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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,675 records · Page 93
All sourcesNASA NTRSDOE OSTI
NASA NTRS2013

Scheduling and Separating Departures Crossing Arrival Flows in Shared Airspace

Flight efficiency and reduction of flight delays are among the primary goals of NextGen. In this paper, we propose a concept of shared airspace where departures fly across arrival flows, provided gaps are available in these flows. We have explored solutions to separate departures temporally from arrival traffic and pre-arranged procedures to support controllers' decisions. We conducted a Human-in-the-Loop simulation and assessed the efficiency and safety of 96 departures from the San Jose airport (SJC) climbing across the arrival airspace of the Oakland and San Francisco arrival flows. In our simulation, the SJC tower had a tool to schedule departures to fly across predicted gaps in the arrival flow. When departures were mistimed and separation could not be ensured, a safe but less efficient route was provided to the departures to fly under the arrival flows. A coordination using a point-out procedure allowed the arrival controller to control the SJC departures right after takeoff. We manipulated the accuracy of departure time (accurate vs. inaccurate) as well as which sector took control of the departures after takeoff (departure vs. arrival sector) in a 2x2 full factorial plan. Results show that coordination time decreased and climb efficiency increased when the arrival sector controlled the aircraft right after takeoff. Also, climb efficiency increased when the departure times were more accurate. Coordination was shown to be a critical component of tactical operations in shared airspace. Although workload, coordination, and safety were judged by controllers as acceptable in the simulation, it appears that in the field, controllers would need improved tools and coordination procedures to support this procedure.

shared airspace↗
NASA NTRS2014

Thermal Analysis of Cryogenic Hydrogen Liquid Separator

During launch for the new Space Launch System (SLS) liquid hydrogen is bleed through the engines during replenish, pre-press, and extended pre-press to condition the engines prior to launch. The predicted bleed flow rates are larger than for the shuttle program. A consequence of the increased flow rates is having liquif hydrogen in the vent system, which the facilities was never designed to handle. To remedy the problem a liquid separator is being designed in the system to accumulated the liquid propellant and protect the facility flare stack (which can only handle gas). The attached document is a presentation of the current thermalfluid analysis performed for the separator and will be presented at the Thermal and Fluid Analysis Workshop (NASA workshop) next week in Cleveland, Ohio.

liquid separator↗
NASA NTRS2016

Separation Assurance and Scheduling Coordination in the Arrival Environment

Separation assurance (SA) automation has been proposed as either a ground-based or airborne paradigm. The arrival environment is complex because aircraft are being sequenced and spaced to the arrival fix. This paper examines the effect of the allocation of the SA and scheduling functions on the performance of the system. Two coordination configurations between an SA and an arrival management system are tested using both ground and airborne implementations. All configurations have a conflict detection and resolution (CD&R) system and either an integrated or separated scheduler. Performance metrics are presented for the ground and airborne systems based on arrival traffic headed to Dallas/ Fort Worth International airport. The total delay, time-spacing conformance, and schedule conformance are used to measure efficiency. The goal of the analysis is to use the metrics to identify performance differences between the configurations that are based on different function allocations. A surveillance range limitation of 100 nmi and a time delay for sharing updated trajectory intent of 30 seconds were implemented for the airborne system. Overall, these results indicate that the surveillance range and the sharing of trajectories and aircraft schedules are important factors in determining the efficiency of an airborne arrival management system. These parameters are not relevant to the ground-based system as modeled for this study because it has instantaneous access to all aircraft trajectories and intent. Creating a schedule external to the CD&R and the scheduling conformance system was seen to reduce total delays for the airborne system, and had a minor effect on the ground-based system. The effect of an external scheduler on other metrics was mixed.

function allocation↗
NASA NTRS2015

Implicit LES of Turbulent, Separated Flow: Wall-Mounted Hump Configuration

Direct simulations (ILES) of turbulent, separated flow over the wall-mounted hump configuration is conducted to investigate the physics of separated flows. A chord-based Reynolds number of Re(sub c) = 47,500 is set up, with a turbulent in flow of Re(sub theta) = 1,400 (theta/c = 3%). FDL3DI, a code that solves the compressible Navier-Stokes equations using high- order compact-difference scheme and filter, with the standard recycling/rescaling method of turbulence generation, is used. Two different configurations of the upper-wall are analyzed, and results are compared with both a higher Re(sub c) (= 936,000, Re(sub theta) = 7,200, theta/c = 0.77%) experiment for major flow features, and RANS (k-omega SST) results. A lower Rec allows for DNS-like mesh resolution, and an adequately wide span. Both ILES and RANS show delayed reattachment compared to experiment, and significantly higher skin friction in the forebody of the hump, as expected. The upper-wall shape influences the C(sub p) distribution only. Results from this study are being used to setup higher Rec (lower theta/c) ILES.

Implicit LES↗
NASA NTRS2019

Synthesis and Performance of 6FDA-Based Polyimide-Ionenes and Composites with Ionic Liquids as Gas Separation Membranes

Three new isomeric 6FDA-based polyimide-ionenes, with imidazolium moieties and varying regiochemistry (para-, meta-, and ortho- connectivity), and composites with three different ionic liquids (ILs) have been developed as gas separation membranes. The structural-property relationships and gas separation behaviors of the newly developed 6FDA polyimide-ionene + IL composites have been extensively studied. All the 6FDA-based polyimide-ionenes exhibited good compatibility with the ILs and produced homogeneous hybrid membranes with the high thermal stability of ~380 °C. Particularly, [6FDA I4A pXy][Tf2N] ionene + IL hybrids having [C4mim][Tf2N] and [Bnmim][Tf2N] ILs offered mechanically stable matrixes with high CO2 affinity. The permeability of CO2 was increased by factors of 2 and 3 for C4mim and Bnmim hybrids (2.15 to 6.32 barrers), respectively, compared to the neat [6FDA I4A pXy][Tf2N] without sacrificing their permselectivity for CO2/CH4 and CO2/N2 gas pairs.

Ionenes↗
NASA NTRSDate not supplied

Uncertainty Propagation in Pre-Flight Prediction of Unmanned Aerial Vehicle Separation Violation

Current forecasts on the future of aeronautics suggest an in- creasing number of unmanned aerial vehicles entering the low- altitude airspace in the next decades (FAA, 2018; Kopardekar et al., 2016). Small vehicles for package delivery as well as larger vehicles for urban air mobility will change the airspace drastically, increasing density of operations both in time, i.e. high number of take-off and landings per unit time, and in space, operating in dense urban environment. This scenario poses challenges to the current approach to air traffic control, and large efforts from academia, industry and regulatory bodies are dedicated to the development of new traffic management strategies that leverage higher computing and simulating capabilities available today. In this paper, we propose a simple look-ahead approach to predict potential minimum separation violations at the strategic level, that is before vehicles start flying, depending on the predefined 4D trajectories and uncertainty affecting the wind acting along those routes. The wind field is extracted from the NOAA North America Mesoscale Forecast System and interpolated using Gaussian process regression, while uncertainty affecting the expected cruise airspeed is propagated through error intervals. The approach allows the prediction of aircraft separation as a function of time, highlighting potential safety violations that would go undetected if uncertainty affecting the expected 4D trajectories is not considered. The paper will also discuss issues related to accuracy and scalability of the approach to multiple vehicle operations.

Trajectory Prediction↗
NASA NTRSDate not supplied

Design and Qualification or the Low-Earth Orbit Flight Test of an Inflatable Decelerator(LOFTID) Payload Adapter Separation System (PASS)

On November 10, 2022, NASA and United Launch Alliance (ULA) launched Low-Earth Orbit Flight Test of an Inflatable Decelerator (LOFTID) as a secondary payload on an Atlas V Centaur from Vandenburg Space Force Base (VSFB). After deploying the primary payload, JPSS-2, to a sun-synchronous orbit, the Centaur reoriented LOFTID for reentry, ejecting the Payload Adaptor to expose the stowed LOFTID reentry vehicle (RV). The Hypersonic Inflatable Aerodynamic Decelerator (HIAD) was then deployed and inflated, and the Centaur reoriented the RV to the desired entry attitude, spun the vehicle to roughly three rpm, and separated the reentry vehicle. After nearly half an orbit of free flight, LOFTID reentered the atmosphere at >8 km/sec, demonstrating stable flight from hypersonic entry through subsonic parachute deployment. A mission-unique Payload Adapter Separation System (PASS) enabled the successful LOFTID flight demonstration, allowing the launch vehicle to accommodate a superstack of two independent, similarly sized payloads. This paper discusses the design, development, and qualification of the LOFTID PASS along with lessons learned.

HIAD↗
DOE OSTI2017

Development of Separate Sensible and Latent Cooling System Using Electrochemical Compressor

Separate sensible and latent cooling systems offer superior energy efficiency performance compared to conventional vapor compression air conditioning systems. In this paper we describe an innovative non-vapor compression system that uses electrochemical compressor (ECC) to pump hydrogen between 2-metal hydride reservoirs to provide the sensible cooling effect. The heat rejected during this process is used to regenerate the ionic liquid (IL) used for desiccant dehumidification. The overall system design is illustrated. The Xergy version 4C electrochemical compressor, while not designed as a high pressure system, develops in excess of 2 MPa (300 psia) and pressure ratios > 30. The projected base efficiency improvement of the electrochemical compressor is expected to be ~ 20% with higher efficiency when in low capacity mode due to being throttleable to lower capacity with improved efficiency. The IL was tailored to maximize the absorption/desorption rate of water vapor at moderate regeneration temperature. This IL, namely, [EMIm].OAc, is a hydrophilic IL with a working concentration range of 28.98% when operating between 25 75 C. The ECC metal hydride system is expected to show superior performance to typical vapor compression systems. As such, the combined efficiency gains from the use of ECC and separate and sensible cooling would offer significant potential savings to existing vapor compression cooling technology. A high efficiency Window Air Conditioner system is described based on this novel configuration. The system s schematic is provided. Models compared well with actual operating data obtained by running the prototype system. Finally, a model of an LiCl desiccant system in conjunction with the ECC-based metal hydride heat exchangers is provided.

Electrochemical Compression↗
DOE OSTI2023

Advanced Mineral Separations with Novel Simulated Moving Beds

Lithium is a critical mineral that is widely used in batteries and energy storage applications, making it increasingly important in the next few decades. To meet the growing demand for lithium and secure domestic supply chains, there is a need to exploit unconventional lithium resources. However, utilizing current lithium extraction processes is challenging due to the high salinity in those resources. Thus, it is essential to develop energy-efficient, and less chemical-intensive separation processes that can exploit high-salinity lithium resources. Accordingly, this project aims to design a novel zwitterionic stationary phase and use it to develop a continuous chromatography process to recover LiCl minerals from traditionally unexploited domestic saline resources. The developed zwitterionic stationary phase allows fractionating minerals based on their different sorbent affinities under water elution. A systematically designed continuous process can separate lithium from other minerals, reducing the risk of material fouling and the overall chemical consumption to produce battery-grade lithium. This approach is expected to significantly enhance the efficiency and sustainability of the lithium extraction process while also reducing the environmental impact associated with traditional processes. At the end of the project, the technology will be demonstrated in continuous mode using a simulated moving bed (SMB) to recover >100 g of LiCl from real resource waters. The U.S.-based resources that this project targets for LiCl recovery are formation water, oil-produced water, and geothermal brines, supplied by Standard Lithium Ltd. and Shell Inc, respectively.

critical minerals↗
DOE OSTI2023

An Overview of the Radioisotope Electromagnetic Isotope Separation Capabilities at Idaho National Laboratory

Electromagnetic isotope separation (EMIS) has been an effective tool for the enrichment of isotopes for over 80 years. In the early 1990’s the U.S. reduced or eliminated electromagnetic isotope separation capabilities, but in the last decade, increased demand for both stable and radioactive enriched isotopes have led to the reestablishment of small-medium scale EMIS capabilities in the U.S. National Laboratory Complex.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2022

INL Mass Separator Operations

Electromagnetic isotope separation (EMIS) has been an effective tool for the enrichment of isotopes for over 80 years. In the early 1990’s the U.S. reduced or eliminated electromagnetic isotope separation capabilities, but in the last decade, increased demand for both stable and radioactive enriched isotopes have led to the reestablishment of small-medium scale EMIS capabilities in the U.S. National Laboratory Complex.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2024

Pressure-Gradient-Based RANS Model for Predicting Separation in Transitional and Turbulent Flows

Predicting flow separation poses a significant challenge for RANS models, particularly in transitional flows over airfoils. We propose a novel improvement to RANS models to predict incipient separation in both transitional and fully turbulent flows. Our approach modifies the eddy viscosity model in regions indicated by a pressure-gradient criterion that accounts for intermittency - determining whether the boundary layer is laminar or turbulent. This model demonstrates robust generalization across various airfoil shapes and Reynolds numbers. Applied to the NREL Phase VI wind turbine rotor, our model shows improved aerodynamic performance predictions compared to the baseline RANS model.

k-omega SST↗
DOE OSTI2025

Fabrication and Scale-Up of Porous Polybenzimidazole (PBI) Supports for Gas Separation Composite Membranes

Industrial gas separation often uses thin film composite (TFC) membranes comprising a porous support overlaid with a single-/multi-layer gas-selective thin film. An optimal porous support should possess high surface porosity to minimize gas transport resistance and nano-sized pores to ease pore penetration occurring during the thin film coating process. Good chemical and thermal stabilities are essential to withstand the aggressive solvents and heat required for the thin film coating and curing. However, few porous membranes satisfy all these requirements. This study presents a scalable membrane formation method of making highly porous polybenzimidazole (PBI) supports via non-solvent induced phase separation. This presentation also details the scale-up fabrication of PBI supports using a custom roll-to-roll membrane casting machine.

gas separation↗
DOE OSTI2021

Multifunctional Separator Allows Stable Cycling of Potassium Metal Anodes and of Potassium Metal Batteries

Here, this is the first report of a multifunctional separator for potassium-metal batteries (KMBs). Here, double-coated tape-cast microscale AlF 3 on polypropylene (AlF 3 @PP) yields state-of-the-art electrochemical performance: symmetric cells are stable after 1000 cycles (2000 h) at 0.5 mA cm –2 and 0.5 mAh cm –2 , with 0.042 V overpotential. Stability is maintained at 5.0 mA cm –2 for 600 cycles (240 h), with 0.138 V overpotential. Postcycled plated surface is dendrite-free, while stripped surface contains smooth solid electrolyte interphase (SEI). Conventional PP cells fail rapidly, with dendrites at plating, and “dead metal” and SEI clumps at stripping. Potassium hexacyanoferrate(III) cathode KMBs with AlF 3 @PP display enhanced capacity retention (91% at 100 cycles vs 58%). AlF 3 partially reacts with K to form an artificial SEI containing KF, AlF 3 , and Al 2 O 3 phases. The AlF 3 @PP promotes complete electrolyte wetting and enhances uptake, improves ion conductivity, and increases ion transference number. The higher of K + transference number is ascribed to the strong interaction between AlF 3 and FSI – anions, as revealed through 19 F NMR. The enhancement in wetting and performance is general, being demonstrated with ester- and ether-based solvents, with K-, Na-, or Li- salts, and with different commercial separators. In full batteries, AlF 3 prevents Fe crossover and cycling-induced cathode pulverization.

NMB↗
DOE OSTI2025

Mesoscale Magnetostructural Phase Separation in Fe‐deficient Fe 5 GeTe 2

Two-dimensional van der Waals ferromagnet Fe 5-x GeTe 2 (F5GT) is promising for spintronic applications due to its high Curie temperature, layered structure, and ability to host complex magnetic textures. However, the origin of its sample-dependent magnetic anisotropy remains unclear, hindering control of its magnetic behavior. Here, we use spatially resolved cryogenic scanning transmission electron microscopy (STEM) to correlatively map magnetism, lattice structure, and chemistry across atomic-to-micron scales. We reveal that only mesoscale, not nanoscale, inclusions of a Fe-deficient secondary phase significantly modify magnetic behavior, establishing a previously unrecognized critical length scale. This phase separation, induced by quenching, leads to in-plane magnetic anisotropy, while slow cooling confines separation to a few nanometers and preserves out-of-plane anisotropy. These findings reconcile prior inconsistencies and establish a predictive framework for tuning magnetism in F5GT through thermal processing, with broader implications for controlling anisotropy in other two-dimensional magnetic materials.

2D ferromagnets↗
DOE OSTI2017

Solvent‐Templated Block Ionomers for Base‐ and Acid‐Gas Separations: Effect of Humidity on Ammonia and Carbon Dioxide Permeation

Abstract As energy needs continue to drive the development of biogas and fossil‐fuel technologies, methods by which to selectively remove basic (NH 3 ) and acidic (CO 2 ) gases are becoming increasingly important, especially in light of global climate change. Block copolymers are considered as suitable membrane candidates in gas separations due to the ability of such copolymers to microphase‐separate and spontaneously form nanoscale morphologies that exhibit spatially modulated chemical specificity. Incorporation of charged moieties along the midblock of a thermoplastic elastomeric multiblock copolymer yields an amphiphilic block ionomer possessing a flexible molecular network stabilized by rigid endblocks. The presence of hydrophilic microdomains introduces an important consideration regulating molecular transport: humidity. In this study, solvent‐templating paradigms are employed to control the morphologies of midblock‐sulfonated pentablock ionomers, as discerned by electron microscopy and X‐ray scattering. The effect of humidity on the permeation of NH 3 , CO 2 , and N 2 is then investigated through the resulting membranes. As expected, NH 3 permeates significantly faster than N 2 , especially under humid conditions. Although not as pronounced, similar behavior is observed for CO 2 , thereby establishing that this block ionomer is generally selective to humidified polar gases.

Ansaloni, Luca↗
DOE OSTI2021

Separating Physically Distinct Mechanisms in Complex Infrared Plasmonic Nanostructures via Machine Learning Enhanced Electron Energy Loss Spectroscopy

Electron energy loss spectroscopy (EELS) enables direct exploration of plasmonic phenomena at the nanometer level. To isolate individual plasmon modes, linear unmixing methods can be used to separate different physical mechanisms, but in larger and more complex systems the interpretability of the components becomes uncertain. Here, infrared plasmonic resonances in self-assembled heterogeneous monolayer films of doped-semiconductor nanoparticles are examined beyond linear unmixing techniques, and both supervised and unsupervised machine-learning-based analyses of hyperspectral EELS datasets are demonstrated. Additionally, in the supervised approach, a human operator labels a small number of pixels in the hyperspectral dataset corresponding to features of interest which are then propagated across the entire dataset. In the unsupervised approach, non-linear autoencoders are used to create a highly-reduced latent-space representation of the dataset, within which insight into the relevant physics can be gleaned from straightforward distance metrics that do not depend on operator input and bias. The advantage of these approaches is that the labeling separates physical mechanisms without altering the data, enabling robust analyses of the influence of heterogeneities in mesoscale complex systems.

36 MATERIALS SCIENCE↗