Microwave-Assisted Catalytic Co-Gasification of Plastic-Corn Stover to Produce Clean H2
Poster for the Tri-State Catalysis Club Symposium, Morgantown, WV, September 1, 2023.
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Poster for the Tri-State Catalysis Club Symposium, Morgantown, WV, September 1, 2023.
For presentation at the AICHE Fall 2023 National Meeting, Orlando, FL, November 5-10, 2023.
gasifier and a gasification process provides a long, uniform temperature zone in the gasifier, regardless of the particle size, chemical composition, and moisture content of the fuel by sandwiching a reduction zones between two oxidation zones. The gasifier and gasification process produces a char that is more energy-dense and almost devoid of moisture, affording an additional (char) oxidation zone with a temperature that is higher than a first oxidation zone which is closer to an evaporation and devolatilization zone. As such, the additional (char) oxidation zone contributes to augmenting the reduction zone temperature, providing a favorable dual impact in improving syngas composition and near-complete conversion of the tar.
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The performance of the major facilities used in Fukushima for the treatment of {sup 137}Cs-bearing waters is reviewed. The facilities include Kurion zeolite system, SARRY and the ALPS systems. These utilize chabazite zeolite, silico-titanate CST and hexacyanoferrate based CsTreat{sup R} materials, respectively. The average processing capacity of chabazite is 0.41 m{sup 3}/kg and that of silico-titanate 2.81 m{sup 3}/kg. CsTreat{sup R} material has shown a processing capacity > 38.6 m{sup 3}/kg during its initial operation.A theoretical analysis shows that the selectivity of the materials for cesium over sodium, measured in terms of selectivity coefficient kCs/Na, largely determines their processing capacities. There is a increasing linear relationship between the processing capacity and kCs/Na in logarithmic scales. Also, the decontamination factors obtained with the material for {sup 137}Cs increase with increasing kCs/Na. (authors)
Overall cleanup of large plumes is perceived as being impossible because of issues of scale, contaminant mass accessibility, time to achieve cleanup, and cost. As a result, when a groundwater pump and treat (P and T) remedy is applied to larger plumes, the focus is usually hydraulic containment of contaminated groundwater to prevent further plume migration, rather than a total restoration objective. Recent experience with dynamic operation of groundwater extraction, treatment, and strategic reinjection (collectively referred to as dynamic groundwater recirculation [DGR]) demonstrates that large plume remediation can be accomplished cost effectively and in a timely manner. The insight from operating DGR remedies at multiple sites has demonstrated that contaminant mass residing in a complex aquifer setting is most appropriately described by a three-compartment model, which is a new revelation in contaminant hydrogeology redefining what is possible in restoration. A large-scale application of DGR was implemented under a firm fixed price contract at former Reese Air Force Base (AFB) located in Lubbock, Texas. The strategy was successful in restoration of a sole-source drinking water aquifer affected by a 3-mile long trichloroethene (TCE) plume. DGR allowed groundwater P and T rates to be decreased from over 3,400 liters per minute (lpm) to less than 1,500 lpm through initial optimization efforts. The DGR strategy focused extraction and reinjection on two key objectives: 1) maximizing contaminant mass recovery and 2) maintaining hydraulic control of the plume. Extraction and injection wells were dynamically operated and cycled to maintain a remediation pace that restored 0.8 to 1.2 hectares of the plume per week over a 6-year period. Plume cleanup to drinking water standards was achieved in 9 years of optimized operation. (authors)
In recognition of the high up-front costs and potentially long timescales to implement the more traditional methods of encapsulating wastes, in the UK alternative approaches to help accelerate hazard reduction and reduce such costs are being deployed. When considering such the cost of alternative approaches to waste packaging strategies, it is important that the complete waste life cycle is taken into account. This paper will demonstrate that when evaluating waste packaging options, whilst individual elements (e.g. container costs) within an overall waste management programme may appear to offer a cost benefit by comparison with alternatives, the programme as a whole may not necessarily be the most cost effective solution when life cycle costs are taken into account, or when other technical issues are considered. To illustrate this point this paper will present a view of the application of LCC, utilising a number of waste packaging scenarios, to promote discussion and consideration of the benefits of undertaking a holistic assessment of the investment decision as part of an overall waste management strategy. (authors)
In 2010, the UK Nuclear Decommissioning Authority (NDA) secured a funding settlement of British Pounds 2.5 Bn from the Government for the period to 2015 for the Magnox Care and Maintenance programme. This settlement was a reflection of the importance placed on discharging the decommissioning liability associated with the UK's first generation Magnox reactors. It also reflected the NDA's confidence in the Magnox Optimised Decommissioning Plan (MODP), which aimed to accelerate entry into Care and Maintenance and reduce the Magnox decommissioning liability by British Pounds 1.2 Bn. Despite the settlement, huge challenges remained if the MODP was to be delivered within the funding envelope. Essentially, the supply chain had to be able to participate in the delivery of the MODP and make the investment in skills and techniques required to minimise the threats and uncertainties remaining in the Programme. The Magnox Commercial and Supply Chain Strategy was, therefore, an integral part of the MODP. At the highest level, the Strategy involved: - Classifying and segregating procurements by risk and value - Moving the contracting philosophy from risk transfer to risk management - Focusing on relationships and results rather than activities and processes By aligning the supply chain to the MODP, Magnox was able to better organise itself to deliver against the MODP, to act on feedback from suppliers and enable a culture of 'Lead and Learn' to take root. Using feedback and learning from other organisations and applying these to contract management approaches improved project outcomes. In particular, learning from previous experience of dealing with Programme 'unknowns' increased the company's ability to control and improve on the overall Programme cost and schedule. The impact of the MODP was to reduce the Magnox baseline by over British Pounds 1.5 Bn and remove 34 reactor-years from the Care and Maintenance preparations period. This huge gain resulted from a range of technical, process and commercial improvements across the organisation. Perhaps the greatest achievement of the MODP and its supply chain strategy was to quantify and stabilise the Magnox Life-cycle scope and cost and enable the successful competition and transfer of the Management and Operating (M and O) contract in 2014 and lay the foundations for further cost-savings to the UK taxpayer. (authors)
The Advanced Mixed Waste Treatment Project (AMWTP) has been retrieving, treating, characterizing, and shipping legacy Transuranic (TRU) waste for disposal since 2003 as part of the overall Idaho Cleanup Project (ICP) in support of the US Department of Energy. As the ICP has progressed, over 700 containers have been identified that cannot be successfully assayed using the current suite of non-destructive assay (NDA) instruments. To meet this challenge, Fluor Idaho, LLC, and Mirion Technologies (formerly Canberra Industries) have teamed to deploy the In-Situ Object Counting System (ISOCS) to supplement the current NDA capabilities. ISOCS has long been used in various radioactive waste management applications, but never has the ISOCS ability to perform intrinsic efficiency modeling of discrete waste containers been employed to characterize and certify TRU waste for disposal at the Waste Isolation Pilot Plant (WIPP), near Carlsbad, New Mexico. Since the primary disposal facility for this waste is the WIPP, the characterization processes for determining the quantity of radioactive material entrained in the waste are subject to WIPP Waste Acceptance Criteria (WAC) quality requirements and associated performance criteria. Until now, the Carlsbad Field Office (CBFO) WIPP-certified NDA equipment has utilized pre-defined efficiency calibrations for fixed geometries. However, due to the radioactive material content, activity levels, waste stream matrix, and/or the geometries of various size drums, boxes and other-odd-shaped containers or container integrity issues, it may not be suitable to characterize these containers with any of the existing WIPP-certified NDA equipment located at the AMWTP. Therefore, advanced technologies are needed to complete characterization of these problematic waste containers. The July 5, 2016 release of the WIPP WAC, DOE/WIPP-02-3122, Revision 8.0, Appendix A, 'Radioassay Requirements for Transuranic Waste,' was expanded to include several newer concepts such as American Society for Testing and Materials (ASTM) approved methods for efficiency-based calibrations and the use of mathematical computer modeling techniques for calibration. This change prompted AMWTP to pursue obtaining WIPP certification authority for expanded ISOCS techniques to deal with the remaining challenging waste containers and the development and implementation of Mirion's Figures of Merit (FOM) evaluations. These vital FOM evaluations enhance the ISOCS's modeling capabilities by optimizing the dynamic efficiency calibration for each object and reducing the assay's Total Measurement Uncertainty (TMU) budget. (authors)
Barely 9% of the 353 million metric tons of plastic waste produced worldwide over the last two decades has been recycled, with the majority of it being either landfilled or incinerated. Recycling and upcycling plastic waste is thus essential in mitigating environmental pollution. Gasification is the thermochemical conversion of solid carbon feedstock at high temperatures using a gasifying agent to produce hydrogen-rich syngas. Existing gasification technologies are energy-intensive and require high operating temperatures (>1000 °C), leaving them uncommercial. Microwave heating has sparked attention in a variety of chemical processes due to its specific advantages over traditional heating technologies, such as rapid and selective heating to improve process efficiency. NETL’s research team recently investigated the synergistic advantages of corn stover and mixed plastics in producing hydrogen-rich syngas via microwave heating. As a continuation of the research, this study provides an outlook over the non-catalytic versus catalytic effects of plastic-corn stover gasification via process electrification to enhance H2 production, minimize undesired tar, and improve process efficiency. Our aim is to provide complete electrification of the existing gasification process by using waste plastics as a starting block to produce valuable fuel and support the nation’s net zero goals.
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The National Renewable Energy Laboratory (NREL) uses the Mobility Energy Productivity (MEP) as a metric and a lens to guide applied research into high performance public mobility. In the current initiative to abate global warming, the US needs not only zero-emission vehicles in the transit fleet (such as buses and shuttles) but also time- and cost-effective services to connect people with goods, services and employment toward a high-quality of life. Our current transportation system is overly dependent on personally-owned automobiles for high quality mobility, with public modes being less viable in many areas. Simply electrifying the drivetrains of existing public transit modes will fail to improve the quality of mobility for those that do not have access to private automobiles. The slow rebound by transit from the pandemic reveals the need to reinvent public transit service. Using the MEP lens, NREL researchers have tracked various novel developments in the public mobility space, with the confluence of shared, on-demand transit (ODT) services using light duty vehicles emerging as a key enabler of high-efficiency public mobility. Deployments such as those in Arlington, TX, Dallas, TX, Fort Erie, ON, and Innisfil, ON showcase the use of fleets of light-duty vehicles as the basis for community circulation and first/last mile to intra-regional transit. ODT services have demonstrated improvements in being more time efficient for riders, more energy efficient in operation (even before the introduction of fully electric vehicles), as well as being cost effective. It appears that aspects of the long-awaited promise of Personal Rapid Transit from the 1970s are beginning to be realized through ODT deployments, leveraging transportation network company (TNC) logistics, popularized by Uber and Lyft, but applied to public mobility. Currently, manually driven ODT operations are already cost competitive with traditional transit systems on a cost per ride basis, and full automation promises to reduce costs by 50% while providing additional safety and verified customer service. Connecting these ODT systems with efficient and effective intra-regional backbone transit service is the next step, with transit agencies like DART providing early results. This discussion will walk through the evidence for this postulated outcome and show results from a series of case-studies.
Municipal electricity utilities and communities with public power are increasingly interested in the opportunities afforded by locally-sited solar projects. Understanding the allocation of costs and benefits of a solar project across affected entities and stakeholders such as customer types can be critical for community buy-in. This case study looked specifically at an analysis done for the City of Frankfort and how plans to meet 100% of city government electricity loads with renewable energy by 2023 could affect an all requirements contract the city's municipal utility has with a regional electricity provider. While the results are specific to Frankfort and the electricity contracts in place at the time of the study, it is an example of how the question of cross-subsidization can be addressed using a quantitative study, with the goal of increasing transparency and buy-in across multiple stakeholders.
Currently, 80% of the global final energy consumption occurs in form of fuels and only 20% as electricity. On the other hand, renewable energy additions come almost exclusively in the form of electricity (dominantly photovoltaics and wind). Thus, a successful energy transition will require enormous growth in renewables, sufficient to convert excess electricity into fuels, as well as the development of non-electricity based solar fuel technologies. As much as photovoltaic capacities have grown over the past 20 years, it is far from clear that current technologies and materials are up to the task to grow from here by yet another factor 100 until 2050. Therefore, sustained research efforts on emerging inorganic semiconductors for solar electricity and fuels are essential for facing the double challenge of climate change and energy security. Computational materials science can make important contributions, guiding and supporting research activities through both materials search and discovery and through detailed studies that help to develop a mechanistic understanding of materials performance and bottlenecks. This presentation will highlight three recent computational projects with relevance for photovoltaics and solar fuels (1) Defect graph neural networks (dGNN) for materials discovery in solar thermochemical hydrogen (STCH) [1]. The dGNN approach facilitates broad and fast materials screening for defect properties. (2) Modeling highly off-stoichiometric systems by evaluating the free energy of defect interaction [2]. This approach allows quantitative prediction of H2 production in complex STCH oxides. (3) First-principles atomic structure prediction for interfaces [3]. This work showed how an atomically thin CdCl2 interlayer phase enables in principle ideal electron transport across the incommensurate SnO2/CdTe interface. [1] M.D. Witman, A. Goyal, T. Ogitsu, A.H. McDaniel, S. Lany, Nat. Comput. Sci. (2023). https://doi.org/10.1038/s43588-023-00495-2. [2] A. Goyal, M.D. Sanders, R.P. O'Hayre, S. Lany, PRX Energy 3, 013008 (2024). https://doi.org/10.1103/PRXEnergy.3.013008. [3] A. Sharan, M. Nardone, D. Krasikov, N. Singh, S. Lany, Appl. Phys. Rev. 9, 041411 (2022). https://doi.org/10.1063/5.0104008.
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The Iowa Tribe of Kansas and Nebraska (ITKN) is a federally recognized Native American Tribe located along the Missouri River on the border of northeast Kansas and southeastern Nebraska. There are over 800 residents (Tribal citizens and non-Tribal) who live on the reservation, as well as more than 500 people who visit or work on the reservation on a daily basis. The ITKN faces many energy challenges, including rising service costs and dozens of power outages annually that impact resident well-being and business activities on Tribal lands. Power service issues are made more challenging by the remoteness of the reservation, which is 20 miles from the nearest town. Despite this, the ITKN has a long history of cultural and economic resilience: Local self-reliance, environmental stewardship, respecting the carrying capacity of the land, and strengthening the community are Tribal communities' traditional strengths. Long-term energy goals for the ITKN are centered around achieving energy sovereignty. Priority actions include: (1) Establishing a Tribal Utility Authority (TUA) to promote social welfare and community development.; (2) Deploying renewable community microgrids with ground-mount solar arrays and sustainable energy storage systems to advance energy sovereignty, resilience, and reliability. To advance these goals, the ITKN partnered with the U.S. Department of Energy's (DOE's) Communities LEAP (Local Energy Action Program) pilot. From August 2022 to March 2024, the ITKN community coalition collaborated with technical assistance providers at DOE's National Renewable Energy Laboratory (NREL) and Sandia National Laboratories to evaluate TUA planning needs and microgrid deployment scenarios. This fact sheet provides an overview of the results and outcomes from the Communities LEAP technical assistance process.
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