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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,675 records · Page 93

Development of uniform and predictable battery materials for nickel-cadmium aerospace cells

The objective of this study was to analyze battery materials and manufacturing methods with the aim of developing uniform and predictable battery plates for nickel cadmium aerospace cells. The results are presented of an extensive factorially-designed experiment aimed at illuminating, in a comparative study, the effect of plaque preparation, plaque thickness, impregnation process, and loading level with active material. The following impregnation processes were investigated: (1) chemical conversion, (2) electrochemical conversion, and (3) high temperature electrochemical impregnation. The test parameter on which the conclusion regarding the manufacturing variables are based was the capacity change during a simulated near-earth orbit cycle regime. As operational variables, the effect of various charge and discharge rates was investigated. During the 100 test cycles, overall capacity changes of positive plates and the differences between the various plates were found to be small. Plates prepared by the high temperature electrochemical impregnation of slurry-coated plaque (at the conditions used) showed surface buildup of active material. They also retained slightly less of their capacity during cycling compared to other plate preparations.

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Theory, Modeling, Software and Hardware Development for Analytical and Computational Materials Science

The focus of this Cooperative Agreement between the Computational Materials Laboratory (CML) of the Processing Science and Technology Branch of the NASA Glenn Research Center (GRC) and the Department of Theoretical and Applied Mathematics at The University of Akron was in the areas of system development of the CML workstation environment, modeling of microgravity and earth-based material processing systems, and joint activities in laboratory projects. These efforts complement each other as the majority of the modeling work involves numerical computations to support laboratory investigations. Coordination and interaction between the modelers, system analysts, and laboratory personnel are essential toward providing the most effective simulations and communication of the simulation results. Toward these means, The University of Akron personnel involved in the agreement worked at the Applied Mathematics Research Laboratory (AMRL) in the Department of Theoretical and Applied Mathematics while maintaining a close relationship with the personnel of the Computational Materials Laboratory at GRC. Network communication between both sites has been established. A summary of the projects we undertook during the time period 9/1/03 - 6/30/04 is included.

Young, Gerald W.↗

Development and evaluation of an ablative closeout material for solid rocket booster thermal protection system

A trowellable closeout/repair material designated as MTA-2 was developed and evaluated for use on the Solid Rocket Booster. This material is composed of an epoxy-polysulfide binder and is highly filled with phenolic microballoons for density control and ablative performance. Mechanical property testing and thermal testing were performed in a wind tunnel to simulate the combined Solid Rocket Booster trajectory aeroshear and heating environments. The material is characterized by excellent thermal performance and was used extensively on the Space Shuttle STS-1 and STS-2 flight hardware.

Patterson, W. J.↗

Space Shuttle vernier thruster long-life chamber development

The Space Shuttle Reaction Control Subsystem (RCS) vernier thruster is a pressure fed engine that utilizes storable propellants to provide precise attitude control for the Orbiter. The current vernier thruster is life limited due to its chamber material. By developing an iridium-lined rhenium chamber for the vernier, substantial gains could be achieved in the operational life of the chamber. The present RCS vernier, its requirements, operating characteristics, and life limitations are described. The current technology status of iridium-lined rhenium is presented along with a description of the operational life capabilities to be gained from implementing this material into the design of a long life vernier chamber. Discussion of the proposed demonstration program to be performed by the NASA Lyndon B. Johnson Space Center to attain additional insight into the application of this technology to the RCS vernier, includes the technical objectives, approach, and program schedule. The plans for further development and integration with the Orbiter and the Shuttle system are also presented.

Krohn, Douglas D.↗

SOMAS: a platform for data-driven material discovery in redox flow battery development

Abstract Aqueous organic redox flow batteries offer an environmentally benign, tunable, and safe route to large-scale energy storage. The energy density is one of the key performance parameters of organic redox flow batteries, which critically depends on the solubility of the redox-active molecule in water. Prediction of aqueous solubility remains a challenge in chemistry. Recently, machine learning models have been developed for molecular properties prediction in chemistry and material science. The fidelity of a machine learning model critically depends on the diversity, accuracy, and abundancy of the training datasets. We build a comprehensive open access organic molecular database “Solubility of Organic Molecules in Aqueous Solution” (SOMAS) containing about 12,000 molecules that covers wider chemical and solubility regimes suitable for aqueous organic redox flow battery development efforts. In addition to experimental solubility, we also provide eight distinctive quantum descriptors including optimized geometry derived from high-throughput density functional theory calculations along with six molecular descriptors for each molecule. SOMAS builds a critical foundation for future efforts in artificial intelligence-based solubility prediction models.

25 ENERGY STORAGE↗

Fast X-ray Nanotomography with Sub-10 nm Resolution as a Powerful Imaging Tool for Nanotechnology and Energy Storage Applications

In the last decade, transmission X-ray microscopes (TXMs) have come into operation in most of the synchrotrons worldwide. They have proven to be outstanding tools for non-invasive ex and in situ 3D characterization of materials at the nanoscale across varying range of scientific applications. However, their spatial resolution has not improved in many years, while newly developed functional materials and microdevices with enhanced performances exhibit nanostructures always finer. Here, optomechanical breakthroughs leading to fast 3D tomographic acquisitions (85 min) with sub-10 nm spatial resolution, narrowing the gap between X-ray and electron microscopy, are reported. These new achievements are first validated with 3D characterizations of nanolithography objects corresponding to ultrahigh-aspect-ratio hard X-ray zone plates. Then, this powerful technique is used to investigate the morphology and conformality of nanometer-thick film electrodes synthesized by atomic layer deposition and magnetron sputtering deposition methods on 3D silicon scaffolds for electrochemical energy storage applications.

36 MATERIALS SCIENCE↗

All-in-One Chip

Under an SBIR contract, EMC Technology, Inc., was funded to develop a family of Temperature Compensating Attenuators. These devices are used to compensate for changes in amplifier gain with temperatures. Special thermistor materials were developed that not only satisfied NASA requirements, but also proved useful on several new commercial products. New Thermopad devices with greater compensation and lower loss were developed and used by companies such as Hughes Space and Communications, Motorola, Lucent, Ericsson, and General Instrument. A Power Sensing Termination (Smartload) was also developed for use in communication systems that require accurate, reliable, low cost power detection for level control and alarm circuits.

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Development Study of Cartridge/Crucible Tube Materials

The limitations of traditional alloys and the desire for improved performance for components is driving the increased utilization of refractory metals in tile space industry. From advanced propulsion systems to high temperature furnace components for microgravity processing, refractory metals are being used for their high melting temperatures and inherent chemical stability. Techniques have been developed to produce near net shape refractory metal components utilizing vacuum plasma spraying. Material utilization is very high, and laborious machining can be avoided. As-spray formed components have been tested and found to perform adequately. However, increased mechanical and thermal properties are needed. To improve these properties, post processing thermal treatments such as hydrogen sintering and vacuum annealing have been performed. Components formed from alloys of tungsten, rhenium, tantalum, niobium, and molybdenum are discussed and a metallurgical analyses detailing the results are presented. A qualitative comparison of mechanical properties is also included.

McKechnie, Timothy N.↗

Custom Machines Advance Composite Manufacturing

Here is a brief list of materials that NASA will not be using to construct spacecraft: wood, adobe, fiberglass, bone. While it might be obvious why these materials would not make for safe space travel, they do share a common characteristic with materials that may well be the future foundation of spacecraft design: They all are composites. Formed of two or more unlike materials - such as cellulose and lignin in the case of wood, or glass fibers and plastic resin in the case of fiberglass-composites provide enhanced mechanical and physical properties through the combination of their constituent materials. For this reason, composites are used in everything from buildings, bathtubs, and countertops to boats, racecars, and sports equipment. NASA continually works to develop new materials to enable future space missions - lighter, less expensive materials that can still withstand the extreme demands of space travel. Composites such as carbon fiber materials offer promising solutions in this regard, providing strength and stiffness comparable to metals like aluminum but with less weight, allowing for benefits like better fuel efficiency and simpler propulsion system design. Composites can also be made fatigue tolerant and thermally stable - useful in space where temperatures can swing hundreds of degrees. NASA has recently explored the use of composites for aerospace applications through projects like the Composite Crew Module (CCM), a composite-constructed version of the aluminum-lithium Multipurpose Crew Capsule. The CCM was designed to give NASA engineers a chance to gain valuable experience developing and testing composite aerospace structures.

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Development of a Framework and Methodology for an Advanced Reactor Materials Environmental Effects Design Guide

Advanced non-light-water reactor components may operate at elevated temperature while experiencing cyclic loading, significant neutron irradiation, and exposure to reactor coolant. ASME Boiler and Pressure Vessel Code, Section III, Division 5, provides design rules for elevated-temperature service but does not include specific procedures to account for environmental effects on material properties. This report develops an initial framework and methodology for an Environmental Effects Design Guide (EEDG) focused on neutron irradiation; coolant-environment effects are reserved for future work. The proposed approach treats irradiation as a property-based overlay on the existing Division 5 design process, with two routes: a sparse-data route applying two reduction factors — FCR on creep-rupture strength and FF on fatigue life — for the creep-fatigue evaluations that typically control the design of advanced high-temperature reactor components, and a fuller framework developing the property-to-rule chain across the four Division 5 checks (primary load, strain limits and ratcheting, creep-fatigue, and buckling), together with swelling and weldments as scope items. Both routes are scoped by an in-pile qualification that restricts the use of post-irradiation-examination-derived properties in regimes where an in-pile mechanism could control the design outcome. Illustrative outputs derived on a compiled annealed Type 316 database — FCR ≈ 0.78–0.86 and FF ≈ 0.4 — demonstrate the calculation method within that specific dataset. The framework is an initial, testable design-rule concept; it identifies a practical path for preliminary design evaluations under sparse data and the material data and testing needed to develop the framework further.

Barua, Bipul (ORCID:0000000247184113)↗

Ettringite-Related Dimensional Stability of CO 2 -Cured Portland Cement Mortars

Carbonation curing, where cement is cured in a CO 2 -rich environment, is an emerging technology in the precast industry that promotes CO 2 sequestration in construction materials. It demonstrates good promise for enhancing material strength development, chemical resistance and manufacturing sustainability. A critically important but little studied aspect of carbonation curing is the dimensional stability of the cured materials, which poses a significant impact on longevity of cement-based materials and structures. In this study, we propose to use carbonation curing to substitute the conventional energy-intensive steam curing and time-consuming moisture curing, and examine the dimensional stability of Portland cement mortars manufactured by different curing approaches. The common pathology in precast concrete that potentially creates undesirable expansions, known as Delayed Ettringite Formation (DEF), is particularly investigated. Four curing approaches were examined including moist, steam (maximum temperature at 85°C to purposefully induce DEF), combined steam-carbonation, and carbonation curing in which steam curing was used to verify favorable cement chemistry for DEF and to indicate DEF onset timing. It was found that, among the four curing approaches designed in this study, the carbonation-cured mortars demonstrated the lowest expansion (~0%) whereas the steam-cured mortars showed the highest (>0.6%) after 500 days of storage in saturated limewater. Mortar expansion after the combined steam-carbonation curing (~0.1%) was lower than that of steam curing, but remained higher with respect to the moisture-cured reference. Here, the mineral ettringite was detected at 500 days after all curing approaches. However, larger ettringite crystal size (5-10 μm) with greater dispersion was observed via scanning electron microscopy after steam curing in reference to carbonation curing (< 5 μm). Additionally, the calcium carbonate precipitated by CO 2 carbonation was found to participate in the post-carbonation hydration to promote formation of monocarboaluminate and hemicarboaluminate, which stabilize ettringite and potentially lead to a secondary densification of the mortar microstructure.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Thermal design of the space shuttle solid rocket booster

The thermal protection systems (TPS) to meet the quick turnaround and low cost required for reuse of the solid rocket booster (SRB) hardware. The TPS development considered the ease of application, changing ascent/reentry environments, and the problem of cleaning the residual insulation upon recovery. A sprayable ablator TPS material was developed. The challenges involved in design and development of this thermal system are discussed.

Fisher, R. R.↗

Overview of NASA Ultracapacitor Technology

NASA needed a lower mass, reliable, and safe medium for energy storage for ground-based and space applications. Existing industry electrochemical systems are limited in weight, charge rate, energy density, reliability, and safety. We chose a ceramic perovskite material for development, due to its high inherent dielectric properties, long history of use in the capacitor industry, and the safety of a solid state material.

Hill, Curtis W.↗

Overview of NASA Ultracapacitor Technology

NASA needed a lower mass, reliable, and safe medium for energy storage for ground-based and space applications. Existing industry electrochemical systems are limited in weight, charge rate, energy density, reliability, and safety. We chose a ceramic perovskite material for development, due to its high inherent dielectric properties, long history of use in the capacitor industry, and the safety of a solid state material.

Hill, Curtis W.↗

The thermal and mechanical stability of composite materials for space structures

A continuing research objective of the National Aeronautical and Space Administration (NASA) is to develop advanced composite materials for space structures. The thrust of this research is to gain fundamental understanding of the performance of advanced composites in the space environment. The emphasis has been to identify and model changes in the thermal-physical properties due to induced damage and develop improved materials.

Tompkins, S. S.↗

Chapter 1: Introduction - Motivation of Polycrystalline Thin-Film Solar Cells

Thin-film solar cell development may be conceptualized as improving processes to lower costs and improve performance, with characterization as a guide along the way. Yet, pushing the boundaries of characterization is as much at the core of thin-film solar cell development as material synthesis. As PV continues to mature, there is an endless drive to improve performance to compete. Hence, PV technology is striving for increasing levels of perfection, requiring a corresponding sophistication in characterization and understanding. Consequently, the topic of this book -advanced characterization-is timely and critical to develop the potential of thin-film solar technology.

material synthesis↗

Challenges and Solutions for Fast Neutron Irradiation of Bulk Material Specimens

Reactor developers continue to recognize opportunities for further enhancing fast spectrum reactor designs with advanced core materials, but all the material test reactors currently available to the United States are thermal spectrum designs. Fortunately, the Advanced Test Reactor and High Flux Isotope Reactor are versatile high flux facilities where spectral modification strategies can be used to reduce undesirable thermal neutron capture transmutation damage and augment fast flux delivered to specimens. New opportunities to leverage high flux regions and specially designed fast flux boosting experiment configurations can be used to achieve meaningful fast fluences on large specimens in ATR. New optimization potentials can be employed to achieve even higher fluences, albeit for smaller specimens, using thermal neutron filters in HFIR test positions. These capabilities, while not true fast reactors, can provide highly relevant environments for researchers needing to study the effects of fast neutron damage in bulk material specimens.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Dendritic Growth with Fluid Flow for Pure Materials

We have developed a three-dimensional, adaptive, parallel finite element code to examine solidification of pure materials under conditions of forced flow. We have examined the effect of undercooling, surface tension anisotropy and imposed flow velocity on the growth. The flow significantly alters the growth process, producing dendrites that grow faster, and with greater tip curvature, into the flow. The selection constant decreases slightly with flow velocity in our calculations. The results of the calculations agree well with the transport solution of Saville and Beaghton at high undercooling and high anisotropy. At low undercooling, significant deviations are found. We attribute this difference to the influence of other parts of the dendrite, removed from the tip, on the flow field.

Jeong, Jun-Ho↗