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At least 1,693 records · Page 94

nuSTORM Accelerator Challenges and Opportunities

The nuSTORM facility uses a stored muon beam to generate a neutrino source. Muons are captured and stored in a storage ring using stochastic injection. The facility will aim to measure neutrino-nucleus scattering cross-sections with uniquely well-characterized neutrino beams; to facilitate the search for sterile neutrino and other Beyond Standard Model processes with exquisite sensitivity, and to provide a muon source that makes an excellent technology test-bed required for the development of muon beams capable of serving as a multi-TeV collider. In this paper, we describe the latest status of the development of nuSTORM, the R&D needs, and the potential for nuSTORM as a Muon Collider test facility.

43 PARTICLE ACCELERATORS↗

Hydrogeological and multi-isotopic approach to define nitrate pollution and denitrification processes in a coastal aquifer (Sardinia, Italy)

Agricultural coastal areas are frequently affected by the superimposition of various processes, with a combination of anthropogenic and natural sources, which degrade groundwater quality. In the coastal multi-aquifer system of Arborea (Italy)—a reclaimed morass area identified as a nitrate vulnerable zone, according to Nitrate Directive 91/676/EEC—intensive agricultural and livestock activities contribute to substantial nitrate contamination. For this reason, the area can be considered a bench test for tuning an appropriate methodology aiming to trace the nitrate contamination in different conditions. An approach combining environmental isotopes, water quality and hydrogeological indicators was therefore used to understand the origins and attenuation mechanisms of nitrate pollution and to define the relationship between contaminant and groundwater flow dynamics through the multi-aquifer characterized by sandy (SHU), alluvial (AHU), and volcanic hydrogeological (VHU) units. Various groundwater chemical pathways were consistent with both different nitrogen sources and groundwater dynamics. Isotope composition suggests a mixed source for nitrate (organic and synthetic fertilizer), especially for the AHU and SHU groundwater. Moreover, marked heterotrophic denitrification and sulfate reduction processes were detected; although, for the contamination related to synthetic fertilizer, the attenuation was inefficient at removing NO{sub 3}{sup −} to less than the human consumption threshold of 50 mg/L. Various factors contributed to control the distribution of the redox processes, such as the availability of carbon sources (organic fertilizer and the presence of lagoon-deposited aquitards), well depth, and groundwater flow paths. The characterization of these processes supports water-resource management plans, future actions, and regulations, particularly in nitrate vulnerable zones.

54 ENVIRONMENTAL SCIENCES↗

Results and Lessons from MODIS Thermal Emissive Bands Calibration: Pre-launch to On-orbit

MODIS is a major instrument for the NASA EOS Terra (launched in December 1999) and Aqua (launched in May 2002) missions. It was designed and built to enhance and extend its heritage sensors' measurements and data records with applications covering a wide range of studies of the Earth's land, oceans, and atmosphere. Its 16 thermal emissive bands (TEB), each with 10 detectors, are located on the two cold focal plane assemblies (FPAs) controlled by a passive radiative cooler. Because of instrument design complexity and stringent calibration requirements, extensive calibration and characterization activities were conducted pre-launch by the sensor vendor for both Terra and Aqua MODIS. For TEB, these activities include characterization of detectors' noise and non-linearity and evaluation of their radiometric performance in thermal vacuum at difference instrument temperatures and FPA temperatures. In addition TEB system level response versus scan-angle (RVS) and relative spectral response (RSR) were characterized. MODIS TEB radiometric calibration transfer from pre-launch to on-orbit was performed using spectral bands' responses to the instrument on-board blackbody and a laboratory blackbody calibration source (BCS) traceable to NIST standards. This paper provides a summary of MODIS TEB pre-launch and on-orbit calibration and characterization activities, challenges, data analysis results, and lessons learned with focus on sensors' radiometric performance. A comparison between Terra and Aqua MODIS TEB performance is also presented. A similar summary for the reflective solar bands (RSB) is reported in a separate paper in these proceedings.

Xiong, X.↗

Synthesis and Characterization of Tris(trimethylsilyl)siloxide Derivatives of Early Transition Metal Alkoxides That Thermally Convert to Varied Ceramic–Silica Architecture Materials

In an effort to generate single-source precursors for the production of metal-siloxide (MSiO x ) materials, the tris(trimethylsilyl)silanol (H-SST or H-OSi(SiMe 3 ) 3 (1) ligand was reacted with a series of group 4 and 5 metal alkoxides. The group 4 products were crystallographically characterized as: [Ti(SST) 2 (OR) 2 ] (OR = OPr i (2), OBu t (3), ONep (4)); [Ti(SST) 3 (OBu n )] (5); [Zr(SST) 2 (OBu t ) 2 (py)] (6); [Zr(SST) 3 (OR)] (OR = OBu t (7), ONep, (8)); [Hf(SST) 2 (OBu t ) 2 ] (9); and [Hf(SST) 2 (ONep) 2 (py) n ] (n = 1 (10) , n = 2 (10a)) where OPr i = OCH(CH 3 ) 2 , OBu t = OC(CH 3 ) 3 , OBu n = O(CH 2 ) 3 CH 3 , ONep = OCH 2 C(CH 3 ) 3 , py = pyridine. The crystal structures revealed SST substituted: monomeric Ti species that adopted a tetrahedral (T-4) geometry; monomeric Zr compounds with coordination that varied from T-4 to trigonal bipyramidal (TBPY- 5); and monomeric Hf complexes isolated in a TBPY-5 geometry. For the group 5 species, the following derivatives were structurally identified as: [V(SST) 3 (py) 2 ] (11), [Nb(SST) 3 (OEt) 2 ] (12), [Nb(0)(SST) 3 (py)] (13), 2[H][(Nb(μ-0) 2 (SST)) 6 (μ 6 -0)] (14), [Nb 8 O 10 (OEt) 18 (SST) 2 •1/5Na 2 O] (15), [Ta(SST)([μ-OEt)(OEt) 3 ] 2 (16), and [Ta(SST) 3 (OEt) 2 ] (17) where OEt = OCH 2 CH 3 . The group 5 monomeric complexes were solved in a TBPY-5 arrangement, whereas the Ta of the dinculear 16 was solved in an octahedral coordination environment. Thermal analyses of these precursors revealed a stepwise loss of ligand, which indicated their potential utility for generating the MSiO x , materials. The complexes were thermally processed (350 - 1100 °C, 4h, ambient atmosphere) but instead of the desired MSiO x , transmission electron microscopy analyses revealed fractions of the group 4 and group 5 precursors had formed unusual architectures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

On the Characterization and Mitigation of Noise in Space-borne Microwave Sounding Instruments

Space-borne microwave sounding instruments have become vital data sources for weather prediction and climate change studies. Among the various radiometer configurations, the total power microwave radiometer is particularly appealing for current and future operational satellites due to its superior sensitivity and simple design. However, its performance is vulnerable to degradation caused by receiver gain fluctuations, electronic 1/f noise, and other time varying receiver characteristics. For Numerical Weather Prediction (NWP) users, 1/f noise introduces inter-channel correlations, complicating the assimilation of affected observations and reducing their accuracy. Addressing this noise issue in ground data processing system is essential to enhance the utility of microwave sounding data. This paper focuses on the characterization and mitigation of noise in current and future microwave sounding instruments, with particular emphasis on the impact of 1/f noise. Various methods are applied to quantitatively characterize noise features in both frequency and time domains. Additionally, the influence of calibration parameters on 1/f noise are analyzed. Based on these findings, we propose a mitigation algorithm for reducing noise during the on-orbit calibration of microwave sounding instruments, aiming to improve the quality of retrieved data for operational use.

calibration↗

Entanglement Capacity Estimates and Throughput Measurements of Quantum Channels

The throughput is an important performance metric of entangled qubit distribution quantum networks, and may be characterized by the number of distributed entangled qubit pairs per second (ebps). It is measured over physical quantum network connections using specialized instruments, including photonic entanglement sources and single photon detectors. Extensive theory has been developed to estimate the entangled qubit capacity of quantum channels using abstractions of physical connections. These two quantities both characterize the throughput performance but in different ways, and typically have been hard to relate to each other in concrete terms, in part due to the lack of precise measurements with matching analytical models and derivations. We describe measurements on a physical testbed with fiber connections of lengths 0-75 kilometers. We obtain the normalized analytic capacity estimates using the transmissivity approximations derived using single photon coincidence measurements, and convert them to bounds on throughput (measured in ebps) using a multiplier derived from co-located detector measurements. The results indicate consistent throughput measurements upper-bounded by their analytical capacity estimates across all connections. We show that previous capacity estimates using light measurements are below ebps measurements for some connections, due to the inclusion of non-representative decrease of light levels outside C-band with distance.

Rao, Nageswara↗

Introducing the Video In Situ Snowfall Sensor (VISSS)

The open-source Video In Situ Snowfall Sensor (VISSS) is introduced as a novel instrument for the characterization of particle shape and size in snowfall. The VISSS consists of two cameras with LED backlights and telecentric lenses that allow accurate sizing and combine a large observation volume with relatively high pixel resolution and a design that limits wind disturbance. VISSS data products include various particle properties such as maximum extent, cross-sectional area, perimeter, complexity, and sedimentation velocity. Initial analysis shows that the VISSS provides robust statistics based on up to 10 000 unique particle observations per minute. Comparison of the VISSS with the collocated PIP (Precipitation Imaging Package) and Parsivel instruments at Hyytiälä, Finland, shows excellent agreement with the Parsivel but reveals some differences for the PIP that are likely related to PIP data processing and limitations of the PIP with respect to observing smaller particles. The open-source nature of the VISSS hardware plans, data acquisition software, and data processing libraries invites the community to contribute to the development of the instrument, which has many potential applications in atmospheric science and beyond.

54 ENVIRONMENTAL SCIENCES↗

Real-time visualization of impact damage in monolithic silicon carbide and fibrous silicon carbide ceramic composite

Impact resistance from foreign debris is a critical requirement for brittle ceramic and ceramic composite materials intended for use in the hot-section of gas turbine engines. A design to mitigate against such impact failures necessitates a detailed understanding of the driving failure mechanisms. The present study introduces a unique time-resolved experimental method which advances the latter effort. Specifically, a pulsed synchrotron X-ray source, in phase contrast imaging (PCI) configuration, is used as a medium, to visually characterize the evolution of damage inside the target materials during impact. As a proof of concept, two types of ceramic materials were tested: monolithic silicon carbide and fibrous silicon carbide composite. Impact was performed using a light-gas gun and 1.5 mm diameter spheres of partially stabilized zirconia (PSZ) and silicon nitride (Si 3 N 4 ). The retrieved dynamic X-ray image sequences provided clear outlines of the damage features. In the case of the monolithic ceramic, the impact by a PSZ projectile initially produced a cone crack and complete failure resulted by extension of a median crack. By contrast, the fibrous composite deformed readily prior to cone crack formation. Nearly identical damage features were observed in the monolith for the Si 3 N 4 projectile, with the exception of the added vertical tensile crack. For this same projectile, the fibrous ceramic showed very limited surface deformation and enhanced cone cracking and kinking of laminates along the crack path. The latter response is attributed to the change in projectile properties. Some of the target materials were recovered, and post-mortem analysis via scanning electron microscopy (SEM) showed correlation with observed X-ray damage profiles. Furthermore, simple Hertzian contact was used to estimate damage for the elastic portion of impact. This approach was found to yield a reasonable match with experimental results for the surface displacement near the contact interface.

36 MATERIALS SCIENCE↗

Broadband polarization-entangled source for C+L-band flex-grid quantum networks

The rising demand for transmission capacity in optical networks has motivated steady interest in expansion beyond the standard C-band (1530–1565 nm) into the adjacent L-band (1565–1625 nm) for an approximate doubling of capacity in a single stroke. However, in the context of quantum networking, the L-band has yet to be fully leveraged with the suite of advanced tools for characterization and management available from classical lightwave communications. In this work, we demonstrate an ultrabroadband two-photon source integrating both C- and L-band wavelength-selective switches for complete control of spectral routing and allocation across 7.5 THz in a single setup. Polarization state tomography of all 150 pairs of 25-GHz-wide channels reveals an average fidelity of 0.98 and total distillable entanglement greater than 181 kebits/s. This source is explicitly designed for flex-grid optical networks and can facilitate optimal utilization of entanglement resources across the full C+L-band.

42 ENGINEERING↗

Molecular Gas in Three z ∼ 7 Quasar Host Galaxies

We present ALMA band 3 observations of the CO(6–5), CO(7–6), and [C i] 369 μm emission lines in three of the highest-redshift quasar host galaxies at 6.6 2″, or ≳14 kpc) CO emission in all three quasar hosts. In two sources, we detect the continuum emission around 400 μm (rest-frame), and in one source we detect [C i] at low significance. We derive molecular gas reservoirs of (1–3) × 10{sup 10} M{sub ⊙} in the quasar hosts, i.e., approximately only 10 times the mass of their central supermassive black holes. The extrapolated [C ii]-to-CO(1–0) luminosity ratio is 2500–4200, consistent with measurements in galaxies at lower redshift. The detection of the [C i] line in one quasar host galaxy and the limit on the [C i] emission in the other two hosts enables a first characterization of the physical properties of the interstellar medium in z ∼ 7 quasar hosts. In the sources, the derived global CO/[C ii]/[C i] line ratios are consistent with expectations from photodissociation regions, but not X-ray-dominated regions. This suggest that quantities derived from the molecular gas and dust emission are related to ongoing star-formation activity in the quasar hosts, providing further evidence that the quasar hosts studied here harbor intense starbursts in addition to their active nucleus.

79 ASTRONOMY AND ASTROPHYSICS↗

Use of CFD in the Design of the 10- by 10-Foot Supersonic Wind Tunnel Characterization Array

At the 10- by 10-Foot Supersonic Wind Tunnel at the NASA Glenn Research Center, a future full test section characterization generated an ideal opportunity to design and build new characterization hardware to improve the understanding of the flow field, including flow quality, uniformity, and uncertainty in primary variables of interest. An array of flow sensing probes, referred to as the Characterization Array, was designed and built to replace 1960’s-era test section characterization hardware. Many references exist to guide wind tunnel characterization practitioners in the design of new hardware to properly measure various aspects of the flow within their wind tunnel facilities. Although reliable sources of information, these references tend to be over 30 years old and are not exhaustive. In scenarios where design decisions needed to be validated, computational simulations of the flow field around the characterization hardware were used. Decisions regarding probe location, probe spacing, and performance of various probes were justified using computational fluid dynamic simulations and rules-of-thumb from the legacy resources available in literature. This paper is intended to serve as an example of the benefits from integrating CFD into the design of wind tunnel hardware, particularly hardware for wind tunnel characterization.

CFD↗

Use of CFD in the Design of the 10- by 10-Foot Supersonic Wind Tunnel Characterization Array

At the 10- by 10-Foot Supersonic Wind Tunnel at the NASA Glenn Research Center, a future full test section characterization generated an ideal opportunity to design and build new characterization hardware to improve the understanding of the flow field, including flow quality, uniformity, and uncertainty in primary variables of interest. An array of flow sensing probes, referred to as the Characterization Array, was designed and built to replace 1960’s-era test section characterization hardware. Many references exist to guide wind tunnel characterization practitioners in the design of new hardware to properly measure various aspects of the flow within their wind tunnel facilities. Although reliable sources of information, these references tend to be over 30 years old and are not exhaustive. In scenarios where design decisions needed to be validated, computational simulations of the flow field around the characterization hardware were used. Decisions regarding probe location, probe spacing, and performance of various probes were justified using computational fluid dynamic simulations and rules-of-thumb from the legacy resources available in literature. This paper is intended to serve as an example of the benefits from integrating CFD into the design of wind tunnel hardware, particularly hardware for wind tunnel characterization.

CFD↗

Characterization of a boron-loaded deuterated liquid scintillator for fast and thermal neutron detection

The preparation and characterization of novel boron-loaded deuterated liquid scintillators (BLDLS) are presented for the first time to investigate the performance of a detector sensitive to both fast and thermal neutrons intended for future neutron spectroscopy measurements. Three deuterated toluene-based scintillation cocktails were produced, one without boron, one loaded with ortho-carborane (natural boron isotopic abundance), and one with 96 wt% 10B enriched ortho-carborane. General optical and material properties were analyzed to include the composition, density, index of refraction, photoluminescence emission spectra, and absorbance spectra in addition to the relative light yield, resolution, relative efficiency, and pulse-shape-discrimination performance for all three scintillators and a hydrogen-based EJ-309 scintillator to evaluate the effects of boron loading in comparison with a common commercially-available scintillator and feasibility for future neutron spectroscopy measurements. Finally, the detection of shielded neutron sources was explored to capitalize on the 10B thermal neutron capture reaction. The results showed loading the scintillators with boron deteriorated the PSD performance slightly compared to the unloaded deuterated scintillator and resulted in a relative light yield loss of 26% and 41% for the 10B enriched and natural boron BLDLS, respectively. Lastly, the BLDLS have a higher relative detection efficiency than the unloaded deuterated scintillator for shielded neutron sources, based on total count rate, a desirable characteristic for missions related to finding and characterizing illicitly-trafficked special nuclear material.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

An Overview of Atmospheric Features Over the Western North Atlantic Ocean and North American East Coast - Part 1: Analysis of Aerosols, Gases, and Wet Deposition Chemistry

The Western North Atlantic Ocean (WNAO) and adjoining East Coast of North America are of great importance for atmospheric research and have been extensively studied for several decades. This broad region exhibits complex meteorological features, diverse cloud types, and a wide range of conditions associated with gas and particulate species that originate from many sources regionally and from other continents. As Part 1 of a 2-part paper series, this work provides a characterization of quantities associated with atmospheric chemistry, including gases, aerosols, and wet deposition, based on satellite observations, ground-based data, model simulations, and reanalysis products. Key results include spatial and seasonal differences in composition along the North American East Coast and over the WNAO associated with varying sources of smoke and dust and meteorological drivers such as temperature, moisture, and precipitation. Spatial and seasonal variations of tropospheric carbon monoxide and ozone highlight different pathways towards accumulation of these species in the troposphere. Spatial distributions of speciated aerosol optical depth and vertical profiles of aerosol mass mixing ratios show a clear seasonal cycle highlighting the influence of both natural and anthropogenic sources in addition to the impact of intercontinental transport on their vertical profiles. Analysis of long-term climate model simulations of aerosol species and satellite observations of carbon monoxide confirm that there has been a significant decline in recent decades among anthropogenic constituents owing to regulatory activities. The results can inform current and future lines of research for the region.

Corral, Andrea↗

Mid-Atlantic US observations of radiocarbon in CO 2 : fossil and biogenic source partitioning and model evaluation

Accurately quantifying regional anthropogenic CO 2 fluxes is fundamental to improving our understanding of the carbon cycle and for creating effective carbon mitigation policies, and the radiocarbon to total carbon ratio in atmospheric CO 2 (Δ 14 CO 2 ) is a robust tracer of fossil fuel CO 2 that can discriminate between biogenic and fossil fuel CO 2 sources. NASA's Atmospheric Carbon and Transport-America (ACT-America) airborne mission between 2016 and 2019 aimed to improve the accuracy of regional greenhouse gas flux estimates, through refining our understanding and characterization of fluxes and flux uncertainties in models. Δ 14 CO 2 observations from 26 flights are presented for examining seasonal CO 2 source partitioning in the Mid-Atlantic USA. Observed variability in boundary layer CO 2 at timescales ranging from intra-day to seasonal was largely driven by biogenic CO 2 (CO 2bio ) variability that ranged from −19.7 ppm in summer to 16.2 ppm in fall, while fossil fuel CO 2 (CO 2ff ) variability remained at 3.3±2.0 ppm. Carbonyl sulfide uptake was well-correlated with CO 2bio uptake, and examining this relationship, as well as that between CO 2 and CO 2bio variability reinforces the seasonal extent of gross primary productivity response throughout ACT-America. We use airborne Δ 14 CO 2 flask sampling alongside in situ carbon monoxide measurements to calculate high-frequency CO 2ff and evaluate the magnitude and diurnal variability of modeled CO 2ff , deducing likely transport errors in an example flight. Although ACT-America CO 2ff signals were attenuated due to the broad source regions sampled, results illustrate the value of Δ 14 CO 2 sampling and observation-based methodologies for regional CO 2 flux attribution, evaluation and improvement of modeled CO 2 .

Baier, Bianca C. [National Oceanic and Atmospheric↗

Characterization of Oxidative Modifications to Short Peptides Using Low Dose Rate X-Rays

The method of X-ray footprinting and mass spectrometry (XFMS) using high flux synchrotron X-ray sources has become an established method in structural biology and is based on the radiolytic production of hydroxyl radicals, which oxidatively modify protein sidechains. While other methods of producing hydroxyl radicals are available, one benefit of using high flux density sources is that hydroxyl radical scavenging reactions can be minimized, and exposure times kept short to minimize secondary reactions. Here we present an application of the XFMS method using low dose rate X-rays from a commercial instrument. We demonstrate the feasibility of the approach using short peptides, characterizing the oxidative modifications +14, +16, and +32 Da under both aerobic and low oxygen conditions, and we additionally quantify the hydrogen peroxide production for various doses using the low dose rate source. These results provide fundamental information on the oxidative damage to peptides due to hydroxyl radicals using a low dose rate X-ray source.

X-ray methods↗

Dark Energy Survey Year 1 Results: Cross-Correlation Redshifts - Methods and Systematics Characterization

We use numerical simulations to characterize the performance of a clustering-based method to calibrate photometric redshift biases. In particular, we cross-correlate the weak lensing (WL) source galaxies from the Dark Energy Survey Year 1 (DES Y1) sample with redMaGiC galaxies (luminous red galaxies with secure photometric red- shifts) to estimate the redshift distribution of the former sample. The recovered redshift distributions are used to calibrate the photometric redshift bias of standard photo-z methods applied to the same source galaxy sample. We also apply the method to three photo-z codes run in our simulated data: Bayesian Photometric Redshift (BPZ), Directional Neighborhood Fitting (DNF), and Random Forest-based photo-z (RF). We characterize the systematic uncertainties of our calibration procedure, and find that these systematic uncertainties dominate our error budget. The dominant systematics are due to our assumption of unevolving bias and clustering across each redshift bin, and to differences between the shapes of the redshift distributions derived by clustering vs photo-z's. The systematic uncertainty in the mean redshift bias of the source galaxy sample is z ≲ 0.02, though the precise value depends on the redshift bin under consideration. Here, we discuss possible ways to mitigate the impact of our dominant systematics in future analyses.

79 ASTRONOMY AND ASTROPHYSICS↗