surface Radiation Network (BSRN) data, the DHI and DirHI are, respectively, positively and negatively biased against the BSRN data, and so is the direct normal irradiance (DNI) derived simply by dividing the DirHI by the cosine of the hourly solar zenith angle (SZA). We found that the biases tend to be well-defined functions of cos(SZA) and the cloud fraction (CLFR). We thus performed a bias-correction on the hourly DHI and DNI in the latitude-cos(SZA)-CLFR phase space, and therefrom, we derived the hourly global tilted irradiance (GTI) at a number of tilt angles using the isotropic diffuse irradiance model, and the results agree well with the GTI derived from the original BSRN near-instantaneous records. Meanwhile, the National Renewable Energy Laboratory (NREL) has produced the National Solar Radiation Database (NSRDB) with finer spatiotemporal resolution using its Physical Solar Model (PSM) and surface-based measured data, model results and satellite-based data as inputs. Now the NSRDB data covers not only the United States and its neighboring regions, but Europe, Africa, Asia and Oceania. The available temporal resolutions are 5, 10, 15, 30 and 60 minutes and the spatial resolutions are 2, 4 and 10 km, depending on the selected region. In this presentation, we compare both the CERES-based and NSRDB GHI, DHI and DNI with their BSRN counterparts and show how finer spatial resolution may give us an advantage in data accuracy and usability.

Taiping Zhang↗
DOE OSTI2019

Isotopic evidence for a young lunar magma ocean

Herein, mare basalt sources and ferroan anorthosite suite cumulates define a linear array on a 146 Sm/ 144 Nd versus 142 Nd/ 144 Nd isochron plot demonstrating these materials were derived from a common reservoir at 4336 +31 / –32 Ma. The minimum proportion of the Moon that was in isotopic equilibrium at this time is estimated to be 1-3% of its entire volume based on the geographic extent from which the analyzed samples were collected and the calculated depths from which the samples were derived. Scenarios in which large portions of the Moon were molten to depths of many hundreds of kilometers are required to produce the observed Sm-Nd isotopic equilibrium between the mantle and crustal rocks at 4.34 Ga. This is a consequence of the fact that limited heating of a solid Moon above the blocking temperature of the Sm-Nd isotopic system is insufficient to diffusively homogenize radiogenic Nd throughout the mantle and crust. There are three scenarios that might account for global-scale isotopic equilibrium on the Moon relatively late in Solar System history including: (1) Sm-Nd re-equilibration of a solid Moon resulting from widespread melting in response to mantle overturn or a very large impact, (2) early accretion of the Moon followed by delayed cooling due to the presence of an additional heat source that kept a large portion of the Moon molten until 4.34 Ga, or (3) late accretion of the Moon followed by rapid cooling of the magma ocean late in Solar System history. Neither density-driven overturn of the mantle, nor a large impact, are likely to homogenize the mantle and crust to the extent required by the Sm-Nd isochron. Likewise, secondary heating mechanisms, such as tidal heating or radioactive decay, are not efficient enough to keep the Moon molten to the depth of the mare basalt source regions for many tens to hundreds of millions of years. Instead, the age of equilibrium between such a compositionally diverse set of rocks, produced on a global scale, likely records the time of primordial solidification of the Moon from a magma ocean. This scenario accounts for both the petrogenetic characteristics of lunar rock suites, as well as their Sm-Nd isotopic systematics. It is supported by the preponderance of ~4.35 Ga ages obtained for other hypothetical magma ocean crystallization products, such as ferroan anorthosite suite rocks and K, REE, and P enriched cumulates that are thought to represent flotation cumulates of the magma ocean and the last vestiges of magma ocean solidification, respectively.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2024

Rooftop Photovoltaics and Electric Vehicle Co-Adoption: Attitudes, Norms, Diffusion, and Economics

The overall objectives of the project were to (1) Identify personal and social norms, peer effects, demographics and contextual factors (such as household energy expenditures, experience with outages, charging infrastructure availability) that may facilitate or hinder Solar-EV co-adoption; (2) outline strategies for the design of programs and practices that will enable reasoned RPV and EV adoption and their co-adoption; and (3) assemble a dataset comprised of survey responses of RPV-EV co-adopters, RPV-only adopters, EV-only adopters, and non-adopters. These objectives were only partially fulfilled given the decision to terminate the project. The research team was able to complete the semi-structured interviews, the core BY1 task and summarize the results below. As well, once the team learned of the research project’s fate, it sought and obtained the DOE SETO Technical Manager’s approval to repurpose funds for BY2 tasks to the extent feasible. Rather than invest further resources in expanding the pool of potential survey respondents and having no budget to survey, the research team repurposed funds subject and undertook a more limited (geographically) survey, but also expanded to it to include contingent valuation questions. The analysis of the survey data will necessarily be delayed given the lack of budget support, although some information on the respondent sample is in the results. Given a lack of attention to co-adoption previously, the insights generated in this project should assist decision-makers and industry actors in the development of programs and practices that enable reasoned RPV adoption and EV adoption and their co-adoption.

14 SOLAR ENERGY↗
NASA NTRS1972

Solar radiation calibration facility.

A recently completed calibration facility for the NASA Mississippi Test Site is described. It combines the spectrum of water cooled long arc xenon radiation sources with the integration sphere concept covered by a special barium sulfate diffusely reflecting paint. The sphere is six feet in diameter and completely encompasses the four xenon sources (2.5 kW each) and the five pyranometers under calibration. The sources are contained within the base of the central pedestal and allow the radiation to be emitted into the lower hemisphere. Only through diffuse reflection and multiple scattering is the radiation finally incident upon the test zone, which is in the equatorial plane of the sphere on the top of the pedestal. The sphere is temperature controlled.

Hershey, T. L.↗
NASA NTRS1973

Observations of spatial structure in the soft X-ray diffuse flux.

Repeated observations of a diffuse source in the region of about 200 deg and +10 deg galactic longitude and latitude, respectively, illustrate the complexity of the low-energy X-ray background. The source is not well correlated with known objects or features, and cannot be explained by geometrically simple models of diffuse emission. The measurements indicate that this emission feature, and by implication a large fraction of the 1/4-keV flux observed in the galactic plane, probably originates outside the solar system.

Bunner, A. N.↗
NASA NTRS1973

Magnetic field reconnection and particle acceleration

After a brief review of steady state reconnection models, the processes are discussed which place an upper limit on the reconnection rate. In many applications the requirement that the width of the diffusion region exceed the ion gyroradius leads to a severe restriction on this limit. Unless the conductivity is much less than the value given by Spitzer's formula, solar flare times may result which are too long by a factor of 1000 or more. Turbulent and gyro effects which may lead to a reduced conductivity are shown to be operative, but only for sufficiently small ratios of plasma to magnetic pressure in the inflow. Particle energization processes associated with magnetic field reconnection and particle reflection by fast shocks are considered. These processes are effective as a first stage in the acceleration of charged particles, but additional multistep processes are needed to reach proton energies above a few MeV.

Sonnerup, B. U. O.↗
NASA NTRS1976

Depletion of solar wind plasma near a planetary boundary

A mathematical model is presented that describes the squeezing of solar wind plasma out along interplanetary magnetic field lines in the region between the bow shock and the effective planetary boundary (in the case of the earth, the magnetopause). In the absence of local magnetic merging the squeezing process should create a 'depletion layer', a region of very low plasma density just outside the magnetopause. Numerical solutions are obtained for the dimensionless magnetohydrodynamic equations describing this depletion process for the case where the solar wind magnetic field is perpendicular to the solar wind flow direction. For the case of the earth, the theory predicts that the density should be reduced by a factor exceeding 2 in a layer about 700-1300 km thick if the Alfven Mach number in the solar wind, is equal to 8. Scaling of the model calculations to Venus and Mars suggests layer thicknesses about 1/10 and 1/15 those of the earth, respectively, neglecting diffusion and ionospheric effects.

Zwan, B. J.↗
NASA NTRS1977

On the fragmentation of cosmic gas clouds. I - The formation of galaxies and the first generation of stars

The formation of galaxies is studied in the context of the fragmentation of massive diffuse ionized gas clouds. A semiquantitative discussion of the role of cooling indicates that there is a characteristic mass of a galaxy (of the order of 500 billion solar masses) which can fragment out of an ionized medium of density not exceeding 10 to the -25th power g/cu cm, whereas more massive galaxies attain a characteristic radius of the order of 60 kpc. The relationship between binding energy and mass is investigated for spheroidal galaxies. The role of H2 and Ly-alpha cooling in the fragmentation of primordial gas clouds is evaluated, and relatively qualitative arguments indicate that the first stars have masses of at least 0.3 solar mass with a characteristic mass of approximately 20 solar masses. When the average heavy-element abundance by mass exceeds about 0.00001, heavy-element cooling prevails over Ly-alpha cooling, and subsequent fragmentation forms second-generation stars of low characteristic mass.

Silk, J.↗