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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,711 records · Page 95

DOE LeRC photovoltaic systems test facility

The facility was designed and built and is being operated as a national facility to serve the needs of the entire DOE National Photovoltaic Program. The object of the facility is to provide a place where photovoltaic systems may be assembled and electrically configured, without specific physical configuration, for operation and testing to evaluate their performance and characteristics. The facility as a breadboard system allows investigation of operational characteristics and checkout of components, subsystems and systems before they are mounted in field experiments or demonstrations. The facility as currently configured consist of 10 kW of solar arrays built from modules, two inverter test stations, a battery storage system, interface with local load and the utility grid, and instrumentation and control necessary to make a flexible operating facility. Expansion to 30 kW is planned for 1978. Test results and operating experience are summaried to show the variety of work that can be done with this facility.

Cull, R. C.↗

Bifacial PV System Mismatch Loss Estimation and Parameterization: Preprint

Non-uniform irradiance on the rear-side of bifacial PV systems can cause additional mismatch loss which may not be appropriately captured in PV energy production estimates and software. We have evaluated several scenarios including horizontal single-axis tracking (HSAT) and rooftop mounted systems over high albedo reflective roofs. Mismatch losses of up to 2% annual loss for very close-mounted (0.15 m) rooftop systems were found, but losses for HSAT systems and high ground-clearance rooftop systems were lower (<0.5%). A simplified empirical relationship was found that links the spatial variation of irradiance (specifically the mean absolute difference of irradiance) to the resulting mismatch loss factor, with a R2 fit better than 0.985. This approximate relationship has been validated by experiments on mismatched PV modules, and provides a basis for fast estimation of bifacial mismatch loss factors for use in hourly PV performance simulations such as PVSyst or SAM.

14 SOLAR ENERGY↗

Zinc Phthalocyanine–Phosphonic Acid Monolayers on ITO: Influence of Molecular Orientation, Aggregation, and Tunneling Distance on Charge-Transfer Kinetics

Efficient charge harvesting at electrodes is critical for the effective performance of organic photovoltaics and is strongly influenced by the first molecular monolayer at the transparent conducting oxide electrode. In this work, we introduce a study of the relationship between molecular orientation and tunneling distance on charge-transfer rates between a tethered sub-monolayer/monolayer of phosphonic acid (PA)-functionalized Zn phthalocyanines (ZnPcs) and an indium tin oxide (ITO) surface by a combination of electrochemical techniques and waveguide tools such as attenuated total reflectance (ATR) UV–vis spectroscopy and potential-modulated ATR (PM-ATR) spectroelectrochemistry. The distance between the main chromophore and PA anchoring group was modulated by an aliphatic carbon of various lengths (n = 3, 9, 10, or 11) that resulted in an extended distance of 7–18 Å between the ZnPcs and the ITO surface. Modified ITO surfaces were composed of monomeric and aggregated subpopulations of ZnPcs with molecular orientations predominantly in-plane (36–39°) and out-of-plane (72–75°), respectively. Charge-transfer rate constants (k s,opt ) were measured using PM-ATR. For a given tether length, the aggregated subpopulations exhibit higher ks,opt values compared to the monomeric subpopulations. Furthermore, the observed k s,opt values had an exponential dependence on the effective tunneling distance with a decay constant (β) that ranged from 0.32 to 0.47 Å –1 , depending on the chromophore orientation and aggregation state. The fastest charge-transfer rate constants were found for the chromophores with the smallest tunneling distance (n = 3). A k s,opt of 3.9 × 10 4 s –1 represents the fastest rate constant measured by PM-ATR for a PA-functionalized ZnPc chromophore tethered to an ITO waveguide electrode.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Long-term impact of light- and elevated temperature-induced degradation on photovoltaic arrays

Low levelized cost of electricity (LCOE) has been identified as critical for widespread adoption of photovoltaics (PV) without subsidies. Maintaining decades-long high-energy production is often an under-recognized opportunity in meeting cost goals because component lifetimes are not fully quantified at the time of manufacture. Whereas certain standardized tests minimize risk of early failure, there is little guidance to quantitatively predict degradation (or lack thereof) over decades, based on accelerated tests. In this article, we move toward bridging the understanding between indoor accelerated tests and outdoor performance data, with the goal of predicting energy yield with enough accuracy to inform financial decisions. Light- and elevated temperature-induced degradation (LETID) in p-type Si modules is analyzed in terms of impact on long-term module performance and thus LCOE. A method to predict the progression of LETID, using fixed kinetic constants and a numerical solution to the basic reaction rate equations, is detailed. Predictions are compared against both published data and that new to this study. These data include both indoor accelerated tests and fielded modules. We use the results in financial models to derive LCOE of modules in different climates with varying amounts of LETID, including uncertainty. Cost models based on the predictions indicate that LETID has a significant and climate-dependent impact on LCOE. Finally, we show that - even given the uncertainties identified in the study - these financial calculations can provide useful guidance to quantify risk based on accelerated test results. The analysis serves as an example of developing a predictive approach to PV reliability using physics of failure.

14 SOLAR ENERGY↗

Analysis of the Solar Energy Collection for In-Plane Rotation Two Axes Micro-Tracking Systems

Concentrator photovoltaic technologies (CPV) have long been regarded as the obvious way to increase the solar power collection efficiency but the use of bulky two axes tracking systems has been proven to be a fatal handicap for both economic and technical reasons. On the other hand, the continuous development of multijunction high efficiency solar cells encourages the research of novel CPV architectures that can leverage the new cells potential. Here we present a study on the solar energy collection of an ideal hybrid two axes micro-tracking system suitable for rooftop installations. In this study, we analyze in detail the optimal installation angle in relation to the latitude and the partial shading effect on modules of the same solar panel. The study is focused on optimizing the average collection efficiency over the astronomical year period as opposed to maximize the collection on any given day of the year. Additionally, we conducted a techno-economic analysis of the hybrid In-Plane Micro Tracker, using “Bottom-Up” methodology for determining the cost of the micro-tracking concept where the materials, assembly, utilities, maintenance costs are included for each step of the manufacturing process.

14 SOLAR ENERGY↗

Large-Area Material and Junction Damage in c–Si Solar Cells by Potential-Induced Degradation

This paper reports a new potential-induced degradation (PID) mechanism for crystalline silicon (c-Si), where Na diffuses everywhere and causes large-area material and junction degradation with point defects. Multiple characterization techniques are combined - Kelvin probe force microscopy, electron-beam induced current, dark lock-in thermography, transmission electron microscopy, time-of-flight secondary-ion mass spectrometry, and microwave photoconductance decay - as well as density functional theory (DFT) calculations. These characterization techniques and theoretical calculations are complementary in various aspects of a material's chemical, structural, electrical, and optoelectrical nature, as well as in atomic, nanometer, micrometer, millimeter, and cell and module scales. All results point consistently to a new discovery: substantial large-area deterioration of materials and junctions play a major role in c-Si PID (in addition to the previously reported local shunting defect caused by Na diffusion to planar defects). Furthermore, this new finding reveals a key PID component and leads to a new strategy for tailoring c-Si photovoltaics to ultimately resolve the PID issue.

14 SOLAR ENERGY↗

Solar cell efficiency tables (version 59)

Consolidated tables showing an extensive listing of the highest independently confirmed efficiencies for solar cells and modules are presented. Furthermore, guidelines for inclusion of results into these tables are outlined, and new entries since June 2021 are reviewed.

14 SOLAR ENERGY↗

Solar cell efficiency tables (version 62)

Abstract Consolidated tables showing an extensive listing of the highest independently confirmed efficiencies for solar cells and modules are presented. Guidelines for inclusion of results into these tables are outlined, and new entries since January 2023 are reviewed.

14 SOLAR ENERGY↗

Solar cell efficiency tables (Version 63)

Abstract Consolidated tables showing an extensive listing of the highest independently confirmed efficiencies for solar cells and modules are presented. Guidelines for inclusion of results into these tables are outlined and new entries since July 2023 are reviewed.

14 SOLAR ENERGY↗

III-Vs at Scale: A PV Manufacturing Cost Analysis of the Thin Film Vapor-Liquid-Solid Growth Mode

The authors present a manufacturing cost analysis for producing thin-film indium phosphide modules by combining a novel thin-film vapor-liquid-solid (TF-VLS) growth process with a standard monolithic module platform. The example cell structure is ITO/n-TiO2/p-InP/Mo. For a benchmark scenario of 12% efficient modules, the module cost is estimated to be $0.66/W(DC) and the module cost is calculated to be around $0.36/W(DC) at a long-term potential efficiency of 24%. The manufacturing cost for the TF-VLS growth portion is estimated to be ~$23/m2, a significant reduction compared with traditional metalorganic chemical vapor deposition. The analysis here suggests the TF-VLS growth mode could enable lower-cost, high-efficiency III-V photovoltaics compared with manufacturing methods used today and open up possibilities for other optoelectronic applications as well.

14 SOLAR ENERGY↗

The next generation CdTe technology- Substrate foil based solar cells

The main objective of this project was the development of one of the most promising Photovoltaic (PV) materials CdTe into a versatile, cost effective, and high throughput technology, by demonstrating substrate devices on foil substrates using high throughput fabrication conditions. The typical CdTe cell is of the superstrate configuration where the solar cell is fabricated on a glass superstrate by the sequential deposition of a TCO, n-type heterojunction partner, p-CdTe absorber, and back contact. Large glass modules are heavy and present significant challenges during manufacturing (uniform heating, etc.). If a substrate CdTe cell could be developed (the main goal of this project) a roll-to-toll high throughput technology could be developed.

14 SOLAR ENERGY↗

Space and Terrestrial Photovoltaics: Synergy and Diversity

A historical view of the research and development in photovoltaics from the perspective of both the terrestrial and the space communities is presented from the early days through the '70s and '80s and the '90s and beyond. The synergy of both communities in the beginning and once again in the present and hopefully future are highlighted, with examples of the important features in each program. The space community which was impressed by the light-weight and reliability of photovoltaics drove much of the early development. Even up to today, nearly every satellites and other scientific space probe that has been launched has included some solar power. However, since the cost of these power systems were only a small fraction of the satellite and launch cost, the use of much of this technology for the terrestrial marketplace was not feasible. It was clear that the focus of the terrestrial community would be best served by reducing costs. This would include addressing a variety of manufacturing issues and raising the rate of production. Success in these programs and a resulting globalization of effort resulted in major strides in the reduction of PV module costs and increased production. Although, the space community derived benefit from some of these advancements, its focus was on pushing the envelope with regard to cell efficiency. The gap between theoretical efficiencies and experimental efficiencies for silicon, gallium arsenide and indium phosphide became almost non-existent. Recent work by both communities have focused on the development thin film cells of amorphous silicon, CuInSe2 and CdTe. These cells hold the promise of lower costs for the terrestrial community as well as possible flexible substrates, better radiation resistance, and higher specific power for the space community. It is predicted that future trends in both communities will be directed toward advances through the application of nanotechnology. A picture is emerging in which the space and terrestrial solar cell communities shall once again share many common goals and, in fact, companies may manufacture both space and terrestrial solar cells in III-V materials and thin film materials. Basic photovoltaics research including these current trends in nanotechnology provides a valuable service for both worlds in that fundamental understanding of cell processes is still vitally important, particularly with new materials or new cell structures. It is entirely possible that one day we might have one solar array design that will meet the criteria for success in both space and on the Earth or perhaps the Moon or Mars.

Bailey, Sheila↗

An in-depth field validation of “DUSST”: A novel low-maintenance soiling measurement device

This study presents indoor and field validation results for two versions of the “DUSST” optical soiling sensor, intended to be a low-cost and low-maintenance device for measuring photovoltaic soiling losses. Indoor testing covers irradiance calibration and temperature dependencies, which are necessary to achieve high accuracy, low uncertainty field measurements. Field testing includes an array of different environments including Saudi Arabia, California, Utah, and Colorado. DUSST versions include a configuration with a 530-nm light emitting diode (LED) (discussed in previous work) and a unit with seven white LEDs and a polycarbonate collimating optic. The new design increases light intensity fivefold and demonstrates a single linear calibration coefficient is effective to measure soiling losses as high as 75%. Field data from Utah and California demonstrate that daily soiling loss measurements and soiling rate calculations closely match both reference cell and full-size module measurements of soiling losses and soiling rates. Corrective methods employed on the Utah DUSST sensor suggest that it is possible to achieve measurement errors as low as ±0.1% at two standard deviations. Field data from both Colorado and Saudi Arabia demonstrate that LED lens soiling can occur and that further design optimizations are needed. The lesson learned from all the field deployment locations suggests directions for future design improvements.

14 SOLAR ENERGY↗

Solar Industry Update (Fall 2022) [Slides]

Each quarter, the National Renewable Energy Laboratory (NREL) conducts the Quarterly Solar Industry Update, a presentation of technical trends within the solar industry, to the solar office staff. Each presentation focuses on global and U.S. supply and demand, module and system price, investment trends and business models, and updates on U.S. government programs supporting the solar industry.

14 SOLAR ENERGY↗

Three year performance of the NTS-2 solar cell experiment

Twelve different solar cell modules from the NTS 2 experiment are functioning after more than three years in a severe trapped radiation orbit of 20,367 km (10,990 nm) circular, 63 deg inclination. The rate of maximum power degradation may be fit to a predicted rate which is based on twice the value of 1 MeV electron equivalent damage fluence calculated from the space electron model AEI 7. The photovoltaic parameters of the cells are compared to their original values to demonstrate rank order of performance.

Statler, R. L.↗

A Modular Multilevel Converter with Power Mismatch Control for Grid-Connected Photovoltaic Systems

A modular multilevel power converter configuration for grid connected photovoltaic (PV) systems is proposed. The converter configuration replaces the conventional bulky line frequency transformer with several high frequency transformers, potentially reducing the balance of systems cost of PV systems. The front-end converter for each port is a neutral-point diode clamped (NPC) multi-level dc-dc dual-active bridge (ML-DAB) which allows maximum power point tracking (MPPT). The integrated high frequency transformer provides the galvanic isolation between the PV and grid side and also steps up the low dc voltage from PV source. Following the ML-DAB stage, in each port, is a NPC inverter. N number of NPC inverters’ outputs are cascaded to attain the per-phase line-to-neutral voltage to connect directly to the distribution grid (i.e., 13.8 kV). The cascaded NPC (CNPC) inverters have the inherent advantage of using lower rated devices, smaller filters and low total harmonic distortion required for PV grid interconnection. The proposed converter system is modular, scalable, and serviceable with zero downtime with lower foot print and lower overall cost. A novel voltage balance control at each module based on power mismatch among N-ports, have been presented and verified in simulation. Analysis and simulation results are presented for the N-port converter. The converter performance has also been verified on a hardware prototype.

14 SOLAR ENERGY↗

Solar cell efficiency tables (Version 55)

Here, consolidated tables showing an extensive listing of the highest independently confirmed efficiencies for solar cells and modules are presented. Guidelines for inclusion of results into these tables are outlined, and new entries since July 2019 are reviewed.

14 SOLAR ENERGY↗