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At least 1,675 records · Page 93

An integrated methodology for optimizing the passive damping of composite structures

A method is presented for tailoring plate and shell composite structures for optimal forced damped dynamic response. The damping of specific vibration modes is optimized with respect to dynamic performance criteria including placement of natural frequencies and minimization of resonance amplitudes. The structural composite damping is synthesized from the properties of the constituent materials, laminate parameters, and structural geometry based on a specialty finite element. Application studies include the optimization of laminated composite beams and composite shells with fiber volume ratios and ply angles as design variables. The results illustrate the significance of damping tailoring to the dynamic performance of composite structures, and the effectiveness of the method in optimizing the structural dynamic response.

Saravanos, D. A.↗

Dynamical evolution of topology of large-scale structure

The nonlinear effects of statistical biasing and gravitational evolution on the genus are studied. The biased galaxy subset is picked for the first time by actually identifying galaxy-sized peaks above a fixed threshold in the initial conditions, and their subsequent evolution is followed. It is found that in the standard cold dark matter (CDM) model the statistical biasing in the locations of galaxies produces asymmetry in the genus curve and coupling with gravitational evolution gives rise to a shift in the genus curve to the left in moderately nonlinear regimes. Gravitational evolution alone reduces the amplitude of the genus curve due to strong phase correlations in the density field and also produces asymmetry in the curve. Results on the genus of the mass density field for both CDM and hot dark matter models are consistent with previous work by Melott, Weinberg, and Gott (1987).

Park, Changbom↗

Some Experimental Studies of Panel Flutter at Mach Number 1.3

Experimental studies of panel flutter using thin metal plates were conducted at a Mach number of 1.3 to verify its existence and to study the effects of some structural parameters on the flutter characteristics. The effects of tensile forces and buckling were studied on panels clamped front and rear, in addition to initially buckled panels clamped on all four edges. Panel flutter was obtained under controlled laboratory conditions and it was found that tensile forces, shortening the panels, and increasing the bending stiffness were effective means for eliminating flutter. Buckled panels were more susceptible to flutter than unbuckled panels. No apparent systematic trends in the flutter modes or frequencies could be observed.

VIBRATION AND FLUTTER↗

Fluid-Thermal-Structural Interactions in Ramp-Induced Shock-Wave Boundary-Layer Interactions at Mach6

Shock-wave boundary-layer interactions (SWBLI) pose unique challenges for the slender airframes and sharp control surfaces characteristic of high-speed airbreathing aircraft. Spikes in pressure and thermal loading have been shown to occur in SWBLI regions; thus, predicting their location and behavior proves critical for assuring aircraft structural integrity and fatigue resilience. SWBLIs frequently lead to severe turbulent boundary-layer separation and corresponding unsteady motions characterized by a wide range of frequencies. Low-frequency motion has been shown to couple with the structure of a compliant panel, and turbulent boundary layers thus present a particular danger for thin control surfaces. Previous studies have shown that the thermal loading on a compliant panel in a ramp-induced SWBLI may have a signi cant impact on the panel vibrations. A multitude of studies has investigated the heating on rigid structures, but a charactrization of the heating effects on compliant structures is necessary to fully understand the fluid-thermal-structural interactions (FTSI) occurring in ramp-induced SWBLIs. This studuses infrared thermography and high-frequency Kulite pressure transducers to examine the heating loads on rigid and compliant ramps at various angles and flow conditions at Mach 6.

Hypersonic↗

Fluid-Thermal-Structural Interactions in Ramp-Induced Shock-Wave Boundary-Layer Interactions at Mach 6

Shock-wave boundary-layer interactions (SWBLI) pose unique challenges for the slender airframes and sharp control surfaces characteristic of high-speed airbreathing aircraft. Spikes in pressure and thermal loading have been shown to occur in SWBLI regions; thus, predicting their location and behavior proves critical for assuring aircraft structural integrity and fatigue resilience. SWBLIs frequently lead to severe turbulent boundary-layer separation and corresponding unsteady motions characterized by a wide range of frequencies. Low-frequency motion has been shown to couple with the structure of a compliant panel, and turbulent boundary layers thus present a particular danger for thin control surfaces. Previous studies have shown that the thermal loading on a compliant panel in a ramp-induced SWBLI may have a signi cant impact on the panel vibrations. A multitude of studies has investigated the heating on rigid structures, but a charactrization of the heating effects on compliant structures is necessary to fully understand the fluid-thermal-structural interactions (FTSI) occurring in ramp-induced SWBLIs. This studuses infrared thermography and high-frequency Kulite pressure transducers to examine the heating loads on rigid and compliant ramps at various angles and flow conditions at Mach 6.

Hypersonic↗

Low-Temperature Formation of Carbonaceous Grains from PAHs

Astronomical observations have detected interstellar carbon in the form of polycyclic aromatic hydrocarbons(PAHs) as well as carbonaceous dust, confirming its presence in both gaseous and solid phases. The goal of this study is to experimentally investigate low-temperature chemical pathways between these two phases in order to better understand the evolution of cosmic carbon. Cosmic dust analogs are produced in the supersonic expansion of an argon jet seeded with aromatic molecules: benzene, naphthalene, anthracene, phenanthrene, and pyrene. These are prototype aromatic molecules of compact and non compact structure, and are used to evaluate the effect of precursor structure on the molecular complexity of the resulting grains. The seeded jet is exposed to an electrical discharge and the carbonaceous grains are collected and probed ex situ via laser desorption mass spectrometry. Mass spectra reveal a rich molecular diversity within the grains, including fragments of the parent molecule but also growth into larger complex organic molecules (COMs). In all experiments, the largest number of products is found in the m/z range 200-250, and C16H10 (attributed to pyrene and/or its isomers) is found to be a dominant product, pointing at the formation of this stable PAH as a preferential route in the growth to larger PAHs. Comparison to mass spectra from the Murchison meteorite reveals a similar dominance of compounds related toC16H10 at m/z = 202. Evidence of the methyl addition-cyclization mechanism in the anthracene experiment is reported. PAH structure is found to impact the dust production yield, as seen by the greater yield for the anthracene compared to the phenanthrene experiment. PAH growth at low temperatures via barrierless routes involving the addition of alkyl- and phenyl-type radicals is suggested as a viable pathway to COMs. These results suggest that PAH growth and dust formation from PAHs are feasible at low temperatures in photon-dominated regions and circumstellar envelopes.

L Gavilan↗

Vegetation structural complexity and biodiversity in the Great Smoky Mountains

Vegetation structural complexity and biodiversity tend to be positively correlated, but understanding of this relationship is limited in part by structural metrics tending to quantify only horizontal or vertical variation, and that do not reflect internal structure. We developed new metrics for quantifying internal vegetation structural complexity using terrestrial LiDAR scanning and applied them to 12 NEON forest plots across an elevational gradient in Great Smoky Mountains National Park, USA. We asked (1) How do our newly developed structure metrics compare to traditional metrics? (2) How does forest structure vary with elevation in a high-biodiversity, high topographic complexity region? (3) How do forest structural metrics vary in the strength of their relationships with vascular plant biodiversity? Our new measures of canopy density (Depth) and structural complexity (σDepth), and their canopy height-normalized counterparts, were sensitive to structural variations and effectively summarized horizontal and vertical dimensions of structural complexity. Forest structure varied widely across plots spanning the elevational range of GRSM, with taller, more structurally complex forests at lower elevation. Vascular plant biodiversity was negatively correlated with elevation and more strongly positively correlated with vegetation structure variables. The strong correlations we observed between canopy structural complexity and biodiversity suggest that structural complexity metrics could be used to assay plant biodiversity over large areas in concert with airborne and spaceborne platforms.

Jonathan A. Walter↗

The effect of irradiation on the atomic structure and chemical durability of calcite and dolomite

When exposed to irradiation—e.g., in nuclear power plant environments—minerals may experience alterations in their atomic structure which, in turn, result in changes in their physical and chemical properties. Herein, we mimic via Ar + implantation the effects of neutron irradiation on calcite (CaCO 3 ) and dolomite (CaMg(CO 3 ) 2 ) – two carbonate minerals that often find use as aggregates in concrete: a material that is extensively used in the construction of critical structural and safety components in nuclear power plants. By a pioneering combination of nanoscale quantifications of mineral dissolution rates (i.e., a proxy for chemical durability) in alkaline solutions, vibrational (infrared and Raman) spectroscopy, and molecular simulations, we find that irradiation minimally affects the atomic structure and properties of these carbonate minerals. This insensitivity to radiation arises from the predominantly ionic nature of the interatomic bonds in these minerals which can relax and recover their initial configuration, thus ensuring minimal damage and permanent alterations to these minerals following radiation exposure. The outcomes have significant implications on the selection, use, and specification of mineral aggregates for use in nuclear concrete construction.

63 RADIATION, THERMAL, AND OTHER ENVIRON. POLLUTAN↗

Investigation of the Substituting Effect of Chromium on the Electronic Structures and the Half-Metallic Ferromagnetic Properties of BaO

The first-principle methods of density functional theory were used to investigate the doping effect of 3d chromium (Cr) impurities on the electronic properties and the ferromagnetic arrangement of (BaO) barium oxide such as Ba{sub 1−x}Cr{sub x}O compounds at concentrations x = 0.25, 0.5, and 0.75. The p–d exchange coupling between 2p states of oxygen (O) and 3d (Cr) partially filled levels induces magnetism in the Ba{sub 1−x}Cr{sub x}O compounds. The majority- and minority-spin states exhibit respectively metallic and semiconducting features, leading to a half-metallic (HM) character with 100% spin polarization for all concentrations. The Ba{sub 0.75}Cr{sub 0.25}O, Ba{sub 0.5}Cr{sub 0.5}O, and Ba{sub 0.25}Cr{sub 0.75}O compounds have integral total magnetic moments of 4 μ{sub B} per Cr atom with HM gaps of 0.055, 0.218, and 0.308 eV, respectively. These behaviors form accurate half-metallic ferromagnets and make Ba{sub 1−x}Cr{sub x}O as potential materials for possible spintronics applications.

36 MATERIALS SCIENCE↗

Effect of fine-tuning pore structures on the dynamics of confined water

Confinement of water in sub-nanometer pores strongly alters its vibrational dynamics from that of bulk water. The effect of confinement can, moreover, be finely tuned by small changes in the size and symmetry of the confining pore. Using inelastic neutron scattering (INS), we recently studied the dynamics of water confined in the channels of beryl and cordierite in which, at low temperatures, water shows similar behavior, indicating an absence of hydrogen bonds acting on the water molecule and a shallow water potential in the direction perpendicular to the channels. In addition, we observed multiple tunneling modes (between 0.66 and 14.7 meV) in the INS spectra of beryl due to transitions between the split ground-state of the water protons. Here, we introduce a study of (i) the effect of pressure on the dynamics of water in beryl, (ii) the dynamics of water in beryl containing alkali metals (which results in changing the orientation of the water molecule in the crystal), and (iii) the dynamics of water in cordierite at low energies. We found a shift in the tunneling and vibrational modes of water in beryl to higher energies at 22 kbar relative to 1 bar. No tunneling modes were observed for water in cordierite and type-II water in beryl. Thus, we conclude that very small differences in the size and structure of the pores and the orientation of the water molecule in these minerals result in changes in the potential of the water protons and drastic changes in the confined water dynamics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The Effect of Polyurethane Glycolysate on the Structure and Properties of Natural Rubber/Carbon Black Composites

In this work the use of polyurethane chemical recycling product (i.e. glycolysis of polyurethane waste realized with the mass excess of polymer) as a plasticizer for natural rubber-based composites was proposed. The effect of plasticizer type (napthenic oil and polyurethane foam glycolysate) and amount (2, 4, 6 or 8 parts per 100 parts of natural rubber) on the processing properties of rubber mixtures and chemical structure, swelling, mechanical and thermo-mechanical properties of natural rubber/carbon black composites was investigated. The effect of applied plasticizer was studied in the context of accelerated thermal aging (thermo-oxidative aging) which was applied for the prepared natural rubber-based composites. The obtained results confirm that the polyurethane foam glycolysate can be successfully used as a plasticizer for the preparation of natural rubber composites. Moreover, it was found that glycolysate acts as a vulcanization accelerator and reduces decreasing of mechanical properties during the accelerated thermal aging.

36 MATERIALS SCIENCE↗

Effect of Ti Doping on the Crystallography, Phase, Surface/interface Structure and Optical Band Gap of Ga2O3 Thin Films

The effect of titanium (Ti) doping on the crystal structure, phase, surface/interface chemistry, microstructure and optical band gap of gallium oxide (Ga2O3) (GTO) films is reported. The Ti content was varied from 0 to * 5 at% in cosputtering, using Ga2O3 ceramic and Ti metal targets, deposited GTO films produced. The sputtering power to the Ti target was varied in the range of 0–100 W, while keeping the sputtering power to Ga2O3 constant at 100 W, to produce GTO films with 0–5 at% Ti. The Ti-incorporation-induced effects were significant for the crystal structure, phase, surface/interface chemistry and morphology, which in turn induce changes in the band gap. The high-resolution core-level X-ray photoelectron spectroscopy (XPS) analyses confirm that the Ga ions exist as Ga3? in both intrinsic Ga oxide and GTO films. However, XPS data reveal the formation of Ga2O3–TiO2 films with the presence of Ti4? ions with increasing Ti sputtering power, i.e., higher Ti contents in GTO. Evidence for the formation of nanocrystalline Ga2O3–TiO2 films was also found in the structural analyses performed using electron microscopy and grazing incidence X-ray diffraction. Significant band gap reduction (Eg * 0.9 eV) occurs in GTO films with increasing Ti dopant concentration from 0 to 5 at%. A correlation between the Ti dopant concentration, surface/interface chemistry, microstructure and band gap of GTO films is established.

Manandhar, Sandeep↗

Effects of Al concentration on the structure and conductivity of lithium lanthanum zirconium oxide

Cubic Li 7-3x Al x La 3 Zr 2 O 12 (LLZO) is a promising, next-generation solid electrolyte due to its stability with Li-metal and high bulk conductivity (~1 mS cm -1 ). However, the source of the high conductivity is not completely understood. In this work, we address this key knowledge gap through the integration of elemental analysis, neutron diffraction sensitive to Li and O atoms, and impedance spectroscopy to understand the structure–property correlations for LLZO. We show the metal–oxygen framework structure remains constant with variation in Al substitution, resulting in a constant activation energy of ~0.35 eV and little effect on the bulk conductivity. Instead, Li concentration, Al blocking and trapping of mobile defects, and Li–Li nearest neighbor interactions largely control the Al substituted LLZO bulk conductivity, resulting in decreases from 0.73 to 0.22 mS cm -1 as the Al concentration increases from 0.17 to 0.32 mol. These results differ from those of Ta substituted LLZO, where the framework structure and Li–Li site distances play large roles in controlling the conductivity. The increased understanding of the controlling factors of conductivity allows for greater ability to tailor the design of and substitution into the LLZO structure for improved conductivity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Effect of Al on the formation and structure of alkali-silica reaction products

The use of Al-rich supplementary cementitious materials can effectively reduce the expansion of concrete caused by alkali-silica reaction (ASR). However, the role of Al in mitigating the formation and structure of ASR products is only poorly understood, since direct investigation of the reaction in the micro-scale veins of aggregates is difficult. Recent successful synthesis of ASR products provides a unique opportunity to directly assess the role of Al in ASR. In this study, the effect of Al on the formation and structure of ASR products synthesized at 40 and 80 °C is investigated. It is found that the presence of Al in concentration lower than 0.1 mM neither prevents ASR nor alters the structure of the crystalline ASR products formed at 40 °C. However, formation of the crystalline ASR product at 80 °C is lowered at higher Al content due to the formation of a zeolitic precursor.

36 MATERIALS SCIENCE↗

On the inclusion principle and spillover effect in the identification of distributed structures

Distributed structures are Distributed-Parameter Systems (DPS) and must be modeled by large-dimensional systems. Practical limitations require that only a subset of the modes be actively controlled. Control of the residual (uncontrolled) modes is known as control spillover, and it can degrade the system performance. The contamination of the sensor signals by the residual modes is known as observation spillover and it can destabilize the system. An analogous effect exists in the identification problem. Distributed structures must be represented by discretized (finite-dimensional) models or lumped-parameter systems. The contamination of the measurements by the residual (unmodeled) modes is referred to as identification spillover, and it is the object of this study. To study the effects of identification spillover, we use a variational formulation to obtain the natural frequencies and mode shapes. This formulation has direct application to DPS. The identification technique consists of finding the stationary values of a pseudo-Rayleigh quotient.

Norris, Mark. A.↗

Effects of three-dimensional heliospheric structures on cosmic-ray modulation

The theory of cosmic-ray transport in the heliosphere contains four distinct physical processes - diffusion, convection, adiabatic cooling, and drifts. The last of these has only recently been evaluated. Extrapolation of present understanding of the regions near the heliospheric equator to high heliographic latitudes leads to the conclusion that particle drift in the large-scale magnetic field plays an important role in cosmic-ray modulation. The large-scale, three-dimensional structure of the interplanetary magnetic field is therefore very important in understanding cosmic rays. Several key observed modulation effects are summarized, each of which is a natural consequence of drift, but which requires special assumptions if drift plays no role. It is concluded that particle drifts play an important and possibly dominant role in transport in the heliosphere.

Jokipii, J. R.↗

Design, analysis, and testing of a reusable wingbox for ballistic evaluation of composite structures

Future fighter aircraft will continue to be subjected to severe mechanical loading and ballistic impact. In the past aircraft primary wing structure was constructed predominantly with aluminum, but with increasing aircraft performance the need for more structurally efficient materials is necessary. In an attempt to achieve structural efficiency requirements, aircraft designers have begun using an increasing amount of composite materials. Composite materials were indicated to have a low level of ballistic tolerance in some applications. Composite materials possess the characteristic of structural tailoring, which was utilized to demonstrate that survivability can be designed into a structure. The combat flight environment subjects fighter aircraft wing structures to the effects of combined loading during ballistic impact. These loads were previously demonstrated independently, i.e., the application of structural load, hydrodynamic ram damage, and the effects of airflow. The objective was to design a reusable test fixture for the ballistic evaluation of advanced composite structures under all the effects of combined loading. The fixture that was developed provides a test bed that can completely simulate the flight environment of a generic fighter aircraft wing, but can be used for an indefinite number and variety of tests. It is intended that this fixture will provide a standardized method of ballistically evaluating an advanced composite primary wing structure. This fixture will be used to accomplish the development of designs and/or advanced concepts that lead to a survivable composite wing structure.

Baron, W. G.↗