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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,693 records · Page 94

A first order theory of the p/+/-n-n/+/ edge-illuminated silicon solar cell at very high injection levels

A first order theory of the edge-illuminated p(+)-n-n(+) silicon solar cell under very high injection levels has been derived. The very high injection level illuminated J-V characteristic is derived for any general base width to diffusion length (W/L) ratio and it includes the minority carrier reflection by the n-n(+) high-low junction. The beneficial effects of the high-low junction are shown to be significant until extremely high injection levels are reached. The theoretical dependencies of Jsc and Voc on temperature, incident intensity, and base resistivity are derived and discussed in detail. Some experimental results are given and these are discussed in relation to the theory.

Goradia, C.↗

Laser-zone growth in a Ribbon-To-Ribbon (RTR) process. Silicon sheet growth development for the large area silicon sheet task of the low cost silicon solar array project

The Ribbon-to-Ribbon (RTR) approach to silicon ribbon growth is investigated. An existing RTR apparatus is to be upgraded to its full capabilities and operated routinely to investigate and optimize the effects of various growth parameters on growth results. A new RTR apparatus was constructed to incorporate increased capabilities and improvements over the first apparatus and to be capable of continuous growth. New high power lasers were implemented and this led to major improvements in growth velocity -- 4 inch/min. growth has been demonstrated. A major step in demonstration of the full feasibility of the RTR process is reported in the demonstration of RTR growth from CVD polyribbon rather than sliced polyribbon ingots. Average solar cell efficiencies of greater than 9% and a best cell efficiency of 11.7% are reported. Processing was shown to provide a substantial improvement in material minority carrier diffusion length. An economic analysis is reported which treats both the polyribbon fabrication and RTR processes.

Gurtler, R. W.↗

Jovian modulation of interplanetary electrons as observed with Voyagers 1 and 2

The release of magnetospheric electrons from Jupiter into interplanetary space is modulated by the Jovian rotation period. The Voyager 1 and 2 observations showed that the modulation period agrees on the average with the synodic period of Jupiter (9h 55m 33.12s), but over intervals of weeks it can differ from the synodic period by several minutes. The lack of exact synchronization is attributed to changes of the plasma population in the Jovian magnetosphere. The Jovian modulation appears to be a persistent feature of the interaction between the solar wind and the magnetosphere and the disappearance of the modulation away from Jupiter is attributed to interplanetary propagation conditions. This leads to the following limits on the diffuse coefficient for interplanetary electrons: kappa perpendicular is or = 8 x 10 to the 19th power sq cm/s and kappa parallel is or = 10 to the 21st power sq cm/s. Modulation was still detectable at 3.8 A.U. behind Jupiter in the far magnetotail. This requires a mean free path in the tail 0.75 A.U. and good field connection along the tail to Jupiter.

Schardt, A. W.↗

Limitations on solar cell open-circuit voltage and efficiency

Techniques used to determine the open-circuit voltage of solar cells are analyzed. It is noted that the computational procedures for determining the output characteristics of a solar cell depend on a thorough understanding of the behavior of individual components. However, amorphous materials and combination solar cells exhibit increasingly complex behaviors and theoretical analyses therefore are continually more dependent on experimental data for verification. Formulations are defined for the base region and for diffusion length measurement. Experimental results are cited to show that, for low resistivity, planar surface cells, the dark current from the emitter is the dominant factor limiting increases in the Voc, which can be enhanced by improving the efficiency of the doping levels and profile to minimize the effects of bandgap narrowing, junction recombination current, and diffusion length of the emitter region.

Meulenberg, A., Jr.↗

Screen printed interdigitated back contact solar cell

Interdigitated back contact solar cells are made by screen printing dopant materials onto the back surface of a semiconductor substrate in a pair of interdigitated patterns. These dopant materials are then diffused into the substrate to form junctions having configurations corresponding to these patterns. Contacts having configurations which match the patterns are then applied over the junctions.

Baraona, C. R.↗

Excimer laser annealing for fabrication of low-cost solar cells

Pulsed excimer laser annealing was successfully performed using a 50 w laser. Both polished and texturized cells were tried, however, there are serious problems with nonuniformity on texturized cells. A number of cells were produced and compared to diffusion furnace annealed cells. There was no clear economic advantage in using an excimer laser and there was a small penalty on average efficiency. The conclusion was that the excimer laser anneal process must be able to produce superior cells to be considered as a viable process option.

Spitzer, M. B.↗

Studies of hot B subdwarfs. III - Carbon, nitrogen, and silicon abundances in three sdB stars

Optical and high-dispersion IUE observations of three hot B subdwarfs (UV 1758 + 36, Ton S-227, and Feige 65) are presented. These data are analyzed with model atmosphere techniques, and element abundances for C, N, and Si are derived. The abundances are either near (N) or below (C, Si) the solar value; large variations (1) in the extent of underabundances of carbon and silicon among the objects, as well as (2) in the abundances (with respect to the solar values) characterizing each star are observed. A preliminary interpretation of the observed variations in these and other hot subdwarfs in terms of radiative forces disrupting the downward diffusion of heavy elements is presented.

Lamontagne, R.↗

Ballistic transport in planetary ring systems due to particle erosion mechanisms. I - Theory, numerical methods, and illustrative examples

Ballistic transport, defined as the net radial transport of mass and angular momentum due to exchanges of meteoroid hypersonic-impact ejecta by neighboring planetary ring regions on time-scales orders-of-magnitude shorter than the age of the solar system, is presently considered as a problem in mathematical physics. The preliminary results of a numerical scheme for following the combined effects of ballistic transport and viscous diffusion demonstrate that ballistic transport generates structure near sharp edges already present in the ring-mass distribution; the entire ring system ultimately develops an undulatory structure whose length scale is typically of the order of the radial excursion of the impact ejecta.

Durisen, Richard H.↗

Thermal plasma in outer planet magnetospheres

The plasma environments of the outer planets are a study in contrasts. The magnetosphere of Jupiter is dominated by the prodigious plasma output of Io, with losses due to diffusion driven by mass loading. At Saturn, the small icy satellites are the major sources of plasma for the inner magnetosphere. The low mass loading rates there imply that the densities of the plasma tori are limited by dissociative recombination, rather than diffusive transport. At Uranus, the icy satellites are negligible plasma sources compared to the input from the extended neutral hydrogen cloud and the ionosphere. Convection driven by the solar wind penetrates deep into the inner magnetosphere because of the unique orientation of the rotation axis of Uranus. The expected magnetosphere of Neptune is similar to that of Saturn and Jupiter, with Triton, the ring arcs, and the planet as possible plasma sources. The Voyager 2 encounter with Neptune holds out the hope of a passage through a nonterrestrial auroral region, a unique event in planetary exploration.

Belcher, J. W.↗

CubeSats for Gamma-Ray Astronomy [Book Chapter]

After many years of flying in space primarily for educational purposes, CubeSats – tiny satellites with form factors corresponding to arrangements of “1U” units, or cubes, each 10 cm on a side – have come into their own as valuable platforms for technology advancement and scientific investigations. CubeSats offer comparatively rapid, low-cost access to space for payloads that can be built, tested, and operated by relatively small teams, with substantial contributions from students and early career researchers. Continuing advances in compact, low-power detectors, readout electronics, and flight computers have now enabled X-ray and gamma-ray sensing payloads that can fit within the constraints of CubeSat missions, permitting in-orbit demonstrations of new techniques and innovative high-energy astronomy observations. Gamma-ray-sensing CubeSats are certain to make an important contribution in the new era of multi-messenger, time-domain astronomy by detecting and localizing bright transients such as gamma-ray bursts, solar flares, and terrestrial gamma-ray flashes; however, other astrophysical science areas requiring long observations in a low-background environment, including gamma-ray polarimetry, studies of nuclear lines, and measurement of diffuse backgrounds, will likely benefit as well. Here we present the primary benefits of CubeSats for high-energy astronomy, highlight the scientific areas currently or soon to be studied, and review the missions that are currently operating, under development, or proposed. A rich portfolio of CubeSats for gamma-ray astronomy already exists, and the potential for a broad range of creative and scientifically productive missions in the near future is very high.

79 ASTRONOMY AND ASTROPHYSICS↗

Ultrafast probes at the interfaces of solar energy conversion materials

Ultrafast carrier dynamics at interfaces plays a major role in governing solar energy conversion efficiency in solar conversion systems, especially in solar cells and photoelectrochemical devices. Here, we discuss recent advances in ultrafast spectroscopic probes to understand the dynamics at such interfaces. Transient reflectance (TR) enables monitoring of the surface carriers that are within ~10 nm of the surface or interface of interest. Crucial parameters such as surface recombination velocity and carrier diffusion can be determined. When a strong surface or interfacial field is present the reflectance spectrum will exhibit Franz–Kelydesh oscillations. Monitoring the transient formation or decay of such oscillations informs about the interfacial field and is referred to as transient photoreflectance (TPR). Such fields are helpful in designing systems in order to move carriers away from surfaces where photocorrosion can occur and towards catalytic surfaces. Finally, we discuss transient infrared attenuated total reflection (TATR) to probe the ultrafast reaction intermediates in a photo-driven chemical reaction.

14 SOLAR ENERGY↗

Influence of Tabula Rasa on Process- and Light-Induced Degradation of Solar Cells Fabricated From Czochralski Silicon

Monocrystalline Si solar cells are fabricated from Czochralski (Cz) Si, which contains 10 17 –10 18 cm -3 oxygen atoms. Cz Si undergoes degradation during high-temperature thermal processing steps, such as dopant diffusion to form the p - n junction. This degradation in the bulk minority carrier lifetime can be related to the formation of oxygen precipitates. We found that a high-temperature annealing process known as tabula rasa (TR) not only mitigates process-induced degradation via oxygen precipitate nuclei dissolution, but also modifies subsequent light-induced degradation. We report on the bulk carrier lifetime of n - and p -type Cz Si after TR, which homogenizes the interstitial oxygen in the bulk Si to its monoatomic form in either an N 2 or O 2 environment. A control sample, which was not subjected to a TR processing step, experienced severe process-induced degradation during a boron emitter thermal budget as oxygen precipitates were formed in the Si bulk. These precipitates could be imaged using photoluminescence. Additionally, samples that underwent a TR processing step prior to the boron emitter thermal budget show efficient gettering of metallic impurities compared to the control sample, which showed a decline in the implied open-circuit voltage after the gettering step. Furthermore, modification of the interstitial oxygen bonding by TR had a strong effect on the light-induced degradation kinetics. Instead of a typically observed monotonic decrease, minority carrier lifetime increases first, followed by a nonmonotonic decrease over a ~20 h period. Finally, we conclude that by modifying the interstitial oxygen bonding via TR pretreatment, p -type Cz Si wafers become substantially resistant to harsh solar cell processes and strongly modified light-induced degradation, which would open alternative ways to mitigate this degradation mechanism.

14 SOLAR ENERGY↗

On-Sun Characterization of Microchannel Supercritical Carbon Dioxide Solar Thermal Receivers - Preliminary Findings

The design of, and preliminary on-sun tests on, an 8 cm x 8 cm microchannel supercritical carbon dioxide (sCO2) receiver is presented. The receiver has a laminated design, wherein sheets of Haynes 230 nickel superalloy are patterned and diffusion bonded to form microscale flow passages. The microscale pattern is in the form of square pins with width and height of 500 μm and 200 μm respectively. The pins are arranged in an in-line pattern with respect to the flow direction. The longitudinal and transverse pitch ratios of the micro pin fins are identical and equal to two times the side width of the pillar. A sCO2 test facility is developed with the ability to supply sCO2 at 200 bar pressure and at temperatures between 300-500°C to the receiver inlet. The sCO2 facility is coupled to a seven meter diameter parabolic dish with a 25 kW rating and a concentration ratio of about 800. On-sun tests are performed at a receiver inlet pressure of 150 bar and a receiver inlet temperature between 110-130°C. Receiver and thermal efficiencies in excess of 0.91 and 0.96 respectively for the incident heat flux ranging from 8 to 80 W/cm2, and average surface temperatures ranging from 150-550°C are obtained in these experiments.

14 SOLAR ENERGY↗

Temperature Coefficients of Perovskite Photovoltaics for Energy Yield Calculations

Temperature coefficients for maximum power (TPCE), open circuit voltage (VOC), and short circuit current (JSC) are standard specifications included in data sheets for any commercially available photovoltaic module. To date, there has been little work on determining the TPCE for perovskite photovoltaics (PV). We fabricate perovskite solar cells with a TPCE of -0.08 rel %/°C and then disentangle the temperature-dependent effects of the perovskite absorber, contact layers, and interfaces by comparing different device architectures and using drift-diffusion modeling. A main factor contributing to the small TPCE of perovskites is their low intrinsic carrier concentrations with respect to Si and GaAs, which can be explained by its wider band gap. In this work, we demonstrate that the unique increase in Eg with increasing temperatures seen for perovskites results in a reduction in JSC but positively influences VOC. The current limiting factors for the TPCE in perovskite PV are identified to originate from interfacial effects.

14 SOLAR ENERGY↗

Review of Recent Results in Global MHD Modeling: ISTP Project Scientist for Theory and Ground-Based Observations

Global MHD (magnetohydrodynamic) simulations have shown a remarkable ability to describe the global dynamics of geospace. The limitations of the physical approximations underlying MHD would seem to limit the effectiveness of these codes, since kinetic and hybrid effects should manifest themselves by cross-scale coupling from microscales to mesoscales to global scales. However three effects appear to allow the codes to operate much more successfully than one would at first believe. They are:(l) the globally self-consistent nature of the codes with very well defined exterior boundary conditions (the solar wind) which allows the proper intercommunication between magnetospheric regions on MHD scales, (2) the control by global dynamics of the boundary layer locations where micro and meso scale processes operate, and (3) the critical role of numerical diffusion and with a sufficiently high resolution grid, the use of an empirical resistivity term, which if set at a level where the major magnetosphere boundaries properly calibrate against their observed locations, appear to well represent the effects of kinetic and hybrid processes on the global dynamics. The effectiveness of the global MHD codes, which have been developed under the ISTP mission, in describing Wind, Polar and Geotail observations, as well as ground-based observations are described. Particular emphasis is placed upon the Polar imaging data which when combined with ground-based data and global MHD-based synthetic aurora and convection patterns provide a powerful tool in understanding the final link in the solar-terrestrial chain: coupling into the atmosphere and ionosphere.

Curtis, Steven↗

New description of charged particle propagation in random magnetic fields

When charged particles spiral along a large constant magnetic field, their trajectories are scattered by random components that are superposed on the guiding field. In the simplest analysis of this situation, scattering causes the particles to diffuse parallel to the guiding field. At the next level of approximation, moving pulses that correspond to a coherent mode of propagation are present, but they are represented by delta-functions whose infinitely narrow width makes no sense physically and is inconsistent with the finite duration of coherent pulses observed in solar energetic particle events. To derive a more realistic description, the transport problem is formulated in terms of 4 x 4 matrices, which derive from a representation of the particle distribution function in terms of eigenfunctions of the scattering operator, and which lead to useful approximations that give explicit predictions of the detailed evolution not only of the coherent pulses, but also of the diffusive wake. More specifically, the new description embodies a simple convolution of a narrow Gaussian with the solutions above that involve delta-functions, but with a slightly reduced coherent velocity. The validity of these approximations, which can easily be calculated on a desktop computer, has been exhaustively confirmed by comparison with results of Monte Carlo simulations which kept track of 50 million particles and which were carried out on the Maspar computer at Goddard Space Flight Center.

Earl, James A.↗

Automatic phase control in solar power satellite systems

Various approaches to the problem of generating, maintaining and distributing a coherent, reference phase signal over a large area are suggested, mathematically modeled and analyzed with respect to their ability to minimize: phase build-up, beam diffusion and beam steering phase jitter, cable length, and maximize power transfer efficiency. In addition, phase control configurations are suggested which alleviate the need for layout symmetry.

Lindsey, W. C.↗

Relation Between Type II Bursts and CMEs Inferred from STEREO Observations

The inner coronagraph (COR1) of the Solar Terrestrial Relations Observatory (STEREO) mission has made it possible to observe CMEs in the spatial domain overlapping with that of the metric type II radio bursts. The type II bursts were associated with generally weak flares (mostly B and C class soft X-ray flares), but the CMEs were quite energetic. Using CME data for a set of type II bursts during the declining phase of solar cycle 23, we determine the CME height when the type II bursts start, thus giving an estimate of the heliocentric distance at which CME-driven shocks form. This distance has been determined to be approx. 1.5Rs (solar radii), which coincides with the distance at which the Alfven speed profile has a minimum value.We also use type II radio observations from STEREO/WAVES and Wind/WAVES observations to show that CMEs with moderate speed drive either weak shocks or no shock at all when they attain a height where the Alfven speed peaks (approx. 3Rs - 4Rs). Thus the shocks seem to be most efficient in accelerating electrons in the heliocentric distance range of 1.5Rs to 4Rs. By combining the radial variation of the CME speed in the inner corona (CME speed increase) and interplanetary medium (speed decrease) we were able to correctly account for the deviations from the universal drift-rate spectrum of type II bursts, thus confirming the close physical connection between type II bursts and CMEs. The average height (approx 1.5Rs) of STEREO CMEs at the time of type II bursts is smaller than that (2.2Rs) obtained for SOHO (Solar and Heliospheric Observatory) CMEs. We suggest that this may indicate, at least partly, the density reduction in the corona between the maximum and declining phases, so a given plasma level occurs closer to the Sun in the latter phase. In two cases, there was a diffuse shock-like feature ahead of the main body of the CME, indicating a standoff distance of 1Rs - 2Rs by the time the CME left the LASCO field of view.

Solar Energetic Particles↗