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At least 1,693 records · Page 94

Greenhouse Gas Reductions in the Power Industry Using Domestic Coal and Biomass - Volume 1: IGCC

The objective of this study was to simulate biomass co-firing in a dry-fed, entrained-flow gasifier in an integrated gasification combined cycle (IGCC) power plant and examine the resulting performance, environmental response, and economic response. To develop a more complete understanding of the impact of co-feeding biomass, each case was examined using a limited life cycle greenhouse gas (GHG) analysis, which examines GHG emissions beyond the plant stack. Included in the limited life cycle GHG analysis were anthropogenic greenhouse gas emissions from the production, processing, transportation, and fertilization of biomass and from mining, transporting and handling coal.

01 COAL, LIGNITE, AND PEAT↗

Greenhouse Gas Reductions in the Power Industry Using Domestic Coal and Biomass - Volume 2: PC Plants

The objective of this study was to simulate biomass co-firing in greenfield Pulverized Coal (PC) power plants and examine the resulting performance, environmental response, and economic response. To develop a more complete understanding of the impact of co-feeding biomass, each case was examined using a limited life cycle greenhouse gas (GHG) analysis, which examines GHG emissions beyond the plant stack. Included in the limited life cycle GHG analysis were anthropogenic greenhouse gas emissions from the production, processing, transportation, and fertilization of biomass and from mining, transporting and handling coal.

01 COAL, LIGNITE, AND PEAT↗

Improving Fission Products at CARIBU: Near Field Detection (Q4/FY19 Quarterly Progress Report)

We have been having ongoing discussions about the analysis and the text of the 95 Zr manuscript with our collaborators at Texas A&M University (TAMU). K. Kolos has travelled to Texas to discuss, once again, some details of our GEANT4 simulation used to determine the gas-counter efficiency. In that process, we discovered that there was a slight disagreement (~0.5%) between our results and the results obtained with the EGS code used by the TAMU group. We are currently working to determine and magnitude and source of the discrepancy. This has taken a considerable amount of time and, unfortunately, has hindered us from sending out the paper to all of our collaborators. We also recently found out that Benjamin Schroeder, the Texas A&M student supported by the CENTUAR Center of Excellence who joined our project earlier this year, has decided to leave graduate school after obtaining his Master Thesis. Although this is a loss for our team, we do not foresee this to cause a major disruption in the project. Our TAMU collaborators are still committed to the success of these measurements.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Demonstrations of Holistic, Lower Cost/Energy Effluent Water Management Approaches for Coal-Fired Energy Plants

The project work conducted under DOE award DE-FE0031678 was comprised of three overarching project goals: (1) evaluate the performance of Saltworks’ Flex EDR Selective process for treating wet flue gas desulfurization (FGD) wastewater, (2) conduct bench-scale testing of wastewater encapsulation as a byproduct management technology for the EDR generated brine, and (3) develop a dynamic water balance model encompassing the results of the aforementioned testing.

01 COAL, LIGNITE, AND PEAT↗

The Potential for Electrons to Molecules Using Solar Energy

Solar photovoltaics (PV) do and will continue to play an important role in the electric power sector and can potentially support other sectors that are in need of decarbonized energy sources. Chemicals such as hydrogen, ammonia, and hydrocarbons including ethylene are currently produced from natural gas and crude oil. Thus, processes to produce them emit carbon dioxide and other greenhouse gases both directly and in upstream feedstock recovery processes. Electrons-to-molecules (E2M) technologies are being developed to convert carbon dioxide, water, and atmospheric nitrogen to desired chemical products and they are large electricity loads. Thus, they are emerging as a potential applications for PV. In its essence, they can act as electrochemical energy storage, thereby providing a means to further utilize the energy generated from PV and store it in molecular form. E2M systems offer an array of potential products and system designs that can be tailored to different end-uses and applications. It involves electrochemical conversion which uses electricity to break molecular bonds and produce new molecules. Various electrochemical conversion technologies split water into hydrogen and oxygen, reduce carbon dioxide into other hydrocarbon molecules, and several other possible combinations. While this Chapter does not attempt to provide an exhaustive summary or analysis of the potential products from E2M systems, it does provide an initial overview of the potential opportunities and challenges for PV and E2M systems in this space. This Chapter considers the potential for E2M to produce key chemicals and fuels that currently rely on hydrocarbons for production, either as a reactant or a source of high-grade heat.

14 SOLAR ENERGY↗

Design and demonstration of an economical SRF structure for Continuous Wave (CW), high-energy, Megawatt-class beams

Due to its very high RF-to-beam efficiency, superconducting radiofrequency (SRF) cavities have become the technology of choice for the construction of large linear accelerators (linacs) for basic science applications (examples, ESS and PIP-II). The technology is also attractive for high volume industrial applications such as electron irradiation processing of wastewater and flue gas. However, SRF’s current reliance on liquid helium for cryogenic cooling introduces infrastructural and safety challenges for use in industrial settings. Cryocooler conduction-cooling is a recently developed novel technique for operating SRF cavities without requiring liquid helium. This project aims for technical design and economic assessment of a medium energy, high average power e-beam linac based on the conduction-cooled SRF technique for high volume irradiation treatment of wastewater. The goals of this project are (1) to design a medium energy (10 MeV), high average power (1 MW) electron beam accelerator around the cryocooler conduction-cooled SRF cavity technology, (2) demonstrate the required accelerating voltage on a prototype cavity, and (3) build a cost-model to evaluate capital and operating expense of the accelerator.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Operation and Dynamic Control of Hybrid Power Systems

Poster describing the planned startup process of a solid oxide gas turbine hybrid power system to be constructed at a 20 kW scale. The work is part of the ARPA-E project award to NETL under the INTEGRATE program.

Harun, Nor Farida↗

Integrated Electrocoagulation, Ultrafiltration, Membrane Distillation, and Crystallization for Treating Produced Water

Produced water (PW) generated from hydraulic fracturing operations was treated using an integrated electrocoagulation, ultrafiltration, membrane distillation, and crystallization process (EC UF MDC). The aim was to determine the viability of this integrated process for maximizing water recovery. The results obtained here indicate that optimizing the various unit operations could lead to increased recovery of PW. Membrane fouling limits all membrane separation processes. A pretreatment step to suppress fouling is essential. Here, removal of total suspended solids (TSS) and total organic carbon (TOC) was achieved by electrocoagulation (EC) followed by ultrafiltration (UF). The hydrophobic membrane used in membrane distillation may be fouled by dissolved organic compounds. Reducing membrane fouling is essential to increase the long-term durability of the membrane distillation (MD) system. In addition, combining membrane distillation with crystallization (MDC) can help reduce scale formation. By inducing crystallization in the feed tank, scale formation on the MD membrane was suppressed. The integrated EC UF MDC process can impact Water Resources/Oil & Gas Companies. Conservation of surface and groundwater is possible by treating and reusing PW. Additionally, treating PW reduces the amount of PW disposed in Class II disposal wells and promotes more environmentally sustainable operations.

42 ENGINEERING↗

CHEMISTRY IN A FORMING PROTOPLANETARY DISK: MAIN ACCRETION PHASE

We investigate the chemistry in a radiation-hydrodynamics model of a star-forming core that evolves from a cold (∼10 K) prestellar core to the main accretion phase in ∼10{sup 5} years. A rotationally supported gravitationally unstable disk is formed around a protostar. We extract the temporal variation of physical parameters in ∼1.5 × 10{sup 3} SPH particles that end up in the disk, and perform post-processing calculations of the gas-grain chemistry adopting a three-phase model. Inside the disk, the SPH particles migrate both inward and outward. Since a significant fraction of volatiles such as CO can be trapped in the water-dominant ice in the three-phase model, the ice mantle composition depends not only on the current position in the disk, but also on whether the dust grain has ever experienced higher temperatures than the water sublimation temperature. Stable molecules such as H{sub 2}O, CH{sub 4}, NH{sub 3}, and CH{sub 3}OH are already abundant at the onset of gravitational collapse and are simply sublimated as the fluid parcels migrate inside the water snow line. On the other hand, various molecules such as carbon chains and complex organic molecules (COMs) are formed in the disk. The COMs abundance sensitively depends on the outcomes of photodissociation and diffusion rates of photofragments in bulk ice mantle. As for S-bearing species, H{sub 2}S ice is abundant in the collapse phase. In the warm regions in the disk, H{sub 2}S is sublimated to be destroyed, while SO, H{sub 2}CS, OCS, and SO{sub 2} become abundant.

79 ASTRONOMY AND ASTROPHYSICS↗

How Does Feedback Affect the Star Formation Histories of Galaxies?

Star formation in galaxies is regulated by the interplay of a range of processes that shape the multiphase gas in the interstellar and circumgalactic media. Using the Cosmology and Astrophysics with MachinE Learning Simulations (CAMELS) suite of cosmological simulations, we study the effects of varying feedback and cosmology on the average star formation histories (SFHs) of galaxies at z ∼ 0 across the IllustrisTNG, SIMBA, and ASTRID galaxy formation models. We find that galaxy SFHs in all three models are sensitive to changes in stellar feedback, which affect the efficiency of baryon cycling and the rates at which central black holes grow, whereas the effects of varying active galactic nucleus (AGN) feedback depend on model-specific implementations of black hole seeding, accretion, and feedback. We also find strong interaction terms that couple stellar and AGN feedback, usually by regulating the amount of gas available for the central black hole to accrete. Using a double power law to describe the average SFHs, we derive a general set of equations relating the shape of the SFHs to physical quantities like baryon fraction and black hole mass across all three models. We find that a single set of equations (albeit with different coefficients) can describe the SFHs across all three CAMELS models, with cosmology dominating the SFH at early times, followed by halo accretion, and feedback and baryon cycling at late times. Galaxy SFHs provide a novel, complementary probe to constrain cosmology and feedback, and can connect the observational constraints from current and upcoming galaxy surveys with the physical mechanisms responsible for regulating galaxy growth and quenching.

Iyer, Kartheik G. [Columbia Univ., New York, NY (U↗

RECENT TRENDS IN EMERGING TRANSPORTATION FUELS AND ENERGY CONSUMPTION

Abundance of energy can be improved both by developing new sources of fuel and by improving efficiency of energy utilization, although we really need to pursue both paths to improve energy accessibility in the future. Currently, 2.7 billion people or 38% of the world s population do not have access to modern cooking fuel and depend on wood or dung and 1.4 billion people or 20% do not have access to electricity. It is estimated that correcting these deficiencies will require an investment of $36 billion dollars annually through 2030. In growing economies, energy use and economic growth are strongly linked, but energy use generally grows at a lower rate due to increased access to modern fuels and adaptation of modern, more efficient technology. Reducing environmental impacts of increased energy consumption such as global warming or regional emissions will require improved technology, renewable fuels, and CO2 reuse or sequestration. The increase in energy utilization will probably result in increased transportation fuel diversity as fuels are shaped by availability of local resources, world trade, and governmental, environmental, and economic policies. The purpose of this paper is to outline some of the recently emerging trends, but not to suggest winners. This paper will focus on liquid transportation fuels, which provide the highest energy density and best match with existing vehicles and infrastructure. Data is taken from a variety of US, European, and other sources without an attempt to normalize or combine the various data sources. Liquid transportation fuels can be derived from conventional hydrocarbon resources (crude oil), unconventional hydrocarbon resources (oil sands or oil shale), and biological feedstocks through a variety of biochemical or thermo chemical processes, or by converting natural gas or coal to liquids.

01 COAL, LIGNITE, AND PEAT↗

Renewable Energy for Industrial Environmental Management

Costs for renewable energy technologies have declined rapidly in the past decade and their use for residential, commercial, and utility scale electricity has grown exponentially as they become cost competitive. Simultaneously, industrial and manufacturing processes have been increasingly seeking ways to reduce emissions and operational costs in highly competitive sectors. With these combined drivers of lower cost and reduced environmental impact, renewable energy may become a viable energy provider for industrial processes such as oil and gas, mining, chemical refining, and manufacturing. The Joint Institute for Strategic Energy Analysis (JISEA), which is a partnership of the National Renewable Energy Laboratory (NREL) in Golden and three Colorado universities and others, has been studying to potential for application of clean energy technologies to the heterogenous energy demands in industry. Dr. Jill Engel-Cox will present an overview of NREL and JISEA, the status and potential future of renewable energy technologies, and collaborations with the oil and gas industry and other industrial sectors to improve their environmental performance and reduce operational costs.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Renewable Energy for Industrial Environmental Management

Costs for renewable energy technologies have declined rapidly in the past decade and their use for residential, commercial, and utility scale electricity has grown exponentially as they become cost competitive. Simultaneously, industrial and manufacturing processes have been increasingly seeking ways to reduce emissions and operational costs in highly competitive sectors. With these combined drivers of lower cost and reduced environmental impact, renewable energy may become a viable energy provider for industrial processes such as oil and gas, mining, chemical refining, food production, and manufacturing. Renewable energy technologies may also partner with other reduced emission energy sources, such as small modular nuclear reactors and carbon capture and utilization, to create cleaner and circular industrial systems for reduced resource use. The Joint Institute for Strategic Energy Analysis (JISEA), which is a partnership of the National Renewable Energy Laboratory (NREL) and five universities and others, has been studying to potential for application of clean energy technologies to the heterogenous energy demands in industry. Dr. Jill Engel-Cox will present an overview of NREL and JISEA, the status and potential future of renewable energy technologies, and collaborations with the oil and gas industry and other industrial sectors to improve their environmental performance and reduce operational costs.

ENERGY PLANNING, POLICY, AND ECONOMY↗

Quick Start to Electrifying Your School Bus Fleet

Learn how electric school buses can work for your district by understanding the basics of electrification. Understand what is needed to electrify your fleet, how much it costs, and how the process will effect your greenhouse gas emission impacts.

ADVANCED PROPULSION SYSTEMS↗

Nuclear criticality safety of pipes networks containing uranium - 14437

In nuclear facilities, the transfer of fissile material in solution, gas or powder forms between process stages requires many transfer lines (called 'pipes' in this paper) which may be laid out into bundles or networks. In Nuclear Criticality Safety evaluations, it is usual to assimilate such networks as a unique cylinder which area bounds the sum of the surface of pipes making up the network. However, even if this geometric simplification appears intuitively safe, it is not conservative in all cases. The aim of this paper is therefore to explore the validity and limitations associated to the assessment of pipes networks by a unique cylinder. This paper presents the impact on the k{sub eff} value of a detailed modeling of a pipes network compared to a unique cylinder. Variables of interest considered in such calculations are pipes diameter, composition, pitches and layout. Fissile media taken into account are uranium systems enriched from 5 % to 93.5 % in {sup 235}U. Then, the impact on reactivity of pipes material, such as stainless steel or plastic, is discussed and the minimal or maximal safe thickness of material has been determined. Finally, this paper provides guidance on the nuclear criticality safety assessment of pipes networks for uranium systems. (authors)

42 ENGINEERING↗

Reducing NOx Emissions in Ammonia Combustors

Ammonia continues to attract growing interest as a carbonneutral replacement fuel, motivating numerous research efforts toward understanding fundamental ammonia combustion characteristics. A major challenge for the use of ammonia is the development of combustor technologies for mitigating potentially high NOx emissions from the fuel-bound nitrogen chemical pathways to acceptable levels. Our work focuses on a staged RQL combustor architecture for minimizing the NOx emission levels through burning fuel-rich in the primary stage to formcombustion products containing significant levels of hydrogen in addition to nitrogen and water with minimal NOx formation. The subsequent quench and burnout stages of the combustor must then quickly burn residual hydrogen with flame-temperatures moderated by nitrogen and water forming in the first stage. Chemical Reactor Network modeling was used to understand and identify optimal stoichiometry and residence times in each stage for minimizing NOx emissions and to quantify pressure and temperature effects. Reducing the overall NOx emissions requires relatively long residence times in the primary stage to achieve near equilibrium NO levels due to kinetically controlling processes. For conditions relevant to gas turbines (e.g., 30 atm), our work indicates that NOx emissions below 20 ppm are theoretically achievable in a staged RQL combustor architecture. However, these emission predictions significantly depend on the accuracies of currently available chemical kinetic mechanisms which have not been extensively validated under elevated pressure and temperature conditions relevant to gas turbines.

10 SYNTHETIC FUELS↗

Lifecycle analysis of renewable natural gas and hydrocarbon fuels from wastewater treatment plants’ sludge

Wastewater treatment plants (WWTPs) produce sludge as a byproduct when they treat wastewater. In the United States, over 8 million dry tons of sludge are produced annually just from publicly owned WWTPs. Sludge is commonly treated in anaerobic digesters, which generate biogas; the biogas is then largely flared to reduce emissions of methane, a potent greenhouse gas. Because sludge is quite homogeneous and has a high energy content, it is a good potential feedstock for other conversion processes that make biofuels, bioproducts, and power. For example, biogas from anaerobic digesters can be used to generate renewable natural gas (RNG), which can be further processed to produce compressed natural gas (CNG) and liquefied natural gas (LNG). Sludge can be directly converted into hydrocarbon liquid fuels via thermochemical processes such as hydrothermal liquefaction (HTL). Currently, the environmental impacts of converting sludge into energy are largely unknown, and only a few studies have focused on the environmental impacts of RNG produced from existing anaerobic digesters. As biofuels from sludge generate high interest, however, existing anaerobic digesters could be upgraded to technology with more economic potential and more environmental benefits. The environmental impacts of using a different anaerobic digestion (AD) technology to convert sludge into energy have yet to be analyzed. In addition, no studies are available about the direct conversion of sludge into liquid fuels. In order to estimate the energy consumption and greenhouse gas (GHG) emissions impacts of these alternative pathways (sludge-to-RNG and sludge-to-liquid), this study performed a lifecycle analysis (LCA) using the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET®) model. The energy uses and GHG emissions associated with the RNG and hydrocarbon liquid are analyzed relative to the current typical sludge management case, which consists of a single-stage mesophilic digester with biogas flaring. Along with the alternative HTL process, four types of AD technologies with fuel production—single-stage mesophilic, mesophilic 2-stage, single-stage mesophilic with thermohydrolysis treatment, and mesophilicmesophilic acid/gas phase—are studied. Results show that the sludge-to-CNG pathway via AD and the sludge-to-liquid pathway via HTL reduce GHG emissions consumptions significantly. When we compare the GHG emissions of the alternative fuel production pathways to that of the counterfactual case in terms of the amount of sludge treated, reductions in GHG emissions are 39%–80% and 87% for alternative AD and HTL, respectively. Compared to petroleum gasoline and diesel GHG emission results in terms of MJ, the renewable CNG production pathway via AD and the renewable diesel production pathway via HTL reduce GHG emissions by 193% and 46%, respectively. These large reductions are mainly due to GHG credits from avoiding GHGs under the counterfactual scenario, and/or fertilizer displacement credits. Similarly, reductions in fossil fuel use for sludge-based fuels are huge. However, well-defined counterfactual scenarios are needed because the results of the study depend on the counterfactual scenario, which might vary over time.

03 NATURAL GAS↗

THE CIRCUMGALACTIC MEDIUM OF MASSIVE GALAXIES AT z {approx} 3: A TEST FOR STELLAR FEEDBACK, GALACTIC OUTFLOWS, AND COLD STREAMS

We present new results on the kinematics, thermal and ionization state, and spatial distribution of metal-enriched gas in the circumgalactic medium (CGM) of massive galaxies at redshift {approx}3, using the Eris suite of cosmological hydrodynamic ''zoom-in'' simulations. The reference run adopts a blastwave scheme for supernova feedback that produces large-scale galactic outflows, a star formation recipe based on a high gas density threshold, metal-dependent radiative cooling, and a model for the diffusion of metals and thermal energy. The effect of the local UV radiation field is added in post-processing. The CGM (defined as all gas at R > 0.2 R{sub vir} = 10 kpc, where R{sub vir} is the virial radius) contains multiple phases having a wide range of physical conditions, with more than half of its heavy elements locked in a warm-hot component at T > 10{sup 5} K. Synthetic spectra, generated by drawing sightlines through the CGM, produce interstellar absorption-line strengths of Ly{alpha}, C II, C IV, Si II, and Si IV as a function of the galactocentric impact parameter (scaled to the virial radius) that are in broad agreement with those observed at high redshift by Steidel et al. The covering factor of absorbing material declines less rapidly with impact parameter for Ly{alpha} and C IV compared to C II, Si IV, and Si II, with Ly{alpha} remaining strong (W{sub Ly{alpha}} > 300 mA) to {approx}> 5 R{sub vir} = 250 kpc. Only about one third of all the gas within R{sub vir} is outflowing. The fraction of sightlines within one virial radius that intercept optically thick, N{sub H{sub I}}>10{sup 17.2} cm{sup -2} material is 27%, in agreement with recent observations by Rudie et al. Such optically thick absorption is shown to trace inflowing ''cold'' streams that penetrate deep inside the virial radius. The streams, enriched to metallicities above 0.01 solar by previous episodes of star formation in the main host and in nearby dwarfs, are the origin of strong (N{sub C{sub II}}>10{sup 13} cm{sup -2}) C II absorption with a covering factor of 22% within R{sub vir} and 10% within 2 R{sub vir}. Galactic outflows do not cause any substantial suppression of the cold accretion mode. The central galaxy is surrounded by a large O VI halo, with a typical column density N{sub O{sub VI}} {approx}> 10{sup 14} cm{sup -2} and a near unity covering factor maintained all the way out to 150 kpc. This matches the trends recently observed in star-forming galaxies at low redshift by Tumlinson et al. Our zoom-in simulations of this single system appear then to reproduce quantitatively the complex baryonic processes that determine the exchange of matter, energy, and metals between galaxies and their surroundings.

79 ASTRONOMY AND ASTROPHYSICS↗