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At least 1,711 records · Page 95

Quantifying Uncertainty of Landing and Takeoff Noise for Commercial Supersonic Aircraft

Of the many challenges faced by manufacturers attempting to offer supersonic travel to the public, the uncertainty in predicting the noise of these aircraft in airport operations has an immediate impact. No noise regulation exists in FAA or ICAO for certifying such aircraft, as these organization require solid data, usually from existing aircraft. Manufacturers are taking large risks to design a vehicle not knowing whether it will be allowed to fly. A partial solution to this conundrum is to use physics-based simulations to provide the “data” used to calibrate system-level prediction methods, carefully documenting the uncertainty of the method for application to supersonic aircraft. A close look at the accuracy of empirical prediction methods points to areas where improvements need to be made if noise studies of supersonic aircraft are to be useful. As NASA embarks on a focused research program to improve predictions of noise from the noise-dominant propulsion noise of commercial supersonic aircraft, this paper documents the work done to baseline the uncertainties found in today’s noise prediction methods. A relatively simplistic method was developed, summarizing the error of the empirical methods on a component basis and following their impact on the total aircraft during landing and takeoff operations using Monte Carlo analysis. By this method it is found that current empirical noise prediction methods have an uncertainty of 1.5 EPNdB cumulative for propulsion noise of a representative conventional subsonic passenger aircraft. When applied to likely near-term supersonic commercial aircraft, the uncertainty is 7.6 EPNdB cumulative, a difference that must be reduced if the prediction methods are to guide decision makers.

Airport noise↗

Evaluating Combined Lidar and Polarimeter Measurements of Cloud Top Parameters (Extinction, Scattering Cross Sections, and Droplet Number Density, Liquid Water Content)

We present a new method to derive profiles of extinction from a lidar which is then combined with polarimeter measurements to derive cloud droplet number density (CDNC) in the tops of warm clouds. The method employs polarization-sensitive elastic backscatter lidar measurements to estimate attenuation of the lidar signal within the cloud and polarimeter estimates of cloud droplet size distributions. The measurements used for this demonstration are from NASA Langley Research Center’s High Spectral Resolution Lidar – Generation 2 (HSRL-2) and NASA GISS’s Research Scanning Polarimeter (RSP). The measurements were acquired on NASA’s ACTIVATE mission, during which the instruments were deployed in a down-looking mode from a high-altitude aircraft, which flew in coordination with a low-flying aircraft acquiring coincident in situ measurements of cloud droplet size and number. The high vertical (1.25 m) and horizontal (~50 m) sampling resolution of the HSRL-2 data enabled retrievals of single-scattering extinction profiles to within ~2.5 optical depths of cloud top. Another key feature of the method was the well-calibrated measurement of backscatter at cloud top due to using the HSRL technique. The RSP retrievals of cloud droplet effective radius and variance were accomplished using the “cloud-bow” technique. Overall, the technique provides extinction profile estimates for the top 2.5 optical depths of water clouds that can be used to estimate the cloud droplet number density in various types of warm clouds. The mean extinction values at cloud top (0-1 optical depth) are compared against cloud drop size and number concentration acquired from wing-mounted probes (e.g., DMT Cloud Droplet Probe - CDP, SPEC Fast Cloud Droplet Probe FCDP, and SPEC 2D Stereo Probe - 2DS) that were deployed on the low-flying aircraft. Comparisons between the effective radius and variance from the polarimeter, lidar ratio (extinction to backscatter) from the lidar and polarimeter, and LWC are also presented. All measurements were acquired over the Western North Atlantic over 3 years from 2020 to 2022.

lidar↗

Calibration Issues and Operating System Requirements for Electron-Probe Microanalysis

Instrument purchase requirements and dialogue with manufacturers have established hardware parameters for alignment, stability, and reproducibility, which have helped improve the precision and accuracy of electron microprobe analysis (EPMA). The development of correction algorithms and the accurate solution to quantitative analysis problems requires the minimization of systematic errors and relies on internally consistent data sets. Improved hardware and computer systems have resulted in better automation of vacuum systems, stage and wavelength-dispersive spectrometer (WDS) mechanisms, and x-ray detector systems which have improved instrument stability and precision. Improved software now allows extended automated runs involving diverse setups and better integrates digital imaging and quantitative analysis. However, instrumental performance is not regularly maintained, as WDS are aligned and calibrated during installation but few laboratories appear to check and maintain this calibration. In particular, detector deadtime (DT) data is typically assumed rather than measured, due primarily to the difficulty and inconvenience of the measurement process. This is a source of fundamental systematic error in many microprobe laboratories and is unknown to the analyst, as the magnitude of DT correction is not listed in output by microprobe operating systems. The analyst must remain vigilant to deviations in instrumental alignment and calibration, and microprobe system software must conveniently verify the necessary parameters. Microanalysis of mission critical materials requires an ongoing demonstration of instrumental calibration. Possible approaches to improvements in instrument calibration, quality control, and accuracy will be discussed. Development of a set of core requirements based on discussions with users, researchers, and manufacturers can yield documents that improve and unify the methods by which instruments can be calibrated. These results can be used to continue improvements of EPMA.

Carpenter, P.↗

Direct Reading Particle Counters: Calibration Verification and Multiple Instrument Agreement via Bump Testing

We examined the calibration records of two direct reading instruments designated as condensation particle counters in order to determine the number of times they were found to be out of tolerance at annual manufacturer's recalibration. For both instruments were found to be out of tolerance more times than within tolerance. And, it was concluded that annual calibration alone was insufficient to provide operational confidence in an instrument's response. Thus, a method based on subsequent agreement with data gathered from a newly calibrated instrument was developed to confirm operational readiness between annual calibrations, hereafter referred to as bump testing. The method consists of measuring source particles produced by a gas grille spark igniter in a gallon-size jar. Sampling from this chamber with a newly calibrated instrument to determine the calibrated response over the particle concentration range of interest serves as a reference. Agreement between this reference response and subsequent responses at later dates implies that the instrument is performing as it was at the time of calibration. Side-by-side sampling allows the level of agreement between two or more instruments to be determined. This is useful when simultaneously collected data are compared for differences, i.e., background with process aerosol concentrations. A reference set of data was obtained using the spark igniter. The generation system was found to be reproducible and suitable to form the basis of calibration verification. Finally, the bump test is simple enough to be performed periodically throughout the calibration year or prior to field monitoring.

47 OTHER INSTRUMENTATION↗

A Ground Testing Program to Verify Lunar Dust-Tolerant Hardware for the Artemis Mission

In preparation for NASA’s Artemis Mission that will return humans to the surface of moon by 2024, an extensive test campaign will be undertaken to understand the effects of lunar dust contamination on equipment. Historically, early Apollo astronauts were affected by lunar dust that entered the cabin after their extravehicular activities, and subsequent missions had various cleaning protocols to reduce the impact of the contamination. The longest stays on the lunar surface were Apollo 15, 16, and 17 (just over three days), so equipment and suits were required to operate reliably for a relatively short duration. The ultimate goal of Artemis is a sustained human presence on the lunar surface, beginning with Artemis 3 which targets a six-and-a-half day surface deployment. This requires the design and testing of dust-tolerant infrastructure. Ground testing with aerosolized lunar dust simulants in a specialized chamber is an inexpensive way to verify the performance of equipment. Chambers equipped with various powder dispersers and analysis instrumentation can explore a variety of realistic scenarios relevant to lunar surface missions, from the interaction of dust with sensitive surfaces such as solar panels, textiles, radiators, and scientific equipment, to the effects of dust as it intrudes into habitable areas. These experiments require careful consideration of the expected mass concentrations, aerosolization methods, and transport properties of dust. Instruments that use light-scattering techniques to measure mass concentrations require calibration against lunar simulants for improved accuracy, and different simulants may have different calibration factors. Test facilities, laboratory setup and test methods for aerosolizing lunar simulant will be described along with relevant aerosol instruments and calibration efforts.

Benjamin J Sumlin↗

On the Efficiency $\eta$ and the Homogeneity of TiN Kinetic Inductance Detectors Produced through Atomic Layer Deposition

Microwave Kinetic Inductance Detectors (MKIDs) belong to non-equilibrium superconducting devices. It is a new promising device due to high quantum efficiency, low theoretical noise limit, multiplex frequency domain, photon-number-resolving, and energy resolving. In the case of MKIDs, a change in the kinetic inductance is produced by the breaking of Cooper pairs, modifying the electrodynamic response of the superconductor. The production process of an MKID consists of depositing a superconducting thin film on an insulating substrate and applying standard lithographic patterning techniques to produce a resonator structure. When an MKID is produced via sputtering, film nonuniformity is observed, producing instability, low yield, frequency collisions, and low energy resolution. We exploring film uniformity in films produced with Atomic Layer Deposition (ALD) and through ALD archive high values in the energy resolution. The uniformity of ALD is evaluated via measurement of the critical temperature of 4 MKIDs. Two MKIDs belong to the first fabrication process and the other two to another. The results obtained are: ΔTc/max(σT1,σT2) is 0.45 for A1-B1 and 0.21 for A2-B2. The difference in the Tc for MKIDs of the same wafer is around 5.1 mK and from different wafers, the maximum difference is 66 mk with a minimum of 48 mK. However, with the high uniformity archived, we obtained a poor response of the MKIDs when a photon is absorbed. As a consequence of the low response, we examined in the literature about the process of photon absorption. In this evaluation, we were focusing on the down-conversion efficiency as a possible cause for the degraded energy resolution. In this process, one part of the initial energy of the photon is lost, transferred to the creation of quasiparticles and phonons. The phonons that do not possess enough energy to break a Cooper pair are lost from the system. This loss in energy is accounted for by the eff iciency η which has a constant value reported as 0.57 (! from simulation). Due to the efficiency had been reported always as constant. We proceed to evaluate its value through a new method. The process consists of measuring the gain of the system via the photon transfer curve and thermal calibration. The efficiency obtained with this new method is of 0.008 which has a lower value in comparison with the simulation. The methods to obtain the critical temperature, as well as the new method to evaluate the efficiency of an MKID will be shown in this work.

43 PARTICLE ACCELERATORS↗

SU-E-I-87: Calibrating Cherenkov Emission to Match Superficial Dose in Tissue

Purpose: Through Monte Carlo simulations and phantom studies, the dominant factors affecting the calibration of superficial Cherenkov intensity to absolute surface dose was investigated, including tissue optical properties, curvatures, beam properties and imaging angle. Methods: The phasespace files for the TrueBeam system from Varian were used in GAMOS (a GEANT4 based Monte Carlo simulation toolkit) to simulate surface emission Cherenkov signals and the correlated deposited dose. The parameters examined were: i) different tissue optical properties (skin color from light to dark), ii) beam types (X-ray and electron beam), iii) beam energies, iv) thickness of tissues (2.5 cm to 20 cm), v) SSD (80 cm to 120 cm), vi) field sizes (0.5×0.5 cm2 to 20×20 cm2), vii) entrance/exit sides, viii) curvatures (cylinders with diameters from 2.5 cm to 20cm) and ix) imaging angles (0 to 90 degrees). In a specific case, for any Cherenkov photon emitted from the surface, the original position and direction, final position and direction and energy were recorded. Similar experimental measurements were taken in a range of the most pertinent parameters using tissue phantoms. Results: Combining the dose distribution and sampling sensitivity of Cherenkov emission, quantitatively accurate calibration factors (the amount of radiation dose represented by a single Cherenkov photon) were calculated. The data showed relatively large dependence upon different optical properties, curvature, entrance/exit and beam types. For a diffusive surface, the calibration factor was insensitive to imaging angles smaller than 60 degrees. Normalization with the reflectance image was experimentally validated as a simple and accurate method for calibrations of different optical properties. Conclusion: This study sheds light on how and to what extent different conditions affect the calibration from Cherenkov intensity to absolute superficial dose and provides practical solutions to allow quantitative Cherenkov imaging to be used as a dose surrogate for imaging.

60 APPLIED LIFE SCIENCES↗

Active Subspace Methods for Data-Intensive Inverse Problems

Fostered by advances in computing, simulation and data science have emerged as the third and fourth paradigms enabling scientific discovery. Many mathematical challenges arise when integrating these paradigms to produce new knowledge. One of the most important challenges is the inverse or calibration problem: find the inputs of a simulation such that its outputs agree with a given set of measurements. As both the cost of the complex simulations and the volume of measurement data sets increase, intuition-driven trial-and-error methods for calibration quickly become untenable; modern scientists need more computationally efficient and mathematically rigorous methods. When measurements and simulated predictions contain uncertainty, the Bayesian perspective on statistical inference provides a popular mathematical framework for developing computational methods to solve inverse problems. Markov chain Monte Carlo (MCMC) methods are a mainstay of this framework; they characterize a probability distribution on the space of model inputs that is conditioned on the given measurements. However, despite recent advances, MCMC methods remain impractical for expensive simulations with more than a handful of inputs. At its heart, MCMC searches the space of inputs for corresponding outputs that match measurements, and so it is afflicted with the curse of dimensionality. Additionally, MCMC methods become less efficient as the volume of the measurement data increases, particularly if the measurements are redundant. To make MCMC—and Bayesian methods, in general—amenable to today’s computer models with millions of inputs and terabytes of measurement data, one must devise methods to reduce the dimension of both the simulation inputs and the measurements. For many models used in practice, the outputs vary primarily on a low-dimensional manifold of the nominally high-dimensional input space. Recently developed active subspace methods discover this low-dimensional manifold and exploit it to enable analyses typically suited for low-dimensional settings (e.g., statistical inversion of complex systems). We hypothesize that active subspace methods can provide the necessary dimension reduction, enabling existing Bayesian methods to find solutions for a large class of otherwise intractable statistical inverse problems. We will test the hypothesis with a series of mathematical analyses and computational experiments that will proceed along three research veins: (i) integrating active subspace methods into methods for statistical inversion, (ii) addressing current challenges in active subspace methods, and (iii) incorporating methods for nonlinear dimensionality reduction into active subspace methods. We will apply the methods we develop to real inverse problems in chemical kinetics and turbulent flame modeling. Our team combines expertise in methods for inverse problems, dimension reduction, and reduced order modeling. With a history of active collaboration and thoughtful engagement, we bring enthusiasm and fresh perspectives to a well studied subject. We are excited by the potential opportunity to work together to extend and apply active subspace methods to data-intensive inverse problems.

97 MATHEMATICS AND COMPUTING↗

Validation of Ocean Color Remote Sensing Data using a Moored Databuoy

NASA's Sea-Viewing Wide Field-of-View Sensor (SeaWiFS) aims to measure global ocean color from space to within 5% to provide insights into fundamental ocean processes. SeaWiFS must be backed by comprehensive calibration and validation programs if the mission is to achieve this. In situ measurements of normalized water-leaving radiance (L(sub wn)) made simultaneously with satellite measurements can complement on-orbit methods of tracking changes in the calibration of the satellite radiometer and allow end-to-end vicarious validation of the remotely-sensed data. A moored optical databuoy was developed at Plymouth Marine Laboratory, UK to measure L(sub wn) in the western English Channel. Tests indicate that the buoy is capable of measuring spectral incident irradiance with less than 10% error and water-leaving radiance with less than 20% error; these errors are reduced by averaging and show no bias. There were 24 match-ups with good quality SeaWiFS data at the buoy site during the ten months of deployment within the period May 1997 and September 1998. The differences between the buoy and SeaWiFS measurements of L(sub wn) were found to be variable and often large. The root-mean-square (RMS) differences varied from 102% at 412 nm to 50% at 555 nm. The RMS differences in measurements of L(sub wn) could be reduced to less than 18% by a combination of increasing the calibration coefficients of SeaWiFS by between 0.2 and 4.3% in the visible bands and by tuning the extrapolation of aerosol radiances from the near infrared to the visible wavelengths. These results imply that the monitoring of the absolute calibration of the SeaWiFS bands is imperfect and errors remain in the extrapolation of aerosol radiances for atmospheric correction.

Lavender, Samantha↗

Requirements on the gain calibration for LiteBIRD polarisation data with blind component separation

The detection of primordial B modes of the cosmic microwave background (CMB) could provide information about the early stages of the Universe's evolution. The faintness of this signal requires exquisite calibration accuracy and control of instrumental systematic effects which otherwise could bias the measurements. In this work, we study the impact of an imperfect relative polarisation gain calibration on the recovered value of the tensor-to-scalar ratio r for the LiteBIRD experiment, through the application of the blind Needlet Internal Linear Combination (NILC) foreground-cleaning method. We derive requirements on the relative calibration accuracy of the overall polarisation gain (Δg ν ) for each LiteBIRD frequency channel. Our results show that minimum variance techniques, as NILC, are less sensitive to systematic gain calibration uncertainties compared to a parametric approach, if the latter is not equipped with a proper modelling of these instrumental effects. In this study, the most stringent requirements are found in the channels where the CMB signal is relatively brighter, with the tightest constraints at 166 GHz (Δg ν ≈ 0.16%). This differs from the outcome of an analogous analysis performed with a parametric method, where the tightest requirements are obtained for the foreground-dominated channels. Gain calibration uncertainties, corresponding to the derived requirements, are then simultaneously propagated into all frequency channels. By doing so, we find that the overall impact on estimated r is lower than the total gain systematic budget for LiteBIRD approximately by a factor 5, due to the correlations of the impacts of gain calibration uncertainties in different frequency channels. In order to decouple the systematic effect from the specific choice of the model, we derive the requirements assuming constant spectral parameters for the foreground emission. To assess the robustness of the obtained results against more realistic scenarios, we repeat the analysis assuming sky models of intermediate and high complexity. In these further cases, we adopt an optimised NILC pipeline, called the Multi-Clustering NILC (MC-NILC). We find that the impact of gain calibration uncertainties on r is lower than the LiteBIRD gain systematics budget for the intermediate-complexity sky model. For the high-complexity case, instead, it would be necessary to tighten the requirements by a factor 1.8.

79 ASTRONOMY AND ASTROPHYSICS↗

On multichannel film dosimetry with channel-independent perturbations

Purpose: Different multichannel methods for film dosimetry have been proposed in the literature. Two of them are the weighted mean method and the method put forth byMicke et al. [“Multichannel film dosimetry with nonuniformity correction,” Med. Phys. 38, 2523–2534 (2011)] and Mayer et al. [“Enhanced dosimetry procedures and assessment for EBT2 radiochromic film,” Med. Phys. 39, 2147–2155 (2012)]. The purpose of this work was to compare their results and to develop a generalized channel-independent perturbations framework in which both methods enter as special cases. Methods: Four models of channel-independent perturbations were compared: weighted mean, Micke–Mayer method, uniform distribution, and truncated normal distribution. A closed-form formula to calculate film doses and the associated type B uncertainty for all four models was deduced. To evaluate the models, film dose distributions were compared with planned and measured dose distributions. At the same time, several elements of the dosimetry process were compared: film type EBT2 versus EBT3, different waiting-time windows, reflection mode versus transmission mode scanning, and planned versus measured dose distribution for film calibration and for γ-index analysis. The methods and the models described in this study are publicly accessible through IRISEU. Alpha 1.1 ( http://www.iriseu.com ). IRISEU. is a cloud computing web application for calibration and dosimetry of radiochromic films. Results: The truncated normal distribution model provided the best agreement between film and reference doses, both for calibration and γ-index verification, and proved itself superior to both the weighted mean model, which neglects correlations between the channels, and the Micke–Mayer model, whose accuracy depends on the properties of the sensitometric curves. With respect to the selection of dosimetry protocol, no significant differences were found between transmission and reflection mode scanning, between 75 ± 5 min and 20 ± 1 h waiting-time windows or between employing EBT2 or EBT3 films. Significantly better results were obtained when a measured dose distribution was used instead of a planned one as reference for the calibration, and when a planned dose distribution was used instead of a measured one as evaluation for the γ-analysis. Conclusions: The truncated normal distribution model of channel-independent perturbations was found superior to the other three models under comparison and the authors propose its use for multichannel dosimetry.

61 RADIATION PROTECTION AND DOSIMETRY↗

Co-Optimization of CO 2 -EOR and Storage Processes in Mature Oil Reservoirs

This article presents an optimization methodology for CO 2 enhanced oil recovery in partially depleted reservoirs. A field-scale compositional reservoir flow model was developed for assessing the performance history of an active CO 2 flood and for optimizing both oil production and CO 2 storage in the Farnsworth Unit (FWU), Ochiltree County, Texas. A geological framework model constructed from geophysical, geological, and engineering data acquired from the FWU was the basis for all reservoir simulations and the optimization method. An equation of state was calibrated with laboratory fluid analyses and subsequently used to predict the thermodynamic minimum miscible pressure (MMP). Initial history calibrations of primary, secondary and tertiary recovery were conducted as the basis for the study. After a good match was achieved, an optimization approach consisting of a proxy or surrogate model was constructed with a polynomial response surface method (PRSM). The PRSM utilized an objective function that maximized both oil recovery and CO 2 storage. Experimental design was used to link uncertain parameters to the objective function. Control variables considered in this study included: water alternating gas cycle and ratio, production rates and bottom-hole pressure of injectors and producers. Other key parameters considered in the modeling process were CO 2 purchase, gas recycle and addition of infill wells and/or patterns. The PRSM proxy model was ‘trained’ or calibrated with a series of training simulations. This involved an iterative process until the surrogate model reached a specific validation criterion. A sensitivity analysis was first conducted to ascertain which of these control variables to retain in the surrogate model. A genetic algorithm with a mixed-integer capability optimization approach was employed to determine the optimum developmental strategy to maximize both oil recovery and CO 2 storage. The proxy model reduced the computational cost significantly. The validation criteria of the reduced order model ensured accuracy in the dynamic modeling results. The prediction outcome suggested robustness and reliability of the genetic algorithm for optimizing both oil recovery and CO 2 storage. The reservoir modeling approach used in this study illustrates an improved approach to optimizing oil production and CO 2 storage within partially depleted oil reservoirs such as FWU. Lastly, this study may serve as a benchmark for potential CO 2 –EOR projects in the Anadarko basin and/or geologically similar basins throughout the world.

02 PETROLEUM↗

Active Subspace Methods for Data-Intensive Inverse Problems (Final Report)

Fostered by advances in computing, simulation and data science have emerged as the third and fourth paradigms enabling scientific discovery. Many mathematical challenges arise when integrating these paradigms to produce new knowledge. One of the most important challenges is the inverse or calibration problem: find the inputs of a simulation such that its outputs agree with a given set of measurements. As both the cost of the complex simulations and the volume of measurement data sets increase, intuition-driven trial-and-error methods for calibration quickly become untenable; modern scientists need more computationally efficient and mathematically rigorous methods. When measurements and simulated predictions contain uncertainty, the Bayesian perspective on statistical inference provides a popular mathematical framework for developing computational methods to solve inverse problems. Markov chain Monte Carlo (MCMC) methods are a mainstay of this framework; they characterize a probability distribution on the space of model inputs that is conditioned on the given measurements. However, despite recent advances, MCMC methods remain impractical for expensive simulations with more than a handful of inputs. At its heart, MCMC searches the space of inputs for corresponding outputs that match measurements, and so it is afflicted with the curse of dimensionality. Additionally, MCMC methods become less efficient as the volume of the measurement data increases, particularly if the measurements are redundant. To make MCMC—and Bayesian methods, in general—amenable to today’s computer models with millions of inputs and terabytes of measurement data, one must devise methods to reduce the dimension of both the simulation inputs and the measurements. For many models used in practice, the outputs vary primarily on a low-dimensional manifold of the nominally high-dimensional input space. Recently developed active subspace methods discover this low-dimensional manifold and exploit it to enable analyses typically suited for low-dimensional settings (e.g., statistical inversion of complex systems). We hypothesize that active subspace methods can provide the necessary dimension reduction, enabling existing Bayesian methods to find solutions for a large class of otherwise intractable statistical inverse problems. We will test the hypothesis with a series of mathematical analyses and computational experiments that will proceed along three research veins: (i) integrating active subspace methods into methods for statistical inversion, (ii) addressing current challenges in active subspace methods, and (iii) incorporating methods for nonlinear dimensionality reduction into active subspace methods. We will apply the methods we develop to real inverse problems in chemical kinetics and turbulent flame modeling. Our team combines expertise in methods for inverse problems, dimension reduction, and reduced order modeling. With a history of active collaboration and thoughtful engagement, we bring enthusiasm and fresh perspectives to a well studied subject. We are excited by the potential opportunity to work together to extend and apply active subspace methods to data-intensive inverse problems.

97 MATHEMATICS AND COMPUTING↗

Long-term stability of the Leksell Gamma Knife{sup ®} Perfexion™ patient positioning system (PPS)

Purpose: To assess the long-term mechanical stability and accuracy of the patient positioning system (PPS) of the Leksell Gamma Knife{sup ®} Perfexion™ (LGK PFX). Methods: The mechanical stability of the PPS of the LGK PFX was evaluated using measurements obtained between September 2007 and June 2011. Three methods were employed to measure the deviation of the coincidence of the radiological focus point (RFP) and the PPS calibration center point (CCP). In the first method, the onsite diode test tool with single diode detector was used together with the 4 mm collimator on a daily basis. In the second method, a service diode test tool with three diode detectors was used biannually at the time of the routine preventive maintenance. The test performed with the service diode test tool measured the deviations for all three collimators 4, 8, and 16 mm and also for three different positions of the PPS. The third method employed the conventional film pin-prick method. This test was performed annually for the 4 mm collimator at the time of the routine annual QA. To estimate the effect of the patient weight on the performance of the PPS, the focus precision tests were also conducted with varying weights on the PPS using a set of lead bricks. Results: The average deviations measured from the 641 daily focus precision tests were 0.1 ± 0.1, 0.0 ± 0.0, and 0.0 ± 0.0 mm, respectively, for the 4 mm collimator in the X (left/right of the patient), Y (anterior/posterior of the patient), and Z (superior/inferior of the patient) directions. The average of the total radial deviations as measured during ten semiannual measurements with the service diode test tool were 0.070 ± 0.029, 0.060 ± 0.022, and 0.103 ± 0.028 mm, respectively for the central, long, and short diodes for the 4 mm collimator. Similarly, the average total radial deviations measured during the semiannual measurements for the 4, 8, and 16 mm collimators and using the central diode were 0.070 ± 0.029, 0.097 ± 0.025, 0.159 ± 0.028 mm, respectively. The average values of the deviations as obtained from the five annual film pin-prick tests for the 4 mm collimator were 0.10 ± 0.06, 0.06 ± 0.09, and 0.03 ± 0.03 mm for the X, Y, Z stereotactic directions, respectively. Only a minor change was observed in the total radial deviations of the PPS as a function of the simulated patient weight up to 202 kg on the PPS. Conclusions: Excellent long-term mechanical stability and high accuracy was observed for the PPS of the LGK PFX. No PPS recalibration or any adjustment in the PPS was needed during the monitored period of time. Similarly, the weight on the PPS did not cause any significant disturbance in the performance of the PPS for up to 202 kg simulated patient weight.

61 RADIATION PROTECTION AND DOSIMETRY↗

Calibration of a helium-cooled infrared spatial radiometer and grating spectrometer

Methods used by the Space Dynamics Laboratory of Utah State University (SDL/USU) to calibrate infrared sensors are described, using the Infrared Background Signature Survey (IBSS) spatial radiometer and grating spectrometer as examples. A calibration equation and a radiometric model are given for each sensor to describe their responsivity in terms of individual radiometric parameters. The calibration equation terms include dark offset, linearity, absolute responsivity, and measurement uncertainty, and the radiometric model domains include spatial, spectral, and temporal domains. A portable calibration facility, designed and fabricated by SDL/USU, provided collimated, extended, diffuse scatter, and Jones sources in a single cryogenic dewar. This multi-function calibrator allowed calibration personnel to complete a full calibration of the IBSS infrared radiometer and spectrometer in two 15-day periods. A calibration data system was developed to control and monitor the calibration facility, and to record and analyze sensor data.

Jacobsen, Larry↗

Calibration of Film for Accurate Megavoltage Photon Dosimetry

An accurate method of converting film density to dose is presented. For films oriented parallel to the beam’s central axis, calibration curves were produced at several depths using Kodak XV-2 film for cobalt-60, 4 MV, and 18 MV beams. Then the appropriate curve was employed to convert the film density to dose at a specific depth. It is hypothesized that the change in film response with depth is due to changes in the photon spectra at depth in a phantom.

61 RADIATION PROTECTION AND DOSIMETRY↗

Improved ground truth geoid for the GEOS-3 calibration area

The purpose of this investigation is to develop methods and procedures are reported for computing a detailed geoid to be used as geodetic ground truth for the calibration and verification of GEOS-3 altimeter data. The technique developed is based on rectifying the best available detailed geoid so that the rectified geoid will have correct scale, orientation, shape and position with respect to the geocenter. The approach involved the development of a mathematical model based on a second degree polynomial, in rectangular Cartesian coordinates, describing the geoid undulations at the control stations. A generalized least squares solution was obtained for the polynomial which describes the variation of the undulation differences between the control stations geoid and the gravimetric geoid. Three rectified geoid were determined. These geoids correspond to three sets of tracking station data: (1) WFC/C-band data; (2) GSFC/C-band data; and (3) OSU-275 data. The absolute accuracy of these rectified geoids is linearly correlated with the uncertainties of the tracking station coordinates and, to a certain extent, with those of the detailed geoid being rectified.

Mourad, A. G.↗

Quantitative Separation of Unknown Organic–Metal Complexes by Liquid Chromatography–Inductively Coupled Plasma-Mass Spectrometry

Dissolved organic matter (DOM) is widely recognized to control the solubility and reactivity of trace metals in the environment. However, the mechanisms that govern metal-DOM complexation remain elusive, primarily due to the analytical challenge of fractionating and quantifying metal–organic species within the complex mixture of organic compounds that comprise DOM. Here, we describe a quantitative method for fractionation and element-specific detection of organic–metal complexes using liquid chromatography with online inductively coupled plasma mass spectrometry (LC–ICP-MS). The method implements a post-column compensation gradient to stabilize ICP–MS elemental response across the LC solvent gradient, thereby overcoming a major barrier to achieving quantitative accuracy with LC–ICP-MS. With external calibration and internal standard correction, the method yields concentrations of organic–metal complexes that were consistently within 6% of their true values, regardless of the complex’s elution time. We used the method to evaluate the effects of four stationary phases (C18, phenyl, amide, and pentafluoroylphenyl propyl) on the recovery and separation of environmentally relevant trace metals (Mn, Fe, Co, Ni, Cu, Zn, Cd, and Pb) in Suwannee River Fulvic Acid and Suwannee River Natural Organic Matter. The C18, amide, and phenyl phases generally yielded optimal metal recoveries (>75% for all metals except Pb), with the phenyl phase separating polar species to a greater extent than C18 or amide. We also fractionated organic-bound Fe, Cu, and Ni in oxidized and reduced soils, revealing divergent metal-DOM speciation across soil redox environments. Finally, by enabling quantitative fractionation of DOM-bound metals, our method offers a means for advancing a mechanistic understanding of metal–organic complexation throughout the environment.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗